Minerals in space group 176

In geology and mineralogy, a mineral or mineral species is, broadly speaking, a solid chemical compound with a fairly well-defined chemical composition and a specific crystal structure that occurs naturally in pure form.John P. Rafferty, ed. (2011):
Minerals
'; p. 1. In the series ''Geology: Landforms, Minerals, and Rocks''. Rosen Publishing Group.

The geological definition of mineral normally excludes compounds that occur only in living organisms. However, some minerals are often biogenic (such as calcite) or are organic compounds in the sense of chemistry (such as mellite). Moreover, living organisms often synthesize inorganic minerals (such as hydroxylapatite) that also occur in rocks.

The concept of mineral is distinct from rock, which is any bulk solid geologic material that is relatively homogeneous at a large enough scale. A rock may consist of one type of mineral, or may be an aggregate of two or more different types of minerals, spacially segregated into distinct phases.

Some natural solid substances without a definite crystalline structure, such as opal or obsidian, are more properly called mineraloids.Austin Flint Rogers and Paul Francis Kerr (1942):
Optical mineralogy
', 2nd ed., p. 374. McGraw-Hill; If a chemical compound occurs naturally with different crystal structures, each structure is considered a different mineral species. Thus, for example, quartz and stishovite are two different minerals consisting of the same compound, silicon dioxide.

The International Mineralogical Association (IMA) is the generally recognized standard body for the definition and nomenclature of mineral species. , the IMA recognizes 5,863 official mineral species.

The chemical composition of a named mineral species may vary somewhat by the inclusion of small amounts of impurities. Specific varieties of a species sometimes have conventional or official names of their own. For example, amethyst is a purple variety of the mineral species quartz. Some mineral species can have variable proportions of two or more chemical elements that occupy equivalent positions in the mineral's structure; for example, the formula of mackinawite is given as , meaning , where ''x'' is a variable number between 0 and 9. Sometimes a mineral with variable composition is split into separate species, more or less arbitrarily, forming a mineral group; that is the case of the silicates , the olivine group.

Besides the essential chemical composition and crystal structure, the description of a mineral species usually includes its common physical properties such as habit, hardness, lustre, diaphaneity, colour, streak, tenacity, cleavage, fracture, parting, specific gravity, magnetism, fluorescence, radioactivity, as well as its taste or smell and its reaction to acid.

Minerals are classified by key chemical constituents; the two dominant systems are the Dana classification and the Strunz classification. Silicate minerals comprise approximately 90% of the Earth's crust. Other important mineral groups include the native elements, sulfides, oxides, halides, carbonates, sulfates, and phosphates.

Definitions

International Mineralogical Association

The International Mineralogical Association has established the following requirements for a substance to be considered a distinct mineral:E. H. Nickel & J. D. Grice (1998): "The IMA Commission on New Minerals and Mineral Names: procedures and guidelines on mineral nomenclature". ''Mineralogy and Petrology'', volume 64, issue 1, pages 237–263.

# ''It must be a naturally occurring substance formed by natural geological processes'', on Earth or other extraterrestrial bodies. This excludes compounds directly and exclusively generated by human activities (anthropogenic) or in living beings (biogenic), such as tungsten carbide, urinary calculi, calcium oxalate crystals in plant tissues, and seashells. However, substances with such origins may qualify if geological processes were involved in their genesis (as is the case of evenkite, derived from plant material; or taranakite, from bat guano; or alpersite, from mine tailings). Hypothetical substances are also excluded, even if they are predicted to occur in inaccessible natural environments like the Earth's core or other planets.
# ''It must be a solid substance in its natural occurrence.'' A major exception to this rule is native mercury: it is still classified as a mineral by the IMA, even though crystallizes only below −39 °C, because it was included before the current rules were established. Water and carbon dioxide are not considered minerals, even though they are often found as inclusions in other minerals; but water ice is considered a mineral.
# ''It must have a well-defined crystallographic structure''; or, more generally, an ordered atomic arrangement. This property implies several macroscopic physical properties, such as crystal form, hardness, and cleavage., pp. 13–14 It excludes ozokerite, limonite, obsidian and many other amorphous (non-crystalline) materials that occur in geologic contexts.
# ''It must have a fairly well defined chemical composition''. However, certain crystalline substances with a fixed structure but variable composition may be considered single mineral species. A common class of examples are solid solutions such as mackinawite, (Fe, Ni)₉S₈, which is mostly a ferrous sulfide with a significant fraction of iron atoms replaced by nickel atoms. Other examples include layered crystals with variable layer stacking, or crystals that differ only in the regular arrangement of vacancies and substitutions. On the other hand, some substances that have a continuous series of compositions, may be arbitrarily split into several minerals. The typical example is the olivine group (Mg, Fe)₂SiO₄, whose magnesium-rich and iron-rich end-members are considered separate minerals (forsterite and fayalite).

The details of these rules are somewhat controversial. For instance, there have been several recent proposals to classify amorphous substances as minerals, but they have not been accepted by the IMA.

The IMA is also reluctant to accept minerals that occur naturally only in the form of nanoparticles a few hundred atoms across, but has not defined a minimum crystal size.

Some authors require the material to be a stable or metastable solid at room temperature (25 °C). However, the IMA only requires that the substance be stable enough for its structure and composition to be well-determined. For example, it has recently recognized meridianiite (a naturally occurring hydrate of magnesium sulfate) as a mineral, even though it is formed and stable only below 2 °C.

, 5,863 mineral species are approved by the IMA. They are most commonly named after a person, followed by discovery location; names based on chemical composition or physical properties are the two other major groups of mineral name etymologies. Most names end in "-ite"; the exceptions are usually names that were well-established before the organization of mineralogy as a discipline, for example galena and diamond.

Biogenic minerals

A topic of contention among geologists and mineralogists has been the IMA's decision to exclude biogenic crystalline substances. For example, Lowenstam (1981) stated that "organisms are capable of forming a diverse array of minerals, some of which cannot be formed inorganically in the biosphere."

Skinner (2005) views all solids as potential minerals and includes biominerals in the mineral kingdom, which are those that are created by the metabolic activities of organisms. Skinner expanded the previous definition of a mineral to classify "element or compound, amorphous or crystalline, formed through '' biogeochemical '' processes," as a mineral.

