![Ferrofluid Magnet under glass edit](https://upload.wikimedia.org/wikipedia/commons/2/21/Ferrofluid_Magnet_under_glass_edit.jpg)
Magnetism is the class of physical attributes that are mediated by a
magnetic field, which refers to the capacity to induce attractive and repulsive phenomena in other entities.
Electric currents and the
magnetic moment
In electromagnetism, the magnetic moment is the magnetic strength and orientation of a magnet or other object that produces a magnetic field. Examples of objects that have magnetic moments include loops of electric current (such as electromagne ...
s of elementary particles give rise to a magnetic field, which acts on other currents and magnetic moments. Magnetism is one aspect of the combined phenomena of
electromagnetism
In physics, electromagnetism is an interaction that occurs between particles with electric charge. It is the second-strongest of the four fundamental interactions, after the strong force, and it is the dominant force in the interactions of ...
. The most familiar effects occur in
ferromagnetic materials, which are strongly attracted by magnetic fields and can be
magnetized to become permanent
magnet
A magnet is a material or object that produces a magnetic field. This magnetic field is invisible but is responsible for the most notable property of a magnet: a force that pulls on other ferromagnetic materials, such as iron, steel, nicke ...
s, producing magnetic fields themselves. Demagnetizing a magnet is also possible. Only a few substances are ferromagnetic; the most common ones are
iron
Iron () is a chemical element with Symbol (chemistry), symbol Fe (from la, Wikt:ferrum, ferrum) and atomic number 26. It is a metal that belongs to the first transition series and group 8 element, group 8 of the periodic table. It is, Abundanc ...
,
cobalt
Cobalt is a chemical element with the symbol Co and atomic number 27. As with nickel, cobalt is found in the Earth's crust only in a chemically combined form, save for small deposits found in alloys of natural meteoric iron. The free element, p ...
, and
nickel
Nickel is a chemical element with symbol Ni and atomic number 28. It is a silvery-white lustrous metal with a slight golden tinge. Nickel is a hard and ductile transition metal. Pure nickel is chemically reactive but large pieces are slow ...
and their alloys. The rare-earth metals
neodymium
Neodymium is a chemical element with the symbol Nd and atomic number 60. It is the fourth member of the lanthanide series and is considered to be one of the rare-earth metals. It is a hard, slightly malleable, silvery metal that quickly tarnishe ...
and
samarium
Samarium is a chemical element with symbol Sm and atomic number 62. It is a moderately hard silvery metal that slowly oxidizes in air. Being a typical member of the lanthanide series, samarium usually has the oxidation state +3. Compounds of samar ...
are less common examples. The prefix ' refers to
iron
Iron () is a chemical element with Symbol (chemistry), symbol Fe (from la, Wikt:ferrum, ferrum) and atomic number 26. It is a metal that belongs to the first transition series and group 8 element, group 8 of the periodic table. It is, Abundanc ...
because permanent magnetism was first observed in
lodestone
Lodestones are naturally magnetized pieces of the mineral magnetite. They are naturally occurring magnets, which can attract iron. The property of magnetism was first discovered in antiquity through lodestones. Pieces of lodestone, suspen ...
, a form of natural iron ore called
magnetite
Magnetite is a mineral and one of the main iron ores, with the chemical formula Fe2+Fe3+2O4. It is one of the oxides of iron, and is ferrimagnetic; it is attracted to a magnet and can be magnetized to become a permanent magnet itself. With th ...
, Fe
3O
4.
All substances exhibit some type of magnetism. Magnetic materials are classified according to their bulk susceptibility. Ferromagnetism is responsible for most of the effects of magnetism encountered in everyday life, but there are actually several types of magnetism.
Paramagnetic
Paramagnetism is a form of magnetism whereby some materials are weakly attracted by an externally applied magnetic field, and form internal, induced magnetic fields in the direction of the applied magnetic field. In contrast with this behavior, ...
substances, such as
aluminium
Aluminium (aluminum in American and Canadian English) is a chemical element with the symbol Al and atomic number 13. Aluminium has a density lower than those of other common metals, at approximately one third that of steel. I ...
and
oxygen
Oxygen is the chemical element with the symbol O and atomic number 8. It is a member of the chalcogen group in the periodic table, a highly reactive nonmetal, and an oxidizing agent that readily forms oxides with most elements as ...
, are weakly attracted to an applied magnetic field;
diamagnetic
Diamagnetic materials are repelled by a magnetic field; an applied magnetic field creates an induced magnetic field in them in the opposite direction, causing a repulsive force. In contrast, paramagnetic and ferromagnetic materials are attracted ...
substances, such as
copper
Copper is a chemical element with the symbol Cu (from la, cuprum) and atomic number 29. It is a soft, malleable, and ductile metal with very high thermal and electrical conductivity. A freshly exposed surface of pure copper has a pinkis ...
and
carbon
Carbon () is a chemical element with the symbol C and atomic number 6. It is nonmetallic and tetravalent—its atom making four electrons available to form covalent chemical bonds. It belongs to group 14 of the periodic table. Carbon mak ...
, are weakly repelled; while
antiferromagnetic
In materials that exhibit antiferromagnetism, the magnetic moments of atoms or molecules, usually related to the spins of electrons, align in a regular pattern with neighboring spins (on different sublattices) pointing in opposite directions. ...
materials, such as
chromium and
spin glass
In condensed matter physics, a spin glass is a magnetic state characterized by randomness, besides cooperative behavior in freezing of spins at a temperature called 'freezing temperature' ''Tf''. In ferromagnetic solids, component atoms' magne ...
es, have a more complex relationship with a magnetic field. The force of a magnet on paramagnetic, diamagnetic, and antiferromagnetic materials is usually too weak to be felt and can be detected only by laboratory instruments, so in everyday life, these substances are often described as non-magnetic.
The magnetic state (or magnetic phase) of a material depends on temperature, pressure, and the applied magnetic field. A material may exhibit more than one form of magnetism as these variables change.
The strength of a
magnetic field almost always decreases with distance, though the exact mathematical relationship between strength and distance varies. Different configurations of magnetic moments and electric currents can result in complicated magnetic fields.
Only
magnetic dipole
In electromagnetism, a magnetic dipole is the limit of either a closed loop of electric current or a pair of poles as the size of the source is reduced to zero while keeping the magnetic moment constant. It is a magnetic analogue of the electric ...
s have been observed although some theories predict the existence of
magnetic monopole
In particle physics, a magnetic monopole is a hypothetical elementary particle that is an isolated magnet with only one magnetic pole (a north pole without a south pole or vice versa). A magnetic monopole would have a net north or south "magneti ...
s.
History
![Blacksmith at the anvil](https://upload.wikimedia.org/wikipedia/commons/e/e0/Blacksmith_at_the_anvil._Wellcome_L0005875.jpg)
Magnetism was first discovered in the ancient world when people noticed that
lodestone
Lodestones are naturally magnetized pieces of the mineral magnetite. They are naturally occurring magnets, which can attract iron. The property of magnetism was first discovered in antiquity through lodestones. Pieces of lodestone, suspen ...
s, naturally magnetized pieces of the mineral
magnetite
Magnetite is a mineral and one of the main iron ores, with the chemical formula Fe2+Fe3+2O4. It is one of the oxides of iron, and is ferrimagnetic; it is attracted to a magnet and can be magnetized to become a permanent magnet itself. With th ...
, could attract iron.
The word ''magnet'' comes from the
Greek
Greek may refer to:
Greece
Anything of, from, or related to Greece, a country in Southern Europe:
*Greeks, an ethnic group.
*Greek language, a branch of the Indo-European language family.
