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Perovskite
Perovskite (pronunciation: ) is a calcium titanium oxide mineral composed of calcium titanate (chemical formula ). Its name is also applied to the class of compounds which have the same type of crystal structure as (XIIA2+VIB4+X2−3), known as the perovskite structure. Many different cations can be embedded in this structure, allowing the development of diverse engineered materials. History The mineral was discovered in the Ural Mountains of Russia by Gustav Rose in 1839 and is named after Russian mineralogist Lev Perovski (1792–1856). Perovskite's notable crystal structure was first described by Victor Goldschmidt in 1926 in his work on tolerance factors. The crystal structure was later published in 1945 from X-ray diffraction data on barium titanate by Helen Dick Megaw. Occurrence Found in the Earth's mantle, perovskite's occurrence at Khibina Massif is restricted to the silica under-saturated ultramafic rocks and foidolites, due to the instability in a paragenesis ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Perovskite (structure)
A perovskite is any material with a crystal structure following the formula ABX3, which was first discovered as the mineral called perovskite, which consists of calcium titanium oxide (CaTiO3). The mineral was first discovered in the Ural mountains of Russia by Gustav Rose in 1839 and named after Russian mineralogist L. A. Perovski (1792–1856). 'A' and 'B' are two positively charged ions (i.e. cations), often of very different sizes, and X is a negatively charged ion (an anion, frequently oxide) that bonds to both cations. The 'A' atoms are generally larger than the 'B' atoms. The ideal cubic structure has the B cation in 6-fold coordination, surrounded by an octahedron of anions, and the A cation in 12-fold cuboctahedral coordination. Additional perovskite forms may exist where either/both the A and B sites have a configuration of A1x-1A2x and/or B1y-1B2y and the X may deviate from the ideal coordination configuration as ions within the A and B sites undergo changes in thei ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Calcium Titanate
Calcium titanate is an inorganic compound with the chemical formula Ca Ti O3. As a mineral, it is called perovskite, named after Russian mineralogist, L. A. Perovski (1792-1856). It is a colourless, diamagnetic solid, although the mineral is often coloured owing to impurities. Synthesis CaTiO3 can be prepared by the combination of CaO and TiO2 at temperatures >1300 °C. Sol-gel processes has been used to make a more pure substance, as well as lowering the synthesis temperature. These compounds synthesized are more compressible due to the powders from the sol-gel process as well and bring it closer to its calculated density (~4.04 g/ml). Structure Calcium titanate is obtained as orthorhombic crystals, more specifically perovskite structure. In this motif, the Ti(IV) centers are octahedral and the Ca2+ centers occupy a cage of 12 oxygen centres. Many useful materials adopt related structures, e.g. barium titanate or variations of the structure, e.g. yttrium barium copp ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Helen Dick Megaw
Helen Dick Megaw (1 June 1907 – 26 February 2002) was an Irish crystallographer who was a pioneer in X-ray crystallography. She made measurements of the cell dimensions of ice and established the Perovskite crystal structure. Education and career Megaw was born in Dublin as the daughter of the Irish judge and politician Robert Megaw. She was educated at the Roedean in Dublin. While still at school, Megaw read Bragg's ''X-rays and Crystal Structure.'' She spent a year Queen's University, Belfast before moving to Girton College, Cambridge to study Natural Sciences in 1926. She graduated in 1930 and was a research student in crystallography under J. D. Bernal. Megaw's first speciality was the structure of ice, and she was awarded her PhD in 1934,Personal papers of Helen Megaw' and Girton awarded her a Hertha Ayrton research scholarship which she used to study in Vienna in 1934-1935 under Hermann Francis Mark. In 1935 Megaw co-published with Bernal an influential method for fi ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Barium Titanate
