A light-emitting diode (LED) is a
semiconductor
A semiconductor is a material which has an electrical resistivity and conductivity, electrical conductivity value falling between that of a electrical conductor, conductor, such as copper, and an insulator (electricity), insulator, such as glas ...
device that
emits light when
current flows through it.
Electron
The electron ( or ) is a subatomic particle with a negative one elementary electric charge. Electrons belong to the first generation of the lepton particle family,
and are generally thought to be elementary particles because they have no kn ...
s in the semiconductor recombine with
electron hole
In physics, chemistry, and electronic engineering, an electron hole (often simply called a hole) is a quasiparticle which is the lack of an electron at a position where one could exist in an atom or atomic lattice. Since in a normal atom or ...
s, releasing energy in the form of
photon
A photon () is an elementary particle that is a quantum of the electromagnetic field, including electromagnetic radiation such as light and radio waves, and the force carrier for the electromagnetic force. Photons are massless, so they always ...
s. The color of the light (corresponding to the energy of the photons) is determined by the energy required for electrons to cross the
band gap of the semiconductor. White light is obtained by using multiple semiconductors or a layer of light-emitting
phosphor
A phosphor is a substance that exhibits the phenomenon of luminescence; it emits light when exposed to some type of radiant energy. The term is used both for fluorescent or phosphorescent substances which glow on exposure to ultraviolet or vi ...
on the semiconductor device.
Appearing as practical electronic components in 1962, the earliest LEDs emitted low-intensity
infrared
Infrared (IR), sometimes called infrared light, is electromagnetic radiation (EMR) with wavelengths longer than those of visible light. It is therefore invisible to the human eye. IR is generally understood to encompass wavelengths from around ...
(IR) light.
Infrared LEDs are used in
remote-control
In electronics, a remote control (also known as a remote or clicker) is an electronic device used to operate another device from a distance, usually wirelessly. In consumer electronics, a remote control can be used to operate devices such as ...
circuits, such as those used with a wide variety of consumer electronics. The first visible-light LEDs were of low intensity and limited to red. Early LEDs were often used as indicator lamps, replacing small
incandescent bulbs
An incandescent light bulb, incandescent lamp or incandescent light globe is an electric light with a wire filament heated until it glows. The filament is enclosed in a glass bulb with a vacuum or inert gas to protect the filament from oxida ...
, and in
seven-segment display
A seven-segment display is a form of electronic display device for displaying decimal numerals that is an alternative to the more complex dot matrix displays.
Seven-segment displays are widely used in digital clocks, electronic meters, basic ...
s. Later developments produced LEDs available in
visible
Visibility, in meteorology, is a measure of the distance at which an object or light can be seen.
Visibility may also refer to:
* A measure of turbidity in water quality control
* Interferometric visibility, which quantifies interference contrast ...
,
ultraviolet
Ultraviolet (UV) is a form of electromagnetic radiation with wavelength from 10 nanometer, nm (with a corresponding frequency around 30 Hertz, PHz) to 400 nm (750 Hertz, THz), shorter than that of visible light, but longer than ...
(UV), and infrared wavelengths, with high, low, or intermediate light output, for instance white LEDs suitable for room and outdoor area lighting. LEDs have also given rise to new types of displays and sensors, while their high switching rates are useful in advanced communications technology with applications as diverse as
aviation lighting,
fairy lights
Christmas lights (also known as fairy lights, festive lights or string lights) are lights often used for decoration in celebration of Christmas, often on display throughout the Christmas season including Advent and Christmastide. The custom goe ...
,
automotive headlamps, advertising,
general lighting,
traffic signals
Traffic lights, traffic signals, or stoplights – known also as robots in South Africa are signalling devices positioned at road intersections, pedestrian crossings, and other locations in order to control flows of traffic.
Traffic lights ...
, camera flashes,
lighted wallpaper,
horticultural grow lights, and medical devices.
LEDs have many advantages over incandescent light sources, including lower power consumption, longer lifetime, improved physical robustness, smaller size, and faster switching. In exchange for these generally favorable attributes, disadvantages of LEDs include electrical limitations to low voltage and generally to DC (not AC) power, inability to provide steady illumination from a pulsing DC or an AC electrical supply source, and lesser maximum operating temperature and storage temperature. In contrast to LEDs, incandescent lamps can be made to intrinsically run at virtually any supply voltage, can utilize either AC or DC current interchangeably, and will provide steady illumination when powered by AC or pulsing DC even at a frequency as low as 50 Hz. LEDs usually need electronic support components to function, while an incandescent bulb can and usually does operate directly from an unregulated DC or AC power source.
As a
transducer
A transducer is a device that converts energy from one form to another. Usually a transducer converts a signal in one form of energy to a signal in another.
Transducers are often employed at the boundaries of automation, measurement, and contr ...
of electricity into light, LEDs operate in reverse of
photodiodes
A photodiode is a light-sensitive semiconductor diode. It produces current when it absorbs photons.
The package of a photodiode allows light (or infrared or ultraviolet radiation, or X-rays) to reach the sensitive part of the device. The packag ...
.
History
Discoveries and early devices
Electroluminescence
Electroluminescence (EL) is an optical phenomenon, optical and electrical phenomenon, in which a material emits light in response to the passage of an electric current or to a strong electric field. This is distinct from black body light emissi ...
as a phenomenon was discovered in 1907 by the English experimenter
H. J. Round
Captain Henry Joseph Round (2 June 1881 – 17 August 1966) was an English engineer and one of the early pioneers of radio. He was the first to report observation of electroluminescence from a solid state diode, leading to the discovery of the l ...
of
Marconi Labs, using a crystal of
silicon carbide
Silicon carbide (SiC), also known as carborundum (), is a hard chemical compound containing silicon and carbon. A semiconductor, it occurs in nature as the extremely rare mineral moissanite, but has been mass-produced as a powder and crystal sin ...
and a
cat's-whisker detector. Russian inventor
Oleg Losev
Oleg Vladimirovich Losev (russian: Оле́г Влади́мирович Ло́сев, sometimes spelled Lossev or Lossew in English) (10 May 1903 – 22 January 1942) was a Russian scientist and inventor
An English translatio M. A. Novikov ...
reported creation of the first LED in 1927.
[ English translation: ] His research was distributed in Soviet, German and British scientific journals, but no practical use was made of the discovery for several decades.
In 1936,
Georges Destriau
Georges Destriau (1 August 1903 - 20 January 1960) was a French physicist and early observer of electroluminescence.
Education and Research
In 1926 Destriau became an engineer at the École Centrale des Arts et Manufactures in Paris. Thereafter h ...
observed that electroluminescence could be produced when
zinc sulphide
Zinc sulfide (or zinc sulphide) is an inorganic compound with the chemical formula of ZnS. This is the main form of zinc found in nature, where it mainly occurs as the mineral sphalerite. Although this mineral is usually black because of various i ...
(ZnS) powder is suspended in an insulator and an alternating electrical field is applied to it. In his publications, Destriau often referred to luminescence as Losev-Light. Destriau worked in the laboratories of Madame
Marie Curie
Marie Salomea Skłodowska–Curie ( , , ; born Maria Salomea Skłodowska, ; 7 November 1867 – 4 July 1934) was a Polish and naturalized-French physicist and chemist who conducted pioneering research on radioactivity. She was the first ...
, also an early pioneer in the field of luminescence with research on
radium
Radium is a chemical element with the symbol Ra and atomic number 88. It is the sixth element in group 2 of the periodic table, also known as the alkaline earth metals. Pure radium is silvery-white, but it readily reacts with nitrogen (rather t ...
.
[McGraw-Hill Concise Encyclopedia of Physics: electroluminescence. (n.d.) McGraw-Hill Concise Encyclopedia of Physics. (2002).]
Hungarian
Zoltán Bay Zoltán () is a Hungarian masculine given name. The name days for this name are 8 March and 23 June in Hungary, and 7 April in Slovakia.
Zoltána is the feminine version.
Notable people
* Zoltán of Hungary
* Zoltan Bathory, guitarist of heavy ...
together with
György Szigeti György Szigeti (29 January 1905 – 27 November 1978),
"Fizikai Szemle 1999/5 - Zsolt Bor: Optics by Hungarians" (with Zoltan Bay),
József Attila University, Szeged, Hungary, 1999, webpage:
KFKI-Hungary-Bor
also known as Gyorgy Szige ...
pre-empted
LED lighting
An LED lamp or LED light bulb is an electric light that produces light using light-emitting diodes (LEDs). LED lamps are significantly more energy-efficient than equivalent incandescent lamps
and can be significantly more efficient than mos ...
in Hungary in 1939 by patenting a lighting device based on silicon carbide, with an option on boron carbide, that emitted white, yellowish white, or greenish white depending on impurities present.
Kurt Lehovec
Kurt Lehovec (June 12, 1918 – February 17, 2012) was one of the pioneers of the integrated circuit. While also pioneering the photo-voltaic effect, light-emitting diodes and History of the battery#Invention, lithium batteries, he innovated ...
, Carl Accardo, and Edward Jamgochian explained these first LEDs in 1951 using an apparatus employing
SiC
The Latin adverb ''sic'' (; "thus", "just as"; in full: , "thus was it written") inserted after a quoted word or passage indicates that the quoted matter has been transcribed or translated exactly as found in the source text, complete with any e ...
crystals with a current source of a battery or a pulse generator and with a comparison to a variant, pure, crystal in 1953.
Rubin Braunstein
Rubin Braunstein (1922–2018) was an American physicist and educator. In 1955 he published the first measurements of light emission by semiconductor diodes made from crystals of gallium arsenide (GaAs), gallium antimonide (GaSb), and indium pho ...
of the
Radio Corporation of America
The RCA Corporation was a major American electronics company, which was founded as the Radio Corporation of America in 1919. It was initially a patent trust owned by General Electric (GE), Westinghouse, AT&T Corporation and United Fruit Comp ...
reported on infrared emission from
gallium arsenide
Gallium arsenide (GaAs) is a III-V direct band gap semiconductor with a Zincblende (crystal structure), zinc blende crystal structure.
Gallium arsenide is used in the manufacture of devices such as microwave frequency integrated circuits, monoli ...
(GaAs) and other semiconductor alloys in 1955. Braunstein observed infrared emission generated by simple diode structures using
gallium antimonide
Gallium antimonide (GaSb) is a semiconducting compound of gallium and antimony of the III-V family. It has a lattice constant of about 0.61 nm. It has a band gap of 0.67 eV.
History
The intermetallic compound GaSb was first prepared in 1926 by Vi ...
(GaSb), GaAs,
indium phosphide
Indium phosphide (InP) is a binary semiconductor composed of indium and phosphorus. It has a face-centered cubic ("zincblende") crystal structure, identical to that of GaAs and most of the III-V semiconductors.
Manufacturing
Indium phosphide ca ...
(InP), and
silicon-germanium (SiGe) alloys at room temperature and at 77
kelvin
The kelvin, symbol K, is the primary unit of temperature in the International System of Units (SI), used alongside its prefixed forms and the degree Celsius. It is named after the Belfast-born and University of Glasgow-based engineer and phys ...
s.
In 1957, Braunstein further demonstrated that the rudimentary devices could be used for non-radio communication across a short distance. As noted by Kroemer Braunstein "…had set up a simple optical communications link: Music emerging from a record player was used via suitable electronics to modulate the forward current of a GaAs diode. The emitted light was detected by a PbS diode some distance away. This signal was fed into an audio amplifier and played back by a loudspeaker. Intercepting the beam stopped the music. We had a great deal of fun playing with this setup." This setup presaged the use of LEDs for
optical communication
Optical communication, also known as optical telecommunication, is communication at a distance using light to carry information. It can be performed visually or by using electronic devices. The earliest basic forms of optical communication date b ...
applications.
In September 1961, while working at
Texas Instruments
Texas Instruments Incorporated (TI) is an American technology company headquartered in Dallas, Texas, that designs and manufactures semiconductors and various integrated circuits, which it sells to electronics designers and manufacturers globall ...
in
Dallas
Dallas () is the List of municipalities in Texas, third largest city in Texas and the largest city in the Dallas–Fort Worth metroplex, the List of metropolitan statistical areas, fourth-largest metropolitan area in the United States at 7.5 ...
,
Texas
Texas (, ; Spanish language, Spanish: ''Texas'', ''Tejas'') is a state in the South Central United States, South Central region of the United States. At 268,596 square miles (695,662 km2), and with more than 29.1 million residents in 2 ...
,
James R. Biard
James Robert Biard (May 20, 1931 – September 23, 2022) was an American electrical engineer and inventor who held 73 U.S. patents. Some of his more significant patents include the first infrared light-emitting diode (LED), the optical isolato ...
and Gary Pittman discovered near-infrared (900 nm) light emission from a
tunnel diode
A tunnel diode or Esaki diode is a type of semiconductor diode that has effectively "negative resistance" due to the quantum mechanical effect called tunneling. It was invented in August 1957 by Leo Esaki, Yuriko Kurose, and Takashi Suzuki ...
they had constructed on a GaAs substrate.
By October 1961, they had demonstrated efficient light emission and signal coupling between a GaAs p-n junction light emitter and an electrically isolated semiconductor photodetector. On August 8, 1962, Biard and Pittman filed a patent titled "Semiconductor Radiant Diode" based on their findings, which described a zinc-diffused
p–n junction
A p–n junction is a boundary or interface between two types of semiconductor materials, p-type and n-type, inside a single crystal of semiconductor. The "p" (positive) side contains an excess of holes, while the "n" (negative) side contains ...
LED with a spaced
cathode
A cathode is the electrode from which a conventional current leaves a polarized electrical device. This definition can be recalled by using the mnemonic ''CCD'' for ''Cathode Current Departs''. A conventional current describes the direction in whi ...
contact to allow for efficient emission of infrared light under
forward bias. After establishing the priority of their work based on engineering notebooks predating submissions from
G.E. Labs,
RCA
The RCA Corporation was a major American electronics company, which was founded as the Radio Corporation of America in 1919. It was initially a patent trust owned by General Electric (GE), Westinghouse, AT&T Corporation and United Fruit Comp ...
Research Labs,
IBM Research Labs,
Bell Labs
Nokia Bell Labs, originally named Bell Telephone Laboratories (1925–1984),
then AT&T Bell Laboratories (1984–1996)
and Bell Labs Innovations (1996–2007),
is an American industrial research and scientific development company owned by mult ...
