Titanium is a
chemical element
A chemical element is a species of atoms that have a given number of protons in their nuclei, including the pure substance consisting only of that species. Unlike chemical compounds, chemical elements cannot be broken down into simpler sub ...
with the
symbol
A symbol is a mark, sign, or word that indicates, signifies, or is understood as representing an idea, object, or relationship. Symbols allow people to go beyond what is known or seen by creating linkages between otherwise very different conc ...
Ti and
atomic number
The atomic number or nuclear charge number (symbol ''Z'') of a chemical element is the charge number of an atomic nucleus. For ordinary nuclei, this is equal to the proton number (''n''p) or the number of protons found in the nucleus of every ...
22. Found in nature only as an
oxide
An oxide () is a chemical compound that contains at least one oxygen atom and one other element in its chemical formula. "Oxide" itself is the dianion of oxygen, an O2– (molecular) ion. with oxygen in the oxidation state of −2. Most of the E ...
, it can be reduced to produce a lustrous
transition metal
In chemistry, a transition metal (or transition element) is a chemical element in the d-block of the periodic table (groups 3 to 12), though the elements of group 12 (and less often group 3) are sometimes excluded. They are the elements that can ...
with a silver
color
Color (American English) or colour (British English) is the visual perceptual property deriving from the spectrum of light interacting with the photoreceptor cells of the eyes. Color categories and physical specifications of color are associ ...
, low
density
Density (volumetric mass density or specific mass) is the substance's mass per unit of volume. The symbol most often used for density is ''ρ'' (the lower case Greek letter rho), although the Latin letter ''D'' can also be used. Mathematical ...
, and high strength, resistant to
corrosion
Corrosion is a natural process that converts a refined metal into a more chemically stable oxide. It is the gradual deterioration of materials (usually a metal) by chemical or electrochemical reaction with their environment. Corrosion engine ...
in
sea water
Seawater, or salt water, is water from a sea or ocean. On average, seawater in the world's oceans has a salinity of about 3.5% (35 g/L, 35 ppt, 600 mM). This means that every kilogram (roughly one liter by volume) of seawater has approx ...
,
aqua regia, and
chlorine
Chlorine is a chemical element with the Symbol (chemistry), symbol Cl and atomic number 17. The second-lightest of the halogens, it appears between fluorine and bromine in the periodic table and its properties are mostly intermediate betwee ...
.
Titanium was discovered in
Cornwall
Cornwall (; kw, Kernow ) is a historic county and ceremonial county in South West England. It is recognised as one of the Celtic nations, and is the homeland of the Cornish people. Cornwall is bordered to the north and west by the Atlantic ...
,
Great Britain
Great Britain is an island in the North Atlantic Ocean off the northwest coast of continental Europe. With an area of , it is the largest of the British Isles, the largest European island and the ninth-largest island in the world. It is ...
, by
William Gregor
William Gregor (25 December 1761 – 11 June 1817) was an English clergyman and mineralogist who discovered the elemental metal titanium.
Early years
He was born at the Trewarthenick Estate in Cornwall, the son of Francis Gregor and Mary Co ...
in 1791 and was named by
Martin Heinrich Klaproth
Martin Heinrich Klaproth (1 December 1743 – 1 January 1817) was a German chemist. He trained and worked for much of his life as an apothecary, moving in later life to the university. His shop became the second-largest apothecary in Berlin, and ...
after the
Titans
In Greek mythology, the Titans ( grc, οἱ Τῑτᾶνες, ''hoi Tītânes'', , ''ho Tītân'') were the pre-Olympian gods. According to the ''Theogony'' of Hesiod, they were the twelve children of the primordial parents Uranus (Sky) and Ga ...
of
Greek mythology
A major branch of classical mythology, Greek mythology is the body of myths originally told by the Ancient Greece, ancient Greeks, and a genre of Ancient Greek folklore. These stories concern the Cosmogony, origin and Cosmology#Metaphysical co ...
. The element occurs within a number of
mineral
In geology and mineralogy, a mineral or mineral species is, broadly speaking, a solid chemical compound with a fairly well-defined chemical composition and a specific crystal structure that occurs naturally in pure form.John P. Rafferty, ed. ( ...
s, principally
rutile
Rutile is an oxide mineral composed of titanium dioxide (TiO2), the most common natural form of TiO2. Rarer Polymorphism (materials science), polymorphs of TiO2 are known, including anatase, akaogiite, and brookite.
Rutile has one of the highest ...
and
ilmenite
Ilmenite is a titanium-iron oxide mineral with the idealized formula . It is a weakly magnetic black or steel-gray solid. Ilmenite is the most important ore of titanium and the main source of titanium dioxide, which is used in paints, printing ...
, which are widely distributed in the
Earth's crust
Earth's crust is Earth's thin outer shell of rock, referring to less than 1% of Earth's radius and volume. It is the top component of the lithosphere, a division of Earth's layers that includes the crust and the upper part of the mantle. The ...
and
lithosphere
A lithosphere () is the rigid, outermost rocky shell of a terrestrial planet or natural satellite. On Earth, it is composed of the crust (geology), crust and the portion of the upper mantle (geology), mantle that behaves elastically on time sca ...
; it is found in almost all living things, as well as bodies of water, rocks, and soils.
The metal is extracted from its principal mineral ores by the
Kroll
Kroll is a German, Anglo-Saxon, and Scottish surname.
Notable people with the surname include:
* Colin Kroll (1983/4–2018), American businessman; co-founder of Vine and HQ Trivia
* Eric Kroll (born 1946), American photographer
* Fredric Kr ...
and
Hunter
Hunting is the human activity, human practice of seeking, pursuing, capturing, or killing wildlife or feral animals. The most common reasons for humans to hunt are to harvest food (i.e. meat) and useful animal products (fur/hide (skin), hide, ...
processes. The most common compound,
titanium dioxide
Titanium dioxide, also known as titanium(IV) oxide or titania , is the inorganic compound with the chemical formula . When used as a pigment, it is called titanium white, Pigment White 6 (PW6), or CI 77891. It is a white solid that is insolubl ...
, is a popular
photocatalyst
In chemistry, photocatalysis is the acceleration of a photoreaction in the presence of a catalyst. In catalyzed photolysis, light is absorbed by an adsorbed substrate. In photogenerated catalysis, the photocatalytic activity depends on the abili ...
and is used in the manufacture of white pigments.
Other compounds include
titanium tetrachloride
Titanium tetrachloride is the inorganic compound with the formula . It is an important intermediate in the production of titanium metal and the pigment titanium dioxide. is a volatile liquid. Upon contact with humid air, it forms thick clouds o ...
(TiCl
4), a component of
smoke screen
A smoke screen is smoke released to mask the movement or location of military units such as infantry, tanks, aircraft, or ships.
Smoke screens are commonly deployed either by a canister (such as a grenade) or generated by a vehicle (such as ...
s and
catalyst
Catalysis () is the process of increasing the rate of a chemical reaction by adding a substance known as a catalyst (). Catalysts are not consumed in the reaction and remain unchanged after it. If the reaction is rapid and the catalyst recyc ...
s; and
titanium trichloride
Titanium(III) chloride is the inorganic compound with the formula TiCl3. At least four distinct species have this formula; additionally hydrated derivatives are known. TiCl3 is one of the most common halides of titanium and is an important catalys ...
(TiCl
3), which is used as a catalyst in the production of
polypropylene
Polypropylene (PP), also known as polypropene, is a thermoplastic polymer used in a wide variety of applications. It is produced via chain-growth polymerization from the monomer propylene.
Polypropylene
belongs to the group of polyolefins and ...
.
Titanium can be
alloy
An alloy is a mixture of chemical elements of which at least one is a metal. Unlike chemical compounds with metallic bases, an alloy will retain all the properties of a metal in the resulting material, such as electrical conductivity, ductility, ...
ed with
iron
Iron () is a chemical element with symbol Fe (from la, ferrum) and atomic number 26. It is a metal that belongs to the first transition series and group 8 of the periodic table. It is, by mass, the most common element on Earth, right in f ...
,
aluminium
Aluminium (aluminum in American and Canadian English) is a chemical element with the symbol Al and atomic number 13. Aluminium has a density lower than those of other common metals, at approximately one third that of steel. I ...
,
vanadium
Vanadium is a chemical element with the symbol V and atomic number 23. It is a hard, silvery-grey, malleable transition metal. The elemental metal is rarely found in nature, but once isolated artificially, the formation of an oxide layer ( pas ...
, and
molybdenum
Molybdenum is a chemical element with the symbol Mo and atomic number 42 which is located in period 5 and group 6. The name is from Neo-Latin ''molybdaenum'', which is based on Ancient Greek ', meaning lead, since its ores were confused with lea ...
, among other elements, to produce strong, lightweight alloys for aerospace (
jet engine
A jet engine is a type of reaction engine discharging a fast-moving jet of heated gas (usually air) that generates thrust by jet propulsion. While this broad definition can include rocket, Pump-jet, water jet, and hybrid propulsion, the term ...
s,
missile
In military terminology, a missile is a guided airborne ranged weapon capable of self-propelled flight usually by a jet engine or rocket motor. Missiles are thus also called guided missiles or guided rockets (when a previously unguided rocket i ...
s, and
spacecraft
A spacecraft is a vehicle or machine designed to fly in outer space. A type of artificial satellite, spacecraft are used for a variety of purposes, including communications, Earth observation, meteorology, navigation, space colonization, p ...
), military, industrial processes (chemicals and petrochemicals,
desalination plant
Desalination is a process that takes away mineral components from saline water. More generally, desalination refers to the removal of salts and minerals from a target substance, as in soil desalination, which is an issue for agriculture. Saltwa ...
s,
pulp
Pulp may refer to:
* Pulp (fruit), the inner flesh of fruit
Engineering
* Dissolving pulp, highly purified cellulose used in fibre and film manufacture
* Pulp (paper), the fibrous material used to make paper
* Molded pulp, a packaging material
...
, and
paper
Paper is a thin sheet material produced by mechanically or chemically processing cellulose fibres derived from wood, rags, grasses or other vegetable sources in water, draining the water through fine mesh leaving the fibre evenly distributed ...
), automotive,
agriculture
Agriculture or farming is the practice of cultivating plants and livestock. Agriculture was the key development in the rise of sedentary human civilization, whereby farming of domesticated species created food surpluses that enabled people to ...
(farming), medical
prostheses
In medicine, a prosthesis (plural: prostheses; from grc, πρόσθεσις, prósthesis, addition, application, attachment), or a prosthetic implant, is an artificial device that replaces a missing body part, which may be lost through trau ...
, orthopedic
implants, dental and endodontic instruments and files,
dental implant
A dental implant (also known as an endosseous implant or fixture) is a prosthesis that interfaces with the bone of the jaw or skull to support a dental prosthesis such as a crown, bridge, denture, or facial prosthesis or to act as an orthodonti ...
s, sporting goods, jewelry,
mobile phone
A mobile phone, cellular phone, cell phone, cellphone, handphone, hand phone or pocket phone, sometimes shortened to simply mobile, cell, or just phone, is a portable telephone that can make and receive calls over a radio frequency link whil ...
s, and other applications.
The two most useful properties of the metal are corrosion resistance and
strength-to-density ratio, the highest of any metallic element. In its unalloyed condition, titanium is as strong as some
steel
Steel is an alloy made up of iron with added carbon to improve its strength and fracture resistance compared to other forms of iron. Many other elements may be present or added. Stainless steels that are corrosion- and oxidation-resistant ty ...
s, but less dense.
