Triazolite
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Triazolite
Triazolite is an organic mineral with the chemical structure of NaCu2(N3C2H2)2(NH3)2Cl3·4H2O, and is formed in conjunction with chanabayite, another natural triazolate. Triazolite has only been found in Pabellón de Pica, Chanabaya, Iquique Province, Tarapacá Region, Chile, due to its specific requirements for formation. The first specimens of triazolite were found in what is suspected to be the guano of the Guanay cormorant The Guanay cormorant or Guanay shag (''Leucocarbo bougainvilliorum'') is a member of the cormorant family found on the Pacific coast of Peru and northern Chile. (The Argentinian population on the Patagonian Atlantic coast appears to be extirpat .... The guano reacted to chalcopyrite-bearing gabbro, allowing the formation for triazolite to take place. Triazolite was initially grouped together with chanabayite in 2015, and wasn't identified as a separate mineral until 2017. References {{Reflist Organic minerals Copper(II) minerals Orthorhombic m ...
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Organic Mineral
An organic mineral is an organic compound in mineral form. An organic compound is any compound containing carbon, aside from some simple ones discovered before 1828. There are three classes of organic mineral: hydrocarbons (containing just hydrogen and carbon), salts of organic acids, and miscellaneous. Organic minerals are rare, and tend to have specialized settings such as fossilized cacti and bat guano. Mineralogists have used statistical models to predict that there are more undiscovered organic mineral species than known ones. Definition In general, an organic compound is defined as any compound containing carbon, but some compounds are excepted for historical reasons. Before 1828, chemists thought that organic and inorganic compounds were fundamentally different, with the former requiring a vital force that could only come from living organisms. Then Friedrich Wöhler synthesized urea by heating an inorganic substance called ammonium cyanate, proving that organic compoun ...
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Chanabayaite
Chanabayaite is the first recognized triazolate mineral, having the formula . Minor iron admixture is also present. It is also one of a few currently known minerals containing ammine groups, including also ammineite, joanneumite and shilovite. All the minerals are rare and were found in a single guano deposit in Chile, called Pabellón de Pica. A similar natural phase, formula , likely a precursor of chanabayaite, is described by Zubkova et al. 2016.Zubkova, N.V., Chukanov, N.V., Pekov, I., and Pushcharovsky, D., 2016. The crystal structure of the natural 1,2,4-triazolate compound . Zeitschrift für Kristallographie - Crystalline Materials 231(1), 47–53. Crystal structure The main features of the crystal structure of chanabayaite are: * copper forms octahedra, part of which share corners * 1,2,4-triazolate anions link the octahedra Association Chanabayaite coexists with halite, joanneumite, nitratine, salammoniac and paragenetically-unrelated chalcopyrite. Chalcopyrite is presen ...
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Triazolate
A triazolate is a salt derived from a triazole by replacement of a proton with a cation. Different isomers exist 1,2,4-triazolate or 1,2,3-triazolate, both of which are unsaturated heterocyclic ring compounds containing three nitrogen atoms. The basic formula is C2N3H2−. It can be abbreviated by "tz". Known compounds include zinc, and natural copper minerals, chanabayaite and triazolite. Trizolate is a tridentate ligand, and can form complexes with metals via the three nitrogen atoms. This enables polymers or metal organic framework A metal (from Greek μέταλλον ''métallon'', "mine, quarry, metal") is a material that, when freshly prepared, polished, or fractured, shows a lustrous appearance, and conducts electricity and heat relatively well. Metals are typicall ... compounds to be formed. Triazolate can also be substituted on its carbon atoms. References {{Reflist Heterocyclic compounds with 1 ring Nitrogen compounds ...