, and
Lincoln Lab
The MIT Lincoln Laboratory, located in Lexington, Massachusetts, is a United States Department of Defense federally funded research and development center chartered to apply advanced technology to problems of national security. Research and de ...
at
MIT
The Massachusetts Institute of Technology (MIT) is a private land-grant research university in Cambridge, Massachusetts. Established in 1861, MIT has played a key role in the development of modern technology and science, and is one of the mo ...
, the
U.S. patent office
The United States Patent and Trademark Office (USPTO) is an agency in the U.S. Department of Commerce that serves as the national patent office and trademark registration authority for the United States. The USPTO's headquarters are in Alexan ...
issued the two inventors the patent for the GaAs infrared light-emitting diode (U.S. Paten
US3293513, the first practical LED.
Immediately after filing the patent,
Texas Instruments
Texas Instruments Incorporated (TI) is an American technology company headquartered in Dallas, Texas, that designs and manufactures semiconductors and various integrated circuits, which it sells to electronics designers and manufacturers globall ...
(TI) began a project to manufacture infrared diodes. In October 1962, TI announced the first commercial LED product (the SNX-100), which employed a pure GaAs crystal to emit an 890 nm light output.
In October 1963, TI announced the first commercial hemispherical LED, the SNX-110.
The first visible-spectrum (red) LED was demonstrated by J. W. Allen and R. J. Cherry in late 1961 at the SERL in Baldock, UK. This work was reported in the ''Journal of Physics and Chemistry of Solids'', Volume 23, Issue 5, May 1962, pages 509–511. Another early device was demonstrated by
Nick Holonyak
Nick Holonyak Jr. ( ; November 3, 1928September 18, 2022) was an American engineer and educator. He is noted particularly for his 1962 invention and first demonstration of a semiconductor laser diode that emitted visible light. This device was t ...
on October 9, 1962, while he was working for
General Electric
General Electric Company (GE) is an American multinational conglomerate founded in 1892, and incorporated in New York state and headquartered in Boston. The company operated in sectors including healthcare, aviation, power, renewable energ ...
in
Syracuse, New York
Syracuse ( ) is a City (New York), city in and the county seat of Onondaga County, New York, Onondaga County, New York, United States. It is the fifth-most populous city in the state of New York following New York City, Buffalo, New York, Buffa ...
. Holonyak and Bevacqua reported this LED in the journal ''Applied Physics Letters'' on December 1, 1962.
M. George Craford M. George Craford (born December 29, 1938) is an American electrical engineer known for his work in Light Emitting Diodes (LEDs).
Raised in an Iowa farming community, he studied physics at the University of Iowa, where he earned his BA in 1961. ...
, a former graduate student of Holonyak, invented the first yellow LED and improved the brightness of red and red-orange LEDs by a factor of ten in 1972. In 1976, T. P. Pearsall designed the first high-brightness, high-efficiency LEDs for optical fiber telecommunications by inventing new semiconductor materials specifically adapted to optical fiber transmission wavelengths.
Initial commercial development
The first commercial visible-wavelength LEDs were commonly used as replacements for
incandescent
Incandescence is the emission of electromagnetic radiation (including visible light) from a hot body as a result of its high temperature. The term derives from the Latin verb ''incandescere,'' to glow white. A common use of incandescence is ...
and
neon indicator lamps, and in
seven-segment display
A seven-segment display is a form of electronic display device for displaying decimal numerals that is an alternative to the more complex dot matrix displays.
Seven-segment displays are widely used in digital clocks, electronic meters, basic ...
s, first in expensive equipment such as laboratory and electronics test equipment, then later in such appliances as calculators, TVs, radios, telephones, as well as watches (see list of
signal uses).
Until 1968, visible and infrared LEDs were extremely costly, in the order of
US$
The United States dollar (symbol: $; code: USD; also abbreviated US$ or U.S. Dollar, to distinguish it from other dollar-denominated currencies; referred to as the dollar, U.S. dollar, American dollar, or colloquially buck) is the official ...
200 per unit, and so had little practical use.
Hewlett-Packard
The Hewlett-Packard Company, commonly shortened to Hewlett-Packard ( ) or HP, was an American multinational information technology company headquartered in Palo Alto, California. HP developed and provided a wide variety of hardware components ...
(HP) was engaged in
research and development
Research and development (R&D or R+D), known in Europe as research and technological development (RTD), is the set of innovative activities undertaken by corporations or governments in developing new services or products, and improving existi ...
(R&D) on practical LEDs between 1962 and 1968, by a research team under Howard C. Borden, Gerald P. Pighini at HP Associates and
HP Labs
HP Labs is the exploratory and advanced research group for HP Inc. HP Labs' headquarters is in Palo Alto, California and the group has research and development facilities in Bristol, UK. The development of programmable desktop calculators, ink ...
.
During this time HP collaborated with
Monsanto Company
The Monsanto Company () was an American agrochemical and agricultural biotechnology corporation founded in 1901 and headquartered in Creve Coeur, Missouri. Monsanto's best known product is Roundup (herbicide), Roundup, a glyphosate-based herbic ...
on developing the first usable LED products.
The first usable LED products were HP's
LED display
A LED display is a flat panel display that uses an array of light-emitting diodes as pixels for a video display. Their brightness allows them to be used outdoors where they are visible in the sun for store signs and billboards. In recent y ...
and Monsanto's
LED indicator lamp, both launched in 1968.
Monsanto was the first organization to mass-produce visible LEDs, using GaAsP in 1968 to produce red LEDs suitable for indicators.
Monsanto had previously offered to supply HP with GaAsP, but HP decided to grow its own GaAsP.
In February 1969, Hewlett-Packard introduced the HP Model 5082-7000 Numeric Indicator, the first LED device to use
integrated circuit
An integrated circuit or monolithic integrated circuit (also referred to as an IC, a chip, or a microchip) is a set of electronic circuits on one small flat piece (or "chip") of semiconductor material, usually silicon. Large numbers of tiny ...
(integrated
LED circuit
In electronics, an LED circuit or LED driver is an electrical circuit used to power a light-emitting diode (LED). The circuit must provide sufficient current to light the LED at the required brightness, but must limit the current to prevent damag ...
) technology.
It was the first intelligent LED display, and was a revolution in
digital display
A display device is an output device for presentation of information in visual or tactile form (the latter used for example in tactile electronic displays for blind people). When the input information that is supplied has an electrical signal the ...
technology, replacing the
Nixie tube
A Nixie tube ( ), or cold cathode display, is an electronic device used for displaying numerals or other information using glow discharge.
The glass tube contains a wire-mesh anode and multiple cathodes, shaped like numerals or other symbols ...
and becoming the basis for later LED displays.
In the 1970s, commercially successful LED devices at less than five cents each were produced by Fairchild Optoelectronics. These devices employed compound
semiconductor chip
An integrated circuit or monolithic integrated circuit (also referred to as an IC, a chip, or a microchip) is a set of electronic circuits on one small flat piece (or "chip") of semiconductor material, usually silicon. Large numbers of tiny M ...
s fabricated with the
planar process
The planar process is a manufacturing process used in the semiconductor industry to build individual components of a transistor, and in turn, connect those transistors together. It is the primary process by which silicon integrated circuit chips a ...
(developed by
Jean Hoerni
Jean Amédée Hoerni (September 26, 1924 – January 12, 1997) was a Swiss-American engineer. He was a silicon transistor pioneer, and a member of the " traitorous eight". He developed the planar process, an important technology for reliably fa ...
, ). The combination of planar processing for
chip fabrication
Semiconductor device fabrication is the process used to manufacture semiconductor devices, typically integrated circuit (IC) chips such as modern computer processors, microcontrollers, and memory chips such as NAND flash and DRAM that are pres ...
and innovative
packaging
Packaging is the science, art and technology of enclosing or protecting products for distribution, storage, sale, and use. Packaging also refers to the process of designing, evaluating, and producing packages. Packaging can be described as a co ...
methods enabled the team at Fairchild led by optoelectronics pioneer Thomas Brandt to achieve the needed cost reductions. LED producers continue to use these methods.
The early red LEDs were bright enough only for use as indicators, as the light output was not enough to illuminate an area. Readouts in calculators were so small that plastic lenses were built over each digit to make them legible. Later, other colors became widely available and appeared in appliances and equipment.
Early LEDs were packaged in metal cases similar to those of transistors, with a glass window or lens to let the light out. Modern indicator LEDs are packed in transparent molded plastic cases, tubular or rectangular in shape, and often tinted to match the device color. Infrared devices may be dyed, to block visible light. More complex packages have been adapted for efficient heat dissipation in
high-power LEDs. Surface-mounted LEDs further reduce the package size. LEDs intended for use with
fiber optics
An optical fiber, or optical fibre in Commonwealth English, is a flexible, transparent fiber made by drawing glass (silica) or plastic to a diameter slightly thicker than that of a human hair. Optical fibers are used most often as a means to ...
cables may be provided with an optical connector.
Blue LED
The first blue-violet LED using magnesium-doped
gallium nitride was made at
Stanford University
Stanford University, officially Leland Stanford Junior University, is a private research university in Stanford, California. The campus occupies , among the largest in the United States, and enrolls over 17,000 students. Stanford is consider ...
in 1972 by Herb Maruska and Wally Rhines, doctoral students in materials science and engineering. At the time Maruska was on leave from
RCA Laboratories
The RCA Corporation was a major American electronics company, which was founded as the Radio Corporation of America in 1919. It was initially a patent trust owned by General Electric (GE), Westinghouse, AT&T Corporation and United Fruit Comp ...
, where he collaborated with Jacques Pankove on related work. In 1971, the year after Maruska left for Stanford, his RCA colleagues Pankove and Ed Miller demonstrated the first blue electroluminescence from zinc-doped gallium nitride, though the subsequent device Pankove and Miller built, the first actual gallium nitride light-emitting diode, emitted green light. In 1974 the
U.S. Patent Office
The United States Patent and Trademark Office (USPTO) is an agency in the U.S. Department of Commerce that serves as the national patent office and trademark registration authority for the United States. The USPTO's headquarters are in Alexan ...
awarded Maruska, Rhines and Stanford professor David Stevenson a patent for their work in 1972 (U.S. Paten
US3819974 A. Today, magnesium-doping of gallium nitride remains the basis for all commercial blue LEDs and
laser diode
file:Laser diode chip.jpg, The laser diode chip removed and placed on the eye of a needle for scale
A laser diode (LD, also injection laser diode or ILD, or diode laser) is a semiconductor device similar to a light-emitting diode in which a di ...
s. In the early 1970s, these devices were too dim for practical use, and research into gallium nitride devices slowed.
In August 1989,
Cree
The Cree ( cr, néhinaw, script=Latn, , etc.; french: link=no, Cri) are a Indigenous peoples of the Americas, North American Indigenous people. They live primarily in Canada, where they form one of the country's largest First Nations in Canada ...
introduced the first commercially available blue LED based on the
indirect bandgap semiconductor, silicon carbide (SiC). SiC LEDs had very low efficiency, no more than about 0.03%, but did emit in the blue portion of the visible light spectrum.
In the late 1980s, key breakthroughs in GaN
epitaxial growth and
p-type doping ushered in the modern era of GaN-based
optoelectronic
Optoelectronics (or optronics) is the study and application of electronic devices and systems that find, detect and control light, usually considered a sub-field of photonics. In this context, ''light'' often includes invisible forms of radiatio ...
devices. Building upon this foundation,
Theodore Moustakas
Theodore D. Moustakas (born ) is a materials physicist. He holds the title of ''Distinguished Professor of Photonics and Optoelectronics'' at the Boston University Department of Electrical & Computer Engineering. He was named a Fellow of the Inst ...
at Boston University patented a method for producing high-brightness blue LEDs using a new two-step process in 1991.
Two years later, in 1993, high-brightness blue LEDs were demonstrated by
Shuji Nakamura
is a Japanese-born American electronic engineer and inventor specializing in the field of semiconductor technology, professor at the Materials Department of the College of Engineering, University of California, Santa Barbara (UCSB), and is regar ...
of
Nichia Corporation
is a Japanese chemical engineering and manufacturing company headquartered in Anan, Japan with global subsidiaries. It specializes in the manufacturing and distribution of phosphors, including light-emitting diodes (LEDs), laser diodes, batter ...
using a gallium nitride growth process.
In parallel,
Isamu Akasaki and
Hiroshi Amano
is a Japanese physicist, engineer and inventor specializing in the field of semiconductor technology. For his work he was awarded the 2014 Nobel Prize in Physics together with Isamu Akasaki and Shuji Nakamura for "the invention of efficient bl ...
of
Nagoya University
, abbreviated to or NU, is a Japanese national research university located in Chikusa-ku, Nagoya. It was the seventh Imperial University in Japan, one of the first five Designated National University and selected as a Top Type university of T ...
were working on developing the important
GaN
The word Gan or the initials GAN may refer to:
Places
*Gan, a component of Hebrew placenames literally meaning "garden"
China
* Gan River (Jiangxi)
* Gan River (Inner Mongolia),
* Gan County, in Jiangxi province
* Gansu, abbreviated ''Gā ...
deposition on
sapphire
Sapphire is a precious gemstone, a variety of the mineral corundum, consisting of aluminium oxide () with trace amounts of elements such as iron, titanium, chromium, vanadium, or magnesium. The name sapphire is derived via the Latin "sapphir ...
substrates and the demonstration of
p-type doping of GaN. This new development revolutionized LED lighting, making
high-power blue light sources practical, leading to the development of technologies like
Blu-ray
The Blu-ray Disc (BD), often known simply as Blu-ray, is a digital optical disc data storage format. It was invented and developed in 2005 and released on June 20, 2006 worldwide. It is designed to supersede the DVD format, and capable of sto ...
.
Nakamura was awarded the 2006
Millennium Technology Prize
The Millennium Technology Prize ( fi, Millennium-teknologiapalkinto) is one of the world's largest technology prizes. It is awarded once every two years by Technology Academy Finland, an independent foundation established by Finnish industries, ...
for his invention.
Nakamura,
Hiroshi Amano
is a Japanese physicist, engineer and inventor specializing in the field of semiconductor technology. For his work he was awarded the 2014 Nobel Prize in Physics together with Isamu Akasaki and Shuji Nakamura for "the invention of efficient bl ...
and
Isamu Akasaki were awarded the
Nobel Prize in Physics
)
, image = Nobel Prize.png
, alt = A golden medallion with an embossed image of a bearded man facing left in profile. To the left of the man is the text "ALFR•" then "NOBEL", and on the right, the text (smaller) "NAT•" then " ...
in 2014 for the invention of the blue LED.