There are two
allotropic
Allotropy or allotropism () is the property of some chemical elements to exist in two or more different forms, in the same physical state, known as allotropes of the elements. Allotropes are different structural modifications of an element: th ...
forms
and five naturally occurring
isotope
Isotopes are two or more types of atoms that have the same atomic number (number of protons in their nuclei) and position in the periodic table (and hence belong to the same chemical element), and that differ in nucleon numbers (mass numbers) ...
s of this element,
Ti through Ti, with Ti being the most
abundant (73.8%).
Characteristics
Physical properties
As a metal
A metal (from Greek μέταλλον ''métallon'', "mine, quarry, metal") is a material that, when freshly prepared, polished, or fractured, shows a lustrous appearance, and conducts electricity and heat relatively well. Metals are typicall ...
, titanium is recognized for its high strength-to-weight ratio. It is a strong metal with low density
Density (volumetric mass density or specific mass) is the substance's mass per unit of volume. The symbol most often used for density is ''ρ'' (the lower case Greek letter rho), although the Latin letter ''D'' can also be used. Mathematical ...
that is quite ductile
Ductility is a mechanical property commonly described as a material's amenability to drawing (e.g. into wire). In materials science, ductility is defined by the degree to which a material can sustain plastic deformation under tensile stres ...
(especially in an oxygen
Oxygen is the chemical element with the symbol O and atomic number 8. It is a member of the chalcogen group in the periodic table, a highly reactive nonmetal, and an oxidizing agent that readily forms oxides with most elements as wel ...
-free environment), lustrous, and metallic-white in color
Color (American English) or colour (British English) is the visual perceptual property deriving from the spectrum of light interacting with the photoreceptor cells of the eyes. Color categories and physical specifications of color are associ ...
. The relatively high melting point (1,668 °C or 3,034 °F) makes it useful as a refractory metal
Refractory metals are a class of metals that are extraordinarily resistant to heat and wear. The expression is mostly used in the context of materials science, metallurgy and engineering. The definition of which elements belong to this group diff ...
. It is paramagnetic
Paramagnetism is a form of magnetism whereby some materials are weakly attracted by an externally applied magnetic field, and form internal, induced magnetic fields in the direction of the applied magnetic field. In contrast with this behavior, d ...
and has fairly low electrical
Electricity is the set of physical phenomena associated with the presence and motion of matter that has a property of electric charge. Electricity is related to magnetism, both being part of the phenomenon of electromagnetism, as described by ...
and thermal conductivity
The thermal conductivity of a material is a measure of its ability to conduct heat. It is commonly denoted by k, \lambda, or \kappa.
Heat transfer occurs at a lower rate in materials of low thermal conductivity than in materials of high thermal ...
compared to other metals. Titanium is superconducting
Superconductivity is a set of physical properties observed in certain materials where Electrical resistance and conductance, electrical resistance vanishes and magnetic field, magnetic flux fields are expelled from the material. Any material e ...
when cooled below its critical temperature of 0.49 K.
Commercially pure (99.2% pure) grades
Grade most commonly refers to:
* Grade (education), a measurement of a student's performance
* Grade, the number of the year a student has reached in a given educational stage
* Grade (slope), the steepness of a slope
Grade or grading may also r ...
of titanium have ultimate tensile strength
Ultimate tensile strength (UTS), often shortened to tensile strength (TS), ultimate strength, or F_\text within equations, is the maximum stress that a material can withstand while being stretched or pulled before breaking. In brittle materials t ...
of about 434 MPa
MPA or mPa may refer to:
Academia
Academic degrees
* Master of Performing Arts
* Master of Professional Accountancy
* Master of Public Administration
* Master of Public Affairs
Schools
* Mesa Preparatory Academy
* Morgan Park Academy
* Mound ...
(63,000 psi
Psi, PSI or Ψ may refer to:
Alphabetic letters
* Psi (Greek) (Ψ, ψ), the 23rd letter of the Greek alphabet
* Psi (Cyrillic) (Ѱ, ѱ), letter of the early Cyrillic alphabet, adopted from Greek
Arts and entertainment
* "Psi" as an abbreviatio ...
), equal to that of common, low-grade steel alloys, but are less dense. Titanium is 60% denser than aluminium, but more than twice as strong[ as the most commonly used 6061-T6 aluminium alloy. Certain titanium alloys (e.g., Beta C) achieve tensile strengths of over 1,400 MPa (200,000 psi). However, titanium loses strength when heated above .]
Titanium is not as hard as some grades of heat-treated steel; it is non-magnetic and a poor conductor of heat and electricity. Machining requires precautions, because the material can gall
Galls (from the Latin , 'oak-apple') or ''cecidia'' (from the Greek , anything gushing out) are a kind of swelling growth on the external tissues of plants, fungi, or animals. Plant galls are abnormal outgrowths of plant tissues, similar to be ...
unless sharp tools and proper cooling methods are used. Like steel structures, those made from titanium have a fatigue limit
The fatigue limit or endurance limit is the stress level below which an infinite number of loading cycles can be applied to a material without causing fatigue failure. Some metals such as ferrous alloys and titanium alloys have a distinct limit, ...
that guarantees longevity in some applications.
The metal is a dimorphic allotrope
Allotropy or allotropism () is the property of some chemical elements to exist in two or more different forms, in the same physical state, known as allotropes of the elements. Allotropes are different structural modifications of an element: the ...
of an hexagonal α form that changes into a body-centered cubic (lattice) β form at . The specific heat
In thermodynamics, the specific heat capacity (symbol ) of a substance is the heat capacity of a sample of the substance divided by the mass of the sample, also sometimes referred to as massic heat capacity. Informally, it is the amount of heat t ...
of the α form increases dramatically as it is heated to this transition temperature but then falls and remains fairly constant for the β form regardless of temperature.
Chemical properties
Like aluminium
Aluminium (aluminum in American and Canadian English) is a chemical element with the symbol Al and atomic number 13. Aluminium has a density lower than those of other common metals, at approximately one third that of steel. I ...
and magnesium
Magnesium is a chemical element with the symbol Mg and atomic number 12. It is a shiny gray metal having a low density, low melting point and high chemical reactivity. Like the other alkaline earth metals (group 2 of the periodic ta ...
, the surface of titanium metal and its alloys oxidize
Redox (reduction–oxidation, , ) is a type of chemical reaction in which the oxidation states of substrate change. Oxidation is the loss of electrons or an increase in the oxidation state, while reduction is the gain of electrons or a d ...
immediately upon exposure to air to form a thin non-porous passivation layer that protects the bulk metal from further oxidation or corrosion. When it first forms, this protective layer is only 1–2 nm thick but it continues to grow slowly, reaching a thickness of 25 nm in four years. This layer gives titanium excellent resistance to corrosion, almost equivalent to platinum
Platinum is a chemical element with the symbol Pt and atomic number 78. It is a dense, malleable, ductile, highly unreactive, precious, silverish-white transition metal. Its name originates from Spanish , a diminutive of "silver".
Platinu ...
.
Titanium is capable of withstanding attack by dilute sulfuric and hydrochloric acid
Hydrochloric acid, also known as muriatic acid, is an aqueous solution of hydrogen chloride. It is a colorless solution with a distinctive pungent smell. It is classified as a strong acid
Acid strength is the tendency of an acid, symbol ...
s, chloride solutions, and most organic acids.[ However, titanium is corroded by concentrated acids. As indicated by its negative redox potential, titanium is a very reactive metal that burns in normal air at lower temperatures than the melting point. Melting is possible only in an inert atmosphere or vacuum. At , it combines with chlorine.][ It also reacts with the other halogens and absorbs hydrogen.][
Titanium readily reacts with oxygen at in air, and at in pure oxygen, forming ]titanium dioxide
Titanium dioxide, also known as titanium(IV) oxide or titania , is the inorganic compound with the chemical formula . When used as a pigment, it is called titanium white, Pigment White 6 (PW6), or CI 77891. It is a white solid that is insolubl ...
. Titanium is one of the few elements that burns in pure nitrogen gas, reacting at to form titanium nitride
Titanium nitride (TiN; sometimes known as Tinite) is an extremely hard ceramic material, often used as a physical vapor deposition (PVD) coating on titanium alloys, steel, carbide, and aluminium components to improve the substrate's surface prope ...
, which causes embrittlement. Because of its high reactivity with oxygen, nitrogen, and many other gases, titanium that is evaporated from filaments is the basis for titanium sublimation pump
A titanium sublimation pump (TSP) is a type of vacuum pump used to remove residual gas in ultra-high vacuum systems, maintaining the vacuum.
Principle of operation
Its construction and principle of operation is simple. It consists of a titanium ...
s, in which titanium serves as a scavenger for these gases by chemically binding to them. Such pumps inexpensively produce extremely low pressures in ultra-high vacuum
Ultra-high vacuum (UHV) is the vacuum regime characterised by pressures lower than about . UHV conditions are created by pumping the gas out of a UHV chamber. At these low pressures the mean free path of a gas molecule is greater than approximately ...
systems.
Occurrence
Titanium is the ninth-most abundant element in Earth
Earth is the third planet from the Sun and the only astronomical object known to harbor life. While large volumes of water can be found throughout the Solar System, only Earth sustains liquid surface water. About 71% of Earth's surfa ...
's crust (0.63% by mass
Mass is an intrinsic property of a body. It was traditionally believed to be related to the quantity of matter in a physical body, until the discovery of the atom and particle physics. It was found that different atoms and different elementar ...
) and the seventh-most abundant metal. It is present as oxides in most igneous rock
Igneous rock (derived from the Latin word ''ignis'' meaning fire), or magmatic rock, is one of the three main The three types of rocks, rock types, the others being Sedimentary rock, sedimentary and metamorphic rock, metamorphic. Igneous rock ...
s, in sediments
Sediment is a naturally occurring material that is broken down by processes of weathering and erosion, and is subsequently transported by the action of wind, water, or ice or by the force of gravity acting on the particles. For example, sand a ...
derived from them, in living things, and natural bodies of water. Of the 801 types of igneous rocks analyzed by the United States Geological Survey
The United States Geological Survey (USGS), formerly simply known as the Geological Survey, is a scientific agency of the United States government. The scientists of the USGS study the landscape of the United States, its natural resources, ...
, 784 contained titanium. Its proportion in soils is approximately 0.5 to 1.5%.
Common titanium-containing mineral
In geology and mineralogy, a mineral or mineral species is, broadly speaking, a solid chemical compound with a fairly well-defined chemical composition and a specific crystal structure that occurs naturally in pure form.John P. Rafferty, ed. ( ...
s are anatase
Anatase is a metastable mineral form of titanium dioxide (TiO2) with a tetragonal crystal structure. Although colorless or white when pure, anatase in nature is usually a black solid due to impurities. Three other polymorphs (or mineral forms) ...
, brookite
Brookite is the orthorhombic variant of titanium dioxide (TiO2), which occurs in four known natural polymorphic forms (minerals with the same composition but different structure). The other three of these forms are akaogiite (monoclinic), anatas ...
, ilmenite
Ilmenite is a titanium-iron oxide mineral with the idealized formula . It is a weakly magnetic black or steel-gray solid. Ilmenite is the most important ore of titanium and the main source of titanium dioxide, which is used in paints, printing ...
, perovskite
Perovskite (pronunciation: ) is a calcium titanium oxide mineral composed of calcium titanate (chemical formula ). Its name is also applied to the class of compounds which have the same type of crystal structure as (XIIA2+VIB4+X2−3), known as ...
