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Electron Nuclear Double Resonance
Electron nuclear double resonance (ENDOR) is a magnetic resonance technique for elucidating the molecular and electronic structure of paramagnetic species.Kevan, L and Kispert, L. D. ''Electron Spin Double Resonance Spectroscopy'' Interscience: New York, 1976. The technique was first introduced to resolve interactions in electron paramagnetic resonance (EPR) spectra./Kurreck, H.; Kirste, B.; Lubitz, W. ''Electron Nuclear Double Resonance Spectroscopy of Radicals in Solution'' VCH Publishers: New York, 1988. It is currently practiced in a variety of modalities, mainly in the areas of biophysics and heterogeneous catalysis. CW experiment In the standard continuous wave (cwENDOR) experiment, a sample is placed in a magnetic field and irradiated sequentially with a microwave followed by radio frequency. The changes are then detected by monitoring variations in the polarization of the saturated electron paramagnetic resonance (EPR) transition./ Theory ENDOR is illustrated by a two s ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Electron Paramagnetic Resonance
Electron paramagnetic resonance (EPR) or electron spin resonance (ESR) spectroscopy is a method for studying materials that have unpaired electrons. The basic concepts of EPR are analogous to those of nuclear magnetic resonance (NMR), but the spins excited are those of the electrons instead of the atomic nuclei. EPR spectroscopy is particularly useful for studying metal complexes and organic radicals. EPR was first observed in Kazan State University by Soviet physicist Yevgeny Zavoisky in 1944, and was developed independently at the same time by Brebis Bleaney at the University of Oxford. Theory Origin of an EPR signal Every electron has a magnetic moment and spin quantum number s = \tfrac , with magnetic components m_\mathrm = + \tfrac or m_\mathrm = - \tfrac . In the presence of an external magnetic field with strength B_\mathrm , the electron's magnetic moment aligns itself either antiparallel ( m_\mathrm = - \tfrac ) or parallel ( m_\mathrm = + \tfrac ) to the fi ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Spin Echo
In magnetic resonance, a spin echo or Hahn echo is the refocusing of spin magnetisation by a pulse of resonant electromagnetic radiation. Modern nuclear magnetic resonance (NMR) and magnetic resonance imaging (MRI) make use of this effect. The NMR signal observed following an initial excitation pulse decays with time due to both spin relaxation and any ''inhomogeneous'' effects which cause spins in the sample to precess at different rates. The first of these, relaxation, leads to an irreversible loss of magnetisation. But the inhomogeneous dephasing can be removed by applying a 180° ''inversion'' pulse that inverts the magnetisation vectors. Examples of inhomogeneous effects include a magnetic field gradient and a distribution of chemical shifts. If the inversion pulse is applied after a period ''t'' of dephasing, the inhomogeneous evolution will rephase to form an echo at time 2''t''. In simple cases, the intensity of the echo relative to the initial signal is given by ''e– ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Pulsed EPR
Pulsed electron paramagnetic resonance (EPR) is an electron paramagnetic resonance technique that involves the alignment of the net magnetization vector of the electron spins in a constant magnetic field. This alignment is perturbed by applying a short oscillating field, usually a microwave pulse. One can then measure the emitted microwave signal which is created by the sample magnetization. Fourier transformation of the microwave signal yields an EPR spectrum in the frequency domain. With a vast variety of pulse sequences it is possible to gain extensive knowledge on structural and dynamical properties of paramagnetic compounds. Pulsed EPR techniques such as electron spin echo envelope modulation (ESEEM) or pulsed electron nuclear double resonance (ENDOR) can reveal the interactions of the electron spin with its surrounding nuclear spins. Scope Electron paramagnetic resonance (EPR) or electron spin resonance (ESR) is a spectroscopic technique widely used in biology, chemistry, ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Electron Paramagnetic Resonance
Electron paramagnetic resonance (EPR) or electron spin resonance (ESR) spectroscopy is a method for studying materials that have unpaired electrons. The basic concepts of EPR are analogous to those of nuclear magnetic resonance (NMR), but the spins excited are those of the electrons instead of the atomic nuclei. EPR spectroscopy is particularly useful for studying metal complexes and organic radicals. EPR was first observed in Kazan State University by Soviet physicist Yevgeny Zavoisky in 1944, and was developed independently at the same time by Brebis Bleaney at the University of Oxford. Theory Origin of an EPR signal Every electron has a magnetic moment and spin quantum number s = \tfrac , with magnetic components m_\mathrm = + \tfrac or m_\mathrm = - \tfrac . In the presence of an external magnetic field with strength B_\mathrm , the electron's magnetic moment aligns itself either antiparallel ( m_\mathrm = - \tfrac ) or parallel ( m_\mathrm = + \tfrac ) to the fi ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Magnetic Resonance Imaging
