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Triazolate
A triazolate is a salt derived from a triazole by replacement of a proton with a cation. Different isomers exist 1,2,4-triazolate or 1,2,3-triazolate, both of which are unsaturated heterocyclic ring compounds containing three nitrogen atoms. The basic formula is C2N3H2−. It can be abbreviated by "tz". Known compounds include zinc, and natural copper minerals, chanabayaite and triazolite. Trizolate is a tridentate ligand, and can form complexes with metals via the three nitrogen atoms. This enables polymers or metal organic framework A metal (from Greek μέταλλον ''métallon'', "mine, quarry, metal") is a material that, when freshly prepared, polished, or fractured, shows a lustrous appearance, and conducts electricity and heat relatively well. Metals are typicall ... compounds to be formed. Triazolate can also be substituted on its carbon atoms. References {{Reflist Heterocyclic compounds with 1 ring Nitrogen compounds ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Chanabayaite
Chanabayaite is the first recognized triazolate mineral, having the formula . Minor iron admixture is also present. It is also one of a few currently known minerals containing ammine groups, including also ammineite, joanneumite and shilovite. All the minerals are rare and were found in a single guano deposit in Chile, called Pabellón de Pica. A similar natural phase, formula , likely a precursor of chanabayaite, is described by Zubkova et al. 2016.Zubkova, N.V., Chukanov, N.V., Pekov, I., and Pushcharovsky, D., 2016. The crystal structure of the natural 1,2,4-triazolate compound . Zeitschrift für Kristallographie - Crystalline Materials 231(1), 47–53. Crystal structure The main features of the crystal structure of chanabayaite are: * copper forms octahedra, part of which share corners * 1,2,4-triazolate anions link the octahedra Association Chanabayaite coexists with halite, joanneumite, nitratine, salammoniac and paragenetically-unrelated chalcopyrite. Chalcopyrite is presen ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Triazolite
Triazolite is an organic mineral with the chemical structure of NaCu2(N3C2H2)2(NH3)2Cl3·4H2O, and is formed in conjunction with chanabayite, another natural triazolate. Triazolite has only been found in Pabellón de Pica, Chanabaya, Iquique Province, Tarapacá Region, Chile, due to its specific requirements for formation. The first specimens of triazolite were found in what is suspected to be the guano of the Guanay cormorant The Guanay cormorant or Guanay shag (''Leucocarbo bougainvilliorum'') is a member of the cormorant family found on the Pacific coast of Peru and northern Chile. (The Argentinian population on the Patagonian Atlantic coast appears to be extirpat .... The guano reacted to chalcopyrite-bearing gabbro, allowing the formation for triazolite to take place. Triazolite was initially grouped together with chanabayite in 2015, and wasn't identified as a separate mineral until 2017. References {{Reflist Organic minerals Copper(II) minerals Orthorhombic m ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Triazole
A triazole is a heterocyclic compound featuring a five-membered ring of two carbon atoms and three nitrogen atoms with molecular formula C2H3N3. Triazoles exhibit substantial isomerism, depending on the positioning of the nitrogen atoms within the ring. Many triazoles are versatile, biologically active compounds commonly used as fungicides and plant retardants. However, triazoles are also useful in bioorthogonal chemistry, because the large number of nitrogen atoms causes triazoles to react similar to azides. Lastly, the many free lone pairs in triazoles make them useful as coordination compounds, although not typically as haptic ligands. Isomerism There are four triazole isomers, which are conventionally divided into two pairs of tautomers. In the 1,2,3-triazoles, the three nitrogen atoms are adjacent; in the 1,2,4-triazoles, an interstitial carbon separates out one nitrogen atom. Each category has two tautomers that differ by which nitrogen has a hydrogen bonded ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Cation
An ion () is an atom or molecule with a net electrical charge. The charge of an electron is considered to be negative by convention and this charge is equal and opposite to the charge of a proton, which is considered to be positive by convention. The net charge of an ion is not zero because its total number of electrons is unequal to its total number of protons. A cation is a positively charged ion with fewer electrons than protons while an anion is a negatively charged ion with more electrons than protons. Opposite electric charges are pulled towards one another by electrostatic force, so cations and anions attract each other and readily form ionic compounds. Ions consisting of only a single atom are termed atomic or monatomic ions, while two or more atoms form molecular ions or polyatomic ions. In the case of physical ionization in a fluid (gas or liquid), "ion pairs" are created by spontaneous molecule collisions, where each generated pair consists of a free electron and ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Tridentate Ligand
A tridentate ligand (or terdentate ligand) is a ligand that has three atoms that can function as acceptor atoms in a coordination complex. Well-known tridentate ligands include diethylenetriamine with three nitrogen donor atoms, and the iminodiacetate anion which consists of one deprotonated amine nitrogen and a pair of carboxylate groups. An octahedrally coordinated atom has six positions around it. Two tridentate ligands may form a complex with such an atom. There are two possible arrangements for such a complex: ''fac'' where the coordination is in a triangle on one face of the octahedron, and ''mer'' where the coordinating atoms are in an arc around the central atom, with two atoms of the ligand opposite each other. ''Fac'' tridentate ligands are termed scorpionate ligands, especially in reference to polypyrazolylborates. If the tridentate ligand is not symmetrical, then in the ''fac'' complexes in octahedral coordination there are three possible isomers. In the ''mer'' com ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Metal Organic Framework
A metal (from Greek μέταλλον ''métallon'', "mine, quarry, metal") is a material that, when freshly prepared, polished, or fractured, shows a lustrous appearance, and conducts electricity and heat relatively well. Metals are typically ductile (can be drawn into wires) and malleable (they can be hammered into thin sheets). These properties are the result of the ''metallic bond'' between the atoms or molecules of the metal. A metal may be a chemical element such as iron; an alloy such as stainless steel; or a molecular compound such as polymeric sulfur nitride. In physics, a metal is generally regarded as any substance capable of conducting electricity at a temperature of absolute zero. Many elements and compounds that are not normally classified as metals become metallic under high pressures. For example, the nonmetal iodine gradually becomes a metal at a pressure of between 40 and 170 thousand times atmospheric pressure. Equally, some materials regarded as metals ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Heterocyclic Compounds With 1 Ring
A heterocyclic compound or ring structure is a cyclic compound that has atoms of at least two different elements as members of its ring(s). Heterocyclic chemistry is the branch of organic chemistry dealing with the synthesis, properties, and applications of these heterocycles. Examples of heterocyclic compounds include all of the nucleic acids, the majority of drugs, most biomass (cellulose and related materials), and many natural and synthetic dyes. More than half of known compounds are heterocycles. 59% of US FDA-approved drugs contain nitrogen heterocycles. Classification The study of heterocyclic chemistry focuses especially on unsaturated derivatives, and the preponderance of work and applications involves unstrained 5- and 6-membered rings. Included are pyridine, thiophene, pyrrole, and furan. Another large class of heterocycles refers to those fused to benzene rings. For example, the fused benzene derivatives of pyridine, thiophene, pyrrole, and furan are quinol ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