**Proto-Greek language, the assumed last common ancestor ...
term μαγνῆτις λίθος ''magnētis lithos'', "the Magnesian stone, lodestone." In ancient Greece,
Aristotle
Aristotle (; grc-gre, Ἀριστοτέλης ''Aristotélēs'', ; 384–322 BC) was a Greek philosopher and polymath during the Classical period in Ancient Greece. Taught by Plato, he was the founder of the Peripatetic school of ph ...
attributed the first of what could be called a scientific discussion of magnetism to the philosopher
Thales
Thales of Miletus ( ; grc-gre, Θαλῆς; ) was a Greek mathematician, astronomer, statesman, and pre-Socratic philosopher from Miletus in Ionia, Asia Minor. He was one of the Seven Sages of Greece. Many, most notably Aristotle, regarded ...
of
Miletus, who lived from about 625 BC to about 545 BC. The
ancient Indian medical text ''
Sushruta Samhita'' describes using magnetite to remove arrows embedded in a person's body.
In
ancient China, the earliest literary reference to magnetism lies in a 4th-century BC book named after its author, ''
Guiguzi
Guiguzi () is a collection of ancient Chinese texts compiled between the late Warring States period and the end of the Han Dynasty. The work, between 6,000–7,000 Chinese characters, discusses techniques of rhetoric. Although originally associa ...
''.
The 2nd-century BC annals, ''
Lüshi Chunqiu
The ''Lüshi Chunqiu'', also known in English as ''Master Lü's Spring and Autumn Annals'', is an encyclopedic Chinese classic text compiled around 239 BC under the patronage of the Qin Dynasty Chancellor Lü Buwei. In the evaluation of Micha ...
'', also notes:
"The
lodestone
Lodestones are naturally magnetized pieces of the mineral magnetite. They are naturally occurring magnets, which can attract iron. The property of magnetism was first discovered in antiquity through lodestones. Pieces of lodestone, suspen ...
makes iron approach; some (force) is attracting it."
From the section "''Jingtong''" () of the "Almanac of the Last Autumn Month" (): "]"
The earliest mention of the attraction of a needle is in a 1st-century work ''
Lunheng
The ''Lunheng'', also known by numerous English translations, is a wide-ranging Chinese classic text by Wang Chong (27- ). First published in 80, it contains critical essays on natural science and Chinese mythology, philosophy, and literature ...
'' (''Balanced Inquiries''): "A lodestone attracts a needle."
The 11th-century
Chinese scientist Shen Kuo was the first person to write—in the ''
Dream Pool Essays''—of the magnetic needle compass and that it improved the accuracy of navigation by employing the
astronomical
Astronomy () is a natural science that studies celestial objects and phenomena. It uses mathematics, physics, and chemistry in order to explain their origin and evolution. Objects of interest include planets, moons, stars, nebulae, galaxi ...
concept of
true north
True north (also called geodetic north or geographic north) is the direction along Earth's surface towards the geographic North Pole or True North Pole.
Geodetic north differs from ''magnetic'' north (the direction a compass points toward t ...
.
By the 12th century, the Chinese were known to use the lodestone
compass
A compass is a device that shows the cardinal directions used for navigation and geographic orientation. It commonly consists of a magnetized needle or other element, such as a compass card or compass rose, which can pivot to align itself wit ...
for navigation. They sculpted a directional spoon from lodestone in such a way that the handle of the spoon always pointed south.
Alexander Neckam
Alexander Neckam (8 September 115731 March 1217) was an English magnetician, poet, theologian, and writer. He was an abbot of Cirencester Abbey from 1213 until his death.
Early life
Born on 8 September 1157 in St Albans, Alexander shared his b ...
, by 1187, was the first in Europe to describe the compass and its use for navigation. In 1269,
Peter Peregrinus de Maricourt wrote the ''Epistola de magnete'', the first extant treatise describing the properties of magnets. In 1282, the properties of magnets and the dry compasses were discussed by
Al-Ashraf Umar II
Al‐Malik Al‐Ashraf (Mumahhid Al‐Din) Umar Ibn Yūsuf Ibn Umar Ibn Alī Ibn Rasul (), also as Umar Ibn Yusuf (or also Al-Asharaf Umar II) was the third Rasulid sultan and also an mathematician, astronomer and physician.
Biography
Umar Ibn ...
, a
Yemeni physicist,
astronomer
An astronomer is a scientist in the field of astronomy who focuses their studies on a specific question or field outside the scope of Earth. They observe astronomical objects such as stars, planets, moons, comets and galaxies – in either ...
, and
geographer
A geographer is a physical scientist, social scientist or humanist whose area of study is geography, the study of Earth's natural environment and human society, including how society and nature interacts. The Greek prefix "geo" means "earth" a ...
.
Leonardo Garzoni's only extant work, the ''Due trattati sopra la natura, e le qualità della calamita'', is the first known example of a modern treatment of magnetic phenomena. Written in years near 1580 and never published, the treatise had a wide diffusion. In particular, Garzoni is referred to as an expert in magnetism by Niccolò Cabeo, whose Philosophia Magnetica (1629) is just a re-adjustment of Garzoni's work. Garzoni's treatise was known also to
Giovanni Battista Della Porta
Giambattista della Porta (; 1535 – 4 February 1615), also known as Giovanni Battista Della Porta, was an Italian scholar, polymath and playwright who lived in Naples at the time of the Renaissance, Scientific Revolution and Reformation.
Giamb ...
.
In 1600,
William Gilbert published his ''
De Magnete, Magneticisque Corporibus, et de Magno Magnete Tellure'' (''On the Magnet and Magnetic Bodies, and on the Great Magnet the Earth''). In this work he describes many of his experiments with his model earth called the
terrella
A terrella (Latin for "little earth") is a small magnetised model ball representing the Earth, that is thought to have been invented by the English physician William Gilbert while investigating magnetism, and further developed 300 years later b ...
. From his experiments, he concluded that the
Earth
Earth is the third planet from the Sun and the only astronomical object known to harbor life. While large volumes of water can be found throughout the Solar System, only Earth sustains liquid surface water. About 71% of Earth's surfa ...
was itself magnetic and that this was the reason compasses pointed north whereas, previously, some believed that it was the pole star
Polaris or a large magnetic island on the north pole that attracted the compass.
An understanding of the relationship between
electricity
Electricity is the set of physical phenomena associated with the presence and motion of matter that has a property of electric charge. Electricity is related to magnetism, both being part of the phenomenon of electromagnetism, as describ ...
and magnetism began in 1819 with work by
Hans Christian Ørsted, a professor at the University of Copenhagen, who discovered, by the accidental twitching of a compass needle near a wire, that an electric current could create a magnetic field. This landmark experiment is known as Ørsted's Experiment. Following this were several other scientists' experiments, with
André-Marie Ampère, who in 1820 discovered that the magnetic field circulating in a closed-path was related to the current flowing through a surface enclosed by the path;
Carl Friedrich Gauss
Johann Carl Friedrich Gauss (; german: Gauß ; la, Carolus Fridericus Gauss; 30 April 177723 February 1855) was a German mathematician and physicist who made significant contributions to many fields in mathematics and science. Sometimes refer ...
;
Jean-Baptiste Biot
Jean-Baptiste Biot (; ; 21 April 1774 – 3 February 1862) was a French physicist, astronomer, and mathematician who co-discovered the Biot–Savart law of magnetostatics with Félix Savart, established the reality of meteorites, made an early ba ...
and
Félix Savart
Félix Savart (; ; 30 June 1791, Mézières – 16 March 1841, Paris) was a French physicist and mathematician who is primarily known for the Biot–Savart law of electromagnetism, which he discovered together with his colleague Jean-Bapti ...
, both of whom in 1820 came up with the
Biot–Savart law
In physics, specifically electromagnetism, the Biot–Savart law ( or ) is an equation describing the magnetic field generated by a constant electric current. It relates the magnetic field to the magnitude, direction, length, and proximity of the ...
giving an equation for the magnetic field from a current-carrying wire;
Michael Faraday
Michael Faraday (; 22 September 1791 – 25 August 1867) was an English scientist who contributed to the study of electromagnetism and electrochemistry. His main discoveries include the principles underlying electromagnetic inducti ...