In 2015, a US court ruled that three companies had infringed Moustakas's prior patent, and ordered them to pay licensing fees of not less than US$13 million.
In 1995, Alberto Barbieri at the
Cardiff University
, latin_name =
, image_name = Shield of the University of Cardiff.svg
, image_size = 150px
, caption = Coat of arms of Cardiff University
, motto = cy, Gwirionedd, Undod a Chytgord
, mottoeng = Truth, Unity and Concord
, established = 1 ...
Laboratory (GB) investigated the efficiency and reliability of high-brightness LEDs and demonstrated a "transparent contact" LED using
indium tin oxide (ITO) on (AlGaInP/GaAs).
In 2001 and 2002, processes for growing
gallium nitride (GaN) LEDs on
silicon
Silicon is a chemical element with the symbol Si and atomic number 14. It is a hard, brittle crystalline solid with a blue-grey metallic luster, and is a tetravalent metalloid and semiconductor. It is a member of group 14 in the periodic tab ...
were successfully demonstrated. In January 2012,
Osram
Osram Licht AG is a German company that makes electric lights, headquartered in Munich and Premstätten (Austria). Osram positions itself as a high-tech photonics company that is increasingly focusing on sensor technology, visualization and tre ...
demonstrated high-power InGaN LEDs grown on silicon substrates commercially, and GaN-on-silicon LEDs are in production at
Plessey Semiconductors. As of 2017, some manufacturers are using SiC as the substrate for LED production, but sapphire is more common, as it has the most similar properties to that of gallium nitride, reducing the need for patterning the sapphire wafer (patterned wafers are known as epi wafers).
Samsung
The Samsung Group (or simply Samsung) ( ko, 삼성 ) is a South Korean multinational manufacturing conglomerate headquartered in Samsung Town, Seoul, South Korea. It comprises numerous affiliated businesses, most of them united under the ...
, the
University of Cambridge
, mottoeng = Literal: From here, light and sacred draughts.
Non literal: From this place, we gain enlightenment and precious knowledge.
, established =
, other_name = The Chancellor, Masters and Schola ...
, and
Toshiba
, commonly known as Toshiba and stylized as TOSHIBA, is a Japanese multinational conglomerate corporation headquartered in Minato, Tokyo, Japan. Its diversified products and services include power, industrial and social infrastructure system ...
are performing research into GaN on Si LEDs. Toshiba has stopped research, possibly due to low yields. Some opt for
epitaxy
Epitaxy refers to a type of crystal growth or material deposition in which new crystalline layers are formed with one or more well-defined orientations with respect to the crystalline seed layer. The deposited crystalline film is called an epit ...
, which is difficult on
silicon
Silicon is a chemical element with the symbol Si and atomic number 14. It is a hard, brittle crystalline solid with a blue-grey metallic luster, and is a tetravalent metalloid and semiconductor. It is a member of group 14 in the periodic tab ...
, while others, like the University of Cambridge, choose a multi-layer structure, in order to reduce (crystal) lattice mismatch and different thermal expansion ratios, in order to avoid cracking of the LED chip at high temperatures (e.g. during manufacturing), reduce heat generation and increase luminous efficiency. Sapphire substrate patterning can be carried out with
nanoimprint lithography
Nanoimprint lithography (NIL) is a method of fabricating nanometer scale patterns. It is a simple nanolithography process with low cost, high throughput and high resolution. It creates patterns by mechanical deformation of imprint resist and subse ...
.
GaN-on-Si is difficult but desirable since it takes advantage of existing semiconductor manufacturing infrastructure. It allows for the wafer-level packaging of LED dies resulting in extremely small LED packages.
GaN is often deposited using
Metalorganic vapour-phase epitaxy
Metalorganic vapour-phase epitaxy (MOVPE), also known as organometallic vapour-phase epitaxy (OMVPE) or metalorganic chemical vapour deposition (MOCVD), is a chemical vapour deposition method used to produce single- or polycrystalline thin films. ...
(MOCVD), and it also utilizes
Lift-off
Liftoff, lift-off, or lift off may refer to:
Technology
* Lift-off (microtechnology), a fabrication technique
* Flame lift-off, a separation of flame from burner device
* Takeoff, the first moment of flight of an aerospace vehicle
* Reduction o ...
.
White LEDs and the illumination breakthrough
Even though white light can be created using individual red, green and blue LEDs, this results in poor
color rendering
The color rendering of a light source refers to its ability to reveal the colors of various objects faithfully (i.e. to produce illuminant metamerism) in comparison with an ideal or natural light source. Light sources with good color rendering are ...
, since only three narrow bands of wavelengths of light are being emitted. The attainment of high efficiency blue LEDs was quickly followed by the development of the first
white LED
White is the lightest color and is achromatic (having no hue). It is the color of objects such as snow, chalk, and milk, and is the opposite of black. White objects fully reflect and scatter all the visible wavelengths of light. White on ...
. In this device a :Ce (known as "
YAG" or Ce:YAG phosphor)
cerium
Cerium is a chemical element with the symbol Ce and atomic number 58. Cerium is a soft, ductile, and silvery-white metal that tarnishes when exposed to air. Cerium is the second element in the lanthanide series, and while it often shows the +3 o ...
-doped
phosphor
A phosphor is a substance that exhibits the phenomenon of luminescence; it emits light when exposed to some type of radiant energy. The term is used both for fluorescent or phosphorescent substances which glow on exposure to ultraviolet or vi ...
coating produces yellow light through
fluorescence
Fluorescence is the emission of light by a substance that has absorbed light or other electromagnetic radiation. It is a form of luminescence. In most cases, the emitted light has a longer wavelength, and therefore a lower photon energy, tha ...
. The combination of that yellow with remaining blue light appears white to the eye. Using different phosphors produces green and red light through fluorescence. The resulting mixture of red, green and blue is perceived as white light, with improved color rendering compared to wavelengths from the blue LED/YAG phosphor combination.
The first white LEDs were expensive and inefficient. The light output then increased
exponentially
Exponential may refer to any of several mathematical topics related to exponentiation, including:
*Exponential function, also:
**Matrix exponential, the matrix analogue to the above
* Exponential decay, decrease at a rate proportional to value
*Exp ...
. The latest research and development has been propagated by Japanese manufacturers such as
Panasonic
formerly between 1935 and 2008 and the first incarnation of between 2008 and 2022, is a major Japanese multinational corporation, multinational Conglomerate (company), conglomerate corporation, headquartered in Kadoma, Osaka, Kadoma, Osaka P ...
, and
Nichia
is a Japanese chemical engineering and manufacturing company headquartered in Anan, Japan with global subsidiaries. It specializes in the manufacturing and distribution of phosphors, including light-emitting diodes (LEDs), laser diodes, batter ...
, and by Korean and Chinese manufacturers such as
Samsung
The Samsung Group (or simply Samsung) ( ko, 삼성 ) is a South Korean multinational manufacturing conglomerate headquartered in Samsung Town, Seoul, South Korea. It comprises numerous affiliated businesses, most of them united under the ...
, Solstice, Kingsun, Hoyol and others. This trend in increased output has been called
Haitz's law
Haitz's law is an observation and forecast about the steady improvement, over many years, of light-emitting diodes (LEDs).
It claims that every decade, the cost per lumen (unit of useful light emitted) falls by a factor of 10, and the amount of l ...
after Roland Haitz.
Light output and efficiency of blue and near-ultraviolet LEDs rose and the cost of reliable devices fell. This led to relatively high-power white-light LEDs for illumination, which are replacing incandescent and fluorescent lighting.
Experimental white LEDs were demonstrated in 2014 to produce 303 lumens per watt of electricity (lm/W); some can last up to 100,000 hours. Commercially available LEDs have an efficiency of up to 223 lm/W as of 2018. A previous record of 135 lm/W was achieved by Nichia in 2010. Compared to incandescent bulbs, this is a huge increase in electrical efficiency, and even though LEDs are more expensive to purchase, overall lifetime cost is significantly cheaper than that of incandescent bulbs.
The LED chip is encapsulated inside a small, plastic, white mold. It can be encapsulated using resin (
polyurethane
Polyurethane (; often abbreviated PUR and PU) refers to a class of polymers composed of organic chemistry, organic units joined by carbamate (urethane) links. In contrast to other common polymers such as polyethylene and polystyrene, polyurethan ...
-based), silicone, or epoxy containing (powdered) Cerium-doped YAG phosphor. After allowing the solvents to evaporate, the LEDs are often tested, and placed on tapes for
SMT placement equipment
Surface-mount technology (SMT) component placement systems, commonly called pick-and-place machines or P&Ps, are robotic machines which are used to place surface-mount devices (SMDs) onto a printed circuit board (PCB). They are used for high s ...
for use in LED light bulb production. Encapsulation is performed after probing, dicing, die transfer from wafer to package, and wire bonding or flip chip mounting, perhaps using
Indium tin oxide, a transparent electrical conductor. In this case, the bond wire(s) are attached to the ITO film that has been deposited in the LEDs.
Some "remote phosphor" LED light bulbs use a single plastic cover with YAG phosphor for several blue LEDs, instead of using phosphor coatings on single-chip white LEDs.
The temperature of the phosphor during operation and how it is applied limits the size of an LED die.
Wafer-level packaged white LEDs allow for extremely small LEDs.
Physics of light production and emission
In a light emitting diode, the recombination of electrons and electron holes in a semiconductor produces light (be it infrared, visible or UV), a process called "
electroluminescence
Electroluminescence (EL) is an optical phenomenon, optical and electrical phenomenon, in which a material emits light in response to the passage of an electric current or to a strong electric field. This is distinct from black body light emissi ...
". The wavelength of the light depends on the energy
band gap of the semiconductors used. Since these materials have a high index of refraction, design features of the devices such as special optical coatings and die shape are required to efficiently emit light.
Unlike a
laser
A laser is a device that emits light through a process of optical amplification based on the stimulated emission of electromagnetic radiation. The word "laser" is an acronym for "light amplification by stimulated emission of radiation". The fir ...
, the light emitted from an LED is neither spectrally
coherent
Coherence, coherency, or coherent may refer to the following:
Physics
* Coherence (physics), an ideal property of waves that enables stationary (i.e. temporally and spatially constant) interference
* Coherence (units of measurement), a deri ...
nor even highly
monochromatic
A monochrome or monochromatic image, object or color scheme, palette is composed of one color (or lightness, values of one color). Images using only Tint, shade and tone, shades of grey are called grayscale (typically digital) or Black and wh ...
. Its
spectrum
A spectrum (plural ''spectra'' or ''spectrums'') is a condition that is not limited to a specific set of values but can vary, without gaps, across a continuum. The word was first used scientifically in optics to describe the rainbow of colors i ...
is sufficiently narrow that it appears to the
human eye
The human eye is a sensory organ, part of the sensory nervous system, that reacts to visible light and allows humans to use visual information for various purposes including seeing things, keeping balance, and maintaining circadian rhythm.
...
as a pure (
saturated
Saturation, saturated, unsaturation or unsaturated may refer to:
Chemistry
* Saturation, a property of organic compounds referring to carbon-carbon bonds
** Saturated and unsaturated compounds
**Degree of unsaturation
** Saturated fat or fatty ac ...
) color. Also unlike most lasers, its radiation is not
spatially coherent, so it cannot approach the very high
intensity
Intensity may refer to:
In colloquial use
*Strength (disambiguation)
*Amplitude
* Level (disambiguation)
* Magnitude (disambiguation)
In physical sciences
Physics
*Intensity (physics), power per unit area (W/m2)
*Field strength of electric, ma ...
characteristic of
laser
A laser is a device that emits light through a process of optical amplification based on the stimulated emission of electromagnetic radiation. The word "laser" is an acronym for "light amplification by stimulated emission of radiation". The fir ...
s.
Colors
By
selection of different semiconductor materials, single-color LEDs can be made that emit light in a narrow band of wavelengths from near-infrared through the visible spectrum and into the ultraviolet range. As the wavelengths become shorter, because of the larger band gap of these semiconductors, the operating voltage of the LED increases.
Blue and ultraviolet
Blue LEDs have an active region consisting of one or more InGaN
quantum well
A quantum well is a potential well with only discrete energy values.
The classic model used to demonstrate a quantum well is to confine particles, which were initially free to move in three dimensions, to two dimensions, by forcing them to occupy ...
s sandwiched between thicker layers of GaN, called cladding layers. By varying the relative In/Ga fraction in the InGaN quantum wells, the light emission can in theory be varied from violet to amber.
Aluminium gallium nitride Aluminium gallium nitride (AlGaN) is a semiconductor material. It is any alloy of aluminium nitride and gallium nitride.
The bandgap of AlxGa1−xN can be tailored from 3.4eV (xAl=0) to 6.2eV (xAl=1).
AlGaN is used to manufacture light-emitting d ...
(AlGaN) of varying Al/Ga fraction can be used to manufacture the cladding and quantum well layers for
ultraviolet
Ultraviolet (UV) is a form of electromagnetic radiation with wavelength from 10 nanometer, nm (with a corresponding frequency around 30 Hertz, PHz) to 400 nm (750 Hertz, THz), shorter than that of visible light, but longer than ...
LEDs, but these devices have not yet reached the level of efficiency and technological maturity of InGaN/GaN blue/green devices. If unalloyed GaN is used in this case to form the active quantum well layers, the device emits near-ultraviolet light with a peak wavelength centred around 365 nm. Green LEDs manufactured from the InGaN/GaN system are far more efficient and brighter than green LEDs produced with non-nitride material systems, but practical devices still exhibit efficiency too low for high-brightness applications.
With
AlGaN and
AlGaInN, even shorter wavelengths are achievable. Near-UV emitters at wavelengths around 360–395 nm are already cheap and often encountered, for example, as
black light
A blacklight, also called a UV-A light, Wood's lamp, or ultraviolet light, is a lamp that emits long-wave (UV-A) ultraviolet light and very little visible light. One type of lamp has a violet filter material, either on the bulb or in a separat ...
lamp replacements for inspection of anti-
counterfeiting
To counterfeit means to imitate something authentic, with the intent to steal, destroy, or replace the original, for use in illegal transactions, or otherwise to deceive individuals into believing that the fake is of equal or greater value tha ...
UV watermarks in documents and bank notes, and for
UV curing
UV curing (ultraviolet curing) is the process by which ultraviolet light is used to initiate a photochemical reaction that generates a crosslinked network of polymers. UV curing is adaptable to printing, coating, decorating, stereolithography, an ...