, rutile
Rutile is an oxide mineral composed of titanium dioxide (TiO2), the most common natural form of TiO2. Rarer Polymorphism (materials science), polymorphs of TiO2 are known, including anatase, akaogiite, and brookite.
Rutile has one of the highest ...
, and titanite
Titanite, or sphene (from the Greek ''sphenos'' (σφηνώ), meaning wedge), is a calcium titanium nesosilicate mineral, Ca Ti Si O5. Trace impurities of iron and aluminium are typically present. Also commonly present are rare earth metals in ...
(sphene). Akaogiite
Akaogiite ( IMA symbol Aka) is an exceedingly rare mineral, one of the natural forms of titanium dioxide (TiO2). It is a high-pressure polymorph of TiO2, along with anatase, brookite and another high-pressure phase called "TiO2 II". Rutile is the ...
is an extremely rare mineral consisting of titanium dioxide. Of these minerals, only rutile and ilmenite have economic importance, yet even they are difficult to find in high concentrations. About 6.0 and 0.7 million tonnes of those minerals were mined in 2011, respectively. Significant titanium-bearing ilmenite deposits exist in Australia
Australia, officially the Commonwealth of Australia, is a Sovereign state, sovereign country comprising the mainland of the Australia (continent), Australian continent, the island of Tasmania, and numerous List of islands of Australia, sma ...
, Canada
Canada is a country in North America. Its ten provinces and three territories extend from the Atlantic Ocean to the Pacific Ocean and northward into the Arctic Ocean, covering over , making it the world's second-largest country by tot ...
, China
China, officially the People's Republic of China (PRC), is a country in East Asia. It is the world's most populous country, with a population exceeding 1.4 billion, slightly ahead of India. China spans the equivalent of five time zones and ...
, India
India, officially the Republic of India (Hindi: ), is a country in South Asia. It is the seventh-largest country by area, the second-most populous country, and the most populous democracy in the world. Bounded by the Indian Ocean on the so ...
, Mozambique
Mozambique (), officially the Republic of Mozambique ( pt, Moçambique or , ; ny, Mozambiki; sw, Msumbiji; ts, Muzambhiki), is a country located in southeastern Africa bordered by the Indian Ocean to the east, Tanzania to the north, Malawi ...
, New Zealand
New Zealand ( mi, Aotearoa ) is an island country in the southwestern Pacific Ocean. It consists of two main landmasses—the North Island () and the South Island ()—and over 700 smaller islands. It is the sixth-largest island count ...
, Norway
Norway, officially the Kingdom of Norway, is a Nordic country in Northern Europe, the mainland territory of which comprises the western and northernmost portion of the Scandinavian Peninsula. The remote Arctic island of Jan Mayen and t ...
, Sierra Leone
Sierra Leone,)]. officially the Republic of Sierra Leone, is a country on the southwest coast of West Africa. It is bordered by Liberia to the southeast and Guinea surrounds the northern half of the nation. Covering a total area of , Sierra ...
, South Africa
South Africa, officially the Republic of South Africa (RSA), is the southernmost country in Africa. It is bounded to the south by of coastline that stretch along the South Atlantic and Indian Oceans; to the north by the neighbouring countri ...
, and Ukraine
Ukraine ( uk, Україна, Ukraïna, ) is a country in Eastern Europe. It is the second-largest European country after Russia, which it borders to the east and northeast. Ukraine covers approximately . Prior to the ongoing Russian inv ...
. About 210,000 tonnes of titanium metal sponge
Regular foamed aluminium
A metal foam is a cellular structure consisting of a solid metal (frequently aluminium) with gas-filled pores comprising a large portion of the volume. The pores can be sealed (closed-cell foam) or interconnected (open-c ...
were produced in 2020, mostly in China (110,000 t), Japan (50,000 t), Russia (33,000 t) and Kazakhstan (15,000 t). Total reserves of anatase, ilmenite, and rutile are estimated to exceed 2 billion tonnes.
The concentration of titanium is about 4 picomolar
Molar concentration (also called molarity, amount concentration or substance concentration) is a measure of the concentration of a chemical species, in particular of a solute in a solution, in terms of amount of substance per unit volume of solu ...
in the ocean. At 100 °C, the concentration of titanium in water is estimated to be less than 10−7 M at pH 7. The identity of titanium species in aqueous solution remains unknown because of its low solubility and the lack of sensitive spectroscopic methods, although only the 4+ oxidation state is stable in air. No evidence exists for a biological role, although rare organisms are known to accumulate high concentrations of titanium.
Titanium is contained in meteorite
A meteorite is a solid piece of debris from an object, such as a comet, asteroid, or meteoroid, that originates in outer space and survives its passage through the atmosphere to reach the surface of a planet or Natural satellite, moon. When the ...
s, and it has been detected in the Sun
The Sun is the star at the center of the Solar System. It is a nearly perfect ball of hot plasma, heated to incandescence by nuclear fusion reactions in its core. The Sun radiates this energy mainly as light, ultraviolet, and infrared radi ...
and in M-type star
A star is an astronomical object comprising a luminous spheroid of plasma (physics), plasma held together by its gravity. The List of nearest stars and brown dwarfs, nearest star to Earth is the Sun. Many other stars are visible to the naked ...
s (the coolest type) with a surface temperature of . Rocks
In geology, rock (or stone) is any naturally occurring solid mass or aggregate of minerals or mineraloid matter. It is categorized by the minerals included, its chemical composition, and the way in which it is formed. Rocks form the Earth's ...
brought back from the Moon
The Moon is Earth's only natural satellite. It is the fifth largest satellite in the Solar System and the largest and most massive relative to its parent planet, with a diameter about one-quarter that of Earth (comparable to the width of ...
during the Apollo 17
Apollo 17 (December 7–19, 1972) was the final mission of NASA's Apollo program, the most recent time humans have set foot on the Moon or traveled beyond low Earth orbit. Commander Gene Cernan and Lunar Module Pilot Harrison Schmitt walked on ...
mission are composed of 12.1% TiO2. Native titanium (pure metallic) is very rare.
Isotopes
Naturally occurring titanium is composed of five stable isotope
Isotopes are two or more types of atoms that have the same atomic number (number of protons in their nuclei) and position in the periodic table (and hence belong to the same chemical element), and that differ in nucleon numbers (mass numbers) ...
s: 46Ti, 47Ti, 48Ti, 49Ti, and 50Ti, with 48Ti being the most abundant (73.8% natural abundance
In physics, natural abundance (NA) refers to the abundance of isotopes of a chemical element as naturally found on a planet. The relative atomic mass (a weighted average, weighted by mole-fraction abundance figures) of these isotopes is the atomi ...
). At least 21 radioisotope
A radionuclide (radioactive nuclide, radioisotope or radioactive isotope) is a nuclide that has excess nuclear energy, making it unstable. This excess energy can be used in one of three ways: emitted from the nucleus as gamma radiation; transferr ...
s have been characterized, the most stable of which are 44Ti with a half-life
Half-life (symbol ) is the time required for a quantity (of substance) to reduce to half of its initial value. The term is commonly used in nuclear physics to describe how quickly unstable atoms undergo radioactive decay or how long stable ato ...
of 63 years; 45Ti, 184.8 minutes; 51Ti, 5.76 minutes; and 52Ti, 1.7 minutes. All other radioactive
Radioactive decay (also known as nuclear decay, radioactivity, radioactive disintegration, or nuclear disintegration) is the process by which an unstable atomic nucleus loses energy by radiation. A material containing unstable nuclei is consid ...
isotopes have half-lives less than 33 seconds, with the majority less than half a second.
The isotopes of titanium range in atomic weight
Relative atomic mass (symbol: ''A''; sometimes abbreviated RAM or r.a.m.), also known by the deprecated synonym atomic weight, is a dimensionless physical quantity defined as the ratio of the average mass of atoms of a chemical element in a giv ...
from 39.002 u (39Ti) to 63.999 u (64Ti). The primary decay mode
Radioactive decay (also known as nuclear decay, radioactivity, radioactive disintegration, or nuclear disintegration) is the process by which an unstable atomic nucleus loses energy by radiation. A material containing unstable nuclei is consid ...
for isotopes lighter than 46Ti is positron emission
Positron emission, beta plus decay, or β+ decay is a subtype of radioactive decay called beta decay, in which a proton inside a radionuclide nucleus is converted into a neutron while releasing a positron and an electron neutrino (). Positron ...
(with the exception of 44Ti which undergoes electron capture
Electron capture (K-electron capture, also K-capture, or L-electron capture, L-capture) is a process in which the proton-rich nucleus of an electrically neutral atom absorbs an inner atomic electron, usually from the K or L electron shells. Thi ...
), leading to isotopes of scandium
Naturally occurring scandium (21Sc) is composed of one stable isotope, 45Sc. Twenty-five radioisotopes have been characterized, with the most stable being 46Sc with a half-life of 83.8 days, 47Sc with a half-life of 3.35 days, and 48Sc with a half ...
, and the primary mode for isotopes heavier than 50Ti is beta emission
In nuclear physics, beta decay (β-decay) is a type of radioactive decay in which a beta particle (fast energetic electron or positron) is emitted from an atomic nucleus, transforming the original nuclide to an isobar of that nuclide. For exam ...
, leading to isotopes of vanadium
Naturally occurring vanadium (23V) is composed of one stable isotope 51V and one radioactive isotope 50V with a half-life of 1.5×1017 years. 24 artificial radioisotopes have been characterized (in the range of mass number between 40 and 65) with ...
.
Titanium becomes radioactive upon bombardment with deuterons
Deuterium (or hydrogen-2, symbol or deuterium, also known as heavy hydrogen) is one of two stable isotopes of hydrogen (the other being protium, or hydrogen-1). The nucleus of a deuterium atom, called a deuteron, contains one proton and one n ...
, emitting mainly positrons
The positron or antielectron is the antiparticle or the antimatter counterpart of the electron. It has an electric charge of +1 '' e'', a spin of 1/2 (the same as the electron), and the same mass as an electron. When a positron collides w ...
and hard gamma rays
A gamma ray, also known as gamma radiation (symbol γ or \gamma), is a penetrating form of electromagnetic radiation arising from the radioactive decay of atomic nuclei. It consists of the shortest wavelength electromagnetic waves, typically ...
.
Compounds
The +4 oxidation state
In chemistry, the oxidation state, or oxidation number, is the hypothetical charge of an atom if all of its bonds to different atoms were fully ionic. It describes the degree of oxidation (loss of electrons) of an atom in a chemical compound. C ...
dominates titanium chemistry, but compounds in the +3 oxidation state are also numerous. Commonly, titanium adopts an octahedral coordination geometry
In chemistry, octahedral molecular geometry, also called square bipyramidal, describes the shape of compounds with six atoms or groups of atoms or ligands symmetrically arranged around a central atom, defining the vertices of an octahedron. The oc ...
in its complexes, but tetrahedral TiCl4 is a notable exception. Because of its high oxidation state, titanium(IV) compounds exhibit a high degree of covalent bond
A covalent bond is a chemical bond that involves the sharing of electrons to form electron pairs between atoms. These electron pairs are known as shared pairs or bonding pairs. The stable balance of attractive and repulsive forces between atoms ...
ing.
Oxides, sulfides, and alkoxides
The most important oxide is TiO2, which exists in three important polymorphs; anatase, brookite, and rutile. All three are white diamagnetic solids, although mineral samples can appear dark (see rutile
Rutile is an oxide mineral composed of titanium dioxide (TiO2), the most common natural form of TiO2. Rarer Polymorphism (materials science), polymorphs of TiO2 are known, including anatase, akaogiite, and brookite.
