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Telluric Iron
Telluric iron, also called native iron, is iron that originated on Earth, and is found in a metallic form rather than as an ore. Telluric iron is extremely rare, with only one known major deposit in the world, located in Greenland. Introduction With the exception of its molten core, nearly all elemental iron on Earth is found as iron ores. All metallic iron was thought to have been transformed into iron oxides during the Great Oxidation Event, beginning roughly 2 billion years ago, among other theories. Until the late 1800s, iron as a native metal was only a matter of speculation, outside of isolated Greenland. The only known, terrestrial iron in metallic form were found as meteorites, which were deposited onto the Earth from outer space. Telluric iron is so named after the Latin word ''Tellus'', meaning "Earth" (the planet, as opposed to ''terra'' meaning "earth": the land, ground or soil), combined with the suffix ''-ic'' meaning "of" or "born from", differentiating it from ...
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Native Element Mineral
Native element minerals are those elements that occur in nature in uncombined form with a distinct mineral structure. The elemental class includes metals, intermetallic compounds, alloys, metalloids, and nonmetals. The Nickel–Strunz classification system also includes the naturally occurring phosphides, silicides, nitrides, carbides, and arsenides. Elements The following elements occur as native element minerals or alloys: Nickel–Strunz Classification -01- Native elements This list uses the Classification of Nickel–Strunz ( mindat.org, 10 ed, pending publication). ;Abbreviations: * "*" – discredited (IMA/CNMNC status). * "?" – questionable/doubtful (IMA/CNMNC status). * "REE" – Rare-earth element (Sc, Y, La, Ce, Pr, Nd, Pm, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu) * "PGE" – Platinum-group element (Ru, Rh, Pd, Os, Ir, Pt) * 03.C Aluminofluorides, 06 Borates, 08 Vanadates (04.H V ,6/sup> Vanadates), 09 Silicates: ** Neso: insular (from Greek νησος nÄ ...
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Graphite
Graphite () is a crystalline form of the element carbon. It consists of stacked layers of graphene. Graphite occurs naturally and is the most stable form of carbon under standard conditions. Synthetic and natural graphite are consumed on large scale (300 kton/year, in 1989) for uses in pencils, lubricants, and electrodes. Under high pressures and temperatures it converts to diamond. It is a weak conductor of heat and electricity. Types and varieties Natural graphite The principal types of natural graphite, each occurring in different types of ore deposits, are * Crystalline small flakes of graphite (or flake graphite) occurs as isolated, flat, plate-like particles with hexagonal edges if unbroken. When broken the edges can be irregular or angular; * Amorphous graphite: very fine flake graphite is sometimes called amorphous; * Lump graphite (or vein graphite) occurs in fissure veins or fractures and appears as massive platy intergrowths of fibrous or acicular crystalline ...
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Silicate
In chemistry, a silicate is any member of a family of polyatomic anions consisting of silicon and oxygen, usually with the general formula , where . The family includes orthosilicate (), metasilicate (), and pyrosilicate (, ). The name is also used for any salt of such anions, such as sodium metasilicate; or any ester containing the corresponding chemical group, such as tetramethyl orthosilicate. The name "silicate" is sometimes extended to any anions containing silicon, even if they do not fit the general formula or contain other atoms besides oxygen; such as hexafluorosilicate .Most commonly, silicates are encountered as silicate minerals. For diverse manufacturing, technological, and artistic needs, silicates are versatile materials, both natural (such as granite, gravel, and garnet) and artificial (such as Portland cement, ceramics, glass, and waterglass). Structural principles In all silicates, silicon atom occupies the center of an idealized tetrahedron whose corner ...
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Troilite
Troilite is a rare iron sulfide mineral with the simple formula of FeS. It is the iron-rich endmember of the pyrrhotite group. Pyrrhotite has the formula Fe(1-x)S (x = 0 to 0.2) which is iron deficient. As troilite lacks the iron deficiency which gives pyrrhotite its characteristic magnetism, troilite is non-magnetic. Troilite can be found as a native mineral on Earth but is more abundant in meteorites, in particular, those originating from the Moon and Mars. It is among the minerals found in samples of the meteorite that struck Russia in Chelyabinsk on February 15th, 2013. Uniform presence of troilite on the Moon and possibly on Mars has been confirmed by the Apollo, Viking and Phobos space probes. The relative intensities of isotopes of sulfur are rather constant in meteorites as compared to the Earth minerals, and therefore troilite from Canyon Diablo meteorite is chosen as the international sulfur isotope ratio standard, the Canyon Diablo Troilite (CDT). Structure Troilit ...
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Cohenite
Cohenite is a naturally occurring iron carbide mineral with the chemical structure ( Fe, Ni, Co)3 C. This forms a hard, shiny, silver mineral which was named by E. Weinschenk in 1889 after the German mineralogist Emil Cohen, who first described and analysed material from the Magura meteorite found near Slanica, Žilina Region, Slovakia. Cohenite is found in rod-like crystals in iron meteorites.Vagn F. Buchwald, ''Handbook of Iron Meteorites,'' University of California Press, 1975 On Earth cohenite is stable only in rocks which formed in a strongly reducing environment and contain native iron deposits. Such conditions existed in some places where molten magmas invaded coal deposits, e.g. on Disko Island in Greenland, or at the Bühl near Kassel in Germany. Associated minerals include native iron, schreibersite, troilite and wustite. Similar iron carbides occur also in technical iron alloys and are called cementite. See also * Glossary of meteoritics *List of minerals *Lis ...