. Substantially more expensive, shorter-wavelength diodes are commercially available for wavelengths down to 240 nm. As the photosensitivity of microorganisms approximately matches the absorption spectrum of
DNA, with a peak at about 260 nm, UV LED emitting at 250–270 nm are expected in prospective disinfection and sterilization devices. Recent research has shown that commercially available UVA LEDs (365 nm) are already effective disinfection and sterilization devices.
UV-C wavelengths were obtained in laboratories using
aluminium nitride
Aluminium nitride ( Al N) is a solid nitride of aluminium. It has a high thermal conductivity of up to 321 W/(m·K) and is an electrical insulator. Its wurtzite phase (w-AlN) has a band gap of ~6 eV at room temperature and has a potenti ...
(210 nm),
boron nitride (215 nm)
and
diamond
Diamond is a Allotropes of carbon, solid form of the element carbon with its atoms arranged in a crystal structure called diamond cubic. Another solid form of carbon known as graphite is the Chemical stability, chemically stable form of car ...
(235 nm).
White
There are two primary ways of producing
white
White is the lightest color and is achromatic (having no hue). It is the color of objects such as snow, chalk, and milk, and is the opposite of black. White objects fully reflect and scatter all the visible wavelengths of light. White on ...
light-emitting diodes. One is to use individual LEDs that emit three
primary color
A set (mathematics), set of primary colors or primary colours (see American and British English spelling differences#-our, -or, spelling differences) consists of colorants or colored lights that can be mixed in varying amounts to produce a gamu ...
s—red, green and blue—and then mix all the colors to form white light. The other is to use a phosphor material to convert monochromatic light from a blue or UV LED to broad-spectrum white light, similar to a
fluorescent lamp
A fluorescent lamp, or fluorescent tube, is a low-pressure mercury-vapor gas-discharge lamp that uses fluorescence to produce visible light. An electric current in the gas excites mercury vapor, which produces short-wave ultraviolet lig ...
. The yellow phosphor is
cerium
Cerium is a chemical element with the symbol Ce and atomic number 58. Cerium is a soft, ductile, and silvery-white metal that tarnishes when exposed to air. Cerium is the second element in the lanthanide series, and while it often shows the +3 o ...
-doped
YAG crystals suspended in the package or coated on the LED. This YAG phosphor causes white LEDs to appear yellow when off, and the space between the crystals allow some blue light to pass through in LEDs with partial phosphor conversion. Alternatively, white LEDs may use other phosphors like manganese(IV)-doped
potassium fluorosilicate
Potassium fluorosilicate is a chemical compound with the chemical formula .
When doped with Potassium hexafluoromanganate(IV) () it forms a narrow band red producing phosphor, (often abbreviated PSF or KSF), of economic interest due to its applic ...
(PFS) or other engineered phosphors. PFS assists in red light generation, and is used in conjunction with conventional Ce:YAG phosphor. In LEDs with PFS phosphor, some blue light passes through the phosphors, the Ce:YAG phosphor converts blue light to green and red (yellow) light, and the PFS phosphor converts blue light to red light. The color, emission spectrum or color temperature of white phosphor converted and other phosphor converted LEDs can be controlled by changing the concentration of several phosphors that form a phosphor blend used in an LED package.
The 'whiteness' of the light produced is engineered to suit the human eye. Because of
metamerism, it is possible to have quite different spectra that appear white. The appearance of objects illuminated by that light may vary as the spectrum varies. This is the issue of color rendition, quite separate from color temperature. An orange or cyan object could appear with the wrong color and much darker as the LED or phosphor does not emit the wavelength it reflects. The best color rendition LEDs use a mix of phosphors, resulting in less efficiency and better color rendering.
The first white light-emitting diodes (LEDs) were offered for sale in the autumn of 1996.
RGB systems
Mixing red, green, and blue sources to produce white light needs electronic circuits to control the blending of the colors. Since LEDs have slightly different emission patterns, the color balance may change depending on the angle of view, even if the RGB sources are in a single package, so RGB diodes are seldom used to produce white lighting. Nonetheless, this method has many applications because of the flexibility of mixing different colors, and in principle, this mechanism also has higher quantum efficiency in producing white light.
There are several types of multicolor white LEDs:
di-,
tri-
Numeral or number prefixes are prefixes derived from numerals or occasionally other numbers. In English and many other languages, they are used to coin numerous series of words. For example:
* unicycle, bicycle, tricycle (1-cycle, 2-cycle, 3-cyc ...
, and
tetrachromatic
Tetrachromacy (from Greek ''tetra'', meaning "four" and ''chromo'', meaning "color") is the condition of possessing four independent channels for conveying color information, or possessing four types of cone cell in the eye. Organisms with tetr ...
white LEDs. Several key factors that play among these different methods include color stability,
color rendering
The color rendering of a light source refers to its ability to reveal the colors of various objects faithfully (i.e. to produce illuminant metamerism) in comparison with an ideal or natural light source. Light sources with good color rendering are ...
capability, and luminous efficacy. Often, higher efficiency means lower color rendering, presenting a trade-off between the luminous efficacy and color rendering. For example, the dichromatic white LEDs have the best luminous efficacy (120 lm/W), but the lowest color rendering capability. Although tetrachromatic white LEDs have excellent color rendering capability, they often have poor luminous efficacy. Trichromatic white LEDs are in between, having both good luminous efficacy (>70 lm/W) and fair color rendering capability.
One of the challenges is the development of more efficient green LEDs. The theoretical maximum for green LEDs is 683 lumens per watt but as of 2010 few green LEDs exceed even 100 lumens per watt. The blue and red LEDs approach their theoretical limits.
Multicolor LEDs offer a means to form light of different colors. Most
perceivable colors can be formed by mixing different amounts of three primary colors. This allows precise dynamic color control. Their emission power
decays exponentially with rising temperature,
resulting in a substantial change in color stability. Such problems inhibit industrial use. Multicolor LEDs without phosphors cannot provide good color rendering because each LED is a narrowband source. LEDs without phosphor, while a poorer solution for general lighting, are the best solution for displays, either backlight of LCD, or direct LED based pixels.
Dimming a multicolor LED source to match the characteristics of incandescent lamps is difficult because manufacturing variations, age, and temperature change the actual color value output. To emulate the appearance of dimming incandescent lamps may require a feedback system with color sensor to actively monitor and control the color.
Phosphor-based LEDs
This method involves
coating
A coating is a covering that is applied to the surface of an object, usually referred to as the Substrate (materials science), substrate. The purpose of applying the coating may be decorative, functional, or both. Coatings may be applied as liquid ...
LEDs of one color (mostly blue LEDs made of
InGaN
Indium gallium nitride (InGaN, ) is a semiconductor material made of a mix of gallium nitride (GaN) and indium nitride (InN). It is a ternary group III/group V direct bandgap semiconductor. Its bandgap can be tuned by varying the amount of indi ...
) with
phosphor
A phosphor is a substance that exhibits the phenomenon of luminescence; it emits light when exposed to some type of radiant energy. The term is used both for fluorescent or phosphorescent substances which glow on exposure to ultraviolet or vi ...
s of different colors to form white light; the resultant LEDs are called phosphor-based or phosphor-converted white LEDs (pcLEDs). A fraction of the blue light undergoes the Stokes shift, which transforms it from shorter wavelengths to longer. Depending on the original LED's color, various color phosphors are used. Using several phosphor layers of distinct colors broadens the emitted spectrum, effectively raising the
color rendering index (CRI).
Phosphor-based LEDs have efficiency losses due to heat loss from the
Stokes shift
__NOTOC__
Stokes shift is the difference (in energy, wavenumber or frequency units) between positions of the band maxima of the absorption and emission spectra (fluorescence and Raman being two examples) of the same electronic transition. It ...
and also other phosphor-related issues. Their luminous efficacies compared to normal LEDs depend on the spectral distribution of the resultant light output and the original wavelength of the LED itself. For example, the luminous efficacy of a typical YAG yellow phosphor based white LED ranges from 3 to 5 times the luminous efficacy of the original blue LED because of the human eye's greater sensitivity to yellow than to blue (as modeled in the
luminosity function
A luminous efficiency function or luminosity function represents the average spectral sensitivity of human visual perception of light. It is based on subjective judgements of which of a pair of different-colored lights is brighter, to descri ...
). Due to the simplicity of manufacturing, the phosphor method is still the most popular method for making high-intensity white LEDs. The design and production of a light source or light fixture using a monochrome emitter with phosphor conversion is simpler and cheaper than a complex
RGB
The RGB color model is an additive color model in which the red, green and blue primary colors of light are added together in various ways to reproduce a broad array of colors. The name of the model comes from the initials of the three additiv ...
system, and the majority of high-intensity white LEDs presently on the market are manufactured using phosphor light conversion.
Among the challenges being faced to improve the efficiency of LED-based white light sources is the development of more efficient phosphors. As of 2010, the most efficient yellow phosphor is still the YAG phosphor, with less than 10% Stokes shift loss. Losses attributable to internal optical losses due to re-absorption in the LED chip and in the LED packaging itself account typically for another 10% to 30% of efficiency loss. Currently, in the area of phosphor LED development, much effort is being spent on optimizing these devices to higher light output and higher operation temperatures. For instance, the efficiency can be raised by adapting better package design or by using a more suitable type of phosphor. Conformal coating process is frequently used to address the issue of varying phosphor thickness.
Some phosphor-based white LEDs encapsulate InGaN blue LEDs inside phosphor-coated epoxy. Alternatively, the LED might be paired with a remote phosphor, a preformed polycarbonate piece coated with the phosphor material. Remote phosphors provide more diffuse light, which is desirable for many applications. Remote phosphor designs are also more tolerant of variations in the LED emissions spectrum. A common yellow phosphor material is
cerium
Cerium is a chemical element with the symbol Ce and atomic number 58. Cerium is a soft, ductile, and silvery-white metal that tarnishes when exposed to air. Cerium is the second element in the lanthanide series, and while it often shows the +3 o ...
-
doped yttrium aluminium garnet
Yttrium aluminium garnet (YAG, Y3 Al5 O12) is a synthetic crystalline material of the garnet group. It is a cubic yttrium aluminium oxide phase, with other examples being YAlO3 (YAP) in a hexagonal or an orthorhombic, perovskite-like form, and ...
(Ce
3+:YAG).
White LEDs can also be made by
coating
A coating is a covering that is applied to the surface of an object, usually referred to as the Substrate (materials science), substrate. The purpose of applying the coating may be decorative, functional, or both. Coatings may be applied as liquid ...
near-ultraviolet (NUV) LEDs with a mixture of high-efficiency
europium
Europium is a chemical element with the symbol Eu and atomic number 63. Europium is the most reactive lanthanide by far, having to be stored under an inert fluid to protect it from atmospheric oxygen or moisture. Europium is also the softest lanth ...
-based phosphors that emit red and blue, plus copper and aluminium-doped zinc sulfide (ZnS:Cu, Al) that emits green. This is a method analogous to the way
fluorescent lamp
A fluorescent lamp, or fluorescent tube, is a low-pressure mercury-vapor gas-discharge lamp that uses fluorescence to produce visible light. An electric current in the gas excites mercury vapor, which produces short-wave ultraviolet lig ...
s work. This method is less efficient than blue LEDs with YAG:Ce phosphor, as the Stokes shift is larger, so more energy is converted to heat, but yields light with better spectral characteristics, which render color better. Due to the higher radiative output of the ultraviolet LEDs than of the blue ones, both methods offer comparable brightness. A concern is that UV light may leak from a malfunctioning light source and cause harm to human eyes or skin.
Other white LEDs
Another method used to produce experimental white light LEDs used no phosphors at all and was based on
homoepitaxially grown
zinc selenide
Zinc selenide (ZnSe) is a light-yellow, solid compound comprising zinc (Zn) and selenium (Se). It is an intrinsic semiconductor with a band gap of about 2.70 eV at . ZnSe rarely occurs in nature, and is found in the mineral that was named af ...
(ZnSe) on a ZnSe substrate that simultaneously emitted blue light from its active region and yellow light from the substrate.
A new style of wafers composed of gallium-nitride-on-silicon (GaN-on-Si) is being used to produce white LEDs using 200-mm silicon wafers. This avoids the typical costly
sapphire
Sapphire is a precious gemstone, a variety of the mineral corundum, consisting of aluminium oxide () with trace amounts of elements such as iron, titanium, chromium, vanadium, or magnesium. The name sapphire is derived via the Latin "sapphir ...
substrate in relatively small 100- or 150-mm wafer sizes.
[Next-Generation GaN-on-Si White LEDs Suppress Costs](_blank)
Electronic Design, 19 November 2013 The sapphire apparatus must be coupled with a mirror-like collector to reflect light that would otherwise be wasted. It was predicted that since 2020, 40% of all GaN LEDs are made with GaN-on-Si. Manufacturing large sapphire material is difficult, while large silicon material is cheaper and more abundant. LED companies shifting from using sapphire to silicon should be a minimal investment.
Organic light-emitting diodes (OLEDs)
In an organic light-emitting diode (
OLED
An organic light-emitting diode (OLED or organic LED), also known as organic electroluminescent (organic EL) diode, is a light-emitting diode (LED) in which the emissive electroluminescent layer is a film of organic compound that emits light i ...
), the
electroluminescent
Electroluminescence (EL) is an optical and electrical phenomenon, in which a material emits light in response to the passage of an electric current or to a strong electric field. This is distinct from black body light emission resulting from h ...
material composing the emissive layer of the diode is an
organic compound
In chemistry, organic compounds are generally any chemical compounds that contain carbon-hydrogen or carbon-carbon bonds. Due to carbon's ability to catenate (form chains with other carbon atoms), millions of organic compounds are known. The ...
. The organic material is electrically conductive due to the
delocalization of
pi electrons
In chemistry, pi bonds (π bonds) are covalent chemical bonds, in each of which two lobes of an orbital on one atom overlap with two lobes of an orbital on another atom, and in which this overlap occurs laterally. Each of these atomic orbitals ...
caused by
conjugation
Conjugation or conjugate may refer to:
Linguistics
* Grammatical conjugation, the modification of a verb from its basic form
* Emotive conjugation or Russell's conjugation, the use of loaded language
Mathematics
* Complex conjugation, the chang ...
over all or part of the molecule, and the material therefore functions as an
organic semiconductor
Organic semiconductors are solids whose building blocks are pi-bonded molecules or polymers made up by carbon and hydrogen atoms and – at times – heteroatoms such as nitrogen, sulfur and oxygen. They exist in the form of molecular crystals or ...