Recent advances in high-resolution genetics and X-ray absorption spectroscopy are providing revelations on the biogeochemical relations between microorganisms and minerals that may shed new light on this question. For example, the IMA-commissioned "Working Group on Environmental Mineralogy and Geochemistry " deals with minerals in the hydrosphere, atmosphere, and biosphere. The group's scope includes mineral-forming microorganisms, which exist on nearly every rock, soil, and particle surface spanning the globe to depths of at least 1600 metres below the sea floor and 70 kilometres into the stratosphere (possibly entering the mesosphere).

Biogeochemical cycles have contributed to the formation of minerals for billions of years. Microorganisms can precipitate metals from solution, contributing to the formation of ore deposits. They can also catalyze the dissolution of minerals.

Prior to the International Mineralogical Association's listing, over 60 biominerals had been discovered, named, and published. These minerals (a sub-set tabulated in Lowenstam (1981)) are considered minerals proper according to Skinner's (2005) definition. These biominerals are not listed in the International Mineral Association official list of mineral names; however, many of these biomineral representatives are distributed amongst the 78 mineral classes listed in the Dana classification scheme.

Skinner's (2005) definition of a mineral takes this matter into account by stating that a mineral can be crystalline or amorphous. Although biominerals are not the most common form of minerals, they help to define the limits of what constitutes a mineral proper. Nickel's (1995) formal definition explicitly mentioned crystallinity as a key to defining a substance as a mineral. A 2011 article defined icosahedrite, an aluminium-iron-copper alloy, as mineral; named for its unique natural icosahedral symmetry, it is a quasicrystal. Unlike a true crystal, quasicrystals are ordered but not periodic.

Rocks, ores, and gems

A rock is an aggregate of one or more minerals, pp. 15–16 or mineraloids. Some rocks, such as limestone or quartzite, are composed primarily of one mineral – calcite or aragonite in the case of limestone, and quartz in the latter case. Other rocks can be defined by relative abundances of key (essential) minerals; a granite is defined by proportions of quartz, alkali feldspar, and plagioclase feldspar. The other minerals in the rock are termed accessory minerals, and do not greatly affect the bulk composition of the rock. Rocks can also be composed entirely of non-mineral material; coal is a sedimentary rock composed primarily of organically derived carbon.

In rocks, some mineral species and groups are much more abundant than others; these are termed the rock-forming minerals. The major examples of these are quartz, the feldspars, the micas, the amphiboles, the pyroxenes, the olivines, and calcite; except for the last one, all of these minerals are silicates. Overall, around 150 minerals are considered particularly important, whether in terms of their abundance or aesthetic value in terms of collecting., p. 14

Commercially valuable minerals and rocks, other than gemstones, metal ores, or mineral fuels, are referred to as industrial minerals. For example, muscovite, a white mica, can be used for windows (sometimes referred to as isinglass), as a filler, or as an insulator.

Ores are minerals that have a high concentration of a certain element, typically a metal. Examples are cinnabar (HgS), an ore of mercury; sphalerite (ZnS), an ore of zinc; cassiterite (SnO₂), an ore of tin; and colemanite, an ore of boron.

Gems are minerals with an ornamental value, and are distinguished from non-gems by their beauty, durability, and usually, rarity. There are about 20 mineral species that qualify as gem minerals, which constitute about 35 of the most common gemstones. Gem minerals are often present in several varieties, and so one mineral can account for several different gemstones; for example, ruby and sapphire are both corundum, Al₂O₃., pp. 14–15

Etymology

The first known use of the word "mineral" in the English language ( Middle English) was the 15th century. The word came from , from , mine, ore.mineral
entry in the Merriam-Webster online dictionary. Accessed on 2020-08-28.

The word "species" comes from the Latin ''species'', "a particular sort, kind, or type with distinct look, or appearance".

Chemistry

The abundance and diversity of minerals is controlled directly by their chemistry, in turn dependent on elemental abundances in the Earth. The majority of minerals observed are derived from the Earth's crust. Eight elements account for most of the key components of minerals, due to their abundance in the crust. These eight elements, summing to over 98% of the crust by weight, are, in order of decreasing abundance: oxygen, silicon, aluminium, iron, magnesium, calcium, sodium and potassium. Oxygen and silicon are by far the two most important – oxygen composes 47% of the crust by weight, and silicon accounts for 28%., pp. 4–7

The minerals that form are those that are most stable at the temperature and pressure of formation, within the limits imposed by the bulk chemistry of the parent body. For example, in most igneous rocks, the aluminium and alkali metals (sodium and potassium) that are present are primarily found in combination with oxygen, silicon, and calcium as feldspar minerals. However, if the rock is unusually rich in alkali metals, there will not be enough aluminium to combine with all the sodium as feldspar, and the excess sodium will form sodic amphiboles such as riebeckite. If the aluminium abundance is unusually high, the excess aluminium will form muscovite or other aluminium-rich minerals. If silicon is deficient, part of the feldspar will be replaced by feldspathoid minerals. Precise predictions of which minerals will be present in a rock of a particular composition formed at a particular temperature and pressure requires complex thermodynamic calculations. However, approximate estimates may be made using relatively simple rules of thumb, such as the CIPW norm, which gives reasonable estimates for volcanic rock formed from dry magma.

The chemical composition may vary between end member species of a solid solution series. For example, the plagioclase feldspars comprise a continuous series from sodium-rich end member albite (NaAlSi₃O₈) to calcium-rich anorthite (CaAl₂Si₂O₈) with four recognized intermediate varieties between them (given in order from sodium- to calcium-rich): oligoclase, andesine, labradorite, and bytownite. Other examples of series include the olivine series of magnesium-rich forsterite and iron-rich fayalite, and the wolframite series of manganese-rich hübnerite and iron-rich ferberite.

Chemical substitution and coordination polyhedra explain this common feature of minerals. In nature, minerals are not pure substances, and are contaminated by whatever other elements are present in the given chemical system. As a result, it is possible for one element to be substituted for another. Chemical substitution will occur between ions of a similar size and charge; for example, K⁺ will not substitute for Si⁴⁺ because of chemical and structural incompatibilities caused by a big difference in size and charge. A common example of chemical substitution is that of Si⁴⁺ by Al³⁺, which are close in charge, size, and abundance in the crust. In the example of plagioclase, there are three cases of substitution. Feldspars are all framework silicates, which have a silicon-oxygen ratio of 2:1, and the space for other elements is given by the substitution of Si⁴⁺ by Al³⁺ to give a base unit of lSi₃O₈sup>−; without the substitution, the formula would be charge-balanced as SiO₂, giving quartz. The significance of this structural property will be explained further by coordination polyhedra. The second substitution occurs between Na⁺ and Ca²⁺; however, the difference in charge has to accounted for by making a second substitution of Si⁴⁺ by Al³⁺.