Rutile has one of the highest ...
). They adopt polymeric structures in which Ti is surrounded by six oxide
An oxide () is a chemical compound that contains at least one oxygen atom and one other element in its chemical formula. "Oxide" itself is the dianion of oxygen, an O2– (molecular) ion. with oxygen in the oxidation state of −2. Most of the E ...
ligands that link to other Ti centers.
The term ''titanate In chemistry, titanate usually refers to inorganic compounds composed of titanium oxides.
Together with niobate, titanate salts form the Perovskite group.
In some cases, the term is used more generally for any titanium-containing anion, e.g. iC ...
s'' usually refers to titanium(IV) compounds, as represented by barium titanate
Barium titanate (BTO) is an inorganic compound with chemical formula BaTiO3. Barium titanate appears white as a powder and is transparent when prepared as large crystals. It is a Ferroelectricity, ferroelectric, Pyroelectricity, pyroelectric, and ...
(BaTiO3). With a perovskite structure, this material exhibits piezoelectric
Piezoelectricity (, ) is the electric charge that accumulates in certain solid materials—such as crystals, certain ceramics, and biological matter such as bone, DNA, and various proteins—in response to applied Stress (mechanics), mechanical s ...
properties and is used as a transducer in the interconversion of sound
In physics, sound is a vibration that propagates as an acoustic wave, through a transmission medium such as a gas, liquid or solid.
In human physiology and psychology, sound is the ''reception'' of such waves and their ''perception'' by the ...
and electricity
Electricity is the set of physical phenomena associated with the presence and motion of matter that has a property of electric charge. Electricity is related to magnetism, both being part of the phenomenon of electromagnetism, as described ...
. Many minerals are titanates, such as ilmenite (FeTiO3). Star sapphires
Star Sapphire is the name of several fictional characters in DC Comics; many of them are villainous, and all connected in origin. Within DC continuity, an immortal race of warrior women (the Zamarons) were depicted as having the ancient traditio ...
and rubies
A ruby is a pinkish red to blood-red colored gemstone, a variety of the mineral corundum ( aluminium oxide). Ruby is one of the most popular traditional jewelry gems and is very durable. Other varieties of gem-quality corundum are called sap ...
get their asterism (star-forming shine) from the presence of titanium dioxide impurities.
A variety of reduced oxides (suboxide
Suboxides are a class of oxides wherein the electropositive element is in excess relative to the “normal” oxides. When the electropositive element is a metal, the compounds are sometimes referred to as “metal-rich”. Thus the normal oxide ...
s) of titanium are known, mainly reduced stoichiometries
Stoichiometry refers to the relationship between the quantities of reactants and products before, during, and following chemical reactions.
Stoichiometry is founded on the law of conservation of mass where the total mass of the reactants equals ...
of titanium dioxide obtained by atmospheric plasma spraying
Thermal spraying techniques are coating processes in which melted (or heated) materials are sprayed onto a surface. The "feedstock" (coating precursor) is heated by electrical (plasma or arc) or chemical means (combustion flame).
Thermal sprayi ...
. Ti3O5, described as a Ti(IV)-Ti(III) species, is a purple semiconductor produced by reduction of TiO2 with hydrogen at high temperatures, and is used industrially when surfaces need to be vapor-coated with titanium dioxide: it evaporates as pure TiO, whereas TiO2 evaporates as a mixture of oxides and deposits coatings with variable refractive index. Also known is Ti2O3, with the corundum
Corundum is a crystalline form of aluminium oxide () typically containing traces of iron, titanium, vanadium and chromium. It is a rock-forming mineral. It is a naturally transparent material, but can have different colors depending on the pres ...
structure, and TiO, with the rock salt structure, although often nonstoichiometric.
The alkoxide
In chemistry, an alkoxide is the conjugate base of an alcohol and therefore consists of an organic group bonded to a negatively charged oxygen atom. They are written as , where R is the organic substituent. Alkoxides are strong bases and, whe ...
s of titanium(IV), prepared by treating TiCl4 with alcohols, are colorless compounds that convert to the dioxide on reaction with water. They are industrially useful for depositing solid TiO2 via the sol-gel process. Titanium isopropoxide
Titanium isopropoxide, also commonly referred to as titanium tetraisopropoxide or TTIP, is a chemical compound with the formula . This alkoxide of titanium(IV) is used in organic synthesis and materials science. It is a diamagnetic tetrahedral mo ...
is used in the synthesis of chiral organic compounds via the Sharpless epoxidation
The Sharpless epoxidation reaction is an enantioselective chemical reaction to prepare 2,3-epoxyalcohols from primary and secondary allylic alcohols. The oxidizing agent is ''tert''-butyl hydroperoxide. The method relies on a catalyst formed fro ...
.
Titanium forms a variety of sulfides, but only TiS2 has attracted significant interest. It adopts a layered structure and was used as a cathode in the development of lithium batteries
Lithium battery may refer to:
* Lithium metal battery, a non-rechargeable battery with lithium as an anode
** Rechargeable lithium metal battery, a rechargeable counterpart to the lithium metal battery
* Lithium-ion battery, a rechargeable batte ...
. Because Ti(IV) is a "hard cation", the sulfides of titanium are unstable and tend to hydrolyze to the oxide with release of hydrogen sulfide.
Nitrides and carbides
Titanium nitride
Titanium nitride (TiN; sometimes known as Tinite) is an extremely hard ceramic material, often used as a physical vapor deposition (PVD) coating on titanium alloys, steel, carbide, and aluminium components to improve the substrate's surface prope ...
(TiN) is a refractory solid exhibiting extreme hardness, thermal/electrical conductivity, and a high melting point. TiN has a hardness equivalent to sapphire
Sapphire is a precious gemstone, a variety of the mineral corundum, consisting of aluminium oxide () with trace amounts of elements such as iron, titanium, chromium, vanadium, or magnesium. The name sapphire is derived via the Latin "sapphir ...
and carborundum
Silicon carbide (SiC), also known as carborundum (), is a hard chemical compound containing silicon and carbon. A semiconductor, it occurs in nature as the extremely rare mineral moissanite, but has been mass-produced as a powder and crystal sin ...
(9.0 on the Mohs scale
The Mohs scale of mineral hardness () is a qualitative ordinal scale, from 1 to 10, characterizing scratch resistance of various minerals through the ability of harder material to scratch softer material.
The scale was introduced in 1812 by th ...
), and is often used to coat cutting tools, such as drill bit
Drill bits are cutting tools used in a drill to remove material to create holes, almost always of circular cross-section. Drill bits come in many sizes and shapes and can create different kinds of holes in many different materials. In order ...
s. It is also used as a gold-colored decorative finish and as a barrier layer A diffusion barrier is a thin layer (usually micrometres thick) of metal usually placed between two other metals. It is done to act as a barrier to protect either one of the metals from corrupting the other..
Adhesion of a electroplating, plated me ...
in semiconductor fabrication
Semiconductor device fabrication is the process used to manufacture semiconductor devices, typically integrated circuit (IC) chips such as modern computer processors, microcontrollers, and memory chips such as NAND flash and DRAM that are pres ...
. Titanium carbide
Titanium carbide, Ti C, is an extremely hard ( Mohs 9–9.5) refractory ceramic material, similar to tungsten carbide. It has the appearance of black powder with the sodium chloride (face-centered cubic) crystal structure.
It occurs in nature ...
(TiC), which is also very hard, is found in cutting tools and coatings.
Halides
Titanium tetrachloride
Titanium tetrachloride is the inorganic compound with the formula . It is an important intermediate in the production of titanium metal and the pigment titanium dioxide. is a volatile liquid. Upon contact with humid air, it forms thick clouds o ...
(titanium(IV) chloride, TiCl4) is a colorless volatile liquid (commercial samples are yellowish) that, in air, hydrolyzes with spectacular emission of white clouds. Via the Kroll process The Kroll process is a pyrometallurgical industrial process used to produce metallic titanium from titanium tetrachloride. The Kroll process replaced the Hunter process for almost all commercial production.
Process
In the Kroll process, the TiCl4 ...
, TiCl4 is used in the conversion of titanium ores to titanium metal. Titanium tetrachloride is also used to make titanium dioxide, e.g., for use in white paint. It is widely used in organic chemistry
Organic chemistry is a subdiscipline within chemistry involving the scientific study of the structure, properties, and reactions of organic compounds and organic materials, i.e., matter in its various forms that contain carbon atoms.Clayden, J.; ...
as a Lewis acid
A Lewis acid (named for the American physical chemist Gilbert N. Lewis) is a chemical species that contains an empty orbital which is capable of accepting an electron pair from a Lewis base to form a Lewis adduct. A Lewis base, then, is any sp ...
, for example in the Mukaiyama aldol condensation. In the van Arkel–de Boer process
The van Arkel–de Boer process, also known as the iodide process or crystal-bar process, was the first industrial process for the commercial production of pure ductile titanium, zirconium and some other metals. It was developed by Anton Eduard ...
, titanium tetraiodide
Titanium tetraiodide is an inorganic compound with the formula TiI4. It is a black volatile solid, first reported by Rudolph Weber in 1863. It is an intermediate in the van Arkel–de Boer process for the purification of titanium.
Physical prop ...
(TiI4) is generated in the production of high purity titanium metal.
Titanium(III) and titanium(II) also form stable chlorides. A notable example is titanium(III) chloride
Titanium(III) chloride is the inorganic compound with the formula TiCl3. At least four distinct species have this formula; additionally hydrated derivatives are known. TiCl3 is one of the most common halides of titanium and is an important catalys ...
(TiCl3), which is used as a catalyst
Catalysis () is the process of increasing the rate of a chemical reaction by adding a substance known as a catalyst (). Catalysts are not consumed in the reaction and remain unchanged after it. If the reaction is rapid and the catalyst recyc ...
for production of polyolefin
A polyolefin is a type of polymer with the general formula (CH2CHR)n where R is an alkyl group. They are usually derived from a small set of simple olefins (alkenes). Dominant in a commercial sense are polyethylene and polypropylene. More speciali ...
s (see Ziegler–Natta catalyst A Ziegler–Natta catalyst, named after Karl Ziegler and Giulio Natta, is a catalyst used in the synthesis of polymers of 1-alkenes (alpha-olefins). Two broad classes of Ziegler–Natta catalysts are employed, distinguished by their solubility:
* He ...
) and a reducing agent
Agent may refer to:
Espionage, investigation, and law
*, spies or intelligence officers
* Law of agency, laws involving a person authorized to act on behalf of another
** Agent of record, a person with a contractual agreement with an insuranc ...
in organic chemistry.
Organometallic complexes
Owing to the important role of titanium compounds as polymerization
In polymer chemistry, polymerization (American English), or polymerisation (British English), is a process of reacting monomer, monomer molecules together in a chemical reaction to form polymer chains or three-dimensional networks. There are ...
catalyst, compounds with Ti-C bonds have been intensively studied. The most common organotitanium complex is titanocene dichloride
Titanocene dichloride is the organotitanium compound with the formula ( ''η''5-C5H5)2TiCl2, commonly abbreviated as Cp2TiCl2. This metallocene is a common reagent in organometallic and organic synthesis. It exists as a bright red solid that slowl ...