, who in 1831 found that a time-varying magnetic flux through a loop of wire induced a voltage, and others finding further links between magnetism and electricity.
James Clerk Maxwell
James Clerk Maxwell (13 June 1831 – 5 November 1879) was a Scottish mathematician and scientist responsible for the classical theory of electromagnetic radiation, which was the first theory to describe electricity, magnetism and li ...
synthesized and expanded these insights into
Maxwell's equations
Maxwell's equations, or Maxwell–Heaviside equations, are a set of coupled partial differential equations that, together with the Lorentz force law, form the foundation of classical electromagnetism, classical optics, and electric circuits.
...
, unifying electricity, magnetism, and
optics
Optics is the branch of physics that studies the behaviour and properties of light, including its interactions with matter and the construction of instruments that use or detect it. Optics usually describes the behaviour of visible, ultrav ...
into the field of
electromagnetism
In physics, electromagnetism is an interaction that occurs between particles with electric charge. It is the second-strongest of the four fundamental interactions, after the strong force, and it is the dominant force in the interactions of ...
. In 1905,
Albert Einstein
Albert Einstein ( ; ; 14 March 1879 – 18 April 1955) was a German-born theoretical physicist, widely acknowledged to be one of the greatest and most influential physicists of all time. Einstein is best known for developing the theory ...
used these laws in motivating his theory of
special relativity
In physics, the special theory of relativity, or special relativity for short, is a scientific theory regarding the relationship between space and time. In Albert Einstein's original treatment, the theory is based on two postulates:
# The laws ...
,
[A. Einstein: "On the Electrodynamics of Moving Bodies"](_blank)
June 30, 1905. requiring that the laws held true in all
inertial reference frame
In classical physics and special relativity, an inertial frame of reference (also called inertial reference frame, inertial frame, inertial space, or Galilean reference frame) is a frame of reference that is not undergoing any acceleration. ...
s.
Electromagnetism has continued to develop into the 21st century, being incorporated into the more fundamental theories of
gauge theory,
quantum electrodynamics
In particle physics, quantum electrodynamics (QED) is the relativistic quantum field theory of electrodynamics. In essence, it describes how light and matter interact and is the first theory where full agreement between quantum mechanics and spec ...
,
electroweak theory
In particle physics, the electroweak interaction or electroweak force is the unified description of two of the four known fundamental interactions of nature: electromagnetism and the weak interaction. Although these two forces appear very differe ...
, and finally the
standard model.
Sources
Magnetism, at its root, arises from two sources:
#
Electric current.
#
Spin magnetic moment
In physics, mainly quantum mechanics and particle physics, a spin magnetic moment is the magnetic moment caused by the spin of elementary particles. For example, the electron is an elementary spin-1/2 fermion. Quantum electrodynamics gives the ...
s of
elementary particles
In particle physics, an elementary particle or fundamental particle is a subatomic particle that is not composed of other particles. Particles currently thought to be elementary include electrons, the fundamental fermions (quarks, leptons, anti ...
.
The magnetic properties of materials are mainly due to the magnetic moments of their
atom
Every atom is composed of a nucleus and one or more electrons bound to the nucleus. The nucleus is made of one or more protons and a number of neutrons. Only the most common variety of hydrogen has no neutrons.
Every solid, liquid, gas, ...
s' orbiting
electron
The electron ( or ) is a subatomic particle with a negative one elementary electric charge. Electrons belong to the first generation of the lepton particle family,
and are generally thought to be elementary particles because they have no ...
s. The magnetic moments of the nuclei of atoms are typically thousands of times smaller than the electrons' magnetic moments, so they are negligible in the context of the magnetization of materials. Nuclear magnetic moments are nevertheless very important in other contexts, particularly in
nuclear magnetic resonance
Nuclear magnetic resonance (NMR) is a physical phenomenon in which nuclei in a strong constant magnetic field are perturbed by a weak oscillating magnetic field (in the near field) and respond by producing an electromagnetic signal with a ...
(NMR) and
magnetic resonance imaging (MRI).
Ordinarily, the enormous number of electrons in a material are arranged such that their magnetic moments (both orbital and intrinsic) cancel out. This is due, to some extent, to electrons combining into pairs with opposite intrinsic magnetic moments as a result of the
Pauli exclusion principle
In quantum mechanics, the Pauli exclusion principle states that two or more identical particles with half-integer spins (i.e. fermions) cannot occupy the same quantum state within a quantum system simultaneously. This principle was formulat ...
(see ''
electron configuration''), and combining into filled
subshells with zero net orbital motion. In both cases, the electrons preferentially adopt arrangements in which the magnetic moment of each electron is canceled by the opposite moment of another electron. Moreover, even when the
electron configuration ''is'' such that there are unpaired electrons and/or non-filled subshells, it is often the case that the various electrons in the solid will contribute magnetic moments that point in different, random directions so that the material will not be magnetic.
Sometimes, either spontaneously, or owing to an applied external magnetic field—each of the electron magnetic moments will be, on average, lined up. A suitable material can then produce a strong net magnetic field.
The magnetic behavior of a material depends on its structure, particularly its
electron configuration, for the reasons mentioned above, and also on the temperature. At high temperatures, random
thermal motion
A thermal column (or thermal) is a rising mass of buoyant air, a convective current in the atmosphere, that transfers heat energy vertically. Thermals are created by the uneven heating of Earth's surface from solar radiation, and are an example ...
makes it more difficult for the electrons to maintain alignment.
Due to high longitude of the alpha system the hierarchy doesn't work as well.
Types of magnetism
Diamagnetism
Diamagnetism appears in all materials and is the tendency of a material to oppose an applied magnetic field, and therefore, to be repelled by a magnetic field. However, in a material with paramagnetic properties (that is, with a tendency to enhance an external magnetic field), the paramagnetic behavior dominates.
[
] Thus, despite its universal occurrence, diamagnetic behavior is observed only in a purely diamagnetic material. In a diamagnetic material, there are no unpaired electrons, so the intrinsic electron magnetic moments cannot produce any bulk effect. In these cases, the magnetization arises from the electrons' orbital motions, which can be understood
classically as follows:
This description is meant only as a
heuristic
A heuristic (; ), or heuristic technique, is any approach to problem solving or self-discovery that employs a practical method that is not guaranteed to be optimal, perfect, or rational, but is nevertheless sufficient for reaching an immediate ...
; the
Bohr–Van Leeuwen theorem shows that diamagnetism is impossible according to classical physics, and that a proper understanding requires a
quantum-mechanical description.
All materials undergo this orbital response. However, in paramagnetic and ferromagnetic substances, the diamagnetic effect is overwhelmed by the much stronger effects caused by the unpaired electrons.
Paramagnetism
In a paramagnetic material there are ''unpaired electrons''; i.e.,
atomic or
molecular orbital
In chemistry, a molecular orbital is a mathematical function describing the location and wave-like behavior of an electron in a molecule. This function can be used to calculate chemical and physical properties such as the probability of findin ...
s with exactly one electron in them. While paired electrons are required by the
Pauli exclusion principle
In quantum mechanics, the Pauli exclusion principle states that two or more identical particles with half-integer spins (i.e. fermions) cannot occupy the same quantum state within a quantum system simultaneously. This principle was formulat ...
to have their intrinsic ('spin') magnetic moments pointing in opposite directions, causing their magnetic fields to cancel out, an unpaired electron is free to align its magnetic moment in any direction. When an external magnetic field is applied, these magnetic moments will tend to align themselves in the same direction as the applied field, thus reinforcing it.