Coordination polyhedra are geometric representations of how a cation is surrounded by an anion. In mineralogy, coordination polyhedra are usually considered in terms of oxygen, due its abundance in the crust. The base unit of silicate minerals is the silica tetrahedron – one Si⁴⁺ surrounded by four O²⁻. An alternate way of describing the coordination of the silicate is by a number: in the case of the silica tetrahedron, the silicon is said to have a coordination number of 4. Various cations have a specific range of possible coordination numbers; for silicon, it is almost always 4, except for very high-pressure minerals where the compound is compressed such that silicon is in six-fold (octahedral) coordination with oxygen. Bigger cations have a bigger coordination numbers because of the increase in relative size as compared to oxygen (the last orbital subshell of heavier atoms is different too). Changes in coordination numbers leads to physical and mineralogical differences; for example, at high pressure, such as in the mantle, many minerals, especially silicates such as olivine and garnet, will change to a perovskite structure, where silicon is in octahedral coordination. Other examples are the aluminosilicates kyanite, andalusite, and sillimanite (polymorphs, since they share the formula Al₂SiO₅), which differ by the coordination number of the Al³⁺; these minerals transition from one another as a response to changes in pressure and temperature. In the case of silicate materials, the substitution of Si⁴⁺ by Al³⁺ allows for a variety of minerals because of the need to balance charges.

Because the eight most common elements make up over 98% of the Earth's crust, the small quantities of the other elements that are typically present are substituted into the common rock-forming minerals. The distinctive minerals of most elements are quite rare, being found only where these elements have been concentrated by geological processes, such as hydrothermal circulation, to the point where they can no longer be accommodated in common minerals.

Changes in temperature and pressure and composition alter the mineralogy of a rock sample. Changes in composition can be caused by processes such as weathering or metasomatism ( hydrothermal alteration). Changes in temperature and pressure occur when the host rock undergoes tectonic or magmatic movement into differing physical regimes. Changes in thermodynamic conditions make it favourable for mineral assemblages to react with each other to produce new minerals; as such, it is possible for two rocks to have an identical or a very similar bulk rock chemistry without having a similar mineralogy. This process of mineralogical alteration is related to the rock cycle. An example of a series of mineral reactions is illustrated as follows., p. 549

Orthoclase feldspar (KAlSi₃O₈) is a mineral commonly found in granite, a plutonic igneous rock. When exposed to weathering, it reacts to form kaolinite (Al₂Si₂O₅(OH)₄, a sedimentary mineral, and silicic acid):

:2 KAlSi₃O₈ + 5 H₂O + 2 H⁺ → Al₂Si₂O₅(OH)₄ + 4 H₂SiO₃ + 2 K⁺

Under low-grade metamorphic conditions, kaolinite reacts with quartz to form pyrophyllite (Al₂Si₄O₁₀(OH)₂):

:Al₂Si₂O₅(OH)₄ + SiO₂ → Al₂Si₄O₁₀(OH)₂ + H₂O

As metamorphic grade increases, the pyrophyllite reacts to form kyanite and quartz:

:Al₂Si₄O₁₀(OH)₂ → Al₂SiO₅ + 3 SiO₂ + H₂O

Alternatively, a mineral may change its crystal structure as a consequence of changes in temperature and pressure without reacting. For example, quartz will change into a variety of its SiO₂ polymorphs, such as tridymite and cristobalite at high temperatures, and coesite at high pressures.

Physical properties

Classifying minerals ranges from simple to difficult. A mineral can be identified by several physical properties, some of them being sufficient for full identification without equivocation. In other cases, minerals can only be classified by more complex optical, chemical or X-ray diffraction analysis; these methods, however, can be costly and time-consuming. Physical properties applied for classification include crystal structure and habit, hardness, lustre, diaphaneity, colour, streak, cleavage and fracture, and specific gravity. Other less general tests include fluorescence, phosphorescence, magnetism, radioactivity, tenacity (response to mechanical induced changes of shape or form), piezoelectricity and reactivity to dilute acids.

Crystal structure and habit

Crystal structure results from the orderly geometric spatial arrangement of atoms in the internal structure of a mineral. This crystal structure is based on regular internal atomic or ionic arrangement that is often expressed in the geometric form that the crystal takes. Even when the mineral grains are too small to see or are irregularly shaped, the underlying crystal structure is always periodic and can be determined by X-ray diffraction. Minerals are typically described by their symmetry content. Crystals are restricted to 32 point groups, which differ by their symmetry. These groups are classified in turn into more broad categories, the most encompassing of these being the six crystal families., pp. 69–80

These families can be described by the relative lengths of the three crystallographic axes, and the angles between them; these relationships correspond to the symmetry operations that define the narrower point groups. They are summarized below; a, b, and c represent the axes, and α, β, γ represent the angle opposite the respective crystallographic axis (e.g. α is the angle opposite the a-axis, viz. the angle between the b and c axes):

The hexagonal crystal family is also split into two crystal ''systems'' – the trigonal, which has a three-fold axis of symmetry, and the hexagonal, which has a six-fold axis of symmetry.

Chemistry and crystal structure together define a mineral. With a restriction to 32 point groups, minerals of different chemistry may have identical crystal structure. For example, halite (NaCl), galena (PbS), and periclase (MgO) all belong to the hexaoctahedral point group (isometric family), as they have a similar stoichiometry between their different constituent elements. In contrast, polymorphs are groupings of minerals that share a chemical formula but have a different structure. For example, pyrite and marcasite, both iron sulfides, have the formula FeS₂; however, the former is isometric while the latter is orthorhombic. This polymorphism extends to other sulfides with the generic AX₂ formula; these two groups are collectively known as the pyrite and marcasite groups.

