In chemistry, a mixed oxide is a somewhat informal name for an oxide that contains cations of more than one

chemical element A chemical element is a species of atoms that have a given number of protons in their nuclei, including the pure substance consisting only of that species. Unlike chemical compounds, chemical elements cannot be broken down into simpler sub ...

or cations of a single element in several states of oxidation.Advanced Inorganic Chemistry,

F. A. Cotton Frank Albert Cotton FRS (April 9, 1930 – February 20, 2007) was an American chemist. He was the W.T. Doherty-Welch Foundation Chair and Distinguished Professor of Chemistry at Texas A&M University. He authored over 1600 scientific articles. C ...

, G. Wilkinson, Interscience, 2d Edition, 1966 The term is usually applied to solid ionic compounds that contain the oxide

anion An ion () is an atom or molecule with a net electrical charge. The charge of an electron is considered to be negative by convention and this charge is equal and opposite to the charge of a proton, which is considered to be positive by conve ...

and two or more element cations. Typical examples are

ilmenite Ilmenite is a titanium-iron oxide mineral with the idealized formula . It is a weakly magnetic black or steel-gray solid. Ilmenite is the most important ore of titanium and the main source of titanium dioxide, which is used in paints, printing ...

(), a mixed oxide of

iron Iron () is a chemical element with Symbol (chemistry), symbol Fe (from la, Wikt:ferrum, ferrum) and atomic number 26. It is a metal that belongs to the first transition series and group 8 element, group 8 of the periodic table. It is, Abundanc ...

() and

titanium Titanium is a chemical element with the Symbol (chemistry), symbol Ti and atomic number 22. Found in nature only as an oxide, it can be reduced to produce a lustrous transition metal with a silver color, low density, and high strength, resista ...

() cations,

perovskite Perovskite (pronunciation: ) is a calcium titanium oxide mineral composed of calcium titanate (chemical formula ). Its name is also applied to the class of compounds which have the same type of crystal structure as (XIIA2+VIB4+X2−3), known a ...

and

garnet Garnets () are a group of silicate minerals that have been used since the Bronze Age as gemstones and abrasives. All species of garnets possess similar physical properties and crystal forms, but differ in chemical composition. The different s ...

.The cations may be the same element in different ionization states: a notable example is

magnetite Magnetite is a mineral and one of the main iron ores, with the chemical formula Fe2+Fe3+2O4. It is one of the oxides of iron, and is ferrimagnetic; it is attracted to a magnet and can be magnetized to become a permanent magnet itself. With th ...

, which is also known as ferrosoferric oxide , contains the cations Fe(2+) ("ferrous" iron) and ("ferric" iron) in 1:2 ratio. Other notable examples include

red lead Red is the color at the long wavelength end of the visible spectrum of light, next to orange and opposite violet. It has a dominant wavelength of approximately 625–740 nanometres. It is a primary color in the RGB color model and a secondar ...

, the ferrites,Alex Goldman (1990), ''Modern ferrite technology'' and the

yttrium aluminum garnet Yttrium aluminium garnet (YAG, Y3 Al5 O12) is a synthetic crystalline material of the garnet group. It is a cubic yttrium aluminium oxide phase, with other examples being YAlO3 (YAP) in a hexagonal or an orthorhombic, perovskite-like form, and ...

,K. Byrappa, Masahiro Yoshimura (2001), ''Handbook of hydrothermal technology''. William Andrew. 870 pages. used in

laser A laser is a device that emits light through a process of optical amplification based on the stimulated emission of electromagnetic radiation. The word "laser" is an acronym for "light amplification by stimulated emission of radiation". The fi ...

s. The term is sometimes also applied to compounds of oxygen and two or more other elements, where some or all of the oxygen atoms are covalently bound into

oxyanion An oxyanion, or oxoanion, is an ion with the generic formula (where A represents a chemical element and O represents an oxygen atom). Oxyanions are formed by a large majority of the chemical elements. The formulae of simple oxyanions are determine ...

