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Sillimanite
Sillimanite is an aluminosilicate mineral with the chemical formula Al2SiO5. Sillimanite is named after the American chemist Benjamin Silliman (1779–1864). It was first described in 1824 for an occurrence in Chester, Connecticut. Occurrence Sillimanite is one of three aluminosilicate polymorphs, the other two being andalusite and kyanite. A common variety of sillimanite is known as ''fibrolite'', so named because the mineral appears like a bunch of fibres twisted together when viewed in thin section or even by the naked eye. Both the fibrous and traditional forms of sillimanite are common in metamorphosed sedimentary rocks. It is an index mineral indicating high temperature but variable pressure. Example rocks include gneiss and granulite. It occurs with andalusite, kyanite, potassium feldspar, almandine, cordierite, biotite and quartz in schist, gneiss, hornfels and also rarely in pegmatites. Dumortierite and mullite are similar mineral species found in porcel ...
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Metamorphism
Metamorphism is the transformation of existing rock (the protolith) to rock with a different mineral composition or texture. Metamorphism takes place at temperatures in excess of , and often also at elevated pressure or in the presence of chemically active fluids, but the rock remains mostly solid during the transformation. Metamorphism is distinct from weathering or diagenesis, which are changes that take place at or just beneath Earth's surface. Various forms of metamorphism exist, including regional, contact, hydrothermal, shock, and dynamic metamorphism. These differ in the characteristic temperatures, pressures, and rate at which they take place and in the extent to which reactive fluids are involved. Metamorphism occurring at increasing pressure and temperature conditions is known as ''prograde metamorphism'', while decreasing temperature and pressure characterize ''retrograde metamorphism''. Metamorphic petrology is the study of metamorphism. Metamorphic petrologis ...
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Mineral
In geology and mineralogy, a mineral or mineral species is, broadly speaking, a solid chemical compound with a fairly well-defined chemical composition and a specific crystal structure that occurs naturally in pure form.John P. Rafferty, ed. (2011): Minerals'; p. 1. In the series ''Geology: Landforms, Minerals, and Rocks''. Rosen Publishing Group. The geological definition of mineral normally excludes compounds that occur only in living organisms. However, some minerals are often biogenic (such as calcite) or are organic compounds in the sense of chemistry (such as mellite). Moreover, living organisms often synthesize inorganic minerals (such as hydroxylapatite) that also occur in rocks. The concept of mineral is distinct from rock, which is any bulk solid geologic material that is relatively homogeneous at a large enough scale. A rock may consist of one type of mineral, or may be an aggregate of two or more different types of minerals, spacially segregated into distinct ...
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Kyanite
Kyanite is a typically blue aluminosilicate mineral, found in aluminium-rich metamorphic pegmatites and sedimentary rock. It is the high pressure polymorph of andalusite and sillimanite, and the presence of kyanite in metamorphic rocks generally indicates metamorphism deep in the Earth's crust. Kyanite is also known as disthene or cyanite. Kyanite is strongly anisotropic, in that its hardness varies depending on its crystallographic direction. In kyanite, this anisotropism can be considered an identifying characteristic, along with its characteristic blue color. Its name comes from the same origin as that of the color cyan, being derived from the Ancient Greek word κύανος. This is generally rendered into English as ''kyanos'' or ''kuanos'' and means "dark blue". Kyanite is used as a raw material in the manufacture of ceramics and abrasives, and it is an important index mineral used by geologists to trace metamorphic zones. Properties Kyanite is an aluminum silicat ...
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Hornfels
Hornfels is the group name for a set of contact metamorphic rocks that have been baked and hardened by the heat of intrusive igneous masses and have been rendered massive, hard, splintery, and in some cases exceedingly tough and durable. These properties are due to fine grained non-aligned crystals with platy or prismatic habits, characteristic of metamorphism at high temperature but without accompanying deformation. The term is derived from the German word ''Hornfels'', meaning "hornstone", because of its exceptional toughness and texture both reminiscent of animal horns. These rocks were referred to by miners in northern England as whetstones. Most hornfels are fine-grained, and while the original rocks (such as sandstone, shale, slate and limestone) may have been more or less fissile owing to the presence of bedding or cleavage planes, this structure is effaced or rendered inoperative in the hornfels. Though many hornfels show vestiges of the original bedding, they break acr ...
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Andalusite
Andalusite is an aluminium nesosilicate mineral with the chemical formula Al2SiO5. This mineral was called andalousite by Delamétehrie, who thought it came from Andalusia, Spain. It soon became clear that it was a locality error, and that the specimens studied were actually from El Cardoso de la Sierra, in the Spanish province of Guadalajara, not Andalusia. Andalusite is trimorphic with kyanite and sillimanite, being the lower pressure mid temperature polymorph. At higher temperatures and pressures, andalusite may convert to sillimanite. Thus, as with its other polymorphs, andalusite is an aluminosilicate index mineral, providing clues to depth and pressures involved in producing the host rock. Varieties The variety chiastolite commonly contains dark inclusions of carbon or clay which form a cruciform pattern when shown in cross-section. This stone was known at least from the sixteenth century, being taken to many European countries, as a souvenir, by pilgrims returning from ...
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Aluminosilicate
Aluminosilicate minerals ( IMA symbol: Als) are minerals composed of aluminium, silicon, and oxygen, plus countercations. They are a major component of kaolin and other clay minerals. Andalusite, kyanite, and sillimanite are naturally occurring aluminosilicate minerals that have the composition Al2 Si O5. The triple point of the three polymorphs is located at a temperature of and a pressure of . These three minerals are commonly used as index minerals in metamorphic rocks. Naturally occurring microporous, hydrous aluminosilicate minerals are referred to as zeolites. Feldspar is a common tectosilicate aluminosilicate mineral made of potassium, sodium, and calcium cations surrounded by a negatively charged network of silicon, aluminium and oxygen atoms. The catalyst silica-alumina is an amorphous substance which is not an aluminosilicate compound. Aluminosilicate glasses There exist a wide variety of glass types. The characteristics of these different ty ...