((C5H5)2TiCl2). Related compounds include Tebbe's reagent
Tebbe's reagent is the organometallic compound with the formula (C5H5)2TiCH2ClAl(CH3)2. It is used in the methylenation of carbonyl compounds, that is it converts organic compounds containing the R2C=O group into the related R2C=CH2 derivative. It ...
and Petasis reagent
The Petasis reagent, named after Nicos A. Petasis, is an organotitanium compound with the formula Cp2Ti(CH3)2. It is an orange-colored solid.
Preparation and use
The Petasis reagent is prepared by the salt metathesis reaction of methylmagnesium ...
. Titanium forms carbonyl complexes
In organic chemistry, a carbonyl group is a functional group composed of a carbon atom double-bonded to an oxygen atom: C=O. It is common to several classes of organic compounds, as part of many larger functional groups. A compound containing a ...
, e.g. (C5H5)2Ti(CO)2.
Anticancer therapy studies
Following the success of platinum-based chemotherapy, titanium(IV) complexes were among the first non-platinum compounds to be tested for cancer treatment. The advantage of titanium compounds lies in their high efficacy and low toxicity ''in vivo
Studies that are ''in vivo'' (Latin for "within the living"; often not italicized in English) are those in which the effects of various biological entities are tested on whole, living organisms or cells, usually animals, including humans, and ...
''.[ In biological environments, hydrolysis leads to the safe and inert titanium dioxide. Despite these advantages the first candidate compounds failed clinical trials due to insufficient efficacy to toxicity ratios and formulation complications.][ Further development resulted in the creation of potentially effective, selective, and stable titanium-based drugs.]
History
Titanium was discovered in 1791 by the clergy
Clergy are formal leaders within established religions. Their roles and functions vary in different religious traditions, but usually involve presiding over specific rituals and teaching their religion's doctrines and practices. Some of the ter ...
man and geologist
A geologist is a scientist who studies the solid, liquid, and gaseous matter that constitutes Earth and other terrestrial planets, as well as the processes that shape them. Geologists usually study geology, earth science, or geophysics, althou ...
William Gregor
William Gregor (25 December 1761 – 11 June 1817) was an English clergyman and mineralogist who discovered the elemental metal titanium.
Early years
He was born at the Trewarthenick Estate in Cornwall, the son of Francis Gregor and Mary Co ...
as an inclusion
Inclusion or Include may refer to:
Sociology
* Social inclusion, aims to create an environment that supports equal opportunity for individuals and groups that form a society.
** Inclusion (disability rights), promotion of people with disabiliti ...
of a mineral in Cornwall
Cornwall (; kw, Kernow ) is a historic county and ceremonial county in South West England. It is recognised as one of the Celtic nations, and is the homeland of the Cornish people. Cornwall is bordered to the north and west by the Atlantic ...
, Great Britain.[ Gregor recognized the presence of a new element in ilmenite][ when he found black sand by a stream and noticed the sand was attracted by a ]magnet
A magnet is a material or object that produces a magnetic field. This magnetic field is invisible but is responsible for the most notable property of a magnet: a force that pulls on other ferromagnetic materials, such as iron, steel, nickel, ...
.[ Analyzing the sand, he determined the presence of two metal oxides: ]iron oxide
Iron oxides are chemical compounds composed of iron and oxygen. Several iron oxides are recognized. All are black magnetic solids. Often they are non-stoichiometric. Oxyhydroxides are a related class of compounds, perhaps the best known of whic ...
(explaining the attraction to the magnet) and 45.25% of a white metallic oxide he could not identify. Realizing that the unidentified oxide contained a metal that did not match any known element, in 1791 Gregor reported his findings in both German and French science journals:''Crell's Annalen Crell's Annalen is a German chemistry journal. Its original name is ''Chemische Annalen für die Freunde der Naturlehre, Arzneygelährtheit, Haushaltungskunst und Manufacturen'', which is usually shortened to ''Chemische Annalen'' and often referre ...
'' and ''Observations et Mémoires sur la Physique''.[
Around the same time, ]Franz-Joseph Müller von Reichenstein
Franz-Joseph Müller, Freiherr von Reichenstein or Franz-Joseph Müller von Reichenstein (1 July 1740 or 4 October 1742 – 12 October 1825 or 1826) was an Austrian mineralogist and mining engineer. Müller held several positions in the Habsburg m ...
produced a similar substance, but could not identify it. The oxide was independently rediscovered in 1795 by Prussia
Prussia, , Old Prussian: ''Prūsa'' or ''Prūsija'' was a German state on the southeast coast of the Baltic Sea. It formed the German Empire under Prussian rule when it united the German states in 1871. It was ''de facto'' dissolved by an em ...
n chemist Martin Heinrich Klaproth
Martin Heinrich Klaproth (1 December 1743 – 1 January 1817) was a German chemist. He trained and worked for much of his life as an apothecary, moving in later life to the university. His shop became the second-largest apothecary in Berlin, and ...
in rutile from Boinik (the German name of Bajmócska), a village in Hungary (now Bojničky in Slovakia).
Klaproth found that it contained a new element and named it for the Titans
In Greek mythology, the Titans ( grc, οἱ Τῑτᾶνες, ''hoi Tītânes'', , ''ho Tītân'') were the pre-Olympian gods. According to the ''Theogony'' of Hesiod, they were the twelve children of the primordial parents Uranus (Sky) and Ga ...
of Greek mythology
A major branch of classical mythology, Greek mythology is the body of myths originally told by the Ancient Greece, ancient Greeks, and a genre of Ancient Greek folklore. These stories concern the Cosmogony, origin and Cosmology#Metaphysical co ...
.[ After hearing about Gregor's earlier discovery, he obtained a sample of manaccanite and confirmed that it contained titanium.
The currently known processes for extracting titanium from its various ores are laborious and costly; it is not possible to reduce the ore by heating with ]carbon
Carbon () is a chemical element with the symbol C and atomic number 6. It is nonmetallic and tetravalent
In chemistry, the valence (US spelling) or valency (British spelling) of an element is the measure of its combining capacity with o ...
(as in iron smelting) because titanium combines with the carbon to produce titanium carbide.[ Pure metallic titanium (99.9%) was first prepared in 1910 by Matthew A. Hunter at ]Rensselaer Polytechnic Institute
Rensselaer Polytechnic Institute () (RPI) is a private research university in Troy, New York, with an additional campus in Hartford, Connecticut. A third campus in Groton, Connecticut closed in 2018. RPI was established in 1824 by Stephen Van ...
by heating TiCl4 with sodium
Sodium is a chemical element with the symbol Na (from Latin ''natrium'') and atomic number 11. It is a soft, silvery-white, highly reactive metal. Sodium is an alkali metal, being in group 1 of the periodic table. Its only stable iso ...
at 700–800 °C under great pressure in a batch process known as the Hunter process
The Hunter process was the first industrial process to produce pure ductile metallic titanium. It was invented in 1910 by Matthew A. Hunter, a chemist born in New Zealand who worked in the United States. The process involves reducing titanium tet ...
.[ Titanium metal was not used outside the laboratory until 1932 when ]William Justin Kroll :''See also German classic philologist, Wilhelm Kroll (philologist) (1869–1939).''
William Justin Kroll (born Guillaume Justin Kroll; November 24, 1889 – March 30, 1973) was a Luxembourgish metallurgist. He is best known for inventing the ...
produced it by reducing titanium tetrachloride (TiCl4) with calcium
Calcium is a chemical element with the symbol Ca and atomic number 20. As an alkaline earth metal, calcium is a reactive metal that forms a dark oxide-nitride layer when exposed to air. Its physical and chemical properties are most similar to ...
. Eight years later he refined this process with magnesium and with sodium in what became known as the Kroll process.[ Although research continues to seek cheaper and more efficient routes, such as the ]FFC Cambridge process
The FFC Cambridge process is an electrochemical method for producing Titanium (Ti) from titanium oxide by electrolysis in molten calcium salts.
History
A process for electrochemical production of titanium was described in a 1904 German patent. In ...
, the Kroll process is still predominantly used for commercial production.[
]
Titanium of very high purity was made in small quantities when Anton Eduard van Arkel
Anton Eduard van Arkel, (19 November 1893 – 14 March 1976) was a Dutch chemist.
Van Arkel suggested the names "pnictogen" and "pnictide" to refer to chemical elements in group 15 (the nitrogen group or nitrogen family) of the periodic table.
...
and Jan Hendrik de Boer
Jan Hendrik de Boer (19 March 1899 – 25 April 1971) was a Dutch physicist and chemist.
De Boer was born in Ruinen, De Wolden, and died in The Hague. He studied at the University of Groningen and was later employed in industry.
Together with ...
discovered the iodide process in 1925, by reacting with iodine and decomposing the formed vapors over a hot filament to pure metal.
In the 1950s and 1960s, the Soviet Union pioneered the use of titanium in military and submarine applications[ ( Alfa class and Mike class) as part of programs related to the Cold War. Starting in the early 1950s, titanium came into use extensively in military aviation, particularly in high-performance jets, starting with aircraft such as the ]F-100 Super Sabre
The North American F-100 Super Sabre is an American supersonic jet fighter aircraft that served with the United States Air Force (USAF) from 1954 to 1971 and with the Air National Guard (ANG) until 1979. The first of the Century Series of ...
and Lockheed A-12
The Lockheed A-12 is a high-altitude, Mach 3+ reconnaissance aircraft built for the United States Central Intelligence Agency (CIA) by Lockheed's Skunk Works, based on the designs of Clarence "Kelly" Johnson. The aircraft was designate ...
and SR-71
The Lockheed SR-71 "Blackbird" is a Range (aeronautics), long-range, high-altitude, Mach number, Mach 3+ military strategy, strategic reconnaissance aircraft developed and manufactured by the American aerospace company Lockheed Corporati ...
.
Throughout the Cold War period, titanium was considered a strategic material
Strategic material is any sort of raw material that is important to an individual's or organization's strategic plan and supply chain management. Lack of supply of strategic materials may leave an organization or government vulnerable to disru ...
by the U.S. government, and a large stockpile of titanium sponge
Sponges, the members of the phylum Porifera (; meaning 'pore bearer'), are a basal animal clade as a sister of the diploblasts. They are multicellular organisms that have bodies full of pores and channels allowing water to circulate through t ...
(a porous form of the pure metal) was maintained by the Defense National Stockpile Center The Defense National Stockpile Center (DNSC) is a branch of the United States' Defense Logistics Agency, whose purpose it is to store, secure, and sell raw materials. The DNSC is based in Fort Belvoir and has operations throughout the United States. ...
, until the stockpile was dispersed in the 2000s. As of 2021, the four leading producers of titanium sponge were China (52%), Japan (24%), Russia (16%) and Kazakhstan (7%).
Production
The processing of titanium metal occurs in four major steps: reduction of titanium ore into "sponge", a porous form; melting of sponge, or sponge plus a master alloy to form an ingot; primary fabrication, where an ingot is converted into general mill products such as billet
A billet is a living-quarters to which a soldier is assigned to sleep. Historically, a billet was a private dwelling that was required to accept the soldier.
Soldiers are generally billeted in barracks or garrisons when not on combat duty, alth ...
, bar, plate
Plate may refer to:
Cooking
* Plate (dishware), a broad, mainly flat vessel commonly used to serve food
* Plates, tableware, dishes or dishware used for setting a table, serving food and dining
* Plate, the content of such a plate (for example: ...
, sheet, strip, and tube
Tube or tubes may refer to:
* ''Tube'' (2003 film), a 2003 Korean film
* ''The Tube'' (TV series), a music related TV series by Channel 4 in the United Kingdom
* "Tubes" (Peter Dale), performer on the Soccer AM television show
* Tube (band), a ...