Ferromagnetism
A ferromagnet, like a paramagnetic substance, has unpaired electrons. However, in addition to the electrons' intrinsic magnetic moment's tendency to be parallel to an applied field, there is also in these materials a tendency for these magnetic moments to orient parallel to each other to maintain a lowered-energy state. Thus, even in the absence of an applied field, the magnetic moments of the electrons in the material spontaneously line up parallel to one another.
Every ferromagnetic substance has its own individual temperature, called the
Curie temperature
In physics and materials science, the Curie temperature (''T''C), or Curie point, is the temperature above which certain materials lose their permanent magnetic properties, which can (in most cases) be replaced by induced magnetism. The Cur ...
, or Curie point, above which it loses its ferromagnetic properties. This is because the thermal tendency to disorder overwhelms the energy-lowering due to ferromagnetic order.
Ferromagnetism only occurs in a few substances; common ones are
iron
Iron () is a chemical element with Symbol (chemistry), symbol Fe (from la, Wikt:ferrum, ferrum) and atomic number 26. It is a metal that belongs to the first transition series and group 8 element, group 8 of the periodic table. It is, Abundanc ...
,
nickel
Nickel is a chemical element with symbol Ni and atomic number 28. It is a silvery-white lustrous metal with a slight golden tinge. Nickel is a hard and ductile transition metal. Pure nickel is chemically reactive but large pieces are slow ...
,
cobalt
Cobalt is a chemical element with the symbol Co and atomic number 27. As with nickel, cobalt is found in the Earth's crust only in a chemically combined form, save for small deposits found in alloys of natural meteoric iron. The free element, p ...
, their
alloy
An alloy is a mixture of chemical elements of which at least one is a metal. Unlike chemical compounds with metallic bases, an alloy will retain all the properties of a metal in the resulting material, such as electrical conductivity, ductilit ...
s, and some alloys of
rare-earth
The rare-earth elements (REE), also called the rare-earth metals or (in context) rare-earth oxides or sometimes the lanthanides (yttrium and scandium are usually included as rare earths), are a set of 17 nearly-indistinguishable lustrous silve ...
metals.
Magnetic domains
The magnetic moments of atoms in a
ferromagnetic material cause them to behave something like tiny permanent magnets. They stick together and align themselves into small regions of more or less uniform alignment called
magnetic domains
A magnetic domain is a region within a magnetic material in which the magnetization is in a uniform direction. This means that the individual magnetic moments of the atoms are aligned with one another and they point in the same direction. When ...
or
Weiss domains
A magnetic domain is a region within a magnetic material in which the magnetization is in a uniform direction. This means that the individual magnetic moments of the atoms are aligned with one another and they point in the same direction. When ...
. Magnetic domains can be observed with a
magnetic force microscope to reveal magnetic domain boundaries that resemble white lines in the sketch. There are many scientific experiments that can physically show magnetic fields.
When a domain contains too many molecules, it becomes unstable and divides into two domains aligned in opposite directions so that they stick together more stably.
When exposed to a magnetic field, the domain boundaries move, so that the domains aligned with the magnetic field grow and dominate the structure (dotted yellow area), as shown at the left. When the magnetizing field is removed, the domains may not return to an unmagnetized state. This results in the ferromagnetic material's being magnetized, forming a permanent magnet.
When magnetized strongly enough that the prevailing domain overruns all others to result in only one single domain, the material is
magnetically saturated. When a magnetized ferromagnetic material is heated to the
Curie point
In physics and materials science, the Curie temperature (''T''C), or Curie point, is the temperature above which certain materials lose their permanent magnetic properties, which can (in most cases) be replaced by induced magnetism. The Cur ...
temperature, the molecules are agitated to the point that the magnetic domains lose the organization, and the magnetic properties they cause cease. When the material is cooled, this domain alignment structure spontaneously returns, in a manner roughly analogous to how a liquid can
freeze into a crystalline solid.
Antiferromagnetism
![Antiferromagnetic ordering](https://upload.wikimedia.org/wikipedia/commons/5/5d/Antiferromagnetic_ordering.svg)
In an
antiferromagnet
In materials that exhibit antiferromagnetism, the magnetic moments of atoms or molecules, usually related to the spins of electrons, align in a regular pattern with neighboring spins (on different sublattices) pointing in opposite directions. ...
, unlike a ferromagnet, there is a tendency for the intrinsic magnetic moments of neighboring valence electrons to point in ''opposite'' directions. When all atoms are arranged in a substance so that each neighbor is anti-parallel, the substance is antiferromagnetic. Antiferromagnets have a zero net magnetic moment, meaning that no field is produced by them. Antiferromagnets are less common compared to the other types of behaviors and are mostly observed at low temperatures. In varying temperatures, antiferromagnets can be seen to exhibit diamagnetic and ferromagnetic properties.
In some materials, neighboring electrons prefer to point in opposite directions, but there is no geometrical arrangement in which ''each'' pair of neighbors is anti-aligned. This is called a
spin glass
In condensed matter physics, a spin glass is a magnetic state characterized by randomness, besides cooperative behavior in freezing of spins at a temperature called 'freezing temperature' ''Tf''. In ferromagnetic solids, component atoms' magne ...
and is an example of
geometrical frustration In condensed matter physics, the term geometrical frustration (or in short: frustration) refers to a phenomenon where atoms tend to stick to non-trivial positions or where, on a regular crystal lattice, conflicting inter-atomic forces (each one favo ...
.
Ferrimagnetism
![Ferrimagnetic ordering](https://upload.wikimedia.org/wikipedia/commons/8/81/Ferrimagnetic_ordering.svg)
Like ferromagnetism, ferrimagnets retain their magnetization in the absence of a field. However, like antiferromagnets, neighboring pairs of electron spins tend to point in opposite directions. These two properties are not contradictory, because in the optimal geometrical arrangement, there is more magnetic moment from the sublattice of electrons that point in one direction, than from the sublattice that points in the opposite direction.
Most
ferrites are ferrimagnetic. The first discovered magnetic substance,
magnetite
Magnetite is a mineral and one of the main iron ores, with the chemical formula Fe2+Fe3+2O4. It is one of the oxides of iron, and is ferrimagnetic; it is attracted to a magnet and can be magnetized to become a permanent magnet itself. With th ...
, is a ferrite and was originally believed to be a ferromagnet;
Louis Néel
Louis Eugène Félix Néel (22 November 1904 – 17 November 2000) was a French physicist born in Lyon who received the Nobel Prize for Physics in 1970 for his studies of the magnetic properties of solids.
Biography
Néel studied at the Lycé ...
disproved this, however, after discovering ferrimagnetism.
Superparamagnetism
When a ferromagnet or ferrimagnet is sufficiently small, it acts like a single magnetic spin that is subject to
Brownian motion
Brownian motion, or pedesis (from grc, πήδησις "leaping"), is the random motion of particles suspended in a medium (a liquid or a gas).
This pattern of motion typically consists of random fluctuations in a particle's position insi ...
. Its response to a magnetic field is qualitatively similar to the response of a paramagnet, but much larger.
Other types of magnetism
*
Metamagnetism
Metamagnetism is a sudden (often, dramatic) increase in the magnetization of a material with a small change in an externally applied magnetic field. The metamagnetic behavior may have quite different physical causes for different types of metamagne ...
*
Molecule-based magnets
Molecule-based magnets (MBMs) or molecular magnets are a class of materials capable of displaying ferromagnetism and other more complex magnetic phenomena. This class expands the materials properties typically associated with magnets to include lo ...
*
Single-molecule magnet
*
Spin glass
In condensed matter physics, a spin glass is a magnetic state characterized by randomness, besides cooperative behavior in freezing of spins at a temperature called 'freezing temperature' ''Tf''. In ferromagnetic solids, component atoms' magne ...
