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F. Albert Cotton
Frank Albert Cotton FRS (April 9, 1930 – February 20, 2007) was an American chemist. He was the W.T. Doherty-Welch Foundation Chair and Distinguished Professor of Chemistry at Texas A&M University. He authored over 1600 scientific articles. Cotton was recognized for his research on the chemistry of the transition metals. Education Frank Albert Cotton (known as "Al" Cotton, or "F Albert" on publications) was born on April 9, 1930, in Philadelphia, Pennsylvania. He attended local public schools before Drexel University and then Temple University. After earning his BA degree from Temple in 1951, Cotton pursued a Ph.D. thesis under the guidance of Sir Geoffrey Wilkinson at Harvard University where he worked on metallocenes. He received his Ph.D in 1955. Independent career Following his graduation from Harvard, Cotton began teaching at MIT. In 1961, at thirty-one years of age, he became the youngest person to have received a full professorship at MIT. His work emphasized both ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Philadelphia, PA
Philadelphia, often called Philly, is the largest city in the Commonwealth of Pennsylvania, the sixth-largest city in the U.S., the second-largest city in both the Northeast megalopolis and Mid-Atlantic regions after New York City. Since 1854, the city has been coextensive with Philadelphia County, the