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Rare Earths
The rare-earth elements (REE), also called the rare-earth metals or (in context) rare-earth oxides or sometimes the lanthanides (yttrium and scandium are usually included as rare earths), are a set of 17 nearly-indistinguishable lustrous silvery-white soft heavy metals. Compounds containing rare earths have diverse applications in electrical and electronic components, lasers, glass, magnetic materials, and industrial processes. Scandium and yttrium are considered rare-earth elements because they tend to occur in the same ore deposits as the lanthanides and exhibit similar chemical properties, but have different electronic and magnetic properties. These metals tarnish slowly in air at room temperature and react slowly with cold water to form hydroxides, liberating hydrogen. They react with steam to form oxides, and at elevated temperature (400°C) ignite spontaneously. These elements and their compounds have no biological function other than in several specialized enzymes, s ...
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Neodymium
Neodymium is a chemical element with the symbol Nd and atomic number 60. It is the fourth member of the lanthanide series and is considered to be one of the rare-earth metals. It is a hard, slightly malleable, silvery metal that quickly tarnishes in air and moisture. When oxidized, neodymium reacts quickly producing pink, purple/blue and yellow compounds in the +2, +3 and +4 oxidation states. It is generally regarded as having one of the most complex spectra of the elements. Neodymium was discovered in 1885 by the Austrian chemist Carl Auer von Welsbach, who also discovered praseodymium. It is present in significant quantities in the minerals monazite and bastnäsite. Neodymium is not found naturally in metallic form or unmixed with other lanthanides, and it is usually refined for general use. Neodymium is fairly common—about as common as cobalt, nickel, or copper—and is widely distributed in the Earth's crust. Most of the world's commercial neodymium is mined in China, as is ...
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Lanthanide
The lanthanide () or lanthanoid () series of chemical elements comprises the 15 metallic chemical elements with atomic numbers 57–71, from lanthanum through lutetium. These elements, along with the chemically similar elements scandium and yttrium, are often collectively known as the rare-earth elements or rare-earth metals. The informal chemical symbol Ln is used in general discussions of lanthanide chemistry to refer to any lanthanide. All but one of the lanthanides are f-block elements, corresponding to the filling of the 4f electron shell. There is some dispute on whether lanthanum or lutetium is a d-block element, but lutetium is usually considered so by those who study the matter; it is included due to its chemical similarities with the other 14. All lanthanide elements form trivalent cations, Ln3+, whose chemistry is largely determined by the ionic radius, which decreases steadily from lanthanum to lutetium. These elements are called lanthanides because the elements i ...
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Lanthanide
The lanthanide () or lanthanoid () series of chemical elements comprises the 15 metallic chemical elements with atomic numbers 57–71, from lanthanum through lutetium. These elements, along with the chemically similar elements scandium and yttrium, are often collectively known as the rare-earth elements or rare-earth metals. The informal chemical symbol Ln is used in general discussions of lanthanide chemistry to refer to any lanthanide. All but one of the lanthanides are f-block elements, corresponding to the filling of the 4f electron shell. There is some dispute on whether lanthanum or lutetium is a d-block element, but lutetium is usually considered so by those who study the matter; it is included due to its chemical similarities with the other 14. All lanthanide elements form trivalent cations, Ln3+, whose chemistry is largely determined by the ionic radius, which decreases steadily from lanthanum to lutetium. These elements are called lanthanides because the elements i ...
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Samarium
Samarium is a chemical element with symbol Sm and atomic number 62. It is a moderately hard silvery metal that slowly oxidizes in air. Being a typical member of the lanthanide series, samarium usually has the oxidation state +3. Compounds of samarium(II) are also known, most notably the monoxide SmO, monochalcogenides SmS, SmSe and SmTe, as well as samarium(II) iodide. The last compound is a common reducing agent in chemical synthesis. Samarium has no significant biological role, and some samarium salts are slightly toxic. Samarium was discovered in 1879 by French chemist Paul-Émile Lecoq de Boisbaudran and named after the mineral samarskite from which it was isolated. The mineral itself was named after a Russian mine official, Colonel Vassili Samarsky-Bykhovets, who thus became the first person to have a chemical element named after him, albeit indirectly. Though classified as a rare-earth element, samarium is the 40th most abundant element in Earth's crust and more common than ...
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Yttrium
Yttrium is a chemical element with the symbol Y and atomic number 39. It is a silvery-metallic transition metal chemically similar to the lanthanides and has often been classified as a "rare-earth element". Yttrium is almost always found in combination with lanthanide elements in rare-earth minerals, and is never found in nature as a free element. 89Y is the only stable isotope, and the only isotope found in the Earth's crust. The most important uses of yttrium are LEDs and phosphors, particularly the red phosphors in television set cathode ray tube displays. Yttrium is also used in the production of electrodes, electrolytes, electronic filters, lasers, superconductors, various medical applications, and tracing various materials to enhance their properties. Yttrium has no known biological role. Exposure to yttrium compounds can cause lung disease in humans. The element is named after '' ytterbite'', a mineral first identified in 1787 by the chemist Carl Axel Arrhenius. He n ...
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Gadolinite
Gadolinite, sometimes known as ytterbite, is a silicate mineral consisting principally of the silicates of cerium, lanthanum, neodymium, yttrium, beryllium, and iron with the formula . It is called gadolinite-(Ce) or gadolinite-(Y), depending on the prominent composing element (Y if yttrium predominates, and Ce if cerium). It may contain 35.5% yttria sub-group rare earths, 2.2% ceria earths, as much as to 11.6% BeO, and traces of thorium. It is found in Sweden, Norway, and the US (Texas and Colorado). Characteristics Gadolinite is fairly rare and typically occurs as well-formed crystals. It is nearly black in color and has a vitreous luster. The hardness is between 6.5 and 7 on the Mohs scale, and the specific gravity is between 4.0 and 4.7. It fractures in a conchoidal pattern and streaks grayish-green. It was also thought to exhibit pyrognomic properties, as it can emit visible light when heated to relatively low temperatures, but the scientific consensus is that this is the p ...