Electromagnet
![Electromagnet](https://upload.wikimedia.org/wikipedia/commons/3/3c/Electromagnet.gif)
An
electromagnet
An electromagnet is a type of magnet in which the magnetic field is produced by an electric current. Electromagnets usually consist of wire wound into a coil. A current through the wire creates a magnetic field which is concentrated in ...
is a type of
magnet
A magnet is a material or object that produces a magnetic field. This magnetic field is invisible but is responsible for the most notable property of a magnet: a force that pulls on other ferromagnetic materials, such as iron, steel, nicke ...
in which the
magnetic field is produced by an
electric current. The magnetic field disappears when the current is turned off. Electromagnets usually consist of a large number of closely spaced turns of wire that create the magnetic field. The wire turns are often wound around a
magnetic core made from a
ferromagnetic or
ferrimagnetic
A ferrimagnetic material is a material that has populations of atoms with opposing magnetic moments, as in antiferromagnetism, but these moments are unequal in magnitude so a spontaneous magnetization remains. This can for example occur when ...
material such as
iron
Iron () is a chemical element with Symbol (chemistry), symbol Fe (from la, Wikt:ferrum, ferrum) and atomic number 26. It is a metal that belongs to the first transition series and group 8 element, group 8 of the periodic table. It is, Abundanc ...
; the magnetic core concentrates the
magnetic flux and makes a more powerful magnet.
The main advantage of an electromagnet over a
permanent magnet is that the magnetic field can be quickly changed by controlling the amount of electric current in the winding. However, unlike a permanent magnet that needs no power, an electromagnet requires a continuous supply of current to maintain the magnetic field.
Electromagnets are widely used as components of other electrical devices, such as
motors
An engine or motor is a machine designed to convert one or more forms of energy into mechanical energy.
Available energy sources include potential energy (e.g. energy of the Earth's gravitational field as exploited in hydroelectric power g ...
,
generators,
relay
A relay
Electromechanical relay schematic showing a control coil, four pairs of normally open and one pair of normally closed contacts
An automotive-style miniature relay with the dust cover taken off
A relay is an electrically operated switch ...
s, solenoids,
loudspeaker
A loudspeaker (commonly referred to as a speaker or speaker driver) is an electroacoustic transducer that converts an electrical audio signal into a corresponding sound. A ''speaker system'', also often simply referred to as a "speaker" or ...
s,
hard disks,
MRI machines, scientific instruments, and
magnetic separation
Magnetic separation is the process of separating components of mixtures by using a magnet to attract magnetic substances. The process that is used for magnetic separation separates non-magnetic substances from those which are magnetic. This techniq ...
equipment. Electromagnets are also employed in industry for picking up and moving heavy iron objects such as scrap iron and steel.
Electromagnetism was discovered in 1820.
Magnetism, electricity, and special relativity
As a consequence of Einstein's theory of special relativity, electricity and magnetism are fundamentally interlinked. Both magnetism lacking electricity, and electricity without magnetism, are inconsistent with special relativity, due to such effects as
length contraction
Length contraction is the phenomenon that a moving object's length is measured to be shorter than its proper length, which is the length as measured in the object's own rest frame. It is also known as Lorentz contraction or Lorentz–FitzGerald ...
,
time dilation
In physics and relativity, time dilation is the difference in the elapsed time as measured by two clocks. It is either due to a relative velocity between them ( special relativistic "kinetic" time dilation) or to a difference in gravitational ...
, and the fact that the
magnetic force
In physics (specifically in electromagnetism) the Lorentz force (or electromagnetic force) is the combination of electric and magnetic force on a point charge due to electromagnetic fields. A particle of charge moving with a velocity in an e ...
is velocity-dependent. However, when both electricity and magnetism are taken into account, the resulting theory (
electromagnetism
In physics, electromagnetism is an interaction that occurs between particles with electric charge. It is the second-strongest of the four fundamental interactions, after the strong force, and it is the dominant force in the interactions of ...
) is fully consistent with special relativity.
In particular, a phenomenon that appears purely electric or purely magnetic to one observer may be a mix of both to another, or more generally the relative contributions of electricity and magnetism are dependent on the frame of reference. Thus, special relativity "mixes" electricity and magnetism into a single, inseparable phenomenon called
electromagnetism
In physics, electromagnetism is an interaction that occurs between particles with electric charge. It is the second-strongest of the four fundamental interactions, after the strong force, and it is the dominant force in the interactions of ...
, analogous to how general relativity "mixes" space and time into
spacetime
In physics, spacetime is a mathematical model that combines the three dimensions of space and one dimension of time into a single four-dimensional manifold. Spacetime diagrams can be used to visualize relativistic effects, such as why differ ...
.
All observations on
electromagnetism
In physics, electromagnetism is an interaction that occurs between particles with electric charge. It is the second-strongest of the four fundamental interactions, after the strong force, and it is the dominant force in the interactions of ...
apply to what might be considered to be primarily magnetism, e.g. perturbations in the magnetic field are necessarily accompanied by a nonzero electric field, and propagate at the
speed of light
The speed of light in vacuum, commonly denoted , is a universal physical constant that is important in many areas of physics. The speed of light is exactly equal to ). According to the special theory of relativity, is the upper limit ...
.
Magnetic fields in a material
In a vacuum,
:
where is the
vacuum permeability
The vacuum magnetic permeability (variously ''vacuum permeability'', ''permeability of free space'', ''permeability of vacuum''), also known as the magnetic constant, is the magnetic permeability in a classical vacuum. It is a physical constant, ...
.
In a material,
:
The quantity is called ''magnetic polarization''.
If the field is small, the response of the magnetization in a
diamagnet
Diamagnetic materials are repelled by a magnetic field; an applied magnetic field creates an induced magnetic field in them in the opposite direction, causing a repulsive force. In contrast, paramagnetic and ferromagnetic materials are attract ...
or
paramagnet
Paramagnetism is a form of magnetism whereby some materials are weakly attracted by an externally applied magnetic field, and form internal, induced magnetic fields in the direction of the applied magnetic field. In contrast with this behavior, ...
is approximately linear:
:
the constant of proportionality being called the magnetic susceptibility. If so,
:
In a hard magnet such as a ferromagnet, is not proportional to the field and is generally nonzero even when is zero (see
Remanence).
Magnetic force
The phenomenon of magnetism is "mediated" by the magnetic field. An electric current or magnetic dipole creates a magnetic field, and that field, in turn, imparts magnetic forces on other particles that are in the fields.
Maxwell's equations, which simplify to the
Biot–Savart law
In physics, specifically electromagnetism, the Biot–Savart law ( or ) is an equation describing the magnetic field generated by a constant electric current. It relates the magnetic field to the magnitude, direction, length, and proximity of the ...
in the case of steady currents, describe the origin and behavior of the fields that govern these forces. Therefore, magnetism is seen whenever electrically
charged particles
In physics, a charged particle is a particle with an electric charge. It may be an ion, such as a molecule or atom with a surplus or deficit of electrons relative to protons. It can also be an electron or a proton, or another elementary particle, ...
are in
motion
In physics, motion is the phenomenon in which an object changes its position with respect to time. Motion is mathematically described in terms of displacement, distance, velocity, acceleration, speed and frame of reference to an observer and m ...
—for example, from movement of electrons in an
electric current, or in certain cases from the orbital motion of electrons around an atom's nucleus. They also arise from "intrinsic"
magnetic dipole
In electromagnetism, a magnetic dipole is the limit of either a closed loop of electric current or a pair of poles as the size of the source is reduced to zero while keeping the magnetic moment constant. It is a magnetic analogue of the electric ...
s arising from quantum-mechanical
spin.
The same situations that create magnetic fields—charge moving in a current or in an atom, and intrinsic magnetic dipoles—are also the situations in which a magnetic field has an effect, creating a force. Following is the formula for moving charge; for the forces on an intrinsic dipole, see magnetic dipole.
