Troilite is a rare
iron
Iron () is a chemical element with symbol Fe (from la, ferrum) and atomic number 26. It is a metal that belongs to the first transition series and group 8 of the periodic table. It is, by mass, the most common element on Earth, right in ...
sulfide mineral
The sulfide minerals are a class of minerals containing sulfide (S2−) or disulfide (S22−) as the major anion. Some sulfide minerals are economically important as metal ores. The sulfide class also includes the selenides, the tellurides, th ...
with the simple formula of FeS. It is the iron-rich
endmember of the
pyrrhotite
Pyrrhotite is an iron sulfide mineral with the formula Fe(1-x)S (x = 0 to 0.2). It is a nonstoichiometric variant of FeS, the mineral known as troilite.
Pyrrhotite is also called magnetic pyrite, because the color is similar to pyrite and it i ...
group. Pyrrhotite has the formula Fe
(1-x)S (x = 0 to 0.2) which is iron deficient. As troilite lacks the iron deficiency which gives pyrrhotite its characteristic magnetism, troilite is non-magnetic.
[
Troilite can be found as a native mineral on Earth but is more abundant in ]meteorites
A meteorite is a solid piece of debris from an object, such as a comet, asteroid, or meteoroid, that originates in outer space and survives its passage through the atmosphere to reach the surface of a planet or moon. When the original object ...
, in particular, those originating from the Moon
The Moon is Earth's only natural satellite. It is the fifth largest satellite in the Solar System and the largest and most massive relative to its parent planet, with a diameter about one-quarter that of Earth (comparable to the width of ...
and Mars
Mars is the fourth planet from the Sun and the second-smallest planet in the Solar System, only being larger than Mercury. In the English language, Mars is named for the Roman god of war. Mars is a terrestrial planet with a thin at ...
. It is among the minerals found in samples of the meteorite that struck Russia in Chelyabinsk on February 15th, 2013. Uniform presence of troilite on the Moon and possibly on Mars has been confirmed by the Apollo
Apollo, grc, Ἀπόλλωνος, Apóllōnos, label=genitive , ; , grc-dor, Ἀπέλλων, Apéllōn, ; grc, Ἀπείλων, Apeílōn, label=Arcadocypriot Greek, ; grc-aeo, Ἄπλουν, Áploun, la, Apollō, la, Apollinis, label= ...
, Viking
Vikings ; non, víkingr is the modern name given to seafaring people originally from Scandinavia (present-day Denmark, Norway and Sweden),
who from the late 8th to the late 11th centuries raided, pirated, traded and se ...
and Phobos space probes. The relative intensities of isotopes of sulfur
Sulfur (16S) has 23 known isotopes with mass numbers ranging from 27 to 49, four of which are stable: 32S (95.02%), 33S (0.75%), 34S (4.21%), and 36S (0.02%). The preponderance of sulfur-32 is explained by its production from carbon-12 plus succ ...
are rather constant in meteorites as compared to the Earth minerals, and therefore troilite from Canyon Diablo meteorite
The Canyon Diablo meteorite refers to the many fragments of the asteroid that created Meteor Crater (also called Barringer Crater), Arizona, United States. Meteorites have been found around the crater rim, and are named for nearby Canyon Diabl ...
is chosen as the international sulfur isotope ratio standard, the Canyon Diablo Troilite (CDT).
Structure
Troilite has hexagonal structure (Pearson symbol
The Pearson symbol, or Pearson notation, is used in crystallography as a means of describing a crystal structure, and was originated by W. B. Pearson. The symbol is made up of two letters followed by a number. For example:
* Diamond structure ...
hP24, Space group
In mathematics, physics and chemistry, a space group is the symmetry group of an object in space, usually in three dimensions. The elements of a space group (its symmetry operations) are the rigid transformations of an object that leave it unchan ...
P-62c No 190). Its unit cell is approximately a combination of two vertically stacked basic NiAs-type cells of pyrrhotite, where the top cell is diagonally shifted.[ For this reason, troilite is sometimes called pyrrhotite-2C.]
Discovery
A meteorite fall was observed in 1766 at Albareto, Modena
Modena (, , ; egl, label=Emilian language#Dialects, Modenese, Mòdna ; ett, Mutna; la, Mutina) is a city and ''comune'' (municipality) on the south side of the Po Valley, in the Province of Modena in the Emilia-Romagna region of northern I ...
, Italy. Samples were collected and studied by Domenico Troili
Domenico Troili (1722–1792) was an Italian ''abbate'' and a Jesuit, who held the appointment of custodian of the library of the ruling family of Este in Modena. He is recognized as the first person who documented the fall of a meteorite, in 176 ...
who described the iron sulfide inclusions in the meteorite. These iron sulfides were long considered to be pyrite
The mineral pyrite (), or iron pyrite, also known as fool's gold, is an iron sulfide with the chemical formula Iron, FeSulfur, S2 (iron (II) disulfide). Pyrite is the most abundant sulfide mineral.