s. In sodium zincate , for example, the oxygens are bound to the

zinc Zinc is a chemical element with the symbol Zn and atomic number 30. Zinc is a slightly brittle metal at room temperature and has a shiny-greyish appearance when oxidation is removed. It is the first element in group 12 (IIB) of the periodi ...

atoms forming

zincate In chemistry the term zincate may refer to several substances containing the element zinc: * usually the anion ZnO22−, more properly called tetrahydroxozincate or salts thereof, such as sodium zincate . * the polymeric anion n(OH)3−and its ...

anions.D. Trinschek, M. Jansen (1996): ", ein neues Natriumzinkat". ''Zeitschrift für Naturforschung B'', volume 51, issue 5, pages 711-714. (On the other hand, strontium titanate , despite its name, contains cations and not the anion.) Sometimes the term is applied loosely to

solid solution A solid solution, a term popularly used for metals, is a homogenous mixture of two different kinds of atoms in solid state and have a single crystal structure. Many examples can be found in metallurgy, geology, and solid-state chemistry. The wor ...

s of metal oxides rather than chemical compounds, or to fine mixtures of two or more oxides. Mixed oxide minerals are plentiful in nature. Synthetic mixed oxides are components of many ceramics with remarkable properties and important advanced technological applications, such as strong

magnet A magnet is a material or object that produces a magnetic field. This magnetic field is invisible but is responsible for the most notable property of a magnet: a force that pulls on other ferromagnetic materials, such as iron, steel, nicke ...

s, fine

optics Optics is the branch of physics that studies the behaviour and properties of light, including its interactions with matter and the construction of instruments that use or detect it. Optics usually describes the behaviour of visible, ultrav ...

semiconductor A semiconductor is a material which has an electrical conductivity value falling between that of a conductor, such as copper, and an insulator, such as glass. Its resistivity falls as its temperature rises; metals behave in the opposite way. ...

piezoelectric Piezoelectricity (, ) is the electric charge that accumulates in certain solid materials—such as crystals, certain ceramics, and biological matter such as bone, DNA, and various proteins—in response to applied mechanical stress. The word '' ...

s, superconductors,

catalyst Catalysis () is the process of increasing the rate of a chemical reaction by adding a substance known as a catalyst (). Catalysts are not consumed in the reaction and remain unchanged after it. If the reaction is rapid and the catalyst recyc ...

refractories In materials science, a refractory material or refractory is a material that is resistant to Thermal decomposition, decomposition by heat, pressure, or chemical attack, and retains strength and form at high temperatures. Refractories are polycr ...

gas mantle A Coleman white gas lantern mantle glowing at full brightness An incandescent gas mantle, gas mantle or Welsbach mantle is a device for generating incandescent bright white light when heated by a flame. The name refers to its original heat sou ...

s, nuclear fuels, and more. Piezoelectric mixed oxides, in particular, are extensively used in

pressure Pressure (symbol: ''p'' or ''P'') is the force applied perpendicular to the surface of an object per unit area over which that force is distributed. Gauge pressure (also spelled ''gage'' pressure)The preferred spelling varies by country and e ...

and strain gauges,

microphone A microphone, colloquially called a mic or mike (), is a transducer that converts sound into an electrical signal. Microphones are used in many applications such as telephones, hearing aids, public address systems for concert halls and publ ...

ultrasound Ultrasound is sound waves with frequencies higher than the upper audible limit of human hearing. Ultrasound is not different from "normal" (audible) sound in its physical properties, except that humans cannot hear it. This limit varies ...

transducer A transducer is a device that converts energy from one form to another. Usually a transducer converts a signal in one form of energy to a signal in another. Transducers are often employed at the boundaries of automation, measurement, and cont ...

micromanipulator A micromanipulator is a device which is used to physically interact with a sample under a microscope, where a level of precision of movement is necessary that cannot be achieved by the unaided human hand. It may typically consist of an input joysti ...

s, delay lines, etc..

References

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See also

References