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Closo
In chemistry the polyhedral skeletal electron pair theory (PSEPT) provides electron counting rules useful for predicting the structures of clusters such as borane and carborane clusters. The electron counting rules were originally formulated by Kenneth Wade, and were further developed by others including Michael Mingos; they are sometimes known as Wade's rules or the Wade–Mingos rules. The rules are based on a molecular orbital treatment of the bonding. These notes contained original material that served as the basis of the sections on the 4''n'', 5''n'', and 6''n'' rules. These rules have been extended and unified in the form of the Jemmis ''mno'' rules. Predicting structures of cluster compounds Different rules (4''n'', 5''n'', or 6''n'') are invoked depending on the number of electrons per vertex. The 4''n'' rules are reasonably accurate in predicting the structures of clusters having about 4 electrons per vertex, as is the case for many boranes and carboranes. For suc ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Boranes
Boranes is the name given to compounds with the formula BxHy and related anions. Many such boranes are known. Most common are those with 1 to 12 boron atoms. Although they have few practical applications, the boranes exhibit structures and bonding that differs strongly from the patterns seen in hydrocarbons. Hybrids of boranes and hydrocarbons, the carboranes are also well developed. History The development of the chemistry of boranes led to innovations in synthetic methods as well as structure and bonding. First, new synthetic techniques were required to handle diborane and many of its derivatives, which are both pyrophoric and volatile. Alfred Stock invented the glass vacuum line for this purpose. The structure of diborane was correctly predicted in 1943 many years after its discovery. The structures of the boron hydride clusters were determined beginning in 1948 with the characterization of decaborane. William Lipscomb was awarded the Nobel prize in Chemistry in 1976 for th ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Boranes
Boranes is the name given to compounds with the formula BxHy and related anions. Many such boranes are known. Most common are those with 1 to 12 boron atoms. Although they have few practical applications, the boranes exhibit structures and bonding that differs strongly from the patterns seen in hydrocarbons. Hybrids of boranes and hydrocarbons, the carboranes are also well developed. History The development of the chemistry of boranes led to innovations in synthetic methods as well as structure and bonding. First, new synthetic techniques were required to handle diborane and many of its derivatives, which are both pyrophoric and volatile. Alfred Stock invented the glass vacuum line for this purpose. The structure of diborane was correctly predicted in 1943 many years after its discovery. The structures of the boron hydride clusters were determined beginning in 1948 with the characterization of decaborane. William Lipscomb was awarded the Nobel prize in Chemistry in 1976 for th ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Carborane
Carboranes are electron-delocalized (non-classically bonded) clusters composed of boron, carbon and hydrogen atoms.Grimes, R. N., ''Carboranes 3rd Ed.'', Elsevier, Amsterdam and New York (2016), . Like many of the related boron hydrides, these clusters are polyhedra or fragments of polyhedra. Carboranes are one class of heteroboranes. In terms of scope, carboranes can have as few as 5 and as many as 14 atoms in the cage framework. The majority have two cage carbon atoms. The corresponding C-alkyl and B-alkyl analogues are also known in a few cases. Structure and bonding Carboranes and boranes adopt 3-dimensional cage (cluster) geometries in sharp contrast to typical organic compounds. Cages are compatible with sigma—delocalized bonding, whereas hydrocarbons are typically chains or rings. Like for other electron-delocalized polyhedral clusters, the electronic structure of these cluster compounds can be described by the Wade–Mingos rules. Like the related boron hydrides, th ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Edge-contracted Icosahedron
In geometry, an edge-contracted icosahedron is a polyhedron with 18 triangular faces, 27 edges, and 11 vertices. Construction It can be constructed from the regular icosahedron, with one edge contraction, removing one vertex, 3 edges, and 2 faces. This contraction distorts the circumscribed sphere original vertices. With all equilateral triangle faces, it has 2 sets of 3 coplanar equilateral triangles (each forming a half-hexagon), and thus is not a Johnson solid. If the sets of three coplanar triangles are considered a single face (called a triamond), it has 10 vertices, 22 edges, and 14 faces, 12 triangles and 2 triamonds . It may also be described as having a hybrid square-pentagonal antiprismatic core (an antiprismatic core with one square base and one pentagonal base); each base is then augmented with a pyramid. Related polytopes The dissected regular icosahedron is a variant topologically equivalent to the sphenocorona with the two sets of 3 coplanar faces as tr ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Triangular Bipyramid
In geometry, the triangular bipyramid (or dipyramid) is a type of hexahedron, being the first in the infinite set of face-transitive bipyramids. It is the dual of the triangular prism with 6 isosceles triangle faces. As the name suggests, it can be constructed by joining two tetrahedra along one face. Although all its faces are congruent and the solid is face-transitive, it is not a Platonic solid because some vertices adjoin three faces and others adjoin four. The bipyramid whose six faces are all equilateral triangles is one of the Johnson solids, (). As a Johnson solid with all faces equilateral triangles, it is also a deltahedron. Formulae The following formulae for the height (H), surface area (A) and volume (V) can be used if all faces are regular, with edge length L: :H = L\cdot \frac \approx L\cdot 1.632993162 :A = L^2 \cdot \frac \approx L^2\cdot 2.598076211 :V = L^3 \cdot \frac \approx L^3\cdot 0.235702260 Dual polyhedron The dual polyhedron of the ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