; and secondary fabrication of finished shapes from mill products.
Because it cannot be readily produced by reduction of titanium dioxide,[ titanium metal is obtained by reduction of TiCl4 with magnesium metal in the Kroll process. The complexity of this batch production in the Kroll process explains the relatively high market value of titanium,] despite the Kroll process being less expensive than the Hunter process.[ To produce the TiCl4 required by the Kroll process, the dioxide is subjected to ]carbothermic reduction
Carbothermic reactions involve the reduction of substances, often metal oxides (O^2-), using carbon as the reducing agent. These chemical reactions are usually conducted at temperatures of several hundred degrees Celsius. Such processes are applie ...
in the presence of chlorine
Chlorine is a chemical element with the Symbol (chemistry), symbol Cl and atomic number 17. The second-lightest of the halogens, it appears between fluorine and bromine in the periodic table and its properties are mostly intermediate betwee ...
. In this process, the chlorine gas is passed over a red-hot mixture of rutile or ilmenite in the presence of carbon.
After extensive purification by fractional distillation
Fractional distillation is the separation of a mixture into its component parts, or fractions. Chemical compounds are separated by heating them to a temperature at which one or more fractions of the mixture will vaporize. It uses distillation to ...
, the TiCl4 is reduced with molten magnesium in an argon
Argon is a chemical element with the symbol Ar and atomic number 18. It is in group 18 of the periodic table and is a noble gas. Argon is the third-most abundant gas in Earth's atmosphere, at 0.934% (9340 ppmv). It is more than twice as abu ...
atmosphere.[ Titanium metal can be further purified by the van Arkel–de Boer process, which involves ]thermal decomposition
Thermal decomposition, or thermolysis, is a chemical decomposition caused by heat. The decomposition temperature of a substance is the temperature at which the substance chemically decomposes. The reaction is usually endothermic as heat is req ...
of titanium tetraiodide.
:2FeTiO3 + 7Cl2 + 6C -> 00^oC2FeCl3 + 2TiCl4 + 6CO
:TiCl4 + 2Mg -> 100^oCTi + 2MgCl2
Common titanium alloy
Titanium alloys are alloys that contain a mixture of titanium and other chemical elements. Such alloys have very high tensile strength and toughness (even at extreme temperatures). They are light in weight, have extraordinary corrosion resistance a ...
s are made by reduction. For example, cuprotitanium (rutile with copper
Copper is a chemical element with the symbol Cu (from la, cuprum) and atomic number 29. It is a soft, malleable, and ductile metal with very high thermal and electrical conductivity. A freshly exposed surface of pure copper has a pinkis ...
added is reduced), ferrocarbon titanium (ilmenite reduced with coke in an electric furnace), and manganotitanium (rutile with manganese or manganese oxides) are reduced.
About fifty grades of titanium alloy
Titanium alloys are alloys that contain a mixture of titanium and other chemical elements. Such alloys have very high tensile strength and toughness (even at extreme temperatures). They are light in weight, have extraordinary corrosion resistance a ...
s are designed and currently used, although only a couple of dozen are readily available commercially. The ASTM International
ASTM International, formerly known as American Society for Testing and Materials, is an international standards organization that develops and publishes voluntary consensus technical standards for a wide range of materials, products, systems, an ...
recognizes 31 grades of titanium metal and alloys, of which grades one through four are commercially pure (unalloyed). Those four vary in tensile strength as a function of oxygen content, with grade 1 being the most ductile (lowest tensile strength with an oxygen content of 0.18%), and grade 4 the least ductile (highest tensile strength with an oxygen content of 0.40%).[ The remaining grades are alloys, each designed for specific properties of ductility, strength, hardness, electrical resistivity, creep resistance, specific corrosion resistance, and combinations thereof.
In addition to the ASTM specifications, titanium alloys are also produced to meet aerospace and military specifications (SAE-AMS, MIL-T), ISO standards, and country-specific specifications, as well as proprietary end-user specifications for aerospace, military, medical, and industrial applications.
]Titanium powder Titanium powder metallurgy (P/M) offers the possibility of creating net shape or near net shape parts without the material loss and cost associated with having to machine intricate components from wrought billet. Powders can be produced by the blend ...
is manufactured using a flow production
Flow may refer to:
Science and technology
* Fluid flow, the motion of a gas or liquid
* Flow (geomorphology), a type of mass wasting or slope movement in geomorphology
* Flow (mathematics), a group action of the real numbers on a set
* Flow (psyc ...
process known as the Armstrong process that is similar to the batch production Hunter process. A stream of titanium tetrachloride gas is added to a stream of molten sodium; the products (sodium chloride salt and titanium particles) is filtered from the extra sodium. Titanium is then separated from the salt by water washing. Both sodium and chlorine are recycled to produce and process more titanium tetrachloride.
Fabrication
All welding
Welding is a fabrication (metal), fabrication process that joins materials, usually metals or thermoplastics, by using high heat to melt the parts together and allowing them to cool, causing Fusion welding, fusion. Welding is distinct from lower ...
of titanium must be done in an inert atmosphere of argon or helium
Helium (from el, ἥλιος, helios, lit=sun) is a chemical element with the symbol He and atomic number 2. It is a colorless, odorless, tasteless, non-toxic, inert, monatomic gas and the first in the noble gas group in the periodic table. ...
to shield it from contamination with atmospheric gases (oxygen, nitrogen, and hydrogen).[ Contamination causes a variety of conditions, such as ]embrittlement
Embrittlement is a significant decrease of ductility of a material, which makes the material Brittleness, brittle. Embrittlement is used to describe any phenomena where the environment compromises a stressed material's mechanical performance, such ...
, which reduce the integrity of the assembly welds and lead to joint failure.
Titanium is very difficult to solder
Solder (; NA: ) is a fusible metal alloy used to create a permanent bond between metal workpieces. Solder is melted in order to wet the parts of the joint, where it adheres to and connects the pieces after cooling. Metals or alloys suitable ...
directly, and hence a solderable The solderability of a substrate is a measure of the ease with which a soldered joint can be made to that material. Good solderability requires wetting (low contact angle) of the substrate by the solder.
__TOC__ Of metals
Solderability varies depe ...
metal or alloy such as steel is coated on titanium prior to soldering. Titanium metal can be machined with the same equipment and the same processes as stainless steel
Stainless steel is an alloy of iron that is resistant to rusting and corrosion. It contains at least 11% chromium and may contain elements such as carbon, other nonmetals and metals to obtain other desired properties. Stainless steel's corros ...
.
Forming and forging
Commercially pure flat product (sheet, plate) can be formed readily, but processing must take into account of the tendency of the metal to springback. This is especially true of certain high-strength alloys. Exposure to the oxygen in air at the elevated temperatures used in forging results in formation of an brittle oxygen-rich metallic surface layer called "alpha case
In metallurgy, alpha case is the oxygen-enriched surface phase that occurs when titanium and its alloys are exposed to heated air or oxygen. Alpha case is hard and brittle, and tends to create a series of microcracks that will reduce the metal's p ...
" that worsens the fatigue properties, so it must be removed by milling, etching, or electrochemical treatment.
Applications
Titanium is used in steel as an alloying element ( ferro-titanium) to reduce grain size
Grain size (or particle size) is the diameter of individual grains of sediment, or the lithified particles in clastic rocks. The term may also be applied to other granular materials. This is different from the crystallite size, which refer ...
and as a deoxidizer, and in stainless steel to reduce carbon content. Titanium is often alloyed with aluminium (to refine grain size), vanadium
Vanadium is a chemical element with the symbol V and atomic number 23. It is a hard, silvery-grey, malleable transition metal. The elemental metal is rarely found in nature, but once isolated artificially, the formation of an oxide layer ( pas ...
, copper (to harden), iron
Iron () is a chemical element with symbol Fe (from la, ferrum) and atomic number 26. It is a metal that belongs to the first transition series and group 8 of the periodic table. It is, by mass, the most common element on Earth, right in f ...
, manganese
Manganese is a chemical element with the symbol Mn and atomic number 25. It is a hard, brittle, silvery metal, often found in minerals in combination with iron. Manganese is a transition metal with a multifaceted array of industrial alloy use ...
, molybdenum
Molybdenum is a chemical element with the symbol Mo and atomic number 42 which is located in period 5 and group 6. The name is from Neo-Latin ''molybdaenum'', which is based on Ancient Greek ', meaning lead, since its ores were confused with lea ...
, and other metals. Titanium mill products (sheet, plate, bar, wire, forgings, castings) find application in industrial, aerospace, recreational, and emerging markets. Powdered titanium is used in pyrotechnics
Pyrotechnics is the science and craft of creating such things as fireworks, safety matches, oxygen candles, explosive bolts and other fasteners, parts of automotive airbags, as well as gas-pressure blasting in mining, quarrying, and demolition. ...
as a source of bright-burning particles.
Pigments, additives, and coatings
About 95% of all titanium ore is destined for refinement into titanium dioxide (), an intensely white permanent pigment
A pigment is a colored material that is completely or nearly insoluble in water. In contrast, dyes are typically soluble, at least at some stage in their use. Generally dyes are often organic compounds whereas pigments are often inorganic compo ...
used in paints, paper, toothpaste, and plastics. It is also used in cement, in gemstones, as an optical opacifier in paper, and a strengthening agent in graphite composite fishing rods and golf clubs.
pigment is chemically inert, resists fading in sunlight, and is very opaque: it imparts a pure and brilliant white color to the brown or grey chemicals that form the majority of household plastics.[ In nature, this compound is found in the minerals anatase, brookite, and rutile.][ Paint made with titanium dioxide does well in severe temperatures and marine environments.][ Pure titanium dioxide has a very high ]index of refraction
In optics, the refractive index (or refraction index) of an optical medium is a dimensionless number that gives the indication of the light bending ability of that medium.
The refractive index determines how much the path of light is bent, or ...
and an optical dispersion
In optics, and by analogy other branches of physics dealing with wave propagation, dispersion is the phenomenon in which the phase velocity of a wave depends on its frequency; sometimes the term chromatic dispersion is used for specificity to o ...
higher than diamond
Diamond is a Allotropes of carbon, solid form of the element carbon with its atoms arranged in a crystal structure called diamond cubic. Another solid form of carbon known as graphite is the Chemical stability, chemically stable form of car ...
.[ In addition to being a very important pigment, titanium dioxide is also used in sunscreens.][
]
Aerospace and marine
Because titanium alloys have high tensile strength
Ultimate tensile strength (UTS), often shortened to tensile strength (TS), ultimate strength, or F_\text within equations, is the maximum stress that a material can withstand while being stretched or pulled before breaking. In brittle materials t ...
to density ratio, high corrosion resistance
Corrosion is a natural process that converts a refined metal into a more chemically stable oxide. It is the gradual deterioration of materials (usually a metal) by chemical or electrochemical reaction with their environment. Corrosion engine ...
,[ fatigue resistance, high crack resistance,] and ability to withstand moderately high temperatures without creeping, they are used in aircraft, armor plating, naval ships, spacecraft, and missiles.[ For these applications, titanium is alloyed with aluminium, zirconium, nickel,][ vanadium, and other elements to manufacture a variety of components including critical structural parts, fire walls, ]landing gear
Landing gear is the undercarriage of an aircraft or spacecraft that is used for takeoff or landing. For aircraft it is generally needed for both. It was also formerly called ''alighting gear'' by some manufacturers, such as the Glenn L. Martin ...