When a charged particle moves through a
magnetic field B, it feels a
Lorentz force F given by the
cross product:
:
where
:
is the electric charge of the particle, and
: v is the
velocity
Velocity is the directional speed of an object in motion as an indication of its rate of change in position as observed from a particular frame of reference and as measured by a particular standard of time (e.g. northbound). Velocity i ...
vector
Vector most often refers to:
*Euclidean vector, a quantity with a magnitude and a direction
*Vector (epidemiology), an agent that carries and transmits an infectious pathogen into another living organism
Vector may also refer to:
Mathematic ...
of the particle
Because this is a cross product, the force is
perpendicular
In elementary geometry, two geometric objects are perpendicular if they intersect at a right angle (90 degrees or π/2 radians). The condition of perpendicularity may be represented graphically using the ''perpendicular symbol'', ⟂. It ca ...
to both the motion of the particle and the magnetic field. It follows that the magnetic force does no
work
Work may refer to:
* Work (human activity), intentional activity people perform to support themselves, others, or the community
** Manual labour, physical work done by humans
** House work, housework, or homemaking
** Working animal, an animal t ...
on the particle; it may change the direction of the particle's movement, but it cannot cause it to speed up or slow down. The magnitude of the force is
:
where
is the angle between v and B.
One tool for determining the direction of the velocity vector of a moving charge, the magnetic field, and the force exerted is labeling the
index finger
The index finger (also referred to as forefinger, first finger, second finger, pointer finger, trigger finger, digitus secundus, digitus II, and many other terms) is the second digit of a human hand. It is located between the thumb and the mid ...
"V", the
middle finger
The middle finger, long finger, second finger, third finger, toll finger or tall man is the third digit of the human hand, located between the index finger and the ring finger. It is typically the longest digit. In anatomy, it is also calle ...
"B", and the
thumb "F" with your right hand. When making a gun-like configuration, with the middle finger crossing under the index finger, the fingers represent the velocity vector, magnetic field vector, and force vector, respectively. See also
right-hand rule.
Magnetic dipoles
A very common source of magnetic field found in nature is a
dipole
In physics, a dipole () is an electromagnetic phenomenon which occurs in two ways:
*An electric dipole deals with the separation of the positive and negative electric charges found in any electromagnetic system. A simple example of this system ...
, with a "
South pole
The South Pole, also known as the Geographic South Pole, Terrestrial South Pole or 90th Parallel South, is one of the two points where Earth's axis of rotation intersects its surface. It is the southernmost point on Earth and lies antipod ...
" and a "
North pole
The North Pole, also known as the Geographic North Pole or Terrestrial North Pole, is the point in the Northern Hemisphere where the Earth's rotation, Earth's axis of rotation meets its surface. It is called the True North Pole to distingu ...
", terms dating back to the use of magnets as compasses, interacting with the
Earth's magnetic field
Earth's magnetic field, also known as the geomagnetic field, is the magnetic field that extends from Earth's interior out into space, where it interacts with the solar wind, a stream of charged particles emanating from the Sun. The magnetic ...
to indicate North and South on the
globe
A globe is a spherical model of Earth, of some other celestial body, or of the celestial sphere. Globes serve purposes similar to maps, but unlike maps, they do not distort the surface that they portray except to scale it down. A model glo ...
. Since opposite ends of magnets are attracted, the north pole of a magnet is attracted to the south pole of another magnet. The Earth's
North Magnetic Pole
The north magnetic pole, also known as the magnetic north pole, is a point on the surface of Earth's Northern Hemisphere at which the planet's magnetic field points vertically downward (in other words, if a magnetic compass needle is allowed t ...
(currently in the Arctic Ocean, north of Canada) is physically a south pole, as it attracts the north pole of a compass.
A magnetic field contains
energy
In physics, energy (from Ancient Greek: ἐνέργεια, ''enérgeia'', “activity”) is the quantitative property that is transferred to a body or to a physical system, recognizable in the performance of work and in the form of hea ...
, and physical systems move toward configurations with lower energy. When diamagnetic material is placed in a magnetic field, a ''magnetic dipole'' tends to align itself in opposed polarity to that field, thereby lowering the net field strength. When ferromagnetic material is placed within a magnetic field, the magnetic dipoles align to the applied field, thus expanding the domain walls of the magnetic domains.
Magnetic monopoles
Since a bar magnet gets its ferromagnetism from electrons distributed evenly throughout the bar, when a bar magnet is cut in half, each of the resulting pieces is a smaller bar magnet. Even though a magnet is said to have a north pole and a south pole, these two poles cannot be separated from each other. A monopole—if such a thing exists—would be a new and fundamentally different kind of magnetic object. It would act as an isolated north pole, not attached to a south pole, or vice versa. Monopoles would carry "magnetic charge" analogous to electric charge. Despite systematic searches since 1931, , they have never been observed, and could very well not exist.
Nevertheless, some
theoretical physics
Theoretical physics is a branch of physics that employs mathematical models and abstractions of physical objects and systems to rationalize, explain and predict natural phenomena. This is in contrast to experimental physics, which uses experim ...
models predict the existence of these
magnetic monopoles
In particle physics, a magnetic monopole is a hypothetical elementary particle that is an isolated magnet with only one magnetic pole (a north pole without a south pole or vice versa). A magnetic monopole would have a net north or south "magneti ...
.
Paul Dirac
Paul Adrien Maurice Dirac (; 8 August 1902 – 20 October 1984) was an English theoretical physicist who is regarded as one of the most significant physicists of the 20th century. He was the Lucasian Professor of Mathematics at the Univer ...
observed in 1931 that, because electricity and magnetism show a certain
symmetry, just as
quantum theory
Quantum theory may refer to:
Science
*Quantum mechanics, a major field of physics
*Old quantum theory, predating modern quantum mechanics
* Quantum field theory, an area of quantum mechanics that includes:
** Quantum electrodynamics
** Quantum ...
predicts that individual
positive
Positive is a property of positivity and may refer to:
Mathematics and science
* Positive formula, a logical formula not containing negation
* Positive number, a number that is greater than 0
* Plus sign, the sign "+" used to indicate a posi ...
or
negative electric charges can be observed without the opposing charge, isolated South or North magnetic poles should be observable. Using quantum theory Dirac showed that if magnetic monopoles exist, then one could explain the quantization of electric charge—that is, why the observed
elementary particles
In particle physics, an elementary particle or fundamental particle is a subatomic particle that is not composed of other particles. Particles currently thought to be elementary include electrons, the fundamental fermions (quarks, leptons, anti ...
carry charges that are multiples of the charge of the electron.
Certain
grand unified theories
A Grand Unified Theory (GUT) is a model in particle physics in which, at high energies, the three gauge interactions of the Standard Model comprising the electromagnetic, weak, and strong forces are merged into a single force. Although this u ...
predict the existence of monopoles which, unlike elementary particles, are
solitons
In mathematics and physics, a soliton or solitary wave is a self-reinforcing wave packet that maintains its shape while it propagates at a constant velocity. Solitons are caused by a cancellation of nonlinear and dispersive effects in the mediu ...
(localized energy packets). The initial results of using these models to estimate the number of monopoles created in the
Big Bang contradicted cosmological observations—the monopoles would have been so plentiful and massive that they would have long since halted the expansion of the universe. However, the idea of
inflation
In economics, inflation is an increase in the general price level of goods and services in an economy. When the general price level rises, each unit of currency buys fewer goods and services; consequently, inflation corresponds to a reduct ...
(for which this problem served as a partial motivation) was successful in solving this problem, creating models in which monopoles existed but were rare enough to be consistent with current observations.
Units
SI
Other
*
gauss
Johann Carl Friedrich Gauss (; german: Gauß ; la, Carolus Fridericus Gauss; 30 April 177723 February 1855) was a German mathematician and physicist who made significant contributions to many fields in mathematics and science. Sometimes refer ...