Barium titanate (BTO) is an inorganic compound with chemical formula BaTiO3. Barium titanate appears white as a powder and is transparent when prepared as large crystals. It is a Ferroelectricity, ferroelectric, Pyroelectricity, pyroelectric, and Piezoelectricity, piezoelectric ceramic material that exhibits the photorefractive effect. It is used in capacitors, electromechanical transducers and nonlinear optics. Structure The solid exists in one of four polymorphs depending on temperature. From high to low temperature, these crystal symmetries of the four polymorphs are Cubic crystal system, cubic, Tetragonal crystal system, tetragonal, Orthorhombic crystal system, orthorhombic and Trigonal crystal system, rhombohedral crystal structure. All of these phases exhibit the ferroelectric effect apart from the cubic phase. The high temperature cubic phase is easiest to describe, as it consists of regular corner-sharing octahedral TiO6 units that define a cube with O vertices and Ti- ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Oxide Mineral
The oxide mineral class includes those minerals in which the oxide anion (O2−) is bonded to one or more metal alloys. The hydroxide-bearing minerals are typically included in the oxide class. The minerals with complex anion groups such as the silicates, sulfates, carbonates and phosphates are classed separately. Simple oxides: *XO **Periclase group ***Periclase ***Manganosite **Zincite group ***Zincite *** Bromellite ***Tenorite ***Litharge * **Cuprite **Ice * **Hematite group ***Corundum ***Hematite ***Ilmenite * **Rutile group ***Rutile ***Pyrolusite ***Cassiterite **Baddeleyite **Uraninite **Thorianite * **Spinel group ***Spinel ***Gahnite ***Magnetite ***Franklinite ***Chromite **Chrysoberyl **Columbite *Hydroxide subgroup: **Brucite **Manganite ** Romanèchite **Goethite group: ***Diaspore ***Goethite Nickel–Strunz Classification -04- Oxides IMA-CNMNC proposes a new hierarchical scheme (Mills et al., 2009). This list uses it to modify ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Crystal Structure
In crystallography, crystal structure is a description of the ordered arrangement of atoms, ions or molecules in a crystal, crystalline material. Ordered structures occur from the intrinsic nature of the constituent particles to form symmetric patterns that repeat along the principal directions of Three-dimensional space (mathematics), three-dimensional space in matter. The smallest group of particles in the material that constitutes this repeating pattern is the unit cell of the structure. The unit cell completely reflects the symmetry and structure of the entire crystal, which is built up by repetitive Translation (geometry), translation of the unit cell along its principal axes. The translation vectors define the nodes of the Bravais lattice. The lengths of the principal axes, or edges, of the unit cell and the angles between them are the lattice constants, also called ''lattice parameters'' or ''cell parameters''. The symmetry properties of the crystal are described by the con ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Oxide Minerals
The oxide mineral class includes those minerals in which the oxide anion (O2−) is bonded to one or more metal alloys. The hydroxide-bearing minerals are typically included in the oxide class. The minerals with complex anion groups such as the silicates, sulfates, carbonates and phosphates are classed separately. Simple oxides: *XO **Periclase group ***Periclase ***Manganosite **Zincite group ***Zincite *** Bromellite ***Tenorite ***Litharge * **Cuprite **Ice * **Hematite group ***Corundum ***Hematite ***Ilmenite * **Rutile group ***Rutile ***Pyrolusite *** Cassiterite ** Baddeleyite **Uraninite **Thorianite * **Spinel group ***Spinel ***Gahnite ***Magnetite ***Franklinite *** Chromite **Chrysoberyl **Columbite *Hydroxide subgroup: **Brucite **Manganite ** Romanèchite **Goethite group: ***Diaspore ***Goethite Nickel–Strunz Classification -04- Oxides IMA-CNMNC proposes a new hierarchical scheme (Mills et al., 2009). This list uses it to mod ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Skarn
Skarns or tactites are hard, coarse-grained metamorphic rocks that form by a process called metasomatism. Skarns tend to be rich in calcium-magnesium-iron-manganese-aluminium silicate minerals, which are also referred to as calc-silicate minerals.Ray, G.E., and Webster, I.C.L. (1991): An Overview of Skarn Deposits; in Ore Deposits, Tectonics and Metallogeny in the Canadian Cordillera; McMillan, W.J., compiler, B. C. Ministry of Energy, Mines and Petroleum Resources, Paper 1991-4, pages 213-252.Meinert, L.D., 1992. Skarns and Skarn Deposits; Geoscience Canada, Vol. 19, No. 4, p. 145-162.Hammarstrom, J.M., Kotlyar, B.B., Theodore, T.G., Elliott, J.E., John, D.A., Doebrich, J.L., Nash, J.T., Carlson, R.R., Lee, G.K., Livo, K.E., Klein, D.P., 1995. Cu, Au, and Zn-Pb Skarn Deposits, Chapter 12; United States Geological Survey: Preliminary Compilation of Descriptive Geoenvironmental Mineral Deposit Models: https://pubs.usgs.gov/of/1995/ofr-95-0831/CHAP12.pdf. These minerals form as a res ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Magnet Cove Igneous Complex