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Cementite
Cementite (or iron carbide) is a compound of iron and carbon, more precisely an intermediate transition metal carbide with the formula Fe3C. By weight, it is 6.67% carbon and 93.3% iron. It has an orthorhombic crystal structure. It is a hard, brittle material, normally classified as a ceramic in its pure form, and is a frequently found and important constituent in ferrous metallurgy. While cementite is present in most steels and cast irons, it is produced as a raw material in the iron carbide process, which belongs to the family of alternative ironmaking technologies. The name ''cementite'' originated from the theory of Floris Osmond and J. Werth, in which the structure of solidified steel consists of a kind of cellular tissue, with ferrite as the nucleus and Fe3C the envelope of the cells. The carbide therefore ''cemented'' the iron. Metallurgy In the iron–carbon system (i.e. plain-carbon steels and cast irons) it is a common constituent because ferrite can contain at most ...
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Pearlite
Pearlite is a two-phased, lamellar (or layered) structure composed of alternating layers of ferrite (87.5 wt%) and cementite (12.5 wt%) that occurs in some steels and cast irons. During slow cooling of an iron-carbon alloy, pearlite forms by a eutectoid reaction as austenite cools below (the eutectoid temperature). Pearlite is a microstructure occurring in many common grades of steels. The eutectoid composition of austenite is approximately 0.8% carbon; steel with less carbon content ( hypoeutectoid steel) will contain a corresponding proportion of relatively pure ferrite crystallites that do not participate in the eutectoid reaction and cannot transform into pearlite. Likewise steels with higher carbon content ( hypereutectoid steels) will form cementite before reaching the eutectoid point. The proportion of ferrite and cementite forming above the eutectoid point can be calculated from the iron/iron—carbide equilibrium phase diagram using the lever rule. Steels with p ...
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Cold Working
In metallurgy, cold forming or cold working is any metalworking process in which metal is shaped below its recrystallization temperature, usually at the ambient temperature. Such processes are contrasted with hot working techniques like hot rolling, forging, welding, etc. The same or similar terms are used in glassmaking for the equivalents; for example cut glass is made by "cold work", cutting or grinding a formed object. Cold forming techniques are usually classified into four major groups: squeezing, bending, drawing, and shearing. They generally have the advantage of being simpler to carry out than hot working techniques. Unlike hot working, cold working causes the crystal grains and inclusions to distort following the flow of the metal; which may cause work hardening and anisotropic material properties. Work hardening makes the metal harder, stiffer, and stronger, but less plastic, and may cause cracks of the piece. The possible uses of cold forming are extremely v ...
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Eutectoid
A eutectic system or eutectic mixture ( ) is a homogeneous mixture that has a melting point lower than those of the constituents. The lowest possible melting point over all of the mixing ratios of the constituents is called the ''eutectic temperature''. On a phase diagram, the eutectic temperature is seen as the eutectic point (see plot on the right). Non-eutectic mixture ratios would have different melting temperatures for their different constituents, since one component's lattice will melt at a lower temperature than the other's. Conversely, as a non-eutectic mixture cools down, each of its components would solidify (form a lattice) at a different temperature, until the entire mass is solid. Not all binary alloys have eutectic points, since the valence electrons of the component species are not always compatible, in any mixing ratio, to form a new type of joint crystal lattice. For example, in the silver-gold system the melt temperature (liquidus) and freeze temperature ( ...
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Alloy
An alloy is a mixture of chemical elements of which at least one is a metal. Unlike chemical compounds with metallic bases, an alloy will retain all the properties of a metal in the resulting material, such as electrical conductivity, ductility, opacity (optics), opacity, and lustre (mineralogy), luster, but may have properties that differ from those of the pure metals, such as increased strength or hardness. In some cases, an alloy may reduce the overall cost of the material while preserving important properties. In other cases, the mixture imparts synergistic properties to the constituent metal elements such as corrosion resistance or mechanical strength. Alloys are defined by a metallic bonding character. The alloy constituents are usually measured by mass percentage for practical applications, and in Atomic ratio, atomic fraction for basic science studies. Alloys are usually classified as substitutional or interstitial alloys, depending on the atomic arrangement that forms the ...
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Phase (matter)
In the physical sciences, a phase is a region of space (a thermodynamic system), throughout which all physical properties of a material are essentially uniform. Examples of physical properties include density, index of refraction, magnetization and chemical composition. A simple description is that a phase is a region of material that is chemically uniform, physically distinct, and (often) mechanically separable. In a system consisting of ice and water in a glass jar, the ice cubes are one phase, the water is a second phase, and the humid air is a third phase over the ice and water. The glass of the jar is another separate phase. (See ) The term ''phase'' is sometimes used as a synonym for state of matter, but there can be several immiscible phases of the same state of matter. Also, the term ''phase'' is sometimes used to refer to a set of equilibrium states demarcated in terms of state variables such as pressure and temperature by a phase boundary on a phase diagram. Bec ...
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Reducing Environment
A reducing atmosphere is an atmospheric condition in which oxidation is prevented by removal of oxygen and other oxidizing gases or vapours, and which may contain actively reducing gases such as hydrogen, carbon monoxide, and gases such as hydrogen sulfide that would be oxidized by any present oxygen. Although early in its history the Earth had a reducing atmosphere, it now instead has an oxidizing atmosphere with molecular oxygen (dioxygen, O2) as the primary oxidizing agent. Foundry operations The principal mission of iron foundry is the conversion of iron oxides (purified iron ores) to iron metal. This reduction is usually effected using a reducing atmosphere consisting of some mixture of natural gas, hydrogen (H2), and carbon monoxide. The byproduct is carbon dioxide. Metal processing In metal processing, a reducing atmosphere is used in annealing ovens for relaxation of metal stresses without corroding the metal. A non-oxidizing gas, usually nitrogen or argon, is typ ...
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