Pyrite's metallic Luster (mineralogy), lust ...
(''i.e.'', ). In 1862, German mineralogist
Mineralogy is a subject of geology specializing in the scientific study of the chemistry, crystal structure, and physical (including optical) properties of minerals and mineralized artifacts. Specific studies within mineralogy include the proce ...
Gustav Rose
Prof Gustavus ("Gustav") Rose FRSFor HFRSE (18 March 1798 – 15 July 1873) was a German mineralogist who was a native of Berlin. He was President of the German Geological Society from 1863 to 1873.
Life
He was born in Berlin the son of pharmaco ...
analyzed the material and recognized it as stoichiometric
Stoichiometry refers to the relationship between the quantities of reactants and products before, during, and following chemical reactions.
Stoichiometry is founded on the law of conservation of mass where the total mass of the reactants equ ...
1:1 FeS and gave it the name ''troilite'' in recognition of the work of Domenico Troili
Domenico Troili (1722–1792) was an Italian ''abbate'' and a Jesuit, who held the appointment of custodian of the library of the ruling family of Este in Modena. He is recognized as the first person who documented the fall of a meteorite, in 176 ...
.[
]
Occurrence
Troilite has been reported from a variety of meteorites occurring with daubréelite
Daubréelite is a rare sulfide mineral. It crystallizes with cubic symmetry and has chemical composition of Fe2+Cr3+2S4. It usually occurs as black platy aggregates.
Naming and history
Daubréelite was named after the French mineralogist, petrol ...
, chromite
Chromite is a crystalline mineral composed primarily of iron(II) oxide and chromium(III) oxide compounds. It can be represented by the chemical formula of FeCr2O4. It is an oxide mineral belonging to the spinel group. The element magnesium can s ...
, sphalerite
Sphalerite (sometimes spelled sphaelerite) is a sulfide mineral with the chemical formula . It is the most important ore of zinc. Sphalerite is found in a variety of deposit types, but it is primarily in Sedimentary exhalative deposits, sedimen ...
, graphite
Graphite () is a crystalline form of the element carbon. It consists of stacked layers of graphene. Graphite occurs naturally and is the most stable form of carbon under standard conditions. Synthetic and natural graphite are consumed on large ...
, and a variety of phosphate
In chemistry, a phosphate is an anion, salt, functional group or ester derived from a phosphoric acid. It most commonly means orthophosphate, a derivative of orthophosphoric acid .
The phosphate or orthophosphate ion is derived from phospho ...
and silicate minerals
Silicate minerals are rock-forming minerals made up of silicate groups. They are the largest and most important class of minerals and make up approximately 90 percent of Earth's crust.
In mineralogy, silica (silicon dioxide, ) is usually con ...
.[ It has also been reported from ]serpentinite
Serpentinite is a rock composed predominantly of one or more serpentine group minerals, the name originating from the similarity of the texture of the rock to that of the skin of a snake. Serpentinite has been called ''serpentine'' or ''ser ...
in the Alta mine, Del Norte County, California
), in California
, seat_type = County seat
, seat = Crescent City
, parts_type = Largest city
, parts = Crescent City
, unit_pref = US
, area_total_sq_mi = 1230
, area_land_sq_mi = 1006
, area_water_sq_mi = 223
, elevation_max_footnote ...
and in layered igneous intrusions in Western Australia, the Ilimaussaq intrusion of southern Greenland
Greenland ( kl, Kalaallit Nunaat, ; da, Grønland, ) is an island country in North America that is part of the Kingdom of Denmark. It is located between the Arctic and Atlantic oceans, east of the Canadian Arctic Archipelago. Greenland is t ...
, the Bushveld Complex
The Bushveld Igneous Complex (BIC) is the largest layered igneous intrusion within the Earth's crust. It has been tilted and eroded forming the outcrops around what appears to be the edge of a great geological basin: the Transvaal Basin. It i ...
in South Africa and at Nordfjellmark, Norway
Norway, officially the Kingdom of Norway, is a Nordic country in Northern Europe, the mainland territory of which comprises the western and northernmost portion of the Scandinavian Peninsula. The remote Arctic island of Jan Mayen and t ...
. In the South African and Australian occurrence it is associated with copper, nickel, platinum iron ore deposits occurring with pyrrhotite
Pyrrhotite is an iron sulfide mineral with the formula Fe(1-x)S (x = 0 to 0.2). It is a nonstoichiometric variant of FeS, the mineral known as troilite.
Pyrrhotite is also called magnetic pyrite, because the color is similar to pyrite and it i ...
, pentlandite
Pentlandite is an iron–nickel sulfide with the chemical formula . Pentlandite has a narrow variation range in Ni:Fe but it is usually described as having a Ni:Fe of 1:1. It also contains minor cobalt, usually at low levels as a fraction of wei ...