. The organic materials can be small organic
molecule
A molecule is a group of two or more atoms held together by attractive forces known as chemical bonds; depending on context, the term may or may not include ions which satisfy this criterion. In quantum physics, organic chemistry, and bioch ...
s in a
crystal
A crystal or crystalline solid is a solid material whose constituents (such as atoms, molecules, or ions) are arranged in a highly ordered microscopic structure, forming a crystal lattice that extends in all directions. In addition, macros ...
line
phase
Phase or phases may refer to:
Science
*State of matter, or phase, one of the distinct forms in which matter can exist
*Phase (matter), a region of space throughout which all physical properties are essentially uniform
* Phase space, a mathematic ...
, or
polymer
A polymer (; Greek '' poly-'', "many" + ''-mer'', "part")
is a substance or material consisting of very large molecules called macromolecules, composed of many repeating subunits. Due to their broad spectrum of properties, both synthetic a ...
s.
The potential advantages of OLEDs include thin, low-cost displays with a low driving voltage, wide viewing angle, and high contrast and color
gamut
In color reproduction, including computer graphics and photography, the gamut, or color gamut , is a certain ''complete subset'' of colors. The most common usage refers to the subset of colors which can be accurately represented in a given circ ...
.
Polymer LEDs have the added benefit of printable and
flexible displays. OLEDs have been used to make visual displays for portable electronic devices such as cellphones, digital cameras, lighting and televisions.
Types
LEDs are made in different packages for different applications. A single or a few LED junctions may be packed in one miniature device for use as an indicator or pilot lamp. An LED array may include controlling circuits within the same package, which may range from a simple resistor, blinking or color changing control, or an addressable controller for RGB devices. Higher-powered white-emitting devices will be mounted on heat sinks and will be used for illumination. Alphanumeric displays in dot matrix or bar formats are widely available. Special packages permit connection of LEDs to optical fibers for high-speed data communication links.
Miniature
These are mostly single-die LEDs used as indicators, and they come in various sizes from 2 mm to 8 mm,
through-hole
In electronics, through-hole technology (also spelled "thru-hole") is a manufacturing scheme in which leads on the components are inserted through holes drilled in printed circuit boards (PCB) and soldered to pads on the opposite side, either by ...
and
surface mount
Surface-mount technology (SMT), originally called planar mounting, is a method in which the electrical components are mounted directly onto the surface of a printed circuit board (PCB). An electrical component mounted in this manner is referred ...
packages. Typical current ratings range from around 1 mA to above 20 mA. Multiple LED dies attached to a flexible backing tape form an
LED strip light
An LED strip light (also known as an LED tape or ribbon light) is a flexible circuit board populated by surface mounted light-emitting diodes (SMD LEDs) and other components that usually comes with an adhesive backing. Traditionally, strip light ...
.
Common package shapes include round, with a domed or flat top, rectangular with a flat top (as used in bar-graph displays), and triangular or square with a flat top. The encapsulation may also be clear or tinted to improve contrast and viewing angle. Infrared devices may have a black tint to block visible light while passing infrared radiation.
Ultra-high-output LEDs are designed for viewing in direct sunlight.
5 V and 12 V LEDs are ordinary miniature LEDs that have a series resistor for direct connection to a 5V or 12V supply.
High-power
High-power LEDs (HP-LEDs) or high-output LEDs (HO-LEDs) can be driven at currents from hundreds of mA to more than an ampere, compared with the tens of mA for other LEDs. Some can emit over a thousand lumens. LED
power densities up to 300 W/cm
2 have been achieved. Since overheating is destructive, the HP-LEDs must be mounted on a heat sink to allow for heat dissipation. If the heat from an HP-LED is not removed, the device fails in seconds. One HP-LED can often replace an incandescent bulb in a
flashlight
A flashlight ( US, Canada) or torch ( UK, Australia) is a portable hand-held electric lamp. Formerly, the light source typically was a miniature incandescent light bulb, but these have been displaced by light-emitting diodes (LEDs) since the ...
, or be set in an array to form a powerful
LED lamp
An LED lamp or LED light bulb is an electric light that produces light using light-emitting diodes (LEDs). LED lamps are significantly more energy-efficient than equivalent incandescent lamps
and can be significantly more efficient than mos ...
.
Some well-known HP-LEDs in this category are the Nichia 19 series, Lumileds Rebel Led, Osram Opto Semiconductors Golden Dragon, and Cree X-lamp. As of September 2009, some HP-LEDs manufactured by Cree now exceed 105 lm/W.
Examples for
Haitz's law
Haitz's law is an observation and forecast about the steady improvement, over many years, of light-emitting diodes (LEDs).
It claims that every decade, the cost per lumen (unit of useful light emitted) falls by a factor of 10, and the amount of l ...
—which predicts an exponential rise in light output and efficacy of LEDs over time—are the CREE XP-G series LED, which achieved 105lm/W in 2009
and the Nichia 19 series with a typical efficacy of 140lm/W, released in 2010.
AC-driven
LEDs developed by Seoul Semiconductor can operate on AC power without a DC converter. For each half-cycle, part of the LED emits light and part is dark, and this is reversed during the next half-cycle. The efficiency of this type of HP-LED is typically 40lm/W. A large number of LED elements in series may be able to operate directly from line voltage. In 2009, Seoul Semiconductor released a high DC voltage LED, named 'Acrich MJT', capable of being driven from AC power with a simple controlling circuit. The low-power dissipation of these LEDs affords them more flexibility than the original AC LED design.
Application-specific variations
Flashing
Flashing LEDs are used as attention seeking indicators without requiring external electronics. Flashing LEDs resemble standard LEDs but they contain an integrated
voltage regulator
A voltage regulator is a system designed to automatically maintain a constant voltage. A voltage regulator may use a simple feed-forward design or may include negative feedback. It may use an electromechanical mechanism, or electronic components ...
and a
multivibrator
A multivibrator is an electronic circuit used to implement a variety of simple two-state devices such as relaxation oscillators, timers, and flip-flops. The first multivibrator circuit, the astable multivibrator oscillator, was invented by Henri A ...
circuit that causes the LED to flash with a typical period of one second. In diffused lens LEDs, this circuit is visible as a small black dot. Most flashing LEDs emit light of one color, but more sophisticated devices can flash between multiple colors and even fade through a color sequence using RGB color mixing.
Flashing SMD LEDs in the 0805 and other size formats have been available since early 2019.
Bi-color
Bi-color LEDs contain two different LED emitters in one case. There are two types of these. One type consists of two dies connected to the same two leads
antiparallel to each other. Current flow in one direction emits one color, and current in the opposite direction emits the other color. The other type consists of two dies with separate leads for both dies and another lead for common anode or cathode so that they can be controlled independently. The most common bi-color combination is
red/traditional green. Others include amber/traditional green, red/pure green, red/blue, and blue/pure green.
RGB tri-color
Tri-color LEDs contain three different LED emitters in one case. Each emitter is connected to a separate lead so they can be controlled independently. A four-lead arrangement is typical with one common lead (anode or cathode) and an additional lead for each color. Others have only two leads (positive and negative) and have a built-in electronic controller.
RGB
The RGB color model is an additive color model in which the red, green and blue primary colors of light are added together in various ways to reproduce a broad array of colors. The name of the model comes from the initials of the three additiv ...
LEDs consist of one red, one green, and one blue LED. By independently
adjusting each of the three, RGB LEDs are capable of producing a wide color gamut. Unlike dedicated-color LEDs, these do not produce pure wavelengths. Modules may not be optimized for smooth color mixing.
Decorative-multicolor
Decorative-multicolor LEDs incorporate several emitters of different colors supplied by only two lead-out wires. Colors are switched internally by varying the supply voltage.
Alphanumeric
Alphanumeric LEDs are available in
seven-segment,
starburst
MicroPro International Corporation was an American software company founded in 1978 in San Rafael, California. They are best known as the publisher of WordStar, a popular early word processor for personal computers.
History Founding and early su ...
, and
dot-matrix format. Seven-segment displays handle all numbers and a limited set of letters. Starburst displays can display all letters. Dot-matrix displays typically use 5×7 pixels per character. Seven-segment LED displays were in widespread use in the 1970s and 1980s, but rising use of
liquid crystal display
A liquid-crystal display (LCD) is a flat panel display, flat-panel display or other Electro-optic modulator, electronically modulated optical device that uses the light-modulating properties of liquid crystals combined with polarizers. Liqui ...
s, with their lower power needs and greater display flexibility, has reduced the popularity of numeric and alphanumeric LED displays.
Digital RGB
Digital RGB addressable LEDs contain their own "smart" control electronics. In addition to power and ground, these provide connections for data-in, data-out, clock and sometimes a strobe signal. These are connected in a
daisy chain
Daisy chain may refer to:
* Daisy chain, a garland created from daisy flowers
* Daisy chain (climbing), a type of strap
* Daisy chain (electrical engineering), a wiring scheme
* Daisy chain (fishing), a type of fishing lure
* Daisy chain (knot), ...
. Data sent to the first LED of the chain can control the brightness and color of each LED independently of the others. They are used where a combination of maximum control and minimum visible electronics are needed such as strings for Christmas and LED matrices. Some even have refresh rates in the kHz range, allowing for basic video applications. These devices are known by their part number (WS2812 being common) or a brand name such as
NeoPixel.
Filament
An
LED filament
A LED filament light bulb is a LED lamp which is designed to resemble a traditional incandescent light bulb with visible filaments for aesthetic and light distribution purposes, but with the high efficiency of light-emitting diodes (LEDs). It prod ...
consists of multiple LED chips connected in series on a common longitudinal substrate that forms a thin rod reminiscent of a traditional incandescent filament. These are being used as a low-cost decorative alternative for traditional light bulbs that are being phased out in many countries. The filaments use a rather high voltage, allowing them to work efficiently with mains voltages. Often a simple rectifier and capacitive current limiting are employed to create a low-cost replacement for a traditional light bulb without the complexity of the low voltage, high current converter that single die LEDs need. Usually, they are packaged in bulb similar to the lamps they were designed to replace, and filled with inert gas at slightly lower than ambient pressure to remove heat efficiently and prevent corrosion.
Chip-on-board arrays
Surface-mounted LEDs are frequently produced in
chip on board
Chip on board (COB) is a method of circuit board manufacturing in which the integrated circuits (e.g. microprocessors) are attached (wired, bonded directly) to a printed circuit board, and covered by a blob of epoxy. By eliminating the packagi ...
(COB) arrays, allowing better heat dissipation than with a single LED of comparable luminous output. The LEDs can be arranged around a cylinder, and are called "corn cob lights" because of the rows of yellow LEDs.
Considerations for use
Power sources
The current in an LED or other diodes rises exponentially with the applied voltage (see
Shockley diode equation
The ''Shockley diode equation'' or the ''diode law'', named after transistor co-inventor William Shockley of Bell Telephone Laboratories, gives the I–V (current-voltage) characteristic of an idealized diode in either forward or reverse bias (appl ...
), so a small change in voltage can cause a large change in current. Current through the LED must be regulated by an external circuit such as a
constant current source to prevent damage. Since most common power supplies are (nearly) constant-voltage sources, LED fixtures must include a power converter, or at least a current-limiting resistor. In some applications, the internal resistance of small batteries is sufficient to keep current within the LED rating.
Electrical polarity
Unlike a traditional incandescent lamp, an LED will light only when voltage is applied in the forward direction of the diode. No current flows and no light is emitted if voltage is applied in the reverse direction. If the reverse voltage exceeds the
breakdown voltage, which is typically hundreds of volts, a large current flows and the LED will be damaged. If the reverse current is sufficiently limited to avoid damage, the reverse-conducting LED is a useful
noise diode.
By definition, the energy band gap of any diode is higher when reverse-biased versus forward-biased. Because the band gap energy determines the wavelength of the light emitted, the color cannot be the same when reverse-biased. The reverse breakdown voltage is sufficiently high that the emitted wavelength cannot be similar enough to still be visible. Though dual-LED packages exist that contain a different color LED in each direction, it is not expected that any single LED can emit visible light when reverse-biased.
It is not known if any zener diode could exist that emits light only in reverse-bias mode. Uniquely, this type of LED would conduct when connected backwards.
Safety and health
Certain
blue LEDs and cool-white LEDs can exceed safe limits of the so-called
blue-light hazard
High-energy visible light (HEV light) is high-frequency, high-energy light in the violet/blue band from 400 to 450 nm in the visible spectrum,
which has a number of biological effects, including those on the eye.
HEV light may be a cause ...
as defined in eye safety specifications such as "ANSI/IESNA RP-27.1–05: Recommended Practice for Photobiological Safety for Lamp and Lamp Systems".
One study showed no evidence of a risk in normal use at domestic illuminance, and that caution is only needed for particular occupational situations or for specific populations. In 2006, the
International Electrotechnical Commission
The International Electrotechnical Commission (IEC; in French: ''Commission électrotechnique internationale'') is an international standards organization that prepares and publishes international standards for all electrical, electronic and r ...
published ''IEC 62471 Photobiological safety of lamps and lamp systems'', replacing the application of early laser-oriented standards for classification of LED sources.
While LEDs have the advantage over
fluorescent lamp
A fluorescent lamp, or fluorescent tube, is a low-pressure mercury-vapor gas-discharge lamp that uses fluorescence to produce visible light. An electric current in the gas excites mercury vapor, which produces short-wave ultraviolet lig ...
s, in that they do not contain
mercury
Mercury commonly refers to:
* Mercury (planet), the nearest planet to the Sun
* Mercury (element), a metallic chemical element with the symbol Hg
* Mercury (mythology), a Roman god
Mercury or The Mercury may also refer to:
Companies
* Merc ...
, they may contain other hazardous metals such as
lead
Lead is a chemical element with the symbol Pb (from the Latin ) and atomic number 82. It is a heavy metal that is denser than most common materials. Lead is soft and malleable, and also has a relatively low melting point. When freshly cu ...
and
arsenic
Arsenic is a chemical element with the symbol As and atomic number 33. Arsenic occurs in many minerals, usually in combination with sulfur and metals, but also as a pure elemental crystal. Arsenic is a metalloid. It has various allotropes, but ...
.
In 2016 the
American Medical Association
The American Medical Association (AMA) is a professional association and lobbying group of physicians and medical students. Founded in 1847, it is headquartered in Chicago, Illinois. Membership was approximately 240,000 in 2016.
The AMA's state ...
