Chanabayaite
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Chanabayaite
Chanabayaite is the first recognized triazolate mineral, having the formula . Minor iron admixture is also present. It is also one of a few currently known minerals containing ammine groups, including also ammineite, joanneumite and shilovite. All the minerals are rare and were found in a single guano deposit in Chile, called Pabellón de Pica. A similar natural phase, formula , likely a precursor of chanabayaite, is described by Zubkova et al. 2016.Zubkova, N.V., Chukanov, N.V., Pekov, I., and Pushcharovsky, D., 2016. The crystal structure of the natural 1,2,4-triazolate compound . Zeitschrift für Kristallographie - Crystalline Materials 231(1), 47–53. Crystal structure The main features of the crystal structure of chanabayaite are: * copper forms octahedra, part of which share corners * 1,2,4-triazolate anions link the octahedra Association Chanabayaite coexists with halite, joanneumite, nitratine, salammoniac and paragenetically-unrelated chalcopyrite. Chalcopyrite is presen ...
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Ammineite
Ammineite is the first recognized mineral containing ammine groups. Its formula is uCl2(NH3)2 The mineral is chemically pure. It was found in a guano deposit in Chile. At the same site other ammine-containing minerals were later found:Mindat, Shilovite, http://www.mindat.org/min-46139.html * Chanabayaite, CuCl(N3C2H2)(NH3)·0.25H2O (an alternative formula), a triazolate mineral * Joanneumite, Cu(C3N3O3H2)2(NH3)2, an isocyanurate mineral * Shilovite, Cu(NH3)4(NO3)2 Crystal structure The characteristic features of the structure of ammineite are: * layers of trans form of the copper complex, parallel to (001), connected by Cu-Cl bonds * presence of CuN2Cl4 distorted octahedron ( +2coordination) * edge-sharing of the octahedra produce zigzag chains along the 01direction * hydrogen bonds between NH3 and Cl atoms Associated minerals Ammineite coexists with atacamite, darapskite, halite and salammoniac. Origin Ammineite is supposed to be a result of an interaction of an earlier co ...
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Joanneumite
Joanneumite, confirmed as a new mineral in 2012, is the first recognized isocyanurate mineral, with the formula Cu(C3N3O3H2)2(NH3)2. It is also an ammine-containing mineral, a feature shared with ammineite, chanabayaite and shilovite. All the minerals are very rare and were found in a guano deposit in Pabellón de Pica, Chile.Mindat, Pabellón de Pica, http://www.mindat.org/loc-192704.html See also *Copper(II) cyanurate References

{{reflist Copper(II) minerals Organic minerals Triclinic minerals Minerals in space group 2 Minerals described in 2017 ...
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Organic Mineral
An organic mineral is an organic compound in mineral form. An organic compound is any compound containing carbon, aside from some simple ones discovered before 1828. There are three classes of organic mineral: hydrocarbons (containing just hydrogen and carbon), salts of organic acids, and miscellaneous. Organic minerals are rare, and tend to have specialized settings such as fossilized cacti and bat guano. Mineralogists have used statistical models to predict that there are more undiscovered organic mineral species than known ones. Definition In general, an organic compound is defined as any compound containing carbon, but some compounds are excepted for historical reasons. Before 1828, chemists thought that organic and inorganic compounds were fundamentally different, with the former requiring a vital force that could only come from living organisms. Then Friedrich Wöhler synthesized urea by heating an inorganic substance called ammonium cyanate, proving that organic compoun ...
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Orthorhombic
In crystallography, the orthorhombic crystal system is one of the 7 crystal systems. Orthorhombic lattices result from stretching a cubic lattice along two of its orthogonal pairs by two different factors, resulting in a rectangular prism with a rectangular base (''a'' by ''b'') and height (''c''), such that ''a'', ''b'', and ''c'' are distinct. All three bases intersect at 90° angles, so the three lattice vectors remain mutually orthogonal. Bravais lattices There are four orthorhombic Bravais lattices: primitive orthorhombic, base-centered orthorhombic, body-centered orthorhombic, and face-centered orthorhombic. For the base-centered orthorhombic lattice, the primitive cell has the shape of a right rhombic prism;See , row oC, column Primitive, where the cell parameters are given as a1 = a2, α = β = 90° it can be constructed because the two-dimensional centered rectangular base layer can also be described with primitive rhombic axes. Note that the length a of the primit ...
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Iron
Iron () is a chemical element with symbol Fe (from la, ferrum) and atomic number 26. It is a metal that belongs to the first transition series and group 8 of the periodic table. It is, by mass, the most common element on Earth, right in front of oxygen (32.1% and 30.1%, respectively), forming much of Earth's outer and inner core. It is the fourth most common element in the Earth's crust. In its metallic state, iron is rare in the Earth's crust, limited mainly to deposition by meteorites. Iron ores, by contrast, are among the most abundant in the Earth's crust, although extracting usable metal from them requires kilns or furnaces capable of reaching or higher, about higher than that required to smelt copper. Humans started to master that process in Eurasia during the 2nd millennium BCE and the use of iron tools and weapons began to displace copper alloys, in some regions, only around 1200 BCE. That event is considered the transition from the Bronze Age to the Iron A ...