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Iquique Province
Iquique Province ( es, Provincia de Iquique) is one of two provinces in the northern Chilean region of Tarapacá. Its capital is the port city of Iquique. History Until October 2007, the Province of Iquique was composed of 7 communes: Alto Hospicio, Camina, Colchane, Huara, Iquique, Pica and Pozo Almonte, but since then, with the creation of the Region of Arica and Parinacota, much of the province, specifically the municipalities of Huara, Camina, Colchane, Pozo Almonte and Pica, was transferred administratively to Tamarugal Province, leaving Iquique Province consists of two communes. Geography and demography According to the 2012 census by the National Statistics Institute (''INE''), the province spans an area of and had a population of 275,042 inhabitants, giving it a population density of . Between the 1992 and 2002 censuses, the population grew by 30.8% (50,959 persons). Administration As a province, Iquique is a second-level administrative division of Chile, which is furthe ...
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Tarapacá Region
The Tarapacá Region ( es, Región de Tarapacá, ) is one of Chile's 16 first-order administrative divisions. It comprises two provinces, Iquique and Tamarugal. It borders the Chilean Arica and Parinacota Region to the north, Bolivia's Oruro Department and Potosí Department on the east, Chile's Antofagasta Region to the south and the Pacific Ocean to the west. The port city of Iquique is the region's capital. Much of the region was once the Tarapacá Province of Peru, which was annexed by Chile under the 1883 Treaty of Ancón at the close of the War of the Pacific. The region was important economically as a site of intense saltpeter mining, before synthetic nitrate manufacturing became possible. A number of abandoned mining towns can still be found in the region. The present day Tarapacá Region was created in 2007 by subdividing the former Tarapacá Region under Law No. 20,175, which was signed by President Michelle Bachelet in Arica. Administration The government of the r ...
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Chile
Chile, officially the Republic of Chile, is a country in the western part of South America. It is the southernmost country in the world, and the closest to Antarctica, occupying a long and narrow strip of land between the Andes to the east and the Pacific Ocean to the west. Chile covers an area of , with a population of 17.5 million as of 2017. It shares land borders with Peru to the north, Bolivia to the north-east, Argentina to the east, and the Drake Passage in the far south. Chile also controls the Pacific islands of Juan Fernández, Isla Salas y Gómez, Desventuradas, and Easter Island in Oceania. It also claims about of Antarctica under the Chilean Antarctic Territory. The country's capital and largest city is Santiago, and its national language is Spanish. Spain conquered and colonized the region in the mid-16th century, replacing Inca rule, but failing to conquer the independent Mapuche who inhabited what is now south-central Chile. In 1818, after declaring in ...
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Guano
Guano (Spanish from qu, wanu) is the accumulated excrement of seabirds or bats. As a manure, guano is a highly effective fertilizer due to the high content of nitrogen, phosphate, and potassium, all key nutrients essential for plant growth. Guano was also, to a lesser extent, sought for the production of gunpowder and other explosive materials. The 19th-century seabird guano trade played a pivotal role in the development of modern input-intensive farming. The demand for guano spurred the human colonization of remote bird islands in many parts of the world. Unsustainable seabird guano mining processes can result in permanent habitat destruction and the loss of millions of seabirds. Bat guano is found in caves throughout the world. Many cave ecosystems are wholly dependent on bats to provide nutrients via their guano which supports bacteria, fungi, invertebrates, and vertebrates. The loss of bats from a cave can result in the extinction of species that rely on their guano. U ...
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Guanay Cormorant
The Guanay cormorant or Guanay shag (''Leucocarbo bougainvilliorum'') is a member of the cormorant family found on the Pacific coast of Peru and northern Chile. (The Argentinian population on the Patagonian Atlantic coast appears to be extirpated.) After breeding it spreads south to southern parts of Chile and north to Ecuador, and has also been recorded as far north as Panama and Colombia – probably a result of mass dispersal due to food shortage in El Niño years. Its major habitats include shallow seawater and rocky shores. The Guanay cormorant is similar in coloration to the rock shag, ''Leucocarbo magellanicus'', but larger, measuring 78 cm from the tip of the bill to the end of the tail. Its bill is grayish with some red at the base. The face is red with a green eye-ring. It has roseate feet. The head, neck and back are black as are the outer parts of the thighs. The throat patch, breast and belly are white. In breeding plumage it has a few white feathers on the ...