(AMA) issued a statement concerning the possible adverse influence of blueish
street light
A street light, light pole, lamp pole, lamppost, street lamp, light standard, or lamp standard is a raised source of light on the edge of a road or path. Similar lights may be found on a railway platform. When urban electric power distribution ...
ing on the
sleep-wake cycle
A circadian rhythm (), or circadian cycle, is a natural, internal process that regulates the sleep–wake cycle and repeats roughly every 24 hours. It can refer to any process that originates within an organism (i.e., endogenous) and responds to ...
of city-dwellers. Industry critics claim exposure levels are not high enough to have a noticeable effect.
Advantages
* Efficiency: LEDs emit more lumens per watt than incandescent light bulbs. The efficiency of LED lighting fixtures is not affected by shape and size, unlike fluorescent light bulbs or tubes.
* Color: LEDs can emit light of an intended color without using any color filters as traditional lighting methods need. This is more efficient and can lower initial costs.
* Size: LEDs can be very small (smaller than 2 mm
2) and are easily attached to printed circuit boards.
* Switch on time: LEDs light up extremely quickly. A typical red indicator LED achieves full brightness in under a
microsecond
A microsecond is a unit of time in the International System of Units (SI) equal to one millionth (0.000001 or 10−6 or ) of a second. Its symbol is μs, sometimes simplified to us when Unicode is not available.
A microsecond is equal to 1000 n ...
. LEDs used in communications devices can have even faster response times.
* Cycling: LEDs are ideal for uses subject to frequent on-off cycling, unlike incandescent and fluorescent lamps that fail faster when cycled often, or
high-intensity discharge lamps (HID lamps) that require a long time before restarting.
* Dimming: LEDs can very easily be
dimmed either by
pulse-width modulation
Pulse-width modulation (PWM), or pulse-duration modulation (PDM), is a method of reducing the average power delivered by an electrical signal, by effectively chopping it up into discrete parts. The average value of voltage (and current) fed ...
or lowering the forward current. This pulse-width modulation is why LED lights, particularly headlights on cars, when viewed on camera or by some people, seem to flash or flicker. This is a type of
stroboscopic effect
The stroboscopic effect is a visual phenomenon caused by aliasing that occurs when continuous rotational or other cyclic motion is represented by a series of short or instantaneous samples (as opposed to a continuous view) at a sampling rate clos ...
.
* Cool light: In contrast to most light sources, LEDs radiate very little heat in the form of IR that can cause damage to sensitive objects or fabrics. Wasted energy is dispersed as heat through the base of the LED.
* Slow failure: LEDs mainly fail by dimming over time, rather than the abrupt failure of incandescent bulbs.
[, US Department of Energy]
* Lifetime: LEDs can have a relatively long useful life. One report estimates 35,000 to 50,000 hours of useful life, though time to complete failure may be shorter or longer. Fluorescent tubes typically are rated at about 10,000 to 25,000 hours, depending partly on the conditions of use, and incandescent light bulbs at 1,000 to 2,000 hours. Several
DOE demonstrations have shown that reduced maintenance costs from this extended lifetime, rather than energy savings, is the primary factor in determining the payback period for an LED product.
* Shock resistance: LEDs, being solid-state components, are difficult to damage with external shock, unlike fluorescent and incandescent bulbs, which are fragile.
* Focus: The solid package of the LED can be designed to
focus its light. Incandescent and fluorescent sources often require an external reflector to collect light and direct it in a usable manner. For larger LED packages
total internal reflection
Total internal reflection (TIR) is the optical phenomenon in which waves arriving at the interface (boundary) from one medium to another (e.g., from water to air) are not refracted into the second ("external") medium, but completely reflected b ...
(TIR) lenses are often used to the same effect. When large quantities of light are needed, many light sources are usually deployed, which are difficult to focus or
collimate on the same target.
Disadvantages
* Temperature dependence: LED performance largely depends on the ambient temperature of the operating environment – or thermal management properties. Overdriving an LED in high ambient temperatures may result in overheating the LED package, eventually leading to device failure. An adequate
heat sink
A heat sink (also commonly spelled heatsink) is a passive heat exchanger that transfers the heat generated by an electronic or a mechanical device to a fluid medium, often air or a liquid coolant, where it is dissipated away from the device, th ...
is needed to maintain long life. This is especially important in automotive, medical, and military uses where devices must operate over a wide range of temperatures, and require low failure rates.
* Voltage sensitivity: LEDs must be supplied with a voltage above their
threshold voltage
The threshold voltage, commonly abbreviated as Vth or VGS(th), of a field-effect transistor (FET) is the minimum gate-to-source voltage (VGS) that is needed to create a conducting path between the source and drain terminals. It is an important s ...
and a current below their rating. Current and lifetime change greatly with a small change in applied voltage. They thus require a current-regulated supply (usually just a series resistor for indicator LEDs).
* Color rendition: Most cool-
white LEDs have spectra that differ significantly from a
black body radiator like the sun or an incandescent light. The spike at 460 nm and dip at 500 nm can make the color of objects
appear differently under cool-white LED illumination than sunlight or incandescent sources, due to
metamerism, red surfaces being rendered particularly poorly by typical phosphor-based cool-white LEDs. The same is true with green surfaces. The quality of color rendition of an LED is measured by the
Color Rendering Index (CRI).
* Area light source: Single LEDs do not approximate a
point source
A point source is a single identifiable ''localised'' source of something. A point source has negligible extent, distinguishing it from other source geometries. Sources are called point sources because in mathematical modeling, these sources can ...
of light giving a spherical light distribution, but rather a
lambertian distribution. So, LEDs are difficult to apply to uses needing a spherical light field. Different fields of light can be manipulated by the application of different optics or "lenses". LEDs cannot provide divergence below a few degrees.
*
Light pollution
Light pollution is the presence of unwanted, inappropriate, or excessive use of artificial Visible spectrum, lighting. In a descriptive sense, the term ''light pollution'' refers to the effects of any poorly implemented lighting, during the day ...
: Because
white LEDs emit more short wavelength light than sources such as high-pressure
sodium vapor lamp
A sodium-vapor lamp is a gas-discharge lamp that uses sodium in an excited state to produce light at a characteristic wavelength near 589 nm.
Two varieties of such lamps exist: low pressure and high pressure. Low-pressure sodium lamps are ...
s, the increased blue and green sensitivity of
scotopic vision
In the study of human visual perception, scotopic vision (or scotopia) is the vision of the eye under low-light conditions. The term comes from Greek ''skotos'', meaning "darkness", and ''-opia'', meaning "a condition of sight". In the human eye, ...
means that white LEDs used in outdoor lighting cause substantially more
sky glow
Skyglow (or sky glow) is the diffuse luminance of the night sky, apart from discrete light sources such as the Moon and visible individual stars. It is a commonly noticed aspect of light pollution. While usually referring to luminance arising ...
.
*
Efficiency droop: The efficiency of LEDs decreases as the
electric current
An electric current is a stream of charged particles, such as electrons or ions, moving through an electrical conductor or space. It is measured as the net rate of flow of electric charge through a surface or into a control volume. The moving pa ...
increases. Heating also increases with higher currents, which compromises LED lifetime. These effects put practical limits on the current through an LED in high power applications.
[Stevenson, Richard (August 2009]
The LED’s Dark Secret: Solid-state lighting will not supplant the lightbulb until it can overcome the mysterious malady known as droop
''IEEE Spectrum''
* Impact on wildlife: LEDs are much more attractive to insects than sodium-vapor lights, so much so that there has been speculative concern about the possibility of disruption to
food webs. LED lighting near beaches, particularly intense blue and white colors, can disorient turtle hatchlings and make them wander inland instead. The use of "turtle-safe lighting" LEDs that emit only at narrow portions of the visible spectrum is encouraged by conservancy groups in order to reduce harm.
* Use in winter conditions: Since they do not give off much heat in comparison to incandescent lights, LED lights used for traffic control can have snow obscuring them, leading to accidents.
* Thermal runaway: Parallel strings of LEDs will not share current evenly due to the manufacturing tolerances in their forward voltage. Running two or more strings from a single current source may result in LED failure as the devices warm up. If forward voltage binning is not possible, a circuit is required to ensure even distribution of current between parallel strands.
Applications
LED uses fall into five major categories:
* Visual signals where light goes more or less directly from the source to the human eye, to convey a message or meaning
*
Illumination where light is reflected from objects to give visual response of these objects
* Measuring and interacting with processes involving no human vision
* Narrow band light sensors where
LEDs operate in a reverse-bias mode and respond to incident light, instead of emitting light
* Indoor cultivation, including cannabis.
Indicators and signs
The
low energy consumption, low maintenance and small size of LEDs has led to uses as status indicators and displays on a variety of equipment and installations. Large-area
LED display
A LED display is a flat panel display that uses an array of light-emitting diodes as pixels for a video display. Their brightness allows them to be used outdoors where they are visible in the sun for store signs and billboards. In recent y ...
s are used as stadium displays, dynamic decorative displays, and
dynamic message sign
A variable- (also changeable-, electronic-, or dynamic-) message sign, often abbreviated VMS, CMS, or DMS, and in the UK known as a matrix sign,
is an electronic traffic sign often used on roadways to give travelers information about special ...
s on freeways. Thin, lightweight message displays are used at airports and railway stations, and as
destination displays for trains, buses, trams, and ferries.
One-color light is well suited for
traffic light
Traffic lights, traffic signals, or stoplights – known also as robots in South Africa are signalling devices positioned at intersection (road), road intersections, pedestrian crossings, and other locations in order to control flows of traf ...
s and signals,
exit signs,
emergency vehicle lighting, ships' navigation lights, and
LED-based Christmas lights
Because of their long life, fast switching times, and visibility in broad daylight due to their high output and focus, LEDs have been used in automotive brake lights and turn signals. The use in brakes improves safety, due to a great reduction in the time needed to light fully, or faster rise time, about 0.1 second faster than an incandescent bulb. This gives drivers behind more time to react. In a dual intensity circuit (rear markers and brakes) if the LEDs are not pulsed at a fast enough frequency, they can create a
phantom array, where ghost images of the LED appear if the eyes quickly scan across the array. White LED headlamps are beginning to appear. Using LEDs has styling advantages because LEDs can form much thinner lights than incandescent lamps with
parabolic reflector
A parabolic (or paraboloid or paraboloidal) reflector (or dish or mirror) is a reflective surface used to collect or project energy such as light, sound, or radio waves. Its shape is part of a circular paraboloid, that is, the surface generated ...
s.
Due to the relative cheapness of low output LEDs, they are also used in many temporary uses such as
glowsticks,
throwies
LED art is a form of light art constructed from light-emitting diodes. LEDs (light emitting diodes) are very inexpensive to purchase and have become a new way to make street art. Many artists who use LEDs are guerrilla artists, incorporating LEDs ...
, and the photonic
textile
Textile is an umbrella term that includes various fiber-based materials, including fibers, yarns, filaments, threads, different fabric types, etc. At first, the word "textiles" only referred to woven fabrics. However, weaving is not the ...
Lumalive. Artists have also used LEDs for
LED art
LED art is a form of light art constructed from light-emitting diodes. LEDs (light emitting diodes) are very inexpensive to purchase and have become a new way to make street art. Many artists who use LEDs are guerrilla artists, incorporating LEDs ...
.
Lighting
With the development of high-efficiency and high-power LEDs, it has become possible to use LEDs in lighting and illumination. To encourage the shift to
LED lamp
An LED lamp or LED light bulb is an electric light that produces light using light-emitting diodes (LEDs). LED lamps are significantly more energy-efficient than equivalent incandescent lamps
and can be significantly more efficient than mos ...
s and other high-efficiency lighting, in 2008 the
US Department of Energy
The United States Department of Energy (DOE) is an executive department of the U.S. federal government that oversees U.S. national energy policy and manages the research and development of nuclear power and nuclear weapons in the United State ...
created the
L Prize
The Energy Independence and Security Act of 2007 directed the United States Department of Energy to establish the L-Prize competition, designed to spur development of LED replacements for 60W incandescent lamps and PAR38 halogen lamps as well as an ...
competition. The
Philips
Koninklijke Philips N.V. (), commonly shortened to Philips, is a Dutch multinational conglomerate corporation that was founded in Eindhoven in 1891. Since 1997, it has been mostly headquartered in Amsterdam, though the Benelux headquarters i ...
Lighting North America LED bulb won the first competition on August 3, 2011, after successfully completing 18 months of intensive field, lab, and product testing.
Efficient lighting is needed for
sustainable architecture
Sustainable architecture is architecture that seeks to minimize the negative environmental impact of buildings through improved efficiency and moderation in the use of materials, energy, development space and the ecosystem at large. Sustainable ...
. As of 2011, some LED bulbs provide up to 150 lm/W and even inexpensive low-end models typically exceed 50 lm/W, so that a 6-watt LED could achieve the same results as a standard 40-watt incandescent bulb. The lower heat output of LEDs also reduces demand on
air conditioning
Air conditioning, often abbreviated as A/C or AC, is the process of removing heat from an enclosed space to achieve a more comfortable interior environment (sometimes referred to as 'comfort cooling') and in some cases also strictly controlling ...
systems. Worldwide, LEDs are rapidly adopted to displace less effective sources such as
incandescent lamps
An incandescent light bulb, incandescent lamp or incandescent light globe is an electric light with a wire filament heated until it glows. The filament is enclosed in a glass bulb with a vacuum or inert gas to protect the filament from oxidat ...
and
CFLs and reduce electrical energy consumption and its associated emissions. Solar powered LEDs are used as
street light
A street light, light pole, lamp pole, lamppost, street lamp, light standard, or lamp standard is a raised source of light on the edge of a road or path. Similar lights may be found on a railway platform. When urban electric power distribution ...
s and in
architectural lighting
Architectural lighting design is a field of work or study that is concerned with the design of lighting systems within the built environment, both interior and exterior. It can include manipulation and design of both daylight and electric ...
.
The mechanical robustness and long lifetime are used in
automotive lighting
The lighting system of a motor vehicle consists of lighting and signalling devices mounted to or integrated into the front, rear, sides, and in some cases the top of a motor vehicle. They illuminate the road ahead for the driver and increase t ...
on cars, motorcycles, and
bicycle lights.
LED street light
An LED street light or road light is an integrated light-emitting diode (LED) light fixture that is used for street lighting.
Design and style
An LED street light is an integrated light that uses light emitting diodes (LED) as its light sour ...
s are employed on poles and in parking garages. In 2007, the Italian village of
Torraca
Torraca is a town and ''comune'' in the province of Salerno in the Campania region of south-western Italy.