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Uranium
Uranium is a chemical element with the symbol U and atomic number 92. It is a silvery-grey metal in the actinide series of the periodic table. A uranium atom has 92 protons and 92 electrons, of which 6 are valence electrons. Uranium is weakly radioactive because all isotopes of uranium are unstable; the half-lives of its naturally occurring isotopes range between 159,200 years and 4.5 billion years. The most common isotopes in natural uranium are uranium-238 (which has 146 neutrons and accounts for over 99% of uranium on Earth) and uranium-235 (which has 143 neutrons). Uranium has the highest atomic weight of the primordially occurring elements. Its density is about 70% higher than that of lead, and slightly lower than that of gold or tungsten. It occurs naturally in low concentrations of a few parts per million in soil, rock and water, and is commercially extracted from uranium-bearing minerals such as uraninite. In nature, uranium is found as uranium-238 (99. ...
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Geochemical
Geochemistry is the science that uses the tools and principles of chemistry to explain the mechanisms behind major geological systems such as the Earth's crust and its oceans. The realm of geochemistry extends beyond the Earth, encompassing the entire Solar System, and has made important contributions to the understanding of a number of processes including mantle convection, the formation of planets and the origins of granite and basalt. It is an integrated field of chemistry and geology. History The term ''geochemistry'' was first used by the Swiss-German chemist Christian Friedrich Schönbein in 1838: "a comparative geochemistry ought to be launched, before geognosy can become geology, and before the mystery of the genesis of our planets and their inorganic matter may be revealed." However, for the rest of the century the more common term was "chemical geology", and there was little contact between geologists and chemists. Geochemistry emerged as a separate discipline after ...
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Rare-earth Mineral
A rare-earth mineral contains one or more rare-earth elements as major metal constituents. Rare-earth minerals are usually found in association with alkaline to peralkaline igneous complexes, in pegmatites associated with alkaline magmas and in or associated with carbonatite intrusives. Perovskite mineral phases are common hosts to rare-earth elements within the alkaline complexes. Mantle-derived carbonate melts are also carriers of the rare earths. Hydrothermal deposits associated with alkaline magmatism contain a variety of rare-earth minerals. The following includes the relatively common hydrothermal rare-earth minerals and minerals that often contain significant rare-earth substitution: *Aeschynite-( Y or Ce) *allanite *apatite *bastnäsite *britholite * brockite *cerite * Dollaseite-(Ce) *fluocerite *fluorite * gadolinite *monazite *parisite-( Ce or La) *stillwellite *synchysite *titanite *wakefieldite *xenotime *zircon Zircon () is a mineral belonging to the grou ...
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Precious Metals
Precious metals are rare, naturally occurring metallic chemical elements of high economic value. Chemically, the precious metals tend to be less reactive than most elements (see noble metal). They are usually ductile and have a high lustre. Historically, precious metals were important as currency but are now regarded mainly as investment and industrial raw materials. Gold, silver, platinum, and palladium each have an ISO 4217 currency code. The best known precious metals are the coinage metals, which are gold and silver. Although both have industrial uses, they are better known for their uses in art, jewelry, and coinage. Other precious metals include the platinum group metals: ruthenium, rhodium, palladium, osmium, iridium, and platinum, of which platinum is the most widely traded. The demand for precious metals is driven not only by their practical use but also by their role as investments and a store of value. Historically, precious metals have commanded much higher pri ...
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Rare-earth Mineral
A rare-earth mineral contains one or more rare-earth elements as major metal constituents. Rare-earth minerals are usually found in association with alkaline to peralkaline igneous complexes, in pegmatites associated with alkaline magmas and in or associated with carbonatite intrusives. Perovskite mineral phases are common hosts to rare-earth elements within the alkaline complexes. Mantle-derived carbonate melts are also carriers of the rare earths. Hydrothermal deposits associated with alkaline magmatism contain a variety of rare-earth minerals. The following includes the relatively common hydrothermal rare-earth minerals and minerals that often contain significant rare-earth substitution: *Aeschynite-( Y or Ce) *allanite *apatite *bastnäsite *britholite * brockite *cerite * Dollaseite-(Ce) *fluocerite *fluorite * gadolinite *monazite *parisite-( Ce or La) *stillwellite *synchysite *titanite *wakefieldite *xenotime *zircon Zircon () is a mineral belonging to the grou ...
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Ytterby
Ytterby () is a village on the Swedish island of Resarö, in Vaxholm Municipality in the Stockholm archipelago. Today the residential area is dominated by suburban homes. The name of the village translates to "outer village". Ytterby is perhaps most famous for being the single richest source of elemental discoveries in the world; the chemical elements yttrium (Y), terbium (Tb), erbium (Er), and ytterbium (Yb) are all named after Ytterby, while four more elements were first discovered there. Mine Quartz was mined in the area beginning in the 1600s for the ironworks in Uppland. Feldspar was mined for local porcelain manufacture, such as Gustavsberg, and the porcelain trade with Britain and Poland. The mine is likely the first feldspar mine in Sweden, starting in 1790. Feldspar mining was likely sporadic and based on manufacture demand. This demand took off in the 1860s, leading to deeper mining efforts at Ytterby. The mine became one of the most productive quartz and feldspar ...
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