Calcium titanate is an
inorganic compound
In chemistry, an inorganic compound is typically a chemical compound that lacks carbon–hydrogen bonds, that is, a compound that is not an organic compound. The study of inorganic compounds is a subfield of chemistry known as '' inorganic chemist ...
with the chemical formula
Ca Ti O3. As a mineral, it is called
perovskite
Perovskite (pronunciation: ) is a calcium titanium oxide mineral composed of calcium titanate (chemical formula ). Its name is also applied to the class of compounds which have the same type of crystal structure as (XIIA2+VIB4+X2−3), known as ...
, named after Russian mineralogist,
L. A. Perovski
Count Lev Alekseyevich von Perovski (russian: Лев Алексе́евич Перо́вский, also transliterated as Perofsky, Perovskii, Perovskiy, Perovsky, Perowski, and Perowsky; also credited as L.A. Perovski) (9 September 1792 – 21 No ...
(1792-1856). It is a colourless,
diamagnetic
Diamagnetic materials are repelled by a magnetic field; an applied magnetic field creates an induced magnetic field in them in the opposite direction, causing a repulsive force. In contrast, paramagnetic and ferromagnetic materials are attracted ...
solid, although the mineral is often coloured owing to impurities.
Synthesis
CaTiO
3 can be prepared by the combination of
CaO Cao or CAO may refer to:
Mythology
*Cao (bull), a legendary bull in Meitei mythology
Companies or organizations
* Air China Cargo, ICAO airline designator CAO
*CA Oradea, Romanian football club
*CA Osasuna, Spanish football club
*Canadian Assoc ...
and
TiO2 at temperatures >1300 °C.
Sol-gel processes has been used to make a more pure substance, as well as lowering the synthesis temperature. These compounds synthesized are more compressible due to the powders from the sol-gel process as well and bring it closer to its calculated density (~4.04 g/ml).
Structure
Calcium titanate is obtained as
orthorhombic crystals, more specifically
perovskite structure
A perovskite is any material with a crystal structure following the formula ABX3, which was first discovered as the mineral called perovskite, which consists of calcium titanium oxide (CaTiO3). The mineral was first discovered in the Ural mou ...
. In this motif, the Ti(IV) centers are octahedral and the Ca
2+ centers occupy a cage of 12 oxygen centres. Many useful materials adopt related structures, e.g.
barium titanate
Barium titanate (BTO) is an inorganic compound with chemical formula BaTiO3. Barium titanate appears white as a powder and is transparent when prepared as large crystals. It is a Ferroelectricity, ferroelectric, Pyroelectricity, pyroelectric, and ...
or variations of the structure, e.g.
yttrium barium copper oxide
Yttrium barium copper oxide (YBCO) is a family of crystalline chemical compounds that display high-temperature superconductivity; it includes the first material ever discovered to become superconducting above the boiling point of liquid nitrogen ...
.
Applications
Calcium titanate has relatively little value except as one of the ores of titanium, together with several others. It is reduced to give titanium metal or
ferrotitanium
Ferrotitanium is a ferroalloy, an alloy of iron and titanium with between 10–20% iron and 45–75% titanium and sometimes a small amount of carbon. It is used in steelmaking as a cleansing agent for iron and steel; the titanium is highly reactive ...
alloys.
See also
*
Perovskite
Perovskite (pronunciation: ) is a calcium titanium oxide mineral composed of calcium titanate (chemical formula ). Its name is also applied to the class of compounds which have the same type of crystal structure as (XIIA2+VIB4+X2−3), known as ...
*
Perovskite (structure)
A perovskite is any material with a crystal structure following the formula ABX3, which was first discovered as the mineral called perovskite, which consists of calcium titanium oxide (CaTiO3). The mineral was first discovered in the Ural mou ...
*
Perovskite solar cell
A perovskite solar cell (PSC) is a type of solar cell that includes a perovskite-structured compound, most commonly a hybrid organic–inorganic lead or tin halide-based material as the light-harvesting active layer. Perovskite materials, such a ...
External links
Crystal structure of CaTiO3
References
Calcium compounds
Titanates
Perovskites
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