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Ammineite
Ammineite is the first recognized mineral containing ammine groups. Its formula is uCl2(NH3)2 The mineral is chemically pure. It was found in a guano deposit in Chile. At the same site other ammine-containing minerals were later found:Mindat, Shilovite, http://www.mindat.org/min-46139.html * Chanabayaite, CuCl(N3C2H2)(NH3)·0.25H2O (an alternative formula), a triazolate mineral * Joanneumite, Cu(C3N3O3H2)2(NH3)2, an isocyanurate mineral * Shilovite, Cu(NH3)4(NO3)2 Crystal structure The characteristic features of the structure of ammineite are: * layers of trans form of the copper complex, parallel to (001), connected by Cu-Cl bonds * presence of CuN2Cl4 distorted octahedron ( +2coordination) * edge-sharing of the octahedra produce zigzag chains along the 01direction * hydrogen bonds between NH3 and Cl atoms Associated minerals Ammineite coexists with atacamite, darapskite, halite and salammoniac. Origin Ammineite is supposed to be a result of an interaction of an earlier co ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Chanabayaite
Chanabayaite is the first recognized triazolate mineral, having the formula . Minor iron admixture is also present. It is also one of a few currently known minerals containing ammine groups, including also ammineite, joanneumite and shilovite. All the minerals are rare and were found in a single guano deposit in Chile, called Pabellón de Pica. A similar natural phase, formula , likely a precursor of chanabayaite, is described by Zubkova et al. 2016.Zubkova, N.V., Chukanov, N.V., Pekov, I., and Pushcharovsky, D., 2016. The crystal structure of the natural 1,2,4-triazolate compound . Zeitschrift für Kristallographie - Crystalline Materials 231(1), 47–53. Crystal structure The main features of the crystal structure of chanabayaite are: * copper forms octahedra, part of which share corners * 1,2,4-triazolate anions link the octahedra Association Chanabayaite coexists with halite, joanneumite, nitratine, salammoniac and paragenetically-unrelated chalcopyrite. Chalcopyrite is presen ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Joanneumite
Joanneumite, confirmed as a new mineral in 2012, is the first recognized isocyanurate mineral, with the formula Cu(C3N3O3H2)2(NH3)2. It is also an ammine-containing mineral, a feature shared with ammineite, chanabayaite and shilovite. All the minerals are very rare and were found in a guano deposit in Pabellón de Pica, Chile.Mindat, Pabellón de Pica, http://www.mindat.org/loc-192704.html See also *Copper(II) cyanurate References {{reflist Copper(II) minerals Organic minerals Triclinic minerals Minerals in space group 2 Minerals described in 2017 ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Chloride Mineral
The chloride ion is the anion (negatively charged ion) Cl−. It is formed when the element chlorine (a halogen) gains an electron or when a compound such as hydrogen chloride is dissolved in water or other polar solvents. Chloride salts such as sodium chloride are often very soluble in water.Green, John, and Sadru Damji. "Chapter 3." ''Chemistry''. Camberwell, Vic.: IBID, 2001. Print. It is an essential electrolyte located in all body fluids responsible for maintaining acid/base balance, transmitting nerve impulses and regulating liquid flow in and out of cells. Less frequently, the word ''chloride'' may also form part of the "common" name of chemical compounds in which one or more chlorine atoms are covalently bonded. For example, methyl chloride, with the standard name chloromethane (see IUPAC books) is an organic compound with a covalent C−Cl bond in which the chlorine is not an anion. Electronic properties A chloride ion (diameter 167 pm) is much larger tha ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Atacamite
Atacamite is a copper halide mineral: a copper(II) chloride hydroxide with formula Cu2Cl(OH)3. It was first described for deposits in the Atacama Desert of Chile in 1801 by D. de Fallizen. The Atacama Desert is also the namesake of the mineral. Occurrence Atacamite is polymorphous with botallackite, clinoatacamite, and paratacamite. Atacamite is a comparatively rare mineral, formed from primary copper minerals in the oxidation or weathering zone of arid climates. It has also been reported as a volcanic sublimate from fumarole deposits, as sulfide alteration products in black smokers. The mineral has also been found naturally on oxidized copper deposits in Chile, China, Russia, Czech Republic, Arizona, and Australia. It occurs in association with cuprite, brochantite, linarite, caledonite, malachite, chrysocolla and its polymorphs. Synthetic Occurrence Atacamite has been discovered in the patina of the Statue of Liberty, and as alteration of ancient bronze and copper artifac ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Orthorhombic Minerals
In crystallography, the orthorhombic crystal system is one of the 7 crystal systems. Orthorhombic lattices result from stretching a cubic lattice along two of its orthogonal pairs by two different factors, resulting in a rectangular prism with a rectangular base (''a'' by ''b'') and height (''c''), such that ''a'', ''b'', and ''c'' are distinct. All three bases intersect at 90° angles, so the three lattice vectors remain mutually orthogonal. Bravais lattices There are four orthorhombic Bravais lattices: primitive orthorhombic, base-centered orthorhombic, body-centered orthorhombic, and face-centered orthorhombic. For the base-centered orthorhombic lattice, the primitive cell has the shape of a right rhombic prism;See , row oC, column Primitive, where the cell parameters are given as a1 = a2, α = β = 90° it can be constructed because the two-dimensional centered rectangular base layer can also be described with primitive rhombic axes. Note that the length a of the primiti ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Copper(II) Minerals