– the
centimeter-gram-second (CGS)
unit
Unit may refer to:
Arts and entertainment
* UNIT, a fictional military organization in the science fiction television series ''Doctor Who''
* Unit of action, a discrete piece of action (or beat) in a theatrical presentation
Music
* ''Unit'' (a ...
of magnetic field (denoted B).
*
oersted
The oersted (symbol Oe) is the coherent derived unit of the auxiliary magnetic field H in the centimetre–gram–second system of units (CGS). It is equivalent to 1 dyne per maxwell.
Difference between CGS and SI systems
In the CGS system, ...
– the CGS unit of
magnetizing field
A magnetic field is a vector field that describes the magnetic influence on moving electric charges, electric currents, and magnetic materials. A moving charge in a magnetic field experiences a force perpendicular to its own velocity and to ...
(denoted H)
*
maxwell – the CGS unit for
magnetic flux
* gamma – a unit of ''magnetic flux density'' that was commonly used before the
tesla came into use (1.0 gamma = 1.0 nanotesla)
* ''μ''
0 – common symbol for the
permeability of free space (
newton/(
ampere-turn)
2)
Living things
![Frog diamagnetic levitation](https://upload.wikimedia.org/wikipedia/commons/7/7b/Frog_diamagnetic_levitation.jpg)
Some
organisms
In biology, an organism () is any life, living system that functions as an individual entity. All organisms are composed of cells (cell theory). Organisms are classified by taxonomy (biology), taxonomy into groups such as Multicellular o ...
can detect magnetic fields, a phenomenon known as
magnetoception
Magnetoreception is a sense which allows an organism to detect the Earth's magnetic field. Animals with this sense include some arthropods, molluscs, and vertebrates (fish, amphibians, reptiles, birds, and mammals, though not humans). The se ...
. Some materials in living things are ferromagnetic, though it is unclear if the magnetic properties serve a special function or are merely a byproduct of containing iron. For instance,
chitons
Chitons () are marine molluscs of varying size in the class Polyplacophora (), formerly known as Amphineura. About 940 extant and 430 fossil species are recognized.
They are also sometimes known as gumboots or sea cradles or coat-of-mail sh ...
, a type of marine mollusk, produce magnetite to harden their teeth, and even humans produce
magnetite
Magnetite is a mineral and one of the main iron ores, with the chemical formula Fe2+Fe3+2O4. It is one of the oxides of iron, and is ferrimagnetic; it is attracted to a magnet and can be magnetized to become a permanent magnet itself. With th ...
in bodily tissue.
Magnetobiology
Magnetobiology is the study of biological effects of mainly weak static and low-frequency magnetic fields, which do not cause heating of tissues. Magnetobiological effects have unique features that obviously distinguish them from thermal effects; ...
studies the effects of magnetic fields on living organisms; fields naturally produced by an organism are known as
biomagnetism. Many biological organisms are mostly made of water, and because water is
diamagnetic
Diamagnetic materials are repelled by a magnetic field; an applied magnetic field creates an induced magnetic field in them in the opposite direction, causing a repulsive force. In contrast, paramagnetic and ferromagnetic materials are attracted ...
, extremely strong magnetic fields can repel these living things.
Quantum-mechanical origin of magnetism
While heuristic explanations based on classical physics can be formulated, diamagnetism, paramagnetism and ferromagnetism can be fully explained only using quantum theory.
Ferromagnetism, ''Feynman Lectures in Physics'' Ch 36
/ref>
A successful model was developed already in 1927, by Walter Heitler
Walter Heinrich Heitler (; 2 January 1904 – 15 November 1981) was a German physicist who made contributions to quantum electrodynamics and quantum field theory. He brought chemistry under quantum mechanics through his theory of valence bond ...
and Fritz London
Fritz Wolfgang London (March 7, 1900 – March 30, 1954) was a German physicist and professor at Duke University. His fundamental contributions to the theories of chemical bonding and of intermolecular forces ( London dispersion forces) are today ...
, who derived, quantum-mechanically, how hydrogen molecules are formed from hydrogen atoms, i.e. from the atomic hydrogen orbitals and centered at the nuclei ''A'' and ''B'', see below. That this leads to magnetism is not at all obvious, but will be explained in the following.
According to the Heitler–London theory, so-called two-body molecular -orbitals are formed, namely the resulting orbital is:
:
Here the last product means that a first electron, r1, is in an atomic hydrogen-orbital centered at the second nucleus, whereas the second electron runs around the first nucleus. This "exchange" phenomenon is an expression for the quantum-mechanical property that particles with identical properties cannot be distinguished. It is specific not only for the formation of chemical bond
A chemical bond is a lasting attraction between atoms or ions that enables the formation of molecules and crystals. The bond may result from the electrostatic force between oppositely charged ions as in ionic bonds, or through the sharing of ...
s, but also for magnetism. That is, in this connection the term exchange interaction
In chemistry and physics, the exchange interaction (with an exchange energy and exchange term) is a quantum mechanical effect that only occurs between identical particles. Despite sometimes being called an exchange force in an analogy to classic ...
arises, a term which is essential for the origin of magnetism, and which is stronger, roughly by factors 100 and even by 1000, than the energies arising from the electrodynamic dipole-dipole interaction.
As for the ''spin function'' , which is responsible for the magnetism, we have the already mentioned Pauli's principle, namely that a symmetric orbital (i.e. with the + sign as above) must be multiplied with an antisymmetric spin function (i.e. with a − sign), and ''vice versa''. Thus:
:,
I.e., not only and must be substituted by ''α'' and ''β'', respectively (the first entity means "spin up", the second one "spin down"), but also the sign + by the − sign, and finally ri by the discrete values ''s''i (= ±); thereby we have and . The "singlet state
In quantum mechanics, a singlet state usually refers to a system in which all electrons are paired. The term 'singlet' originally meant a linked set of particles whose net angular momentum is zero, that is, whose overall spin quantum number s=0. A ...
", i.e. the − sign, means: the spins are ''antiparallel'', i.e. for the solid we have antiferromagnetism
In materials that exhibit antiferromagnetism, the magnetic moments of atoms or molecules, usually related to the spins of electrons, align in a regular pattern with neighboring spins (on different sublattices) pointing in opposite directions. ...
, and for two-atomic molecules one has diamagnetism
Diamagnetic materials are repelled by a magnetic field; an applied magnetic field creates an induced magnetic field in them in the opposite direction, causing a repulsive force. In contrast, paramagnetic and ferromagnetic materials are attracte ...
. The tendency to form a (homoeopolar) chemical bond (this means: the formation of a ''symmetric'' molecular orbital, i.e. with the + sign) results through the Pauli principle automatically in an ''antisymmetric'' spin state (i.e. with the − sign). In contrast, the Coulomb repulsion of the electrons, i.e. the tendency that they try to avoid each other by this repulsion, would lead to an ''antisymmetric'' orbital function (i.e. with the − sign) of these two particles, and complementary to a ''symmetric'' spin function (i.e. with the + sign, one of the so-called " triplet functions"). Thus, now the spins would be ''parallel'' (ferromagnetism
Ferromagnetism is a property of certain materials (such as iron) which results in a large observed magnetic permeability, and in many cases a large magnetic coercivity allowing the material to form a permanent magnet. Ferromagnetic materials ...
in a solid, paramagnetism
Paramagnetism is a form of magnetism whereby some materials are weakly attracted by an externally applied magnetic field, and form internal, induced magnetic fields in the direction of the applied magnetic field. In contrast with this behavior, ...
in two-atomic gases).
The last-mentioned tendency dominates in the metals iron
Iron () is a chemical element with Symbol (chemistry), symbol Fe (from la, Wikt:ferrum, ferrum) and atomic number 26. It is a metal that belongs to the first transition series and group 8 element, group 8 of the periodic table. It is, Abundanc ...
, cobalt
Cobalt is a chemical element with the symbol Co and atomic number 27. As with nickel, cobalt is found in the Earth's crust only in a chemically combined form, save for small deposits found in alloys of natural meteoric iron. The free element, p ...
and nickel
Nickel is a chemical element with symbol Ni and atomic number 28. It is a silvery-white lustrous metal with a slight golden tinge. Nickel is a hard and ductile transition metal. Pure nickel is chemically reactive but large pieces are slow ...
, and in some rare earths, which are ''ferromagnetic''. Most of the other metals, where the first-mentioned tendency dominates, are ''nonmagnetic'' (e.g. sodium
Sodium is a chemical element with the symbol Na (from Latin ''natrium'') and atomic number 11. It is a soft, silvery-white, highly reactive metal. Sodium is an alkali metal, being in group 1 of the periodic table. Its only stable ...
, aluminium
Aluminium (aluminum in American and Canadian English) is a chemical element with the symbol Al and atomic number 13. Aluminium has a density lower than those of other common metals, at approximately one third that of steel. I ...
, and magnesium
Magnesium is a chemical element with the symbol Mg and atomic number 12. It is a shiny gray metal having a low density, low melting point and high chemical reactivity. Like the other alkaline earth metals (group 2 of the periodic ta ...
) or ''antiferromagnetic'' (e.g. manganese
Manganese is a chemical element with the symbol Mn and atomic number 25. It is a hard, brittle, silvery metal, often found in minerals in combination with iron. Manganese is a transition metal with a multifaceted array of industrial alloy use ...
). Diatomic gases are also almost exclusively diamagnetic, and not paramagnetic. However, the oxygen molecule, because of the involvement of π-orbitals, is an exception important for the life-sciences.
The Heitler-London considerations can be generalized to the Heisenberg model of magnetism (Heisenberg 1928).
The explanation of the phenomena is thus essentially based on all subtleties of quantum mechanics, whereas the electrodynamics covers mainly the phenomenology.
Optically induced magnetism
Optically induced magnetism is essentially the combination of optics and induced magnetism. Optics
Optics is the branch of physics that studies the behaviour and properties of light, including its interactions with matter and the construction of instruments that use or detect it. Optics usually describes the behaviour of visible, ultrav ...
is the study of the behavior of light and induced magnetism is when an object is kept near a magnet and the object itself becomes magneti
Optically induced magnetism works when an electric current passes through a magnetic layer and the electric current becomes Spin polarization, spin-polarized. The spin-polarized current will exert a spin-transfer torque
Spin-transfer torque (STT) is an effect in which the orientation of a magnetic layer in a magnetic tunnel junction or spin valve can be modified using a spin-polarized current.
Charge carriers (such as electrons) have a property known as spin ...
(STT) on the magnetization. This phenomena can also be generated inside a non-magnetic metal due to the spin–orbit coupling (SOC) Spin%E2%80%93orbit interaction
In quantum physics, the spin–orbit interaction (also called spin–orbit effect or spin–orbit coupling) is a relativistic interaction of a particle's spin with its motion inside a potential. A key example of this phenomenon is the spin–or ...
, and the corresponding torque (spin–orbit torque (SOT).
Method
Optically induced magnetism occurs when an initial photon establishes an electrical polarization within a material and that causes an orbital angular momentum. This occurs on all electric dipoles within the material that transition between L = 0 and L = 1. A second photon can exert a magnetic torque on the orbital angular momentum, and that causes an exchange of orbital angular momentum to rotational angular momentum. The change from orbital angular momentum to rotational angular momentum de-excites the molecule and increases the radius of charge motion. When the radius of charge motion increases, the magnetic dipole Electron magnetic moment
In atomic physics, the electron magnetic moment, or more specifically the electron magnetic dipole moment, is the magnetic moment of an electron resulting from its intrinsic properties of spin and electric charge. The value of the electron magnet ...
increases. This is because the magnetic dipole depends on the area enclosed by the current within the molecule (m = ids). This type of magnetism can occur in materials that are thought to be "non magnetic," such as diamagnets Diamagnetism
Diamagnetic materials are repelled by a magnetic field; an applied magnetic field creates an induced magnetic field in them in the opposite direction, causing a repulsive force. In contrast, paramagnetic and ferromagnetic materials are attracte ...
, as long as the material is dielectric
In electromagnetism, a dielectric (or dielectric medium) is an electrical insulator that can be polarised by an applied electric field. When a dielectric material is placed in an electric field, electric charges do not flow through the mate ...
.
The more you optically excite the dielectric material, the more magnetic dipoles are formed, and therefore the more magnetic the material becomes. However, the electric dipole Electric dipole moment magnitude will always be larger than the magnetic dipole magnitude, and the magnetic dipole moment will always be relative to the electric dipole moment.
See also
* Coercivity
Coercivity, also called the magnetic coercivity, coercive field or coercive force, is a measure of the ability of a ferromagnetic material to withstand an external magnetic field without becoming demagnetized. Coercivity is usually measured in ...
* Gravitomagnetism
Gravitoelectromagnetism, abbreviated GEM, refers to a set of formal analogies between the equations for electromagnetism and relativistic gravitation; specifically: between Maxwell's field equations and an approximation, valid under certain ...
* Magnetic hysteresis
Magnetic hysteresis occurs when an external magnetic field is applied to a ferromagnet such as iron and the atomic dipoles align themselves with it. Even when the field is removed, part of the alignment will be retained: the material has become '' ...
* Magnetar
A magnetar is a type of neutron star with an extremely powerful magnetic field (∼109 to 1011 T, ∼1013 to 1015 G). The magnetic-field decay powers the emission of high-energy electromagnetic radiation, particularly X-rays and gamma rays.War ...
* Magnetic bearing
A magnetic bearing is a type of bearing that supports a load using magnetic levitation. Magnetic bearings support moving parts without physical contact. For instance, they are able to levitate a rotating shaft and permit relative motion with v ...
* Magnetic circuit
* Magnetic cooling
Magnetic refrigeration is a cooling technology based on the magnetocaloric effect. This technique can be used to attain extremely low temperatures, as well as the ranges used in common refrigerators.
A magnetocaloric material warms up when a ma ...
* Magnetic field viewing film
* Magnetic stirrer
A magnetic stirrer or magnetic mixer is a laboratory device that employs a rotating magnetic field to cause a stir bar (or ''flea'') immersed in a liquid to spin very quickly, thus stirring it. The rotating field may be created either by a rota ...
* Magnetic structure
The term magnetic structure of a material pertains to the ordered arrangement of magnetic spins, typically within an ordered crystallographic lattice. Its study is a branch of solid-state physics.
Magnetic structures
Most solid materials are n ...
* Magnetism and temperature
* Micromagnetism
* Neodymium magnet
* Plastic magnet
* Rare-earth magnet
* Spin wave
A spin wave is a propagating disturbance in the ordering of a magnetic material. These low-lying collective excitations occur in magnetic lattices with continuous symmetry. From the equivalent quasiparticle point of view, spin waves are known as ...
* Spontaneous magnetization
Spontaneous magnetization is the appearance of an ordered spin state ( magnetization) at zero applied magnetic field in a ferromagnetic or ferrimagnetic material below a critical point called the Curie temperature or .
Overview
Heated to tempe ...
* Vibrating-sample magnetometer
A vibrating-sample magnetometer (VSM) (also referred to as a Foner magnetometer) is a scientific instrument that measures magnetic properties based on Faraday’s Law of Induction. Simon Foner at MIT Lincoln Laboratory invented VSM in 1955 and rep ...
* Daniel Davis Jr.
References
Further reading
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Bibliography
The Exploratorium Science Snacks – Subject:Physics/Electricity & Magnetism
A collection of magnetic structures – MAGNDATA
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