Polymorphism can extend beyond pure symmetry content. The aluminosilicates are a group of three minerals – kyanite, andalusite, and sillimanite – which share the chemical formula Al₂SiO₅. Kyanite is triclinic, while andalusite and sillimanite are both orthorhombic and belong to the dipyramidal point group. These differences arise corresponding to how aluminium is coordinated within the crystal structure. In all minerals, one aluminium ion is always in six-fold coordination with oxygen. Silicon, as a general rule, is in four-fold coordination in all minerals; an exception is a case like stishovite (SiO₂, an ultra-high pressure quartz polymorph with rutile structure). In kyanite, the second aluminium is in six-fold coordination; its chemical formula can be expressed as Al ^{/sup>Al /sup>SiO₅, to reflect its crystal structure. Andalusite has the second aluminium in five-fold coordination (Al /sup>Al /sup>SiO₅) and sillimanite has it in four-fold coordination (Al /sup>Al /sup>SiO₅).}

Differences in crystal structure and chemistry greatly influence other physical properties of the mineral. The carbon allotropes diamond and graphite have vastly different properties; diamond is the hardest natural substance, has an adamantine lustre, and belongs to the isometric crystal family, whereas graphite is very soft, has a greasy lustre, and crystallises in the hexagonal family. This difference is accounted for by differences in bonding. In diamond, the carbons are in sp³ hybrid orbitals, which means they form a framework where each carbon is covalently bonded to four neighbours in a tetrahedral fashion; on the other hand, graphite is composed of sheets of carbons in sp² hybrid orbitals, where each carbon is bonded covalently to only three others. These sheets are held together by much weaker van der Waals forces, and this discrepancy translates to large macroscopic differences.

Twinning is the intergrowth of two or more crystals of a single mineral species. The geometry of the twinning is controlled by the mineral's symmetry. As a result, there are several types of twins, including contact twins, reticulated twins, geniculated twins, penetration twins, cyclic twins, and polysynthetic twins. Contact, or simple twins, consist of two crystals joined at a plane; this type of twinning is common in spinel. Reticulated twins, common in rutile, are interlocking crystals resembling netting. Geniculated twins have a bend in the middle that is caused by start of the twin. Penetration twins consist of two single crystals that have grown into each other; examples of this twinning include cross-shaped staurolite twins and Carlsbad twinning in orthoclase. Cyclic twins are caused by repeated twinning around a rotation axis. This type of twinning occurs around three, four, five, six, or eight-fold axes, and the corresponding patterns are called threelings, fourlings, fivelings, sixlings, and eightlings. Sixlings are common in aragonite. Polysynthetic twins are similar to cyclic twins through the presence of repetitive twinning; however, instead of occurring around a rotational axis, polysynthetic twinning occurs along parallel planes, usually on a microscopic scale., pp. 41–43

Crystal habit refers to the overall shape of crystal. Several terms are used to describe this property. Common habits include acicular, which describes needlelike crystals as in natrolite, bladed, dendritic (tree-pattern, common in native copper), equant, which is typical of garnet, prismatic (elongated in one direction), and tabular, which differs from bladed habit in that the former is platy whereas the latter has a defined elongation. Related to crystal form, the quality of crystal faces is diagnostic of some minerals, especially with a petrographic microscope. Euhedral crystals have a defined external shape, while anhedral crystals do not; those intermediate forms are termed subhedral.

Hardness

The hardness of a mineral defines how much it can resist scratching. This physical property is controlled by the chemical composition and crystalline structure of a mineral. A mineral's hardness is not necessarily constant for all sides, which is a function of its structure; crystallographic weakness renders some directions softer than others., pp. 28–29 An example of this property exists in kyanite, which has a Mohs hardness of 5 parallel to 01but 7 parallel to 00

The most common scale of measurement is the ordinal Mohs hardness scale. Defined by ten indicators, a mineral with a higher index scratches those below it. The scale ranges from talc, a phyllosilicate, to diamond, a carbon polymorph that is the hardest natural material. The scale is provided below:

Other scales include these;
* Shore's hardness test, which measures the endurance of a mineral based on the indentation of a spring-loaded contraption.
*The Rockwell scale
*The Vickers hardness test
*The Brinell scale

Lustre and diaphaneity

Lustre indicates how light reflects from the mineral's surface, with regards to its quality and intensity. There are numerous qualitative terms used to describe this property, which are split into metallic and non-metallic categories. Metallic and sub-metallic minerals have high reflectivity like metal; examples of minerals with this lustre are galena and pyrite. Non-metallic lustres include: adamantine, such as in diamond; vitreous, which is a glassy lustre very common in silicate minerals; pearly, such as in talc and apophyllite; resinous, such as members of the garnet group; silky which is common in fibrous minerals such as asbestiform chrysotile.Dyar and Darby, pp. 26–28

The diaphaneity of a mineral describes the ability of light to pass through it. Transparent minerals do not diminish the intensity of light passing through them. An example of a transparent mineral is muscovite (potassium mica); some varieties are sufficiently clear to have been used for windows. Translucent minerals allow some light to pass, but less than those that are transparent. Jadeite and nephrite (mineral forms of jade are examples of minerals with this property). Minerals that do not allow light to pass are called opaque., p. 25

The diaphaneity of a mineral depends on the thickness of the sample. When a mineral is sufficiently thin (e.g., in a thin section for petrography), it may become transparent even if that property is not seen in a hand sample. In contrast, some minerals, such as hematite or pyrite, are opaque even in thin-section.

Colour and streak

Colour is the most obvious property of a mineral, but it is often non-diagnostic. It is caused by electromagnetic radiation interacting with electrons (except in the case of incandescence, which does not apply to minerals)., pp. 131–44 Two broad classes of elements (idiochromatic and allochromatic) are defined with regards to their contribution to a mineral's colour: Idiochromatic elements are essential to a mineral's composition; their contribution to a mineral's colour is diagnostic., p. 72, p. 24 Examples of such minerals are malachite (green) and azurite (blue). In contrast, allochromatic elements in minerals are present in trace amounts as impurities. An example of such a mineral would be the ruby and sapphire varieties of the mineral corundum.
The colours of pseudochromatic minerals are the result of interference of light waves. Examples include labradorite and bornite.