Copper is a chemical element with the symbol Cu (from la, cuprum) and atomic number 29. It is a soft, malleable, and ductile metal with very high thermal and electrical conductivity. A freshly exposed surface of pure copper has a pinkish-orange color. Copper is used as a conductor of heat and electricity, as a building material, and as a constituent of various metal alloys, such as sterling silver used in jewelry, cupronickel used to make marine hardware and coins, and constantan used in strain gauges and thermocouples for temperature measurement. Copper is one of the few metals that can occur in nature in a directly usable metallic form (native metals). This led to very early human use in several regions, from circa 8000 BC. Thousands of years later, it was the first metal to be smelted from sulfide ores, circa 5000 BC; the first metal to be cast into a shape in a mold, c. 4000 BC; and the first metal to be purposely alloyed with another metal, tin, to create bronze, c. 350 ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Uric Acid
Uric acid is a heterocyclic compound of carbon, nitrogen, oxygen, and hydrogen with the formula C5H4N4O3. It forms ions and salts known as urates and acid urates, such as ammonium acid urate. Uric acid is a product of the metabolic breakdown of purine nucleotides, and it is a normal component of urine. High blood concentrations of uric acid can lead to gout and are associated with other medical conditions, including diabetes and the formation of ammonium acid urate kidney stones. Chemistry Uric acid was first isolated from kidney stones in 1776 by Swedish chemist Carl Wilhelm Scheele. In 1882, the Ukrainian chemist Ivan Horbaczewski first synthesized uric acid by melting urea with glycine. Uric acid displays lactam–lactim tautomerism (also often described as keto–enol tautomerism). Although the lactim form is expected to possess some degree of aromaticity, uric acid crystallizes in the lactam form, with computational chemistry also indicating that tautomer to be the most s ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Urea
Urea, also known as carbamide, is an organic compound with chemical formula . This amide has two amino groups (–) joined by a carbonyl functional group (–C(=O)–). It is thus the simplest amide of carbamic acid. Urea serves an important role in the metabolism of nitrogen-containing compounds by animals and is the main nitrogen-containing substance in the urine of mammals. It is a colorless, odorless solid, highly soluble in water, and practically non-toxic ( is 15 g/kg for rats). Dissolved in water, it is neither acidic nor alkaline. The body uses it in many processes, most notably nitrogen excretion. The liver forms it by combining two ammonia molecules () with a carbon dioxide () molecule in the urea cycle. Urea is widely used in fertilizers as a source of nitrogen (N) and is an important raw material for the chemical industry. In 1828 Friedrich Wöhler discovered that urea can be produced from inorganic starting materials, which was an important conceptual milestone ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Salammoniac
Salammoniac, also sal ammoniac or salmiac, is a rare naturally occurring mineral composed of ammonium chloride, NH4Cl. It forms colorless, white, or yellow-brown crystals in the isometric-hexoctahedral class. It has very poor cleavage and is brittle to conchoidal fracture. It is quite soft, with a Mohs hardness of 1.5 to 2, and it has a low specific gravity of 1.5. It is water-soluble. Sal ammoniac is also the archaic name for the chemical compound ammonium chloride. Pliny, in Book XXXI of his '' Natural History'', refers to a salt produced in the Roman province of Cyrenaica named ''hammoniacum'', so called because of its proximity to the nearby Temple of Jupiter Amun (Greek Ἄμμων ''Ammon''). However, the description Pliny gives of the salt does not conform to the properties of ammonium chloride. According to Herbert Hoover's commentary in his English translation of Georgius Agricola's '' De re metallica'', it is likely to have been common sea salt. In any case, tha ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Isocyanurate
Cyanuric acid or 1,3,5-triazine-2,4,6-triol is a chemical compound with the formula (CNOH)3. Like many industrially useful chemicals, this triazine has many synonyms. This white, odorless solid finds use as a precursor or a component of bleaches, disinfectants, and herbicides. In 1997, worldwide production was 160 000 tonnes.Klaus Huthmacher, Dieter Most "Cyanuric Acid and Cyanuric Chloride" Ullmann's Encyclopedia of Industrial Chemistry" 2005, Wiley-VCH, Weinheim. doi 10.1002/14356007.a08 191 Properties and synthesis Properties Cyanuric acid can be viewed as the cyclic trimer of the elusive species cyanic acid, HOCN. The ring can readily interconvert between several structures via lactam-lactim tautomerism. Although the triol tautomer may have aromatic character, the keto form predominates in solution. The hydroxyl (-OH) groups assume phenolic character. Deprotonation with base affords a series of cyanurate salts: : (O)NHsub>3 ⇌ (O)NHsub>2 (O)Nsup>− + H+ (pKa = 6. ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