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Granulite
Granulites are a class of high-grade metamorphic rocks of the granulite facies that have experienced high-temperature and moderate-pressure metamorphism. They are medium to coarse–grained and mainly composed of feldspars sometimes associated with quartz and anhydrous ferromagnesian minerals, with granoblastic texture and gneissose to massive structure.D.R. Bowes (1989), ''The Encyclopedia of Igneous and Metamorphic Petrology''; Van Nostrand Reinhold They are of particular interest to geologists because many granulites represent samples of the deep continental crust. Some granulites experienced decompression from deep in the Earth to shallower crustal levels at high temperature; others cooled while remaining at depth in the Earth. The minerals present in a granulite will vary depending on the parent rock of the granulite and the temperature and pressure conditions experienced during metamorphism. A common type of granulite found in high-grade metamorphic rocks of the contin ...
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Cordierite
Cordierite (mineralogy) or iolite (gemology) is a magnesium iron aluminium cyclosilicate. Iron is almost always present and a solid solution exists between Mg-rich cordierite and Fe-rich sekaninaite with a series formula: to . A high-temperature polymorph exists, indialite, which is isostructural with beryl and has a random distribution of Al in the rings. Name and discovery Cordierite, which was discovered in 1813, in specimens from Níjar, Almería, Spain, is named after the French geologist Louis Cordier (1777–1861). Occurrence Cordierite typically occurs in contact or regional metamorphism of pelitic rocks. It is especially common in hornfels produced by contact metamorphism of pelitic rocks. Two common metamorphic mineral assemblages include sillimanite-cordierite-spinel and cordierite-spinel-plagioclase-orthopyroxene. Other associated minerals include garnet (cordierite-garnet-sillimanite gneisses) and anthophyllite. Cordierite also occurs in some granites, p ...
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Schist
Schist ( ) is a medium-grained metamorphic rock showing pronounced schistosity. This means that the rock is composed of mineral grains easily seen with a low-power hand lens, oriented in such a way that the rock is easily split into thin flakes or plates. This texture reflects a high content of platy minerals, such as micas, talc, chlorite, or graphite. These are often interleaved with more granular minerals, such as feldspar or quartz. Schist typically forms during regional metamorphism accompanying the process of mountain building ( orogeny) and usually reflects a medium grade of metamorphism. Schist can form from many different kinds of rocks, including sedimentary rocks such as mudstones and igneous rocks such as tuffs. Schist metamorphosed from mudstone is particularly common and is often very rich in mica (a ''mica schist''). Where the type of the original rock (the protolith) is discernible, the schist is usually given a name reflecting its protolith, such as ''sch ...
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Benjamin Silliman
Benjamin Silliman (August 8, 1779 – November 24, 1864) was an early American chemist and science educator. He was one of the first American professors of science, at Yale College, the first person to use the process of fractional distillation in America, and a founder of the ''American Journal of Science'', the oldest continuously published scientific journal in the United States. Early life Silliman was born in a tavern in North Stratford, now Trumbull, Connecticut, to Mary (Fish) Silliman (widow of John Noyes) and General Gold Selleck Silliman. He was born in August 1779, several months after British forces took his father prisoner and his mother had fled their home in Fairfield, Connecticut, to escape 2,000 British troops who burned Fairfield center to the ground. Silliman was educated at Yale, receiving a B.A. degree in 1796 and a M.A. in 1799. He studied law with Simeon Baldwin from 1798 to 1799 and became a tutor at Yale from 1799 to 1802. He was admitted to the ...
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Mullite
Mullite or porcelainite is a rare silicate mineral formed during contact metamorphism of clay minerals. It can form two stoichiometric forms: 3 Al2 O32 SiO2 or 2Al2O3 SiO2. Unusually, mullite has no charge-balancing cations present. As a result, there are three different aluminium sites: two distorted tetrahedral and one octahedral. Mullite was first described in 1924 for an occurrence on the Isle of Mull, Scotland. It occurs as argillaceous inclusions in volcanic rocks in the Isle of Mull, inclusions in sillimanite within a tonalite at Val Sissone, Italy and with emerylike rocks in Argyllshire, Scotland. Porcellanite Mullite (porcelainite) can be found as a constituent mineral in a type of thermally-metamorphosed rock called porcellanite. Use in porcelain Mullite is present in the form of needles in porcelain. It is produced during various melting and firing processes, and is used as a refractory material,H. Schneider & S. Komarneni (2005) Mullite. Wiley, VCH, 509 pp, becau ...
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Index Mineral
An index mineral is used in geology to determine the degree of metamorphism a rock has experienced. Depending on the original composition of and the pressure and temperature experienced by the protolith (parent rock), chemical reactions between minerals in the solid state produce new minerals. When an index mineral is found in a metamorphosed rock, it indicates the minimum pressure and temperature the protolith must have achieved in order for that mineral to form. The higher the pressure and temperature in which the rock formed, the higher the grade of the rock. The concept traces its roots to 1912, when G. M. Barrow mapped zones of metamorphism in southern Scotland. Each zone is named for the index mineral that appears in it. E.g. the chlorite zone is named for chlorite. Mineralogic zones Mudrock, a fine-grained sedimentary rock often containing aluminium-rich minerals, produces these minerals after being metamorphosed, from low to high grade:Blatt, Harvey and Robert J. Tracy, ...
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