In addition to simple body colour, minerals can have various other distinctive optical properties, such as play of colours, asterism, chatoyancy, iridescence, tarnish, and pleochroism. Several of these properties involve variability in colour. Play of colour, such as in opal, results in the sample reflecting different colours as it is turned, while pleochroism describes the change in colour as light passes through a mineral in a different orientation. Iridescence is a variety of the play of colours where light scatters off a coating on the surface of crystal, cleavage planes, or off layers having minor gradations in chemistry., pp. 24–26 In contrast, the play of colours in opal is caused by light refracting from ordered microscopic silica spheres within its physical structure., p. 73 Chatoyancy ("cat's eye") is the wavy banding of colour that is observed as the sample is rotated; asterism, a variety of chatoyancy, gives the appearance of a star on the mineral grain. The latter property is particularly common in gem-quality corundum.

The streak of a mineral refers to the colour of a mineral in powdered form, which may or may not be identical to its body colour. The most common way of testing this property is done with a streak plate, which is made out of porcelain and coloured either white or black. The streak of a mineral is independent of trace elements or any weathering surface. A common example of this property is illustrated with hematite, which is coloured black, silver, or red in hand sample, but has a cherry-red to reddish-brown streak. Streak is more often distinctive for metallic minerals, in contrast to non-metallic minerals whose body colour is created by allochromatic elements. Streak testing is constrained by the hardness of the mineral, as those harder than 7 powder the ''streak plate'' instead.

Cleavage, parting, fracture, and tenacity

By definition, minerals have a characteristic atomic arrangement. Weakness in this crystalline structure causes planes of weakness, and the breakage of a mineral along such planes is termed cleavage. The quality of cleavage can be described based on how cleanly and easily the mineral breaks; common descriptors, in order of decreasing quality, are "perfect", "good", "distinct", and "poor". In particularly transparent minerals, or in thin-section, cleavage can be seen as a series of parallel lines marking the planar surfaces when viewed from the side. Cleavage is not a universal property among minerals; for example, quartz, consisting of extensively interconnected silica tetrahedra, does not have a crystallographic weakness which would allow it to cleave. In contrast, micas, which have perfect basal cleavage, consist of sheets of silica tetrahedra which are very weakly held together., pp. 29–30

As cleavage is a function of crystallography, there are a variety of cleavage types. Cleavage occurs typically in either one, two, three, four, or six directions. Basal cleavage in one direction is a distinctive property of the micas. Two-directional cleavage is described as prismatic, and occurs in minerals such as the amphiboles and pyroxenes. Minerals such as galena or halite have cubic (or isometric) cleavage in three directions, at 90°; when three directions of cleavage are present, but not at 90°, such as in calcite or rhodochrosite, it is termed rhombohedral cleavage. Octahedral cleavage (four directions) is present in fluorite and diamond, and sphalerite has six-directional dodecahedral cleavage.

Minerals with many cleavages might not break equally well in all of the directions; for example, calcite has good cleavage in three directions, but gypsum has perfect cleavage in one direction, and poor cleavage in two other directions. Angles between cleavage planes vary between minerals. For example, as the amphiboles are double-chain silicates and the pyroxenes are single-chain silicates, the angle between their cleavage planes is different. The pyroxenes cleave in two directions at approximately 90°, whereas the amphiboles distinctively cleave in two directions separated by approximately 120° and 60°. The cleavage angles can be measured with a contact goniometer, which is similar to a protractor.

Parting, sometimes called "false cleavage", is similar in appearance to cleavage but is instead produced by structural defects in the mineral, as opposed to systematic weakness. Parting varies from crystal to crystal of a mineral, whereas all crystals of a given mineral will cleave if the atomic structure allows for that property. In general, parting is caused by some stress applied to a crystal. The sources of the stresses include deformation (e.g. an increase in pressure), exsolution, or twinning. Minerals that often display parting include the pyroxenes, hematite, magnetite, and corundum., pp. 39–40

When a mineral is broken in a direction that does not correspond to a plane of cleavage, it is termed to have been fractured. There are several types of uneven fracture. The classic example is conchoidal fracture, like that of quartz; rounded surfaces are created, which are marked by smooth curved lines. This type of fracture occurs only in very homogeneous minerals. Other types of fracture are fibrous, splintery, and hackly. The latter describes a break along a rough, jagged surface; an example of this property is found in native copper.

Tenacity is related to both cleavage and fracture. Whereas fracture and cleavage describes the surfaces that are created when a mineral is broken, tenacity describes how resistant a mineral is to such breaking. Minerals can be described as brittle, ductile, malleable, sectile, flexible, or elastic.

Specific gravity

Specific gravity numerically describes the density of a mineral. The dimensions of density are mass divided by volume with units: kg/m³ or g/cm³. Specific gravity is defined as the density of the mineral divided by the density of water at 4 °C and thus is a dimensionless quantity, identical in all unit systems. It can be measured as the quotient of the mass of the sample and difference between the weight of the sample in air and its corresponding weight in water. Among most minerals, this property is not diagnostic. Rock forming minerals – typically silicates or occasionally carbonates – have a specific gravity of 2.5–3.5., pp. 43–44

High specific gravity is a diagnostic property of a mineral. A variation in chemistry (and consequently, mineral class) correlates to a change in specific gravity. Among more common minerals, oxides and sulfides tend to have a higher specific gravity as they include elements with higher atomic mass. A generalization is that minerals with metallic or adamantine lustre tend to have higher specific gravities than those having a non-metallic to dull lustre. For example, hematite, Fe₂O₃, has a specific gravity of 5.26 while galena, PbS, has a specific gravity of 7.2–7.6, which is a result of their high iron and lead content, respectively. A very high specific gravity is characteristic of native metals; for example, kamacite, an iron-nickel alloy common in iron meteorites has a specific gravity of 7.9, and gold has an observed specific gravity between 15 and 19.3.

Other properties

Other properties can be used to diagnose minerals. These are less general, and apply to specific minerals.

Dropping dilute acid (often 10% HCl) onto a mineral aids in distinguishing carbonates from other mineral classes. The acid reacts with the carbonate ( O₃sup>2−) group, which causes the affected area to effervesce, giving off carbon dioxide gas. This test can be further expanded to test the mineral in its original crystal form or powdered form. An example of this test is done when distinguishing calcite from dolomite, especially within the rocks ( limestone and dolomite respectively). Calcite immediately effervesces in acid, whereas acid must be applied to powdered dolomite (often to a scratched surface in a rock), for it to effervesce., pp. 44–45 Zeolite minerals will not effervesce in acid; instead, they become frosted after 5–10 minutes, and if left in acid for a day, they dissolve or become a silica gel.