History
The LED city
In 2007, the town spent 280,000 euro to convert all its 700 street lamps to LED technology - a first in Europe - and t ...
was the first place to convert its street lighting to LEDs.
Cabin lighting on recent
Airbus
Airbus SE (; ; ; ) is a European Multinational corporation, multinational aerospace corporation. Airbus designs, manufactures and sells civil and military aerospace manufacturer, aerospace products worldwide and manufactures aircraft througho ...
and
Boeing
The Boeing Company () is an American multinational corporation that designs, manufactures, and sells airplanes, rotorcraft, rockets, satellites, telecommunications equipment, and missiles worldwide. The company also provides leasing and product ...
jetliners uses LED lighting. LEDs are also being used in airport and heliport lighting. LED airport fixtures currently include medium-intensity runway lights, runway centerline lights, taxiway centerline and edge lights, guidance signs, and obstruction lighting.
LEDs are also used as a light source for
DLP projectors, and to
backlight newer
LCD
A liquid-crystal display (LCD) is a flat-panel display or other electronically modulated optical device that uses the light-modulating properties of liquid crystals combined with polarizers. Liquid crystals do not emit light directly but in ...
television (referred to as
LED TV
An LED-backlit LCD is a liquid-crystal display that uses LEDs for backlighting instead of traditional cold cathode fluorescent (CCFL) backlighting. LED-backlit displays use the same TFT LCD (thin-film-transistor liquid-crystal display) technol ...
), computer monitor (including
laptop
A laptop, laptop computer, or notebook computer is a small, portable personal computer (PC) with a screen and alphanumeric keyboard. Laptops typically have a clam shell form factor with the screen mounted on the inside of the upper li ...
) and handheld device LCDs, succeeding older
CCFL-backlit LCDs although being superseded by
OLED
An organic light-emitting diode (OLED or organic LED), also known as organic electroluminescent (organic EL) diode, is a light-emitting diode (LED) in which the emissive electroluminescent layer is a film of organic compound that emits light i ...
screens. RGB LEDs raise the color gamut by as much as 45%. Screens for TV and computer displays can be made thinner using LEDs for backlighting.
LEDs are small, durable and need little power, so they are used in handheld devices such as
flashlight
A flashlight ( US, Canada) or torch ( UK, Australia) is a portable hand-held electric lamp. Formerly, the light source typically was a miniature incandescent light bulb, but these have been displaced by light-emitting diodes (LEDs) since the ...
s. LED
strobe light
A strobe light or stroboscopic lamp, commonly called a strobe, is a device used to produce regular flashes of light. It is one of a number of devices that can be used as a stroboscope. The word originated from the Ancient Greek ('), meaning ...
s or
camera flash
A flash is a device used in photography that produces a brief burst of light (typically lasting 1/1000 to 1/200 of a second) at a color temperature of about 5500 K to help illuminate a scene. A major purpose of a flash is to illuminate a ...
es operate at a safe, low voltage, instead of the 250+ volts commonly found in
xenon
Xenon is a chemical element with the symbol Xe and atomic number 54. It is a dense, colorless, odorless noble gas found in Earth's atmosphere in trace amounts. Although generally unreactive, it can undergo a few chemical reactions such as the ...
flashlamp-based lighting. This is especially useful in cameras on
mobile phone
A mobile phone, cellular phone, cell phone, cellphone, handphone, hand phone or pocket phone, sometimes shortened to simply mobile, cell, or just phone, is a portable telephone that can make and receive calls over a radio frequency link whil ...
s, where space is at a premium and bulky voltage-raising circuitry is undesirable.
LEDs are used for infrared illumination in
night vision
Night vision is the ability to see in low-light conditions, either naturally with scotopic vision or through a night-vision device. Night vision requires both sufficient spectral range and sufficient intensity range. Humans have poor night vi ...
uses including
security camera
A closed-circuit television camera can produce images or recordings for surveillance or other private purposes. Cameras can be either video cameras, or digital stills cameras. Walter Bruch was the inventor of the CCTV camera. The main purpose o ...
s. A ring of LEDs around a
video camera
A video camera is an optical instrument that captures videos (as opposed to a movie camera, which records images on film). Video cameras were initially developed for the television industry but have since become widely used for a variety of other ...
, aimed forward into a
retroreflective
A retroreflector (sometimes called a retroflector or cataphote) is a device or surface that reflects radiation (usually light) back to its source with minimum scattering. This works at a wide range of angle of incidence, unlike a planar mirror, ...
background, allows
chroma keying
Chroma key compositing, or chroma keying, is a visual-effects and post-production technique for compositing (layering) two images or video streams together based on colour hues ( chroma range). The technique has been used in many fields to r ...
in
video production
Video production is the process of producing video content for video. It is the equivalent of filmmaking, but with video recorded either as analog signals on videotape, digitally in video tape or as computer files stored on optical discs, hard dri ...
s.
LEDs are used in
mining operations
Mining is the extraction of valuable minerals or other geological materials from the Earth, usually from an ore body, lode, vein, seam, reef, or placer deposit. The exploitation of these deposits for raw material is based on the economic via ...
, as cap lamps to provide light for miners. Research has been done to improve LEDs for mining, to reduce glare and to increase illumination, reducing risk of injury to the miners.
LEDs are increasingly finding uses in medical and educational applications, for example as mood enhancement.
NASA
The National Aeronautics and Space Administration (NASA ) is an independent agency of the US federal government responsible for the civil space program, aeronautics research, and space research.
NASA was established in 1958, succeeding t ...
has even sponsored research for the use of LEDs to promote health for astronauts.
Data communication and other signalling
Light can be used to transmit data and analog signals. For example, lighting white LEDs can be used in systems assisting people to navigate in closed spaces while searching necessary rooms or objects.
Assistive listening devices in many theaters and similar spaces use arrays of infrared LEDs to send sound to listeners' receivers. Light-emitting diodes (as well as semiconductor lasers) are used to send data over many types of
fiber optic cable, from digital audio over
TOSLINK
TOSLINK (from ''Toshiba Link'') is a standardized optical fiber connector system. Also known generically as optical audio, its most common use is in consumer audio equipment (via a "digital optical" socket), where it carries a digital audio st ...
cables to the very high bandwidth fiber links that form the Internet backbone. For some time, computers were commonly equipped with
IrDA
The Infrared Data Association (IrDA) is an industry-driven interest group that was founded in 1994 by around 50 companies. IrDA provides specifications for a complete set of protocols for wireless infrared communications, and the name "IrDA" also ...
interfaces, which allowed them to send and receive data to nearby machines via infrared.
Because LEDs can
cycle on and off millions of times per second, very high data bandwidth can be achieved. For that reason,
Visible Light Communication
In telecommunications, visible light communication (VLC) is the use of visible light (light with a frequency of 400–800 THz/wavelength of 780–375 nm) as a transmission medium. VLC is a subset of optical wireless communications tec ...
(VLC) has been proposed as an alternative to the increasingly competitive radio bandwidth.
By operating in the visible part of the electromagnetic spectrum, data can be transmitted without occupying the frequencies of radio communications.
The main characteristic of VLC, lies on the incapacity of light to surpass physical opaque barriers. This characteristic can be considered a weak point of VLC, due to the susceptibility of interference from physical objects, but is also one of its many strengths: unlike radio waves, light waves are confined in the enclosed spaces they are transmitted, which enforces a physical safety barrier that requires a receptor of that signal to have physical access to the place where the transmission is occurring.
A promising application of VLC lies on the
Indoor Positioning System
An indoor positioning system (IPS) is a network of devices used to locate people or objects where GPS and other satellite technologies lack precision or fail entirely, such as inside multistory buildings, airports, alleys, parking garages, and und ...
(IPS), an analogous to the GPS built to operate in enclosed spaces where the satellite transmissions that allow the GPS operation are hard to reach. For instance, commercial buildings, shopping malls, parking garages, as well as subways and tunnel systems are all possible applications for VLC-based indoor positioning systems. Additionally, once the VLC lamps are able to perform lighting at the same time as data transmission, it can simply occupy the installation of traditional single-function lamps.
Other applications for VLC involve communication between appliances of a smart home or office. With increasing
IoT
The Internet of things (IoT) describes physical objects (or groups of such objects) with sensors, processing ability, software and other technologies that connect and exchange data with other devices and systems over the Internet or other com ...
-capable devices, connectivity through traditional radio waves might be subjected to interference. Light bulbs with VLC capabilities can transmit data and commands for such devices.
Machine vision systems
Machine vision
Machine vision (MV) is the technology and methods used to provide imaging-based automatic inspection and analysis for such applications as automatic inspection, process control, and robot guidance, usually in industry. Machine vision refers to m ...
systems often require bright and homogeneous illumination, so features of interest are easier to process. LEDs are often used.
Barcode scanners are the most common example of machine vision applications, and many of those scanners use red LEDs instead of lasers. Optical computer mice use LEDs as a light source for the miniature camera within the mouse.
LEDs are useful for machine vision because they provide a compact, reliable source of light. LED lamps can be turned on and off to suit the needs of the vision system, and the shape of the beam produced can be tailored to match the system's requirements.
Biological detection
The discovery of radiative recombination in Aluminum Gallium Nitride (AlGaN) alloys by
U.S. Army Research Laboratory
The U.S. Army Combat Capabilities Development Command Army Research Laboratory (DEVCOM ARL) is the U.S. Army's foundational research laboratory. ARL is headquartered at the Adelphi Laboratory Center (ALC) in Adelphi, Maryland. Its largest singl ...
(ARL) led to the conceptualization of UV light emitting diodes (LEDs) to be incorporated in light induced
fluorescence
Fluorescence is the emission of light by a substance that has absorbed light or other electromagnetic radiation. It is a form of luminescence. In most cases, the emitted light has a longer wavelength, and therefore a lower photon energy, tha ...
sensors used for biological agent detection.
In 2004, the
Edgewood Chemical Biological Center (ECBC) initiated the effort to create a biological detector named TAC-BIO. The program capitalized on Semiconductor UV Optical Sources (SUVOS) developed by the
Defense Advanced Research Projects Agency (DARPA)
The Defense Advanced Research Projects Agency (DARPA) is a research and development agency of the United States Department of Defense responsible for the development of emerging technologies for use by the military.
Originally known as the Adv ...
.
UV induced fluorescence is one of the most robust techniques used for rapid real time detection of biological aerosols.
The first UV sensors were lasers lacking in-field-use practicality. In order to address this,
DARPA
The Defense Advanced Research Projects Agency (DARPA) is a research and development agency of the United States Department of Defense responsible for the development of emerging technologies for use by the military.
Originally known as the Adv ...
incorporated SUVOS technology to create a low cost, small, lightweight, low power device. The TAC-BIO detector's response time was one minute from when it sensed a biological agent. It was also demonstrated that the detector could be operated unattended indoors and outdoors for weeks at a time.
Aerosolized biological particles will fluoresce and scatter light under a UV light beam. Observed fluorescence is dependent on the applied wavelength and the biochemical fluorophores within the biological agent. UV induced fluorescence offers a rapid, accurate, efficient and logistically practical way for biological agent detection. This is because the use of UV fluorescence is reagent less, or a process that does not require an added chemical to produce a reaction, with no consumables, or produces no chemical byproducts.
Additionally, TAC-BIO can reliably discriminate between threat and non-threat aerosols. It was claimed to be sensitive enough to detect low concentrations, but not so sensitive that it would cause false positives. The particle counting algorithm used in the device converted raw data into information by counting the photon pulses per unit of time from the fluorescence and scattering detectors, and comparing the value to a set threshold.
The original TAC-BIO was introduced in 2010, while the second generation TAC-BIO GEN II, was designed in 2015 to be more cost efficient as plastic parts were used. Its small, light-weight design allows it to be mounted to vehicles, robots, and unmanned aerial vehicles. The second generation device could also be utilized as an environmental detector to monitor air quality in hospitals, airplanes, or even in households to detect fungus and mold.
Other applications
The light from LEDs can be modulated very quickly so they are used extensively in
optical fiber
An optical fiber, or optical fibre in Commonwealth English, is a flexible, transparent fiber made by drawing glass (silica) or plastic to a diameter slightly thicker than that of a human hair. Optical fibers are used most often as a means to ...
and
free space optics
Free-space optical communication (FSO) is an optical communication technology that uses light propagating in free space to wirelessly transmit data for telecommunications or computer networking. "Free space" means air, outer space, vacuum, or ...
communications. This includes
remote control
In electronics, a remote control (also known as a remote or clicker) is an electronic device used to operate another device from a distance, usually wirelessly. In consumer electronics, a remote control can be used to operate devices such as ...
s, such as for television sets, where infrared LEDs are often used.
Opto-isolator
An opto-isolator (also called an optocoupler, photocoupler, or optical isolator) is an electronic component that transfers electrical Signal, signals between two isolated circuits by using light. Opto-isolators prevent high voltages from affecti ...
s use an LED combined with a
photodiode
A photodiode is a light-sensitive semiconductor diode. It produces current when it absorbs photons.
The package of a photodiode allows light (or infrared or ultraviolet radiation, or X-rays) to reach the sensitive part of the device. The packag ...
or
phototransistor
A photodiode is a light-sensitive semiconductor diode. It produces current when it absorbs photons.
The package of a photodiode allows light (or infrared or ultraviolet radiation, or X-rays) to reach the sensitive part of the device. The packa ...
to provide a signal path with electrical isolation between two circuits. This is especially useful in medical equipment where the signals from a low-voltage
sensor
A sensor is a device that produces an output signal for the purpose of sensing a physical phenomenon.
In the broadest definition, a sensor is a device, module, machine, or subsystem that detects events or changes in its environment and sends ...
circuit (usually battery-powered) in contact with a living organism must be electrically isolated from any possible electrical failure in a recording or monitoring device operating at potentially dangerous voltages. An optoisolator also lets information be transferred between circuits that do not share a common ground potential.
Many sensor systems rely on light as the signal source. LEDs are often ideal as a light source due to the requirements of the sensors. The Nintendo
Wii
The Wii ( ) is a home video game console developed and marketed by Nintendo. It was released on November 19, 2006, in North America and in December 2006 for most other Regional lockout, regions of the world. It is Nintendo's fifth major ho ...
's sensor bar uses infrared LEDs.