Magnetic resonance imaging (MRI) is a medical imaging technique used in radiology to form pictures of the anatomy and the physiological processes of the body. MRI scanners use strong magnetic fields, magnetic field gradients, and radio waves to generate images of the organs in the body. MRI does not involve X-rays or the use of ionizing radiation, which distinguishes it from CT and PET scans. MRI is a medical application of nuclear magnetic resonance (NMR) which can also be used for imaging in other NMR applications, such as NMR spectroscopy. MRI is widely used in hospitals and clinics for medical diagnosis, staging and follow-up of disease. Compared to CT, MRI provides better contrast in images of soft-tissues, e.g. in the brain or abdomen. However, it may be perceived as less comfortable by patients, due to the usually longer and louder measurements with the subject in a long, confining tube, though "Open" MRI designs mostly relieve this. Additionally, implants and ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Proc
Proc may refer to: * Proč, a village in eastern Slovakia * ''Proč?'', a 1987 Czech film * procfs or proc filesystem, a special file system (typically mounted to ) in Unix-like operating systems for accessing process information * Protein C (PROC) * Proc, a term in video game terminology * Procedures or process, in the programming language ALGOL 68 * People's Republic of China, the formal name of China China, officially the People's Republic of China (PRC), is a country in East Asia. It is the world's List of countries and dependencies by population, most populous country, with a Population of China, population exceeding 1.4 billion, slig ... * the official acronym for the Canadian House of Commons Standing Committee on Procedure and House Affairs {{disambiguation ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Sci
SCI may refer to: Companies * Service Corporation International, an American funeral service provider *Shipping Corporation of India *SCI Systems, merged into Sanmina Corporation, electronics manufacturing *SCi Games, a video game developer Organizations and sporting * Safari Club International * Schistosomiasis Control Initiative * Scientific Computing and Imaging Institute * Seamen's Church Institute of New York and New Jersey * Service Civil International, peace movement * Silverthorn Collegiate Institute, school in Toronto, Ontario, Canada * Sister Cities International * Society of Chemical Industry * Solar Cookers International * Sport Club Internacional, a football club in Brazil * Strategic Computing Initiative, US program to fund AI research * Sustainable Commodity Initiative * Systemics, Cybernetics and Informatics, conference later named WMSCI * Southern Careers Institute Science *Metcalf Center for Science and Engineering, Boston University, USA *Science Citation I ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Gyromagnetic Ratio
In physics, the gyromagnetic ratio (also sometimes known as the magnetogyric ratio in other disciplines) of a particle or system is the ratio of its magnetic moment to its angular momentum, and it is often denoted by the symbol , gamma. Its SI unit is the radian per second per tesla (rad⋅s−1⋅T−1) or, equivalently, the coulomb per kilogram (C⋅kg−1). The term "gyromagnetic ratio" is often used as a synonym for a ''different'' but closely related quantity, the -factor. The -factor only differs from the gyromagnetic ratio in being dimensionless. For a classical rotating body Consider a nonconductive charged body rotating about an axis of symmetry. According to the laws of classical physics, it has both a magnetic dipole moment due to the movement of charge and an angular momentum due to the movement of mass arising from its rotation. It can be shown that as long as its charge and mass density and flow are distributed identically and rotationally symmetric, ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Phys
Physics is the natural science that studies matter, its fundamental constituents, its motion and behavior through space and time, and the related entities of energy and force. "Physical science is that department of knowledge which relates to the order of nature, or, in other words, to the regular succession of events." Physics is one of the most fundamental scientific disciplines, with its main goal being to understand how the universe behaves. "Physics is one of the most fundamental of the sciences. Scientists of all disciplines use the ideas of physics, including chemists who study the structure of molecules, paleontologists who try to reconstruct how dinosaurs walked, and climatologists who study how human activities affect the atmosphere and oceans. Physics is also the foundation of all engineering and technology. No engineer could design a flat-screen TV, an interplanetary spacecraft, or even a better mousetrap without first understanding the basic laws of physics. ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