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Halite
Halite (), commonly known as rock salt, is a type of salt, the mineral (natural) form of sodium chloride ( Na Cl). Halite forms isometric crystals. The mineral is typically colorless or white, but may also be light blue, dark blue, purple, pink, red, orange, yellow or gray depending on inclusion of other materials, impurities, and structural or isotopic abnormalities in the crystals. It commonly occurs with other evaporite deposit minerals such as several of the sulfates, halides, and borates. The name ''halite'' is derived from the Ancient Greek word for "salt", ἅλς (''háls''). Occurrence Halite dominantly occurs within sedimentary rocks where it has formed from the evaporation of seawater or salty lake water. Vast beds of sedimentary evaporite minerals, including halite, can result from the drying up of enclosed lakes and restricted seas. Such salt beds may be hundreds of meters thick and underlie broad areas. Halite occurs at the surface today in playas in regio ...
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Nitratine
Nitratine or nitratite, also known as cubic niter (UK: nitre), soda niter or Chile saltpeter (UK: Chile saltpetre), is a mineral, the naturally occurring form of sodium nitrate, NaNO3. Chemically it is the sodium analogue of saltpeter. Nitratine crystallizes in the trigonal system, but rarely occurs as well formed crystals. It is isostructural with calcite. It is quite soft and light with a Mohs hardness of 1.5 to 2 and a specific gravity of 2.24 to 2.29. Its refractive indices are nω=1.587 and nε=1.336. The typical form is as coatings of white, grey to yellowish brown masses. The rare crystals when found typically have the scalenohedral form of the calcite structure. It is found only as an efflorescence in very dry environments. It is very soluble in water such that it is deliquescent and will absorb water out of the air and turn into a ''puddle'' of sodium nitrate solution when exposed to humid air. Nitratine was once an important source of nitrates for fertilizer and other ...
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Salammoniac
Salammoniac, also sal ammoniac or salmiac, is a rare naturally occurring mineral composed of ammonium chloride, NH4Cl. It forms colorless, white, or yellow-brown crystals in the isometric-hexoctahedral class. It has very poor cleavage and is brittle to conchoidal fracture. It is quite soft, with a Mohs hardness of 1.5 to 2, and it has a low specific gravity of 1.5. It is water-soluble. Sal ammoniac is also the archaic name for the chemical compound ammonium chloride. Pliny, in Book XXXI of his '' Natural History'', refers to a salt produced in the Roman province of Cyrenaica named ''hammoniacum'', so called because of its proximity to the nearby Temple of Jupiter Amun (Greek Ἄμμων ''Ammon''). However, the description Pliny gives of the salt does not conform to the properties of ammonium chloride. According to Herbert Hoover's commentary in his English translation of Georgius Agricola's '' De re metallica'', it is likely to have been common sea salt. In any case, tha ...
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Chalcopyrite
Chalcopyrite ( ) is a copper iron sulfide mineral and the most abundant copper ore mineral. It has the chemical formula CuFeS2 and crystallizes in the tetragonal system. It has a brassy to golden yellow color and a hardness of 3.5 to 4 on the Mohs scale. Its streak is diagnostic as green-tinged black. On exposure to air, chalcopyrite tarnishes to a variety of oxides, hydroxides, and sulfates. Associated copper minerals include the sulfides bornite (Cu5FeS4), chalcocite (Cu2S), covellite (CuS), digenite (Cu9S5); carbonates such as malachite and azurite, and rarely oxides such as cuprite (Cu2O). Is rarely found in association with native copper. Chalcopyrite is a conductor of electricity. Etymology The name chalcopyrite comes from the Greek words , which means copper, and ', which means striking fire. It was sometimes historically referred to as "yellow copper". Identification Chalcopyrite is often confused with pyrite and gold since all three of these minerals have a yell ...
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Amphibole
Amphibole () is a group of inosilicate minerals, forming prism or needlelike crystals, composed of double chain tetrahedra, linked at the vertices and generally containing ions of iron and/or magnesium in their structures. Its IMA symbol is Amp. Amphiboles can be green, black, colorless, white, yellow, blue, or brown. The International Mineralogical Association currently classifies amphiboles as a mineral supergroup, within which are two groups and several subgroups. Mineralogy Amphiboles crystallize into two crystal systems, monoclinic and orthorhombic. In chemical composition and general characteristics they are similar to the pyroxenes. The chief differences from pyroxenes are that (i) amphiboles contain essential hydroxyl (OH) or halogen (F, Cl) and (ii) the basic structure is a double chain of tetrahedra (as opposed to the single chain structure of pyroxene). Most apparent, in hand specimens, is that amphiboles form oblique cleavage planes (at around 120 degrees), whe ...
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Plagioclase
Plagioclase is a series of tectosilicate (framework silicate) minerals within the feldspar group. Rather than referring to a particular mineral with a specific chemical composition, plagioclase is a continuous solid solution series, more properly known as the plagioclase feldspar series. This was first shown by the German mineralogist Johann Friedrich Christian Hessel (1796–1872) in 1826. The series ranges from albite to anorthite endmembers (with respective compositions NaAlSi3O8 to CaAl2Si2O8), where sodium and calcium atoms can substitute for each other in the mineral's crystal lattice structure. Plagioclase in hand samples is often identified by its polysynthetic crystal twinning or 'record-groove' effect. Plagioclase is a major constituent mineral in the Earth's crust, and is consequently an important diagnostic tool in petrology for identifying the composition, origin and evolution of igneous rocks. Plagioclase is also a major constituent of rock in the highlan ...
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