|
Pulse EPR
Pulsed electron paramagnetic resonance (EPR) is an electron paramagnetic resonance technique that involves the alignment of the net magnetization vector of the electron spins in a constant magnetic field. This alignment is perturbed by applying a short oscillating field, usually a microwave pulse. One can then measure the emitted microwave signal which is created by the sample magnetization. Fourier transformation of the microwave signal yields an EPR spectrum in the frequency domain. With a vast variety of pulse sequences it is possible to gain extensive knowledge on structural and dynamical properties of paramagnetic compounds. Pulsed EPR techniques such as electron spin echo envelope modulation (ESEEM) or pulsed electron nuclear double resonance (ENDOR) can reveal the interactions of the electron spin with its surrounding nuclear spins. Scope Electron paramagnetic resonance (EPR) or electron spin resonance (ESR) is a spectroscopic technique widely used in biology, chemistry, ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Larmor Precession
In physics, Larmor precession (named after Joseph Larmor) is the precession of the magnetic moment of an object about an external magnetic field. The phenomenon is conceptually similar to the precession of a tilted classical gyroscope in an external torque-exerting gravitational field. Objects with a magnetic moment also have angular momentum and effective internal electric current proportional to their angular momentum; these include electrons, protons, other fermions, many atomic and nuclear physics, nuclear systems, as well as classical macroscopic systems. The external magnetic field exerts a torque on the magnetic moment, :\vec = \vec\times\vec = \gamma\vec\times\vec, where \vec is the torque, \vec is the magnetic dipole moment, \vec is the angular momentum vector, \vec is the external magnetic field, \times symbolizes the cross product, and \gamma is the gyromagnetic ratio which gives the proportionality constant between the magnetic moment and the angular momentum. The an ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Nuclear Magnetic Resonance
Nuclear magnetic resonance (NMR) is a physical phenomenon in which nuclei in a strong constant magnetic field are perturbed by a weak oscillating magnetic field (in the near field) and respond by producing an electromagnetic signal with a frequency characteristic of the magnetic field at the nucleus. This process occurs near resonance, when the oscillation frequency matches the intrinsic frequency of the nuclei, which depends on the strength of the static magnetic field, the chemical environment, and the magnetic properties of the isotope involved; in practical applications with static magnetic fields up to ca. 20 tesla, the frequency is similar to VHF and UHF television broadcasts (60–1000 MHz). NMR results from specific magnetic properties of certain atomic nuclei. Nuclear magnetic resonance spectroscopy is widely used to determine the structure of organic molecules in solution and study molecular physics and crystals as well as non-crystalline materials. ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Electron Nuclear Double Resonance
Electron nuclear double resonance (ENDOR) is a magnetic resonance technique for elucidating the molecular and electronic structure of paramagnetic species.Kevan, L and Kispert, L. D. ''Electron Spin Double Resonance Spectroscopy'' Interscience: New York, 1976. The technique was first introduced to resolve interactions in electron paramagnetic resonance (EPR) spectra./Kurreck, H.; Kirste, B.; Lubitz, W. ''Electron Nuclear Double Resonance Spectroscopy of Radicals in Solution'' VCH Publishers: New York, 1988. It is currently practiced in a variety of modalities, mainly in the areas of biophysics and heterogeneous catalysis. CW experiment In the standard continuous wave (cwENDOR) experiment, a sample is placed in a magnetic field and irradiated sequentially with a microwave followed by radio frequency. The changes are then detected by monitoring variations in the polarization of the saturated electron paramagnetic resonance (EPR) transition./ Theory ENDOR is illustrated by a two s ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
GWM HahnEchoDecay
Great Wall Motor Co., Ltd. (GWM) is a Chinese privately owned automobile manufacturer headquartered in Baoding, Hebei. Founded in 1984, it is currently the eighth largest automobile manufacturer in China, with 1.281 million sales in 2021. The company produces and sells vehicles under its own branding, such as GWM, Haval, WEY, TANK, POER, ORA. It also produces electric vehicles under some of the previously listed brandings, including dedicated EV brands such as ORA. Named after the Great Wall of China, the company is China's largest producer of sport-utility vehicles (SUVs) and pick-up trucks. In 2021, it was the third largest Chinese plug-in electric vehicle manufacturer in the Chinese market, with 4% of market share, selling under brand names such as Ora and Haval. History Established in 1984, Great Wall began with low volume production trucks such as the CC130. They later made the CC513, using the chassis from the Beijing BJ212. In 1993, they started producing a series of d ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Spin Echo