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Chalcopyrite
Chalcopyrite ( ) is a copper iron sulfide mineral and the most abundant copper ore mineral. It has the chemical formula CuFeS2 and crystallizes in the tetragonal system. It has a brassy to golden yellow color and a hardness of 3.5 to 4 on the Mohs scale. Its streak is diagnostic as green-tinged black. On exposure to air, chalcopyrite tarnishes to a variety of oxides, hydroxides, and sulfates. Associated copper minerals include the sulfides bornite (Cu5FeS4), chalcocite (Cu2S), covellite (CuS), digenite (Cu9S5); carbonates such as malachite and azurite, and rarely oxides such as cuprite (Cu2O). Is rarely found in association with native copper. Chalcopyrite is a conductor of electricity. Etymology The name chalcopyrite comes from the Greek words , which means copper, and ', which means striking fire. It was sometimes historically referred to as "yellow copper". Identification Chalcopyrite is often confused with pyrite and gold since all three of these minerals have a yell ...
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Gabbro
Gabbro () is a phaneritic (coarse-grained), mafic intrusive igneous rock formed from the slow cooling of magnesium-rich and iron-rich magma into a holocrystalline mass deep beneath the Earth's surface. Slow-cooling, coarse-grained gabbro is chemically equivalent to rapid-cooling, fine-grained basalt. Much of the Earth's oceanic crust is made of gabbro, formed at mid-ocean ridges. Gabbro is also found as plutons associated with continental volcanism. Due to its variant nature, the term ''gabbro'' may be applied loosely to a wide range of intrusive rocks, many of which are merely "gabbroic". By rough analogy, gabbro is to basalt as granite is to rhyolite. Etymology The term "gabbro" was used in the 1760s to name a set of rock types that were found in the ophiolites of the Apennine Mountains in Italy. It was named after Gabbro, a hamlet near Rosignano Marittimo in Tuscany. Then, in 1809, the German geologist Christian Leopold von Buch used the term more restrictively in his descri ...
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Organic Minerals
An organic mineral is an organic compound in mineral form. An organic compound is any compound containing carbon, aside from some simple ones discovered before 1828. There are three classes of organic mineral: hydrocarbons (containing just hydrogen and carbon), salts of organic acids, and miscellaneous. Organic minerals are rare, and tend to have specialized settings such as fossilized cacti and bat guano. Mineralogists have used statistical models to predict that there are more undiscovered organic mineral species than known ones. Definition In general, an organic compound is defined as any compound containing carbon, but some compounds are excepted for historical reasons. Before 1828, chemists thought that organic and inorganic compounds were fundamentally different, with the former requiring a vital force that could only come from living organisms. Then Friedrich Wöhler synthesized urea by heating an inorganic substance called ammonium cyanate, proving that organic compou ...
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Copper(II) Minerals
Copper is a chemical element with the symbol Cu (from la, cuprum) and atomic number 29. It is a soft, malleable, and ductile metal with very high thermal and electrical conductivity. A freshly exposed surface of pure copper has a pinkish-orange color. Copper is used as a conductor of heat and electricity, as a building material, and as a constituent of various metal alloys, such as sterling silver used in jewelry, cupronickel used to make marine hardware and coins, and constantan used in strain gauges and thermocouples for temperature measurement. Copper is one of the few metals that can occur in nature in a directly usable metallic form (native metals). This led to very early human use in several regions, from circa 8000 BC. Thousands of years later, it was the first metal to be smelted from sulfide ores, circa 5000 BC; the first metal to be cast into a shape in a mold, c. 4000 BC; and the first metal to be purposely alloyed with another metal, tin, to create bronze, c. 350 ...
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