The Magnet Cove igneous complex is a small alkalic ring complex lying to the west of the town of Magnet Cove in Hot Spring County, Arkansas.Geology of Titanium-Mineral Deposits, Eric R. Force, Geological Society of America, 1991,Google Books/ref> It and the adjacent town are so named due to the existence of magnetite and the terrain being a cove, a basin-shaped valley. The complex is of Mesozoic age, intruded into Paleozoic sediments. Mapping was conducted by the geologists Erickson and Blade in 1963. Units within the complex include carbonatite, nepheline syenite, phonolite, and ijolite. In addition to the magnetite which forms both massive lodestone and crystals, the complex is strewn with odd and rare minerals, and is the type locality for five mineral species. Over 100 different minerals have been identified from the area. There are many titanium minerals such as rutile, anatase, brookite, and perovskite, as well as some vanadium mineralization. Some rare-earth-bearing m ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Carbonate Rock
Carbonate rocks are a class of sedimentary rocks composed primarily of carbonate minerals. The two major types are limestone, which is composed of calcite or aragonite (different crystal forms of CaCO3), and dolomite rock (also known as dolostone), which is composed of mineral dolomite (CaMg(CO3)2). Calcite can be either dissolved by groundwater or precipitated by groundwater, depending on several factors including the water temperature, pH, and dissolved ion concentrations. Calcite exhibits an unusual characteristic called retrograde solubility in which it becomes less soluble in water as the temperature increases. When conditions are right for precipitation, calcite forms mineral coatings that cement the existing rock grains together or it can fill fractures. Karst topography and caves develop in carbonate rocks because of their solubility in dilute acidic groundwater. Cooling groundwater or mixing of different groundwaters will also create conditions suitable for cave ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Arkansas
Arkansas ( ) is a landlocked state in the South Central United States. It is bordered by Missouri to the north, Tennessee and Mississippi to the east, Louisiana to the south, and Texas and Oklahoma to the west. Its name is from the Osage language, a Dhegiha Siouan language, and referred to their relatives, the Quapaw people. The state's diverse geography ranges from the mountainous regions of the Ozark and Ouachita Mountains, which make up the U.S. Interior Highlands, to the densely forested land in the south known as the Arkansas Timberlands, to the eastern lowlands along the Mississippi River and the Arkansas Delta. Arkansas is the 29th largest by area and the 34th most populous state, with a population of just over 3 million at the 2020 census. The capital and most populous city is Little Rock, in the central part of the state, a hub for transportation, business, culture, and government. The northwestern corner of the state, including the Fayetteville–Springdaleâ ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Contact Metamorphism
Metamorphism is the transformation of existing rock (the protolith) to rock with a different mineral composition or texture. Metamorphism takes place at temperatures in excess of , and often also at elevated pressure or in the presence of chemically active fluids, but the rock remains mostly solid during the transformation. Metamorphism is distinct from weathering or diagenesis, which are changes that take place at or just beneath Earth's surface. Various forms of metamorphism exist, including regional, contact, hydrothermal, shock, and dynamic metamorphism. These differ in the characteristic temperatures, pressures, and rate at which they take place and in the extent to which reactive fluids are involved. Metamorphism occurring at increasing pressure and temperature conditions is known as ''prograde metamorphism'', while decreasing temperature and pressure characterize ''retrograde metamorphism''. Metamorphic petrology is the study of metamorphism. Metamorphic petrologists re ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
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