, mackinawite, cubanite
Cubanite is a copper iron sulfide mineral that commonly occurs as a minor alteration mineral in magmatic sulfide deposits. It has the chemical formula CuFe2S3 and when found, it has a bronze to brass-yellow appearance. On the Mohs hardness scale, ...
, valleriite
Valleriite is an uncommon sulfide mineral (hydroxysulfide) of iron and copper with formula: or . It is an opaque, soft, bronze-yellow to brown mineral which occurs as nodules or encrustations.
Discovery and occurrence
Valleriite was first describ ...
, chalcopyrite
Chalcopyrite ( ) is a copper iron sulfide mineral and the most abundant copper ore mineral. It has the chemical formula CuFeS2 and crystallizes in the tetragonal system. It has a brassy to golden yellow color and a hardness of 3.5 to 4 on the Mo ...
and pyrite
The mineral pyrite (), or iron pyrite, also known as fool's gold, is an iron sulfide with the chemical formula Iron, FeSulfur, S2 (iron (II) disulfide). Pyrite is the most abundant sulfide mineral.
Pyrite's metallic Luster (mineralogy), lust ...
.[
Troilite is extremely rarely encountered in the Earth's crust (even pyrrhotite is relatively rare compared to pyrite and ]Iron(II) sulfate
Iron(II) sulfate (British English: iron(II) sulphate) or ferrous sulfate denotes a range of salts with the formula Fe SO4·''x''H2O. These compounds exist most commonly as the heptahydrate (''x'' = 7) but several values for x are know ...
minerals). Most troilite on Earth is of meteoritic origin. One iron meteorite, Mundrabilla contains 25 to 35 volume percent troilite. The most famous troilite-containing meteorite is Canyon Diablo. Canyon Diablo Troilite (CDT) is used as a standard of relative concentration of different isotopes of sulfur. Meteoritic standard was chosen because of the constancy of the sulfur isotopic ratio in meteorites, whereas the sulfur isotopic composition in Earth materials varies due to the bacterial activity. In particular, certain sulfate reducing bacteria
Sulfate-reducing microorganisms (SRM) or sulfate-reducing prokaryotes (SRP) are a group composed of sulfate-reducing bacteria (SRB) and sulfate-reducing archaea (SRA), both of which can perform anaerobic respiration utilizing sulfate () as termina ...
can reduce 1.07 times faster than , which may increase the / ratio by up to 10%.
Troilite is the most common sulfide mineral at the lunar surface. It forms about one percent of the lunar crust and is present in any rock or meteorite originating from moon. In particular, all basalts brought by the Apollo 11
Apollo 11 (July 16–24, 1969) was the American spaceflight that first landed humans on the Moon. Commander Neil Armstrong and lunar module pilot Buzz Aldrin landed the Apollo Lunar Module ''Eagle'' on July 20, 1969, at 20:17 UTC, an ...
, 12, 15 and 16 missions contain about 1% of troilite.
Troilite is regularly found in Martian meteorites (i.e. those originating from Mars
Mars is the fourth planet from the Sun and the second-smallest planet in the Solar System, only being larger than Mercury. In the English language, Mars is named for the Roman god of war. Mars is a terrestrial planet with a thin at ...
). Similar to the Moon's surface and meteorites, the fraction of troilite in Martian meteorites is close to 1%.
Based on observations by the Voyager spacecraft in 1979 and Galileo
Galileo di Vincenzo Bonaiuti de' Galilei (15 February 1564 – 8 January 1642) was an Italian astronomer, physicist and engineer, sometimes described as a polymath. Commonly referred to as Galileo, his name was pronounced (, ). He was ...
in 1996, troilite might also be present in the rocks of Jupiter
Jupiter is the fifth planet from the Sun and the List of Solar System objects by size, largest in the Solar System. It is a gas giant with a mass more than two and a half times that of all the other planets in the Solar System combined, but ...
’s satellites Ganymede and Callisto Callisto most commonly refers to:
*Callisto (mythology), a nymph
*Callisto (moon), a moon of Jupiter
Callisto may also refer to:
Art and entertainment
*''Callisto series'', a sequence of novels by Lin Carter
*''Callisto'', a novel by Torsten Kro ...
. Whereas experimental data for Jupiter's moons are yet very limited, the theoretical modeling assumes large percentage of troilite (~22.5%) in the core of those moons.
See also
* Glossary of meteoritics
This is a glossary of terms used in meteoritics, the science of meteorites.
#
* 2 Pallas – an asteroid from the asteroid belt and one of the likely parent bodies of the CR meteorites.
* 4 Vesta – second-largest asteroid in the asteroid b ...
References
{{Meteorites
Sulfide minerals
Meteorite minerals
Hexagonal minerals
Minerals in space group 190