Magnetism is a very conspicuous property of a few minerals. Among common minerals, magnetite exhibits this property strongly, and magnetism is also present, albeit not as strongly, in pyrrhotite and ilmenite. Some minerals exhibit electrical properties – for example, quartz is piezoelectric – but electrical properties are rarely used as diagnostic criteria for minerals because of incomplete data and natural variation.

Minerals can also be tested for taste or smell. Halite, NaCl, is table salt; its potassium-bearing counterpart, sylvite, has a pronounced bitter taste. Sulfides have a characteristic smell, especially as samples are fractured, reacting, or powdered.

Radioactivity is a rare property found in minerals containing radioactive elements. The radioactive elements could be a defining constituent, such as uranium in uraninite, autunite, and carnotite, or present as trace impurities, as in zircon. The decay of a radioactive element damages the mineral crystal structure rendering it locally amorphous (metamict state); the optical result, termed a ''radioactive halo'' or '' pleochroic halo'', is observable with various techniques, such as thin-section petrography.

Classification

Earliest classifications

In 315 BCE, Theophrastus presented his classification of minerals in his treatise ''On Stones''. His classification was influenced by the ideas of his teachers Plato and Aristotle. Theophrastus classified minerals as stones, earths or metals.

Georgius Agricola's classification of minerals in his book ''De Natura Fossilium'', published in 1546, divided minerals into three types of substance: simple (stones, earths, metals, and congealed juices), compound (intimately mixed) and composite (separable).

Linnaeus

An early classification of minerals was given by Carl Linnaeus in his seminal 1735 book ''Systema Naturae''. He divided the natural world into three kingdoms – plants, animals, and minerals – and classified each with the same hierarchy. In descending order, these were Phylum, Class, Order, Family, Tribe, Genus, and Species.

However, while his system was justified by Charles Darwin's theory of species formation and has been largely adopted and expanded by biologists in the following centuries (who still use his Greek- and Latin-based binomial naming scheme), it had little success among mineralogists (although each distinct mineral is still formally referred to as a mineral ''species'').

Modern classification

Minerals are classified by variety, species, series and group, in order of increasing generality. The basic level of definition is that of mineral species, each of which is distinguished from the others by unique chemical and physical properties. For example, quartz is defined by its formula, SiO₂, and a specific crystalline structure that distinguishes it from other minerals with the same chemical formula (termed polymorphs). When there exists a range of composition between two minerals species, a mineral series is defined. For example, the biotite series is represented by variable amounts of the endmembers phlogopite, siderophyllite, annite, and eastonite. In contrast, a mineral group is a grouping of mineral species with some common chemical properties that share a crystal structure. The pyroxene group has a common formula of XY(Si,Al)₂O₆, where X and Y are both cations, with X typically bigger than Y; the pyroxenes are single-chain silicates that crystallize in either the orthorhombic or monoclinic crystal systems. Finally, a mineral variety is a specific type of mineral species that differs by some physical characteristic, such as colour or crystal habit. An example is amethyst, which is a purple variety of quartz., pp. 20–22

Two common classifications, Dana and Strunz, are used for minerals; both rely on composition, specifically with regards to important chemical groups, and structure. James Dwight Dana, a leading geologist of his time, first published his ''System of Mineralogy'' in 1837; as of 1997, it is in its eighth edition. The Dana classification assigns a four-part number to a mineral species. Its class number is based on important compositional groups; the type gives the ratio of cations to anions in the mineral, and the last two numbers group minerals by structural similarity within a given type or class. The less commonly used Strunz classification, named for German mineralogist Karl Hugo Strunz, is based on the Dana system, but combines both chemical and structural criteria, the latter with regards to distribution of chemical bonds.

As the composition of the Earth's crust is dominated by silicon and oxygen, silicates are by far the most important class of minerals in terms of rock formation and diversity. However, non-silicate minerals are of great economic importance, especially as ores., p. 681 Non-silicate minerals are subdivided into several other classes by their dominant chemistry, which includes native elements, sulfides, halides, oxides and hydroxides, carbonates and nitrates, borates, sulfates, phosphates, and organic compounds. Most non-silicate mineral species are rare (constituting in total 8% of the Earth's crust), although some are relatively common, such as calcite, pyrite, magnetite, and hematite. There are two major structural styles observed in non-silicates: close-packing and silicate-like linked tetrahedra. Close-packed structures are a way to densely pack atoms while minimizing interstitial space. Hexagonal close-packing involves stacking layers where every other layer is the same ("ababab"), whereas cubic close-packing involves stacking groups of three layers ("abcabcabc"). Analogues to linked silica tetrahedra include ( sulfate), ( phosphate), ( arsenate), and ( vanadate) structures. The non-silicates have great economic importance, as they concentrate elements more than the silicate minerals do.

The largest grouping of minerals by far are the silicates; most rocks are composed of greater than 95% silicate minerals, and over 90% of the Earth's crust is composed of these minerals., p. 104 The two main constituents of silicates are silicon and oxygen, which are the two most abundant elements in the Earth's crust. Other common elements in silicate minerals correspond to other common elements in the Earth's crust, such as aluminium, magnesium, iron, calcium, sodium, and potassium. Some important rock-forming silicates include the feldspars, quartz, olivines, pyroxenes, amphiboles, garnets, and micas.

Silicates

The base unit of a silicate mineral is the iO₄sup>4− tetrahedron. In the vast majority of cases, silicon is in four-fold or tetrahedral coordination with oxygen. In very high-pressure situations, silicon will be in six-fold or octahedral coordination, such as in the perovskite structure or the quartz polymorph stishovite (SiO₂). In the latter case, the mineral no longer has a silicate structure, but that of rutile (TiO₂), and its associated group, which are simple oxides. These silica tetrahedra are then polymerized to some degree to create various structures, such as one-dimensional chains, two-dimensional sheets, and three-dimensional frameworks. The basic silicate mineral where no polymerization of the tetrahedra has occurred requires other elements to balance out the base 4- charge. In other silicate structures, different combinations of elements are required to balance out the resultant negative charge. It is common for the Si⁴⁺ to be substituted by Al³⁺ because of similarity in ionic radius and charge; in those cases, the lO₄sup>5− tetrahedra form the same structures as do the unsubstituted tetrahedra, but their charge-balancing requirements are different.