, exhaust ducts (helicopters), and hydraulic systems. In fact, about two thirds of all titanium metal produced is used in aircraft engines and frames.[ The ]titanium 6AL-4V
Titanium alloys are alloys that contain a mixture of titanium and other chemical elements. Such alloys have very high tensile strength and toughness (even at extreme temperatures). They are light in weight, have extraordinary corrosion resistance a ...
alloy accounts for almost 50% of all alloys used in aircraft applications.
The Lockheed A-12 and its development the SR-71 "Blackbird" were two of the first aircraft frames where titanium was used, paving the way for much wider use in modern military and commercial aircraft. A large amount of titanium mill products are used in the production of many aircraft, such as (following values are amount of raw mill products used ... only a fraction of this ends up in the finished aircraft): 116 metric tons are used in the Boeing 787
The Boeing 787 Dreamliner is an American wide-body jet airliner developed and manufactured by Boeing Commercial Airplanes.
After dropping its unconventional Sonic Cruiser project, Boeing announced the conventional 7E7 on January 29, 2003, ...
, 77 in the Airbus A380
The Airbus A380 is a large wide-body airliner that was developed and produced by Airbus. It is the world's largest passenger airliner and only full-length double-deck jet airliner.
Airbus studies started in 1988, and the project was annou ...
, 59 in the Boeing 777
The Boeing 777, commonly referred to as the Triple Seven, is an American long-range wide-body airliner developed and manufactured by Boeing Commercial Airplanes. It is the world's largest twinjet.
The 777 was designed to bridge the gap bet ...
, 45 in the Boeing 747
The Boeing 747 is a large, long-range wide-body airliner designed and manufactured by Boeing Commercial Airplanes in the United States between 1968 and 2022.
After introducing the 707 in October 1958, Pan Am wanted a jet times its size, t ...
, 18 in the Boeing 737
The Boeing 737 is a narrow-body aircraft produced by Boeing at its Renton Factory in Washington.
Developed to supplement the Boeing 727 on short and thin routes, the twinjet retains the 707 fuselage width and six abreast seating with two un ...
, 32 in the Airbus A340
The Airbus A340 is a long-range, wide-body passenger airliner that was developed and produced by Airbus.
In the mid-1970s, Airbus conceived several derivatives of the A300, its first airliner, and developed the A340 quadjet in parallel with ...
, 18 in the Airbus A330
The Airbus A330 is a wide-body aircraft developed and produced by Airbus.
Airbus conceived several derivatives of the A300, its first airliner in the mid-1970s. Then the company began development on the A330 twinjet in parallel with the A340 ...
, and 12 in the Airbus A320
The Airbus A320 family is a series of Narrow-body aircraft, narrow-body airliners developed and produced by Airbus.
The A320 was launched in March 1984, Maiden flight, first flew on 22 February 1987, and was introduced in April 1988 by Air F ...
. In aero engine applications, titanium is used for rotors, compressor blades, hydraulic system components, and nacelle
A nacelle ( ) is a "streamlined body, sized according to what it contains", such as an engine, fuel, or equipment on an aircraft. When attached by a pylon entirely outside the airframe, it is sometimes called a pod, in which case it is attached ...
s. An early use in jet engines was for the Orenda Iroquois
The Orenda PS.13 Iroquois was an advanced turbojet engine designed for military use. It was developed by the Canadian aircraft engine manufacturer Orenda Engines, a part of the Avro Canada group. Intended for the CF-105 Arrow interceptor, de ...
in the 1950s.
Because titanium is resistant to corrosion by sea water, it is used to make propeller shafts, rigging, and heat exchanger
A heat exchanger is a system used to transfer heat between a source and a working fluid. Heat exchangers are used in both cooling and heating processes. The fluids may be separated by a solid wall to prevent mixing or they may be in direct contac ...
s in desalination plant
Desalination is a process that takes away mineral components from saline water. More generally, desalination refers to the removal of salts and minerals from a target substance, as in soil desalination, which is an issue for agriculture. Saltwa ...
s; heater-chillers for salt water aquariums, fishing line and leader, and divers' knives. Titanium is used in the housings and components of ocean-deployed surveillance and monitoring devices for science and the military. The former Soviet Union
The Soviet Union,. officially the Union of Soviet Socialist Republics. (USSR),. was a transcontinental country that spanned much of Eurasia from 1922 to 1991. A flagship communist state, it was nominally a federal union of fifteen national ...
developed techniques for making submarines with hulls of titanium alloys forging titanium in huge vacuum tubes.
Titanium is used in the walls of the Juno spacecraft's vault
Vault may refer to:
* Jumping, the act of propelling oneself upwards
Architecture
* Vault (architecture), an arched form above an enclosed space
* Bank vault, a reinforced room or compartment where valuables are stored
* Burial vault (enclosure ...
to shield on-board electronics.
Industrial
Welded titanium pipe and process equipment (heat exchangers, tanks, process vessels, valves) are used in the chemical and petrochemical industries primarily for corrosion resistance. Specific alloys are used in oil and gas downhole applications and nickel
Nickel is a chemical element with symbol Ni and atomic number 28. It is a silvery-white lustrous metal with a slight golden tinge. Nickel is a hard and ductile transition metal. Pure nickel is chemically reactive but large pieces are slow to ...
hydrometallurgy
Hydrometallurgy is a technique within the field of extractive metallurgy, the obtaining of metals from their ores. Hydrometallurgy involve the use of aqueous solutions for the recovery of metals from ores, concentrates, and recycled or residual m ...
for their high strength (e. g.: titanium beta C alloy), corrosion resistance, or both. The pulp and paper industry
The pulp and paper industry comprises companies that use wood as raw material and produce pulp, paper, paperboard and other cellulose-based products.
Manufacturing process
The pulp is fed to a paper machine where it is formed as a paper web an ...
uses titanium in process equipment exposed to corrosive media, such as sodium hypochlorite
Sodium hypochlorite (commonly known in a dilute solution as bleach) is an Inorganic chemistry, inorganic chemical compound with the chemical formula, formula NaOCl (or NaClO), comprising a sodium cation () and a hypochlorite anion (or ). It may ...
or wet chlorine gas (in the bleachery). Other applications include ultrasonic welding
Ultrasonic welding is an industrial process whereby high-frequency ultrasonic acoustic vibrations are locally applied to work pieces being held together under pressure to create a solid-state weld. It is commonly used for plastics and metals, and ...
, wave soldering
Wave soldering is a bulk soldering process used for the manufacturing of printed circuit boards. The circuit board is passed over a pan of molten solder in which a pump produces an upwelling of solder that looks like a standing wave. As the ci ...
, and sputtering
In physics, sputtering is a phenomenon in which microscopic particles of a solid material are ejected from its surface, after the material is itself bombarded by energetic particles of a plasma or gas. It occurs naturally in outer space, and can ...
targets.
Titanium tetrachloride (TiCl4), a colorless liquid, is important as an intermediate in the process of making TiO2 and is also used to produce the Ziegler–Natta catalyst. Titanium tetrachloride is also used to iridize glass and, because it fumes strongly in moist air, it is used to make smoke screens.
Consumer and architectural
Titanium metal is used in automotive applications, particularly in automobile and motorcycle racing where low weight and high strength and rigidity are critical. The metal is generally too expensive for the general consumer market, though some late model Corvettes
A corvette is a small warship. It is traditionally the smallest class of vessel considered to be a proper (or " rated") warship. The warship class above the corvette is that of the frigate, while the class below was historically that of the sloop ...
have been manufactured with titanium exhausts, and a Corvette Z06's LT4 supercharged engine uses lightweight, solid titanium intake valves for greater strength and resistance to heat.
Titanium is used in many sporting goods: tennis rackets, golf clubs, lacrosse stick shafts; cricket, hockey, lacrosse, and football helmet grills, and bicycle frames and components. Although not a mainstream material for bicycle production, titanium bikes have been used by racing teams and adventure cyclists.
Titanium alloys are used in spectacle frames that are rather expensive but highly durable, long lasting, light weight, and cause no skin allergies. Many backpackers use titanium equipment, including cookware, eating utensils, lanterns, and tent stakes. Though slightly more expensive than traditional steel or aluminium alternatives, titanium products can be significantly lighter without compromising strength. Titanium horseshoes are preferred to steel by farrier
A farrier is a specialist in equine hoof care, including the trimming and balancing of horses' hooves and the placing of shoes on their hooves, if necessary. A farrier combines some blacksmith's skills (fabricating, adapting, and adjus ...
s because they are lighter and more durable.
Titanium has occasionally been used in architecture. The Monument to Yuri Gagarin, the first man to travel in space (), as well as the Monument to the Conquerors of Space
The ''Monument to the Conquerors of Space'' ( rus, Монуме́нт «Покори́телям ко́смоса», r=Monumént "Pokorítelyam kósmosa", p=mənʊˈmʲent pəkɐrʲˈitʲɪlʲɪm ˈkosməsə) is a giant obelisk erected in Mosc ...
on top of the Cosmonaut Museum in Moscow are made of titanium for the metal's attractive color and association with rocketry. The Guggenheim Museum Bilbao
The Guggenheim Museum Bilbao is a museum of modern and contemporary art designed by Canadian-American architect Frank Gehry, and located in Bilbao, Basque Country, Spain. The museum was inaugurated on 18 October 1997 by King Juan Carlos I of Spai ...
and the Cerritos Millennium Library
The Cerritos Library is the civic library for the City of Cerritos, California. It was rededicated on March 16, 2002, with the new moniker and the current futuristic design. It was the first building to feature an exterior clad with titanium pan ...
were the first buildings in Europe and North America, respectively, to be sheathed in titanium panels. Titanium sheathing was used in the Frederic C. Hamilton Building in Denver, Colorado.
Because of titanium's superior strength and light weight relative to other metals (steel, stainless steel, and aluminium), and because of recent advances in metalworking techniques, its use has become more widespread in the manufacture of firearms. Primary uses include pistol frames and revolver cylinders. For the same reasons, it is used in the body of laptop computers (for example, in Apple
An apple is an edible fruit produced by an apple tree (''Malus domestica''). Apple fruit tree, trees are agriculture, cultivated worldwide and are the most widely grown species in the genus ''Malus''. The tree originated in Central Asia, wh ...
's PowerBook line).[
Some upmarket lightweight and corrosion-resistant tools, such as shovels, knife handles and flashlights, are made of titanium or titanium alloys.]
Jewelry
Because of its durability, titanium has become more popular for designer jewelry (particularly, titanium rings).[ Its inertness makes it a good choice for those with allergies or those who will be wearing the jewelry in environments such as swimming pools. Titanium is also alloyed with gold to produce an alloy that can be marketed as 24-karat gold because the 1% of alloyed Ti is insufficient to require a lesser mark. The resulting alloy is roughly the hardness of 14-karat gold and is more durable than pure 24-karat gold.
Titanium's durability, light weight, and dent and corrosion resistance make it useful for ]watch
A watch is a portable timepiece intended to be carried or worn by a person. It is designed to keep a consistent movement despite the motions caused by the person's activities. A wristwatch is designed to be worn around the wrist, attached by ...
cases. Some artists work with titanium to produce sculptures, decorative objects and furniture.
Titanium may be anodized
Anodizing is an electrolytic passivation process used to increase the thickness of the natural oxide layer on the surface of metal parts.