S4 Cluster
S4, S 4, Š-4, S.4 or S-4 may refer to: People * S4 (Dota player), Gustav Magnusson, Swedish ''Dota 2'' player * S4 (military), a logistics officer within military units Places * County Route S4 (California), a road in San Diego, California Science and mathematics Mathematics * S4 algebra, a variety of modal algebras, also called Interior algebra * Symmetric group S4 (S4), an abstract mathematical group * S4, a normal modal logic Chemistry * S4: Keep away from living quarters, a safety phrase in chemistry * Tetrasulfur (S4), an allotrope of sulfur Biology * Fourth heart sound, or S4, an abnormal heart sound often indicative of congestive heart failure or cor pulmonale * Fourth sacrum of the vertebral column in human anatomy * Sacral spinal nerve 4, a spinal nerve of the sacral segment Technology * S (programming language) version 4 * Hibernation a sleeping state in a computer * SG2 Shareable (Fire Control) Software Suite (S4) * Nikon Coolpix S4, a camera * Samsung Galaxy S4, a ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Transition Metal
In chemistry, a transition metal (or transition element) is a chemical element in the d-block of the periodic table (groups 3 to 12), though the elements of group 12 (and less often group 3) are sometimes excluded. They are the elements that can use d orbitals as valence orbitals to form chemical bonds. The lanthanide and actinide elements (the f-block) are called inner transition metals and are sometimes considered to be transition metals as well. Since they are metals, they are lustrous and have good electrical and thermal conductivity. Most (with the exception of group 11 and group 12) are hard and strong, and have high melting and boiling temperatures. They form compounds in any of two or more different oxidation states and bind to a variety of ligands to form coordination complexes that are often coloured. They form many useful alloys and are often employed as catalysts in elemental form or in compounds such as coordination complexes and oxides. Most are strongly param ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Valence Electrons
In chemistry and physics, a valence electron is an electron in the outer shell associated with an atom, and that can participate in the formation of a chemical bond if the outer shell is not closed. In a single covalent bond, a shared pair forms with both atoms in the bond each contributing one valence electron. The presence of valence electrons can determine the element's chemical properties, such as its valence—whether it may bond with other elements and, if so, how readily and with how many. In this way, a given element's reactivity is highly dependent upon its electronic configuration. For a main-group element, a valence electron can exist only in the outermost electron shell; for a transition metal, a valence electron can also be in an inner shell. An atom with a closed shell of valence electrons (corresponding to a noble gas configuration) tends to be chemically inert. Atoms with one or two valence electrons more than a closed shell are highly reactive due to the rela ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Augmentation (geometry)
In geometry, a Johnson solid is a strictly convex polyhedron each face of which is a regular polygon. There is no requirement that each face must be the same polygon, or that the same polygons join around each vertex. An example of a Johnson solid is the square-based pyramid with equilateral sides ( ); it has 1 square face and 4 triangular faces. Some authors require that the solid not be uniform (i.e., not Platonic solid, Archimedean solid, uniform prism, or uniform antiprism) before they refer to it as a “Johnson solid”. As in any strictly convex solid, at least three faces meet at every vertex, and the total of their angles is less than 360 degrees. Since a regular polygon has angles at least 60 degrees, it follows that at most five faces meet at any vertex. The pentagonal pyramid () is an example that has a degree-5 vertex. Although there is no obvious restriction that any given regular polygon cannot be a face of a Johnson solid, it turns out that the faces of Johns ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Icosahedron
In geometry, an icosahedron ( or ) is a polyhedron with 20 faces. The name comes and . The plural can be either "icosahedra" () or "icosahedrons". There are infinitely many non- similar shapes of icosahedra, some of them being more symmetrical than others. The best known is the (convex, non- stellated) regular icosahedron—one of the Platonic solids—whose faces are 20 equilateral triangles. Regular icosahedra There are two objects, one convex and one nonconvex, that can both be called regular icosahedra. Each has 30 edges and 20 equilateral triangle faces with five meeting at each of its twelve vertices. Both have icosahedral symmetry. The term "regular icosahedron" generally refers to the convex variety, while the nonconvex form is called a ''great icosahedron''. Convex regular icosahedron The convex regular icosahedron is usually referred to simply as the ''regular icosahedron'', one of the five regular Platonic solids, and is represented by its Schläfli symbol , con ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Gyroelongated Square Bipyramid
In geometry, the gyroelongated square bipyramid, heccaidecadeltahedron, or tetrakis square antiprism is one of the Johnson solids (). As the name suggests, it can be constructed by gyroelongating an octahedron (square bipyramid) by inserting a square antiprism between its congruent halves. It is one of the eight strictly-convex deltahedra. The dual of the gyroelongated square bipyramid is a square truncated trapezohedron with 10 faces: 8 pentagons and 2 square. See also * Gyroelongated bipyramid * Gyroelongated square pyramid In geometry, the gyroelongated square pyramid is one of the Johnson solids (). As its name suggests, it can be constructed by taking a square pyramid and "gyroelongating" it, which in this case involves joining a square antiprism to its base. ... External links * Johnson solids Deltahedra Pyramids and bipyramids {{Polyhedron-stub ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
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