The degree of polymerization can be described by both the structure formed and how many tetrahedral corners (or coordinating oxygens) are shared (for aluminium and silicon in tetrahedral sites):
;Orthosilicates (or nesosilicates): Have no linking of polyhedra, thus tetrahedra share no corners.
;Disilicates (or sorosilicates): Have two tetrahedra sharing one oxygen atom.
;Inosilicates are chain silicates: Single-chain silicates have two shared corners, whereas double-chain silicates have two or three shared corners.
;Phyllosilicates: Have a sheet structure which requires three shared oxygens; in the case of double-chain silicates, some tetrahedra must share two corners instead of three as otherwise a sheet structure would result.
;Framework silicates (or tectosilicates): Have tetrahedra that share all four corners.
;Ring silicates (or cyclosilicates): Only need tetrahedra to share two corners to form the cyclical structure.

The silicate subclasses are described below in order of decreasing polymerization.

Tectosilicates

Tectosilicates, also known as framework silicates, have the highest degree of polymerization. With all corners of a tetrahedra shared, the silicon:oxygen ratio becomes 1:2. Examples are quartz, the feldspars, feldspathoids, and the zeolites. Framework silicates tend to be particularly chemically stable as a result of strong covalent bonds.

Forming 12% of the Earth's crust, quartz (SiO₂) is the most abundant mineral species. It is characterized by its high chemical and physical resistivity. Quartz has several polymorphs, including tridymite and cristobalite at high temperatures, high-pressure coesite, and ultra-high pressure stishovite. The latter mineral can only be formed on Earth by meteorite impacts, and its structure has been compressed so much that it has changed from a silicate structure to that of rutile (TiO₂). The silica polymorph that is most stable at the Earth's surface is α-quartz. Its counterpart, β-quartz, is present only at high temperatures and pressures (changes to α-quartz below 573 °C at 1 bar). These two polymorphs differ by a "kinking" of bonds; this change in structure gives β-quartz greater symmetry than α-quartz, and they are thus also called high quartz (β) and low quartz (α).

Feldspars are the most abundant group in the Earth's crust, at about 50%. In the feldspars, Al³⁺ substitutes for Si⁴⁺, which creates a charge imbalance that must be accounted for by the addition of cations. The base structure becomes either lSi₃O₈sup>− or l₂Si₂O₈sup>2− There are 22 mineral species of feldspars, subdivided into two major subgroups – alkali and plagioclase – and two less common groups – celsian and banalsite. The alkali feldspars are most commonly in a series between potassium-rich orthoclase and sodium-rich albite; in the case of plagioclase, the most common series ranges from albite to calcium-rich anorthite. Crystal twinning is common in feldspars, especially polysynthetic twins in plagioclase and Carlsbad twins in alkali feldspars. If the latter subgroup cools slowly from a melt, it forms exsolution lamellae because the two components – orthoclase and albite – are unstable in solid solution. Exsolution can be on a scale from microscopic to readily observable in hand-sample; perthitic texture forms when Na-rich feldspar exsolve in a K-rich host. The opposite texture (antiperthitic), where K-rich feldspar exsolves in a Na-rich host, is very rare.

Feldspathoids are structurally similar to feldspar, but differ in that they form in Si-deficient conditions, which allows for further substitution by Al³⁺. As a result, feldspathoids are almost never found in association with quartz. A common example of a feldspathoid is nepheline ((Na, K)AlSiO₄); compared to alkali feldspar, nepheline has an Al₂O₃:SiO₂ ratio of 1:2, as opposed to 1:6 in alkali feldspar. Zeolites often have distinctive crystal habits, occurring in needles, plates, or blocky masses. They form in the presence of water at low temperatures and pressures, and have channels and voids in their structure. Zeolites have several industrial applications, especially in waste water treatment.

Phyllosilicates

Phyllosilicates consist of sheets of polymerized tetrahedra. They are bound at three oxygen sites, which gives a characteristic silicon:oxygen ratio of 2:5. Important examples include the mica, chlorite, and the kaolinite-serpentine groups. In addition to the tetrahedra, phyllosilicates have a sheet of octahedra (elements in six-fold coordination by oxygen) that balance out the basic tetrahedra, which have a negative charge (e.g. i₄O₁₀sup>4−) These tetrahedra (T) and octahedra (O) sheets are stacked in a variety of combinations to create phyllosilicate layers. Within an octahedral sheet, there are three octahedral sites in a unit structure; however, not all of the sites may be occupied. In that case, the mineral is termed dioctahedral, whereas in other case it is termed trioctahedral. The layers are weakly bound by van der Waals forces, hydrogen bonds, or sparse ionic bonds, which causes a crystallographic weakness, in turn leading to a prominent basal cleavage among the phyllosilicates.

The kaolinite-serpentine group consists of T-O stacks (the 1:1 clay minerals); their hardness ranges from 2 to 4, as the sheets are held by hydrogen bonds. The 2:1 clay minerals (pyrophyllite-talc) consist of T-O-T stacks, but they are softer (hardness from 1 to 2), as they are instead held together by van der Waals forces. These two groups of minerals are subgrouped by octahedral occupation; specifically, kaolinite and pyrophyllite are dioctahedral whereas serpentine and talc trioctahedral.

Micas are also T-O-T-stacked phyllosilicates, but differ from the other T-O-T and T-O-stacked subclass members in that they incorporate aluminium into the tetrahedral sheets (clay minerals have Al³⁺ in octahedral sites). Common examples of micas are muscovite, and the biotite series. Mica T-O-T layers are bonded together by metal ions, giving them a greater hardness than other phyllosilicate minerals, though they retain perfect basal cleavage. The chlorite group is related to mica group, but a brucite-like (Mg(OH)₂) layer between the T-O-T stacks.

Because of their chemical structure, phyllosilicates typically have flexible, elastic, transparent layers that are electrical insulators and can be split into very thin flakes. Micas can be used in electronics as insulators, in construction, as optical filler, or even cosmetics. Chrysotile, a species of serpentine, is the most common mineral species in industrial asbestos, as it is less dangerous in terms of health than the amphibole asbestos.