The process is called ''anodizing'' because the part to be treated forms the anode electrode of an electro ...
to vary the thickness of the surface oxide layer, causing optical interference fringe
In physics, interference is a phenomenon in which two waves combine by adding their displacement together at every single point in space and time, to form a resultant wave of greater, lower, or the same amplitude. Constructive and destructive ...
s and a variety of bright colors. With this coloration and chemical inertness, titanium is a popular metal for body piercing
Body piercing, which is a form of body modification, is the practice of puncturing or cutting a part of the human body, creating an opening in which jewelry may be worn, or where an implant could be inserted. The word ''piercing'' can refer to ...
.
Titanium has a minor use in dedicated non-circulating coins and medals. In 1999, Gibraltar released the world's first titanium coin for the millennium celebration. The Gold Coast Titans
The Gold Coast Titans are a professional rugby league football club, based on the Gold Coast, Queensland, Australia. The club competes in the National Rugby League (NRL), Australia and New Zealand's national rugby league club competition. The ...
, an Australian rugby league team, award a medal of pure titanium to their player of the year.
Medical
Because titanium is biocompatible
Biocompatibility is related to the behavior of biomaterials in various contexts. The term refers to the ability of a material to perform with an appropriate host response in a specific situation. The ambiguity of the term reflects the ongoing de ...
(non-toxic and not rejected by the body), it has many medical uses, including surgical implements and implants, such as hip balls and sockets (joint replacement
Replacement arthroplasty (from Greek ''arthron'', joint, limb, articulate, + ''plassein'', to form, mould, forge, feign, make an image of), or joint replacement surgery, is a procedure of orthopedic surgery in which an arthritic or dysfunctional j ...
) and dental implant
A dental implant (also known as an endosseous implant or fixture) is a prosthesis that interfaces with the bone of the jaw or skull to support a dental prosthesis such as a crown, bridge, denture, or facial prosthesis or to act as an orthodonti ...
s that can stay in place for up to 20 years. The titanium is often alloyed with about 4% aluminium or 6% Al and 4% vanadium.
Titanium has the inherent ability to osseointegrate
Osseointegration (from Latin ''osseus'' "bone, bony" and ''integrare'' "to make whole") is the direct structural and functional connection between living bone and the surface of a load-bearing Implant (medicine), artificial implant ("load-bearing ...
, enabling use in dental implants
A dental implant (also known as an endosseous implant or fixture) is a prosthesis that interfaces with the bone of the jaw or skull to support a dental prosthesis such as a crown, bridge, denture, or facial prosthesis or to act as an orthodonti ...
that can last for over 30 years. This property is also useful for orthopedic implant An orthopedic implant is a medical device manufactured to replace a missing joint or bone or to support a damaged bone. The medical implant is mainly fabricated using stainless steel and titanium alloys for strength and the plastic coating that is ...
applications. These benefit from titanium's lower modulus of elasticity (Young's modulus
Young's modulus E, the Young modulus, or the modulus of elasticity in tension or compression (i.e., negative tension), is a mechanical property that measures the tensile or compressive stiffness of a solid material when the force is applied leng ...
) to more closely match that of the bone that such devices are intended to repair. As a result, skeletal loads are more evenly shared between bone and implant, leading to a lower incidence of bone degradation due to stress shielding and periprosthetic Periprosthetic in medicine refers to a structure in close relation to an implant.
Clinically it can refer to:
*Bone fracture or 'periprosthetic fracture' around an artificial joint, e.g. after a knee replacement
*infection around an artificial jo ...
bone fractures, which occur at the boundaries of orthopedic implants. However, titanium alloys' stiffness is still more than twice that of bone, so adjacent bone bears a greatly reduced load and may deteriorate.
Because titanium is non-ferromagnetic
Ferromagnetism is a property of certain materials (such as iron) which results in a large observed magnetic permeability, and in many cases a large magnetic coercivity allowing the material to form a permanent magnet. Ferromagnetic materials ...
, patients with titanium implants can be safely examined with magnetic resonance imaging
Magnetic resonance imaging (MRI) is a medical imaging technique used in radiology to form pictures of the anatomy and the physiological processes of the body. MRI scanners use strong magnetic fields, magnetic field gradients, and radio wave ...
(convenient for long-term implants). Preparing titanium for implantation in the body involves subjecting it to a high-temperature plasma
Plasma or plasm may refer to:
Science
* Plasma (physics), one of the four fundamental states of matter
* Plasma (mineral), a green translucent silica mineral
* Quark–gluon plasma, a state of matter in quantum chromodynamics
Biology
* Blood pla ...
arc which removes the surface atoms, exposing fresh titanium that is instantly oxidized.
Modern advancements in additive manufacturing techniques have increased potential for titanium use in orthopedic implant applications. Complex implant scaffold designs can be 3D-printed using titanium alloys, which allows for more patient-specific applications and increased implant osseointegration.
Titanium is used for the surgical instrument
A surgical instrument is a tool or device for performing specific actions or carrying out desired effects during a surgery or operation, such as modifying biological tissue, or to provide access for viewing it. Over time, many different kinds of ...
s used in image-guided surgery Image-guided surgery (IGS) is any surgical procedure where the surgeon uses tracked surgical instruments in conjunction with preoperative or intraoperative images in order to directly or indirectly guide the procedure. Image guided surgery systems u ...
, as well as wheelchairs, crutches, and any other products where high strength and low weight are desirable.
Titanium dioxide nanoparticle
A nanoparticle or ultrafine particle is usually defined as a particle of matter that is between 1 and 100 nanometres (nm) in diameter. The term is sometimes used for larger particles, up to 500 nm, or fibers and tubes that are less than 1 ...
s are widely used in electronics and the delivery of pharmaceuticals
A medication (also called medicament, medicine, pharmaceutical drug, medicinal drug or simply drug) is a drug used to diagnose, cure, treat, or prevent disease. Drug therapy (pharmacotherapy) is an important part of the medical field and rel ...
and cosmetics.
Nuclear waste storage
Because of its corrosion resistance, containers made of titanium have been studied for the long-term storage of nuclear waste. Containers lasting more than 100,000 years are thought possible with manufacturing conditions that minimize material defects. A titanium "drip shield" could also be installed over containers of other types to enhance their longevity.
Precautions
Titanium is non-toxic even in large doses and does not play any natural role inside the human body
The human body is the structure of a Human, human being. It is composed of many different types of Cell (biology), cells that together create Tissue (biology), tissues and subsequently organ systems. They ensure homeostasis and the life, viabi ...
. An estimated quantity of 0.8 milligrams of titanium is ingested by humans each day, but most passes through without being absorbed in the tissues. It does, however, sometimes bio-accumulate in tissues that contain silica
Silicon dioxide, also known as silica, is an oxide of silicon with the chemical formula , most commonly found in nature as quartz and in various living organisms. In many parts of the world, silica is the major constituent of sand. Silica is one ...
. One study indicates a possible connection between titanium and yellow nail syndrome.
As a powder or in the form of metal shavings, titanium metal poses a significant fire hazard and, when heated in air
The atmosphere of Earth is the layer of gases, known collectively as air, retained by Earth's gravity that surrounds the planet and forms its planetary atmosphere. The atmosphere of Earth protects life on Earth by creating pressure allowing f ...
, an explosion hazard. Water and carbon dioxide
Carbon dioxide (chemical formula ) is a chemical compound made up of molecules that each have one carbon atom covalently double bonded to two oxygen atoms. It is found in the gas state at room temperature. In the air, carbon dioxide is transpar ...
are ineffective for extinguishing a titanium fire; Class D dry powder agents must be used instead.
When used in the production or handling of chlorine, titanium should not be exposed to dry chlorine gas because it may result in a titanium–chlorine fire.
Titanium can catch fire when a fresh, non-oxidized surface comes in contact with liquid oxygen
Liquid oxygen—abbreviated LOx, LOX or Lox in the aerospace, submarine and gas industries—is the liquid form of molecular oxygen. It was used as the oxidizer in the first liquid-fueled rocket invented in 1926 by Robert H. Goddard, an applica ...
.
Function in plants
An unknown mechanism in plant
Plants are predominantly photosynthetic eukaryotes of the kingdom Plantae. Historically, the plant kingdom encompassed all living things that were not animals, and included algae and fungi; however, all current definitions of Plantae exclud ...
s may use titanium to stimulate the production of carbohydrate
In organic chemistry, a carbohydrate () is a biomolecule consisting of carbon (C), hydrogen (H) and oxygen (O) atoms, usually with a hydrogen–oxygen atom ratio of 2:1 (as in water) and thus with the empirical formula (where ''m'' may or ma ...
s and encourage growth. This may explain why most plants contain about 1 part per million
In science and engineering, the parts-per notation is a set of pseudo-units to describe small values of miscellaneous dimensionless quantities, e.g. mole fraction or mass fraction. Since these fractions are quantity-per-quantity measures, they ...
(ppm) of titanium, food plants have about 2 ppm, and horsetail
''Equisetum'' (; horsetail, snake grass, puzzlegrass) is the only living genus in Equisetaceae, a family of ferns, which reproduce by spores rather than seeds.
''Equisetum'' is a "living fossil", the only living genus of the entire subclass Eq ...
and nettle
{{redirect, Nettle
Nettle refers to plants with stinging hairs, particularly those of the genus ''Urtica''. It can also refer to plants which resemble ''Urtica'' species in appearance but do not have stinging hairs. Plants called "nettle" include ...
contain up to 80 ppm.
See also
* List of countries by titanium production
This is a list of countries by titanium sponge production based on USGS figures.https://pubs.usgs.gov/periodicals/mcs2021/mcs2021-titanium.pdf The production figures are for titanium sponge, units are in metric tons.
References
{{Industry cou ...
* Suboxide
Suboxides are a class of oxides wherein the electropositive element is in excess relative to the “normal” oxides. When the electropositive element is a metal, the compounds are sometimes referred to as “metal-rich”. Thus the normal oxide ...
* Titanium in Africa
Titanium mining in Africa has been beset by environmental problems due to the polluting nature of processing rutile, a principal titanium ore. Titanium production in Africa includes the following principal countries and companies.
Kenya
* Base Ti ...
* Titanium in zircon geothermometry
* Titanium Man
The Titanium Man is the name of two supervillains appearing in American comic books published by Marvel Comics. The original Titanium Man first appeared in ''Tales of Suspense'' #68 (September 1965) and was created by Stan Lee and Don Heck.
Fic ...
* VSMPO-AVISMA
VSMPO-AVISMA Corporation (russian: ВСМПО-АВИСМА) is the world's largest titanium producer. Located in Verkhnyaya Salda, Russia, VSMPO-AVISMA also operates facilities in Ukraine, England, Switzerland, Germany, United States and poselok ...
Footnotes
References
Bibliography
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External links
"Titanium: Our Next Major Metal"
''Popular Science
''Popular Science'' (also known as ''PopSci'') is an American digital magazine carrying popular science content, which refers to articles for the general reader on science and technology subjects. ''Popular Science'' has won over 58 awards, incl ...
'', October 1950—one of first general public detailed articles on Titanium
Titanium
at ''The Periodic Table of Videos
''Periodic Videos'' (also known as ''The Periodic Table of Videos'') is a video project and YouTube channel on chemistry. It consists of a series of videos about chemical elements and the periodic table, with additional videos on other topics i ...
'' (University of Nottingham)
Titanium
at The Essential Chemical Industry – online (CIEC Promoting Science at the University of York)
International Titanium Association
Metal of the gods
{{Authority control
Aerospace materials
Biomaterials
Chemical elements with hexagonal close-packed structure
Chemical elements
Native element minerals
Pyrotechnic fuels
Transition metals