Pulse oximeter
Pulse oximetry is a noninvasive method for monitoring a person's oxygen saturation. Peripheral oxygen saturation (SpO2) readings are typically within 2% accuracy (within 4% accuracy in 95% of cases) of the more accurate (and invasive) reading of ...
s use them for measuring
oxygen saturation
Oxygen saturation (symbol SO2) is a relative measure of the concentration of oxygen that is dissolved or carried in a given medium as a proportion of the maximal concentration that can be dissolved in that medium at the given temperature. It ca ...
. Some flatbed scanners use arrays of RGB LEDs rather than the typical
cold-cathode fluorescent lamp
A fluorescent lamp, or fluorescent tube, is a low-pressure mercury-vapor gas-discharge lamp that uses fluorescence to produce visible light. An electric current in the gas excites mercury vapor, which produces short-wave ultraviolet ligh ...
as the light source. Having independent control of three illuminated colors allows the scanner to calibrate itself for more accurate color balance, and there is no need for warm-up. Further, its sensors only need be monochromatic, since at any one time the page being scanned is only lit by one color of light.
Since LEDs can also be used as photodiodes, they can be used for both photo emission and detection. This could be used, for example, in a
touchscreen
A touchscreen or touch screen is the assembly of both an input ('touch panel') and output ('display') device. The touch panel is normally layered on the top of an electronic visual display of an information processing system. The display is often ...
that registers reflected light from a finger or
stylus
A stylus (plural styli or styluses) is a writing utensil or a small tool for some other form of marking or shaping, for example, in pottery. It can also be a computer accessory that is used to assist in navigating or providing more precision w ...
. Many materials and biological systems are sensitive to, or dependent on, light.
Grow lights
A grow light is an electric light to help plants grow. Grow lights either attempt to provide a light spectrum similar to that of the sun, or to provide a spectrum that is more tailored to the needs of the plants being cultivated (typically a var ...
use LEDs to increase
photosynthesis
Photosynthesis is a process used by plants and other organisms to convert light energy into chemical energy that, through cellular respiration, can later be released to fuel the organism's activities. Some of this chemical energy is stored i ...
in
plant
Plants are predominantly photosynthetic eukaryotes of the kingdom Plantae. Historically, the plant kingdom encompassed all living things that were not animals, and included algae and fungi; however, all current definitions of Plantae exclud ...
s, and bacteria and viruses can be removed from water and other substances using UV LEDs for
sterilization.
LEDs of certain wavelengths have also been used for
light therapy
Light therapy, also called phototherapy or bright light therapy is intentional daily exposure to direct sunlight or similar-intensity artificial light in order to treat medical disorders, especially seasonal affective disorder (SAD) and circadi ...
treatment of
neonatal jaundice
Neonatal jaundice is a yellowish discoloration of the white part of the eyes and skin in a newborn baby due to high bilirubin levels. Other symptoms may include excess sleepiness or poor feeding. Complications may include seizures, cerebral pals ...
and
acne
Acne, also known as ''acne vulgaris'', is a long-term Cutaneous condition, skin condition that occurs when Keratinocyte, dead skin cells and Sebum, oil from the skin clog hair follicles. Typical features of the condition include comedo, black ...
.
UV LEDs, with spectra range of 220 nm to 395 nm, have other applications, such as
water
Water (chemical formula ) is an inorganic, transparent, tasteless, odorless, and nearly colorless chemical substance, which is the main constituent of Earth's hydrosphere and the fluids of all known living organisms (in which it acts as a ...
/
air purification, surface disinfection, glue curing, free-space
non-line-of-sight communication
Non-line-of-sight (NLOS) radio propagation occurs outside of the typical line-of-sight (LOS) between the transmitter and receiver, such as in ground reflections.
Near-line-of-sight (also NLOS) conditions refer to partial obstruction by a physica ...
, high performance liquid chromatography, UV curing dye printing,
phototherapy
Light therapy, also called phototherapy or bright light therapy is intentional daily exposure to direct sunlight or similar-intensity artificial light in order to treat medical disorders, especially seasonal affective disorder (SAD) and circadi ...
(295nm
Vitamin D
Vitamin D is a group of fat-soluble secosteroids responsible for increasing intestinal absorption of calcium, magnesium, and phosphate, and many other biological effects. In humans, the most important compounds in this group are vitamin D3 (c ...
, 308nm
Excimer lamp
An excimer lamp (or excilamp) is a source of ultraviolet light based on spontaneous emission of excimer (exciplex) molecules.
Introduction
Excimer lamps are quasimonochromatic light sources operating over a wide range of wavelengths in the ult ...
or laser replacement), medical/ analytical instrumentation, and DNA absorption.
LEDs have also been used as a medium-quality
voltage reference
A voltage reference is an electronic device that ideally produces a fixed (constant) voltage irrespective of the loading on the device, power supply variations, temperature changes, and the passage of time. Voltage references are used in power supp ...
in electronic circuits. The forward voltage drop (about 1.7 V for a red LED or 1.2V for an infrared) can be used instead of a
Zener diode
A Zener diode is a special type of diode designed to reliably allow current to flow "backwards" (inverted polarity) when a certain set reverse voltage, known as the ''Zener voltage'', is reached.
Zener diodes are manufactured with a great varie ...
in low-voltage regulators. Red LEDs have the flattest I/V curve above the knee. Nitride-based LEDs have a fairly steep I/V curve and are useless for this purpose. Although LED forward voltage is far more current-dependent than a Zener diode, Zener diodes with breakdown voltages below 3 V are not widely available.
The progressive miniaturization of low-voltage lighting technology, such as LEDs and OLEDs, suitable to incorporate into low-thickness materials has fostered experimentation in combining light sources and wall covering surfaces for interior walls in the form of
LED wallpaper
A light-emitting diode (LED) is a semiconductor device that emits light when current flows through it. Electrons in the semiconductor recombine with electron holes, releasing energy in the form of photons. The color of the light (cor ...
.
File:LED screen behind Tsach Zimroni in Tel Aviv Israel.jpg, A large LED display behind a disc jockey
A disc jockey, more commonly abbreviated as DJ, is a person who plays recorded music for an audience. Types of DJs include Radio personality, radio DJs (who host programs on music radio stations), club DJs (who work at a nightclub or music f ...
File:LED Digital Display.jpg, Seven-segment display
A seven-segment display is a form of electronic display device for displaying decimal numerals that is an alternative to the more complex dot matrix displays.
Seven-segment displays are widely used in digital clocks, electronic meters, basic ...
that can display four digits and points
File:LED panel and plants.jpg, LED panel light source used in an early experiment on potato
The potato is a starchy food, a tuber of the plant ''Solanum tuberosum'' and is a root vegetable native to the Americas. The plant is a perennial in the nightshade family Solanaceae.
Wild potato species can be found from the southern Unit ...
growth during Shuttle mission STS-73
STS-73 was a Space Shuttle program mission, during October–November 1995, on board the Space Shuttle ''Columbia''. The mission was the second mission for the United States Microgravity Laboratory. The crew, who spent 16 days in space, were bro ...
to investigate the potential for growing food on future long duration missions.
Research and development
Key challenges
LEDs require optimized efficiency to hinge on ongoing improvements such as phosphor materials and
quantum dot
Quantum dots (QDs) are semiconductor particles a few nanometres in size, having light, optical and electronics, electronic properties that differ from those of larger particles as a result of quantum mechanics. They are a central topic in nanote ...
s.
The process of down-conversion (the method by which materials convert more-energetic photons to different, less energetic colors) also needs improvement. For example, the red phosphors that are used today are thermally sensitive and need to be improved in that aspect so that they do not color shift and experience efficiency drop-off with temperature. Red phosphors could also benefit from a narrower spectral width to emit more lumens and becoming more efficient at converting photons.
In addition, work remains to be done in the realms of current efficiency droop, color shift, system reliability, light distribution, dimming, thermal management, and power supply performance.
Potential technology
Perovskite LEDs (PLEDs)
A new family of LEDs are based on the semiconductors called
perovskites
A perovskite is any material with a crystal structure following the formula ABX3, which was first discovered as the mineral called perovskite, which consists of calcium titanium oxide (CaTiO3). The mineral was first discovered in the Ural mou ...
. In 2018, less than four years after their discovery, the ability of perovskite LEDs (PLEDs) to produce light from electrons already rivaled those of the best performing
OLED
An organic light-emitting diode (OLED or organic LED), also known as organic electroluminescent (organic EL) diode, is a light-emitting diode (LED) in which the emissive electroluminescent layer is a film of organic compound that emits light i ...
s. They have a potential for cost-effectiveness as they can be processed from solution, a low-cost and low-tech method, which might allow perovskite-based devices that have large areas to be made with extremely low cost. Their efficiency is superior by eliminating non-radiative losses, in other words, elimination of
recombination pathways that do not produce photons; or by solving outcoupling problem (prevalent for thin-film LEDs) or balancing charge carrier injection to increase the
EQE (external quantum efficiency). The most up-to-date PLED devices have broken the performance barrier by shooting the EQE above 20%.
In 2018, Cao et al. and Lin et al. independently published two papers on developing perovskite LEDs with EQE greater than 20%, which made these two papers a mile-stone in PLED development. Their device have similar planar structure, i.e. the active layer (perovskite) is sandwiched between two electrodes. To achieve a high EQE, they not only reduced non-radiative recombination, but also utilized their own, subtly different methods to improve the EQE.
In the work of Cao ''et al.'',
researchers targeted the outcoupling problem, which is that the optical physics of thin-film LEDs causes the majority of light generated by the semiconductor to be trapped in the device. To achieve this goal, they demonstrated that solution-processed perovskites can spontaneously form submicrometre-scale crystal platelets, which can efficiently extract light from the device. These perovskites are formed via the introduction of
amino acid
Amino acids are organic compounds that contain both amino and carboxylic acid functional groups. Although hundreds of amino acids exist in nature, by far the most important are the alpha-amino acids, which comprise proteins. Only 22 alpha am ...
additives into the perovskite
precursor
Precursor or Precursors may refer to:
*Precursor (religion), a forerunner, predecessor
** The Precursor, John the Baptist
Science and technology
* Precursor (bird), a hypothesized genus of fossil birds that was composed of fossilized parts of unr ...
solutions. In addition, their method is able to passivate perovskite surface
defects and reduce nonradiative recombination. Therefore, by improving the light outcoupling and reducing nonradiative losses, Cao and his colleagues successfully achieved PLED with EQE up to 20.7%.
Lin and his colleague used a different approach to generate high EQE. Instead of modifying the microstructure of perovskite layer, they chose to adopt a new strategy for managing the compositional distribution in the device—an approach that simultaneously provides high
luminescence
Luminescence is spontaneous emission of light by a substance not resulting from heat; or "cold light".
It is thus a form of cold-body radiation. It can be caused by chemical reactions, electrical energy, subatomic motions or stress on a cryst ...
and balanced charge injection. In other words, they still used flat emissive layer, but tried to optimize the balance of electrons and holes injected into the perovskite, so as to make the most efficient use of the charge carriers. Moreover, in the perovskite layer, the crystals are perfectly enclosed by MABr additive (where MA is CH
3NH
3). The MABr shell passivates the nonradiative defects that would otherwise be present perovskite crystals, resulting in reduction of the nonradiative recombination. Therefore, by balancing charge injection and decreasing nonradiative losses, Lin and his colleagues developed PLED with EQE up to 20.3%.
See also
*
History of display technology
Electrically operated display devices have developed from electromechanical systems for display of text, up to all-electronic devices capable of full-motion 3D color graphic displays. Electromagnetic devices, using a solenoid coil to control a v ...
*
LED tattoo
A light-emitting diode tattoo is a type of body modification similar to a tattoo, but specifically involves implantation of technologically based materials versus traditional ink injection into the layers of the skin. LED tattoos are accomplished ...
*
Light-emitting electrochemical cell A light-emitting electrochemical cell (LEC or LEEC) is a solid-state device that generates light from an electric current (electroluminescence). LECs are usually composed of two metal electrodes connected by (e.g. sandwiching) an organic semiconduc ...
*
List of LED failure modes
The most common way for LEDs (and diode lasers) to fail is the gradual lowering of light output and loss of efficiency. Sudden failures, however rare, can occur as well. Early red LEDs were notable for their short lifetime.
Packaging-related
*Ep ...
*
List of light sources
This is a list of sources of light, the visible part of the electromagnetic spectrum. Light sources produce photons from another energy source, such as heat, chemical reactions, or conversion of mass or a different frequency of electromagnetic ener ...
*
Photovoltaics
Photovoltaics (PV) is the conversion of light into electricity using semiconducting materials that exhibit the photovoltaic effect, a phenomenon studied in physics, photochemistry, and electrochemistry. The photovoltaic effect is commercially us ...
*
SMD LED module
An LED lamp or LED light bulb is an electric light that produces light using light-emitting diodes (LEDs). LED lamps are significantly more energy-efficient than equivalent incandescent lamps
and can be significantly more efficient than mos ...
*
Superluminescent diode
A superluminescent diode (SLED or SLD) is an edge-emitting semiconductor light source based on superluminescence. It combines the high power and brightness of laser diodes with the low coherence of conventional light-emitting diodes. Its emission ...
*
MicroLED
microLED, also known as micro-LED, mLED or µLED, first invented in 2000 by the research group of Hongxing Jiang and Jingyu Lin of Texas Tech University while they were at Kansas State University, is an emerging flat-panel display technology. mic ...
*
Solar lamp
A solar lamp, also known as a solar light or solar lantern, is a lighting system composed of an LED lamp, solar panels, battery, charge controller and there may also be an inverter. The lamp operates on electricity from batteries, charged throug ...
*
Solid-state lighting
Solid-state lighting (SSL) is a type of lighting that uses semiconductor light-emitting diodes (LEDs), organic light-emitting diodes (OLED), or polymer light-emitting diodes (PLED) as sources of illumination rather than electrical filaments, pla ...
*
Thermal management of high-power LEDs
High power light-emitting diodes (LEDs) can use 350 milliwatts or more in a single LED. Most of the electricity in an LED becomes heat rather than light (about 70% heat and 30% light). If this heat is not removed, the LEDs run at high tempe ...
*
UV curing
UV curing (ultraviolet curing) is the process by which ultraviolet light is used to initiate a photochemical reaction that generates a crosslinked network of polymers. UV curing is adaptable to printing, coating, decorating, stereolithography, an ...
References
Further reading
*
*
External links
Building a do-it-yourself LEDColor cycling LED in a single two pin package
*
{{Authority control
LED lamps
Optical diodes
Display technology
Signage
20th-century inventions