Inosilicates

Inosilicates consist of tetrahedra repeatedly bonded in chains. These chains can be single, where a tetrahedron is bound to two others to form a continuous chain; alternatively, two chains can be merged to create double-chain silicates. Single-chain silicates have a silicon:oxygen ratio of 1:3 (e.g. i₂O₆sup>4−), whereas the double-chain variety has a ratio of 4:11, e.g. i₈O₂₂sup>12−. Inosilicates contain two important rock-forming mineral groups; single-chain silicates are most commonly pyroxenes, while double-chain silicates are often amphiboles. Higher-order chains exist (e.g. three-member, four-member, five-member chains, etc.) but they are rare.

The pyroxene group consists of 21 mineral species. Pyroxenes have a general structure formula of XY(Si₂O₆), where X is an octahedral site, while Y can vary in coordination number from six to eight. Most varieties of pyroxene consist of permutations of Ca²⁺, Fe²⁺ and Mg²⁺ to balance the negative charge on the backbone. Pyroxenes are common in the Earth's crust (about 10%) and are a key constituent of mafic igneous rocks.

Amphiboles have great variability in chemistry, described variously as a "mineralogical garbage can" or a "mineralogical shark swimming a sea of elements". The backbone of the amphiboles is the i₈O₂₂sup>12−; it is balanced by cations in three possible positions, although the third position is not always used, and one element can occupy both remaining ones. Finally, the amphiboles are usually hydrated, that is, they have a hydroxyl group ( Hsup>−), although it can be replaced by a fluoride, a chloride, or an oxide ion. Because of the variable chemistry, there are over 80 species of amphibole, although variations, as in the pyroxenes, most commonly involve mixtures of Ca²⁺, Fe²⁺ and Mg²⁺., p. 112 Several amphibole mineral species can have an asbestiform crystal habit. These asbestos minerals form long, thin, flexible, and strong fibres, which are electrical insulators, chemically inert and heat-resistant; as such, they have several applications, especially in construction materials. However, asbestos are known carcinogens, and cause various other illnesses, such as asbestosis; amphibole asbestos ( anthophyllite, tremolite, actinolite, grunerite, and riebeckite) are considered more dangerous than chrysotile serpentine asbestos.

Cyclosilicates

Cyclosilicates, or ring silicates, have a ratio of silicon to oxygen of 1:3. Six-member rings are most common, with a base structure of i₆O₁₈sup>12−; examples include the tourmaline group and beryl. Other ring structures exist, with 3, 4, 8, 9, 12 having been described. Cyclosilicates tend to be strong, with elongated, striated crystals.

Tourmalines have a very complex chemistry that can be described by a general formula XY₃Z₆(BO₃)₃T₆O₁₈V₃W. The T₆O₁₈ is the basic ring structure, where T is usually Si⁴⁺, but substitutable by Al₃₊ or B³⁺. Tourmalines can be subgrouped by the occupancy of the X site, and from there further subdivided by the chemistry of the W site. The Y and Z sites can accommodate a variety of cations, especially various transition metals; this variability in structural transition metal content gives the tourmaline group greater variability in colour. Other cyclosilicates include beryl, Al₂Be₃Si₆O₁₈, whose varieties include the gemstones emerald (green) and aquamarine (bluish). Cordierite is structurally similar to beryl, and is a common metamorphic mineral.

Sorosilicates

Sorosilicates, also termed disilicates, have tetrahedron-tetrahedron bonding at one oxygen, which results in a 2:7 ratio of silicon to oxygen. The resultant common structural element is the i₂O₇sup>6− group. The most common disilicates by far are members of the epidote group. Epidotes are found in variety of geologic settings, ranging from mid-ocean ridge to granites to metapelites. Epidotes are built around the structure SiO₄)(Si₂O₇)sup>10− structure; for example, the mineral ''species'' epidote has calcium, aluminium, and ferric iron to charge balance: Ca₂Al₂(Fe³⁺, Al)(SiO₄)(Si₂O₇)O(OH). The presence of iron as Fe³⁺ and Fe²⁺ helps buffer oxygen fugacity, which in turn is a significant factor in petrogenesis., pp. 612–27

Other examples of sorosilicates include lawsonite, a metamorphic mineral forming in the blueschist facies (subduction zone setting with low temperature and high pressure), vesuvianite, which takes up a significant amount of calcium in its chemical structure.

Orthosilicates

Orthosilicates consist of isolated tetrahedra that are charge-balanced by other cations., pp. 116–17 Also termed nesosilicates, this type of silicate has a silicon:oxygen ratio of 1:4 (e.g. SiO₄). Typical orthosilicates tend to form blocky equant crystals, and are fairly hard. Several rock-forming minerals are part of this subclass, such as the aluminosilicates, the olivine group, and the garnet group.

The aluminosilicates –bkyanite, andalusite, and sillimanite, all Al₂SiO₅ – are structurally composed of one iO₄sup>4− tetrahedron, and one Al³⁺ in octahedral coordination. The remaining Al³⁺ can be in six-fold coordination (kyanite), five-fold (andalusite) or four-fold (sillimanite); which mineral forms in a given environment is depend on pressure and temperature conditions. In the olivine structure, the main olivine series of (Mg, Fe)₂SiO₄ consist of magnesium-rich forsterite and iron-rich fayalite. Both iron and magnesium are in octahedral by oxygen. Other mineral species having this structure exist, such as tephroite, Mn₂SiO₄. The garnet group has a general formula of X₃Y₂(SiO₄)₃, where X is a large eight-fold coordinated cation, and Y is a smaller six-fold coordinated cation. There are six ideal endmembers of garnet, split into two group. The pyralspite garnets have Al³⁺ in the Y position: pyrope (Mg₃Al₂(SiO₄)₃), almandine (Fe₃Al₂(SiO₄)₃), and spessartine (Mn₃Al₂(SiO₄)₃). The ugrandite garnets have Ca²⁺ in the X position: uvarovite (Ca₃Cr₂(SiO₄)₃), grossular (Ca₃Al₂(SiO₄)₃) and andradite

HOME


Content is Copyleft
Website design, code, and AI is Copyrighted (c) 2014-2017 by Stephen Payne


Consider donating to Wikimedia



As an Amazon Associate I earn from qualifying purchases