In magnetic resonance, a spin echo or Hahn echo is the refocusing of spin magnetisation by a pulse of resonant electromagnetic radiation. Modern nuclear magnetic resonance (NMR) and magnetic resonance imaging (MRI) make use of this effect. The NMR signal observed following an initial excitation pulse decays with time due to both spin relaxation and any ''inhomogeneous'' effects which cause spins in the sample to precess at different rates. The first of these, relaxation, leads to an irreversible loss of magnetisation. But the inhomogeneous dephasing can be removed by applying a 180° ''inversion'' pulse that inverts the magnetisation vectors. Examples of inhomogeneous effects include a magnetic field gradient and a distribution of chemical shifts. If the inversion pulse is applied after a period ''t'' of dephasing, the inhomogeneous evolution will rephase to form an echo at time 2''t''. In simple cases, the intensity of the echo relative to the initial signal is given by ''e– ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Free Induction Decay
In Fourier transform nuclear magnetic resonance spectroscopy, free induction decay (FID) is the observable NMR signal generated by non-equilibrium nuclear spin magnetization precessing about the magnetic field (conventionally along z). This non-equilibrium magnetization can be created generally by applying a pulse of radio-frequency close to the Larmor frequency of the nuclear spins. If the magnetization vector has a non-zero component in the xy plane, then the precessing magnetisation will induce a corresponding oscillating voltage in a detection coil surrounding the sample. This time-domain signal (a sinusoid) is typically digitised and then Fourier transformed in order to obtain a frequency spectrum of the NMR signal i.e. the NMR spectrum. The duration of the NMR signal is ultimately limited by T2 relaxation, but mutual interference of the different NMR frequencies present also causes the signal to be damped more quickly. When NMR frequencies are well-resolved, as is t ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Rabi Frequency
The Rabi frequency is the frequency at which the probability amplitudes of two atomic energy levels fluctuate in an oscillating electromagnetic field. It is proportional to the Transition Dipole Moment of the two levels and to the amplitude (''not'' intensity) of the Electromagnetic field. Population transfer between the levels of such a 2-level system illuminated with light exactly resonant with the difference in energy between the two levels will occur at the Rabi frequency; when the incident light is detuned from this energy difference (detuned from resonance) then the population transfer occurs at the generalized Rabi frequency. The Rabi frequency is a semiclassical concept since it treats the atom as an object with quantized energy levels and the electromagnetic field as a continuous wave. In the context of a nuclear magnetic resonance experiment, the Rabi frequency is the nutation frequency of a sample's net nuclear magnetization vector about a radio-frequency field. (Not ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Linear Polarization
In electrodynamics, linear polarization or plane polarization of electromagnetic radiation is a confinement of the electric field vector or magnetic field vector to a given plane along the direction of propagation. The term ''linear polarization'' (French: ''polarisation rectiligne'') was coined by Augustin-Jean Fresnel in 1822.A. Fresnel, "Mémoire sur la double réfraction que les rayons lumineux éprouvent en traversant les aiguilles de cristal de roche suivant les directions parallèles à l'axe", read 9 December 1822; printed in H. de Senarmont, E. Verdet, and L. Fresnel (eds.), ''Oeuvres complètes d'Augustin Fresnel'', vol. 1 (1866), pp.731–51; translated as "Memoir on the double refraction that light rays undergo in traversing the needles of quartz in the directions parallel to the axis", , 2021 (open access); §9. See '' polarization'' and ''plane of polarization'' for more information. The orientation of a linearly polarized electromagn ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Animated Rotating Frame
Animation is a method by which still figures are manipulated to appear as moving images. In traditional animation, images are drawn or painted by hand on transparent celluloid sheets to be photographed and exhibited on film. Today, most animations are made with computer-generated imagery (CGI). Computer animation can be very detailed 3D animation, while 2D computer animation (which may have the look of traditional animation) can be used for stylistic reasons, low bandwidth, or faster real-time renderings. Other common animation methods apply a stop motion technique to two- and three-dimensional objects like paper cutouts, puppets, or clay figures. A cartoon is an animated film, usually a short film, featuring an exaggerated visual style. The style takes inspiration from comic strips, often featuring anthropomorphic animals, superheroes, or the adventures of human protagonists. Especially with animals that form a natural predator/prey relationship (e.g. cats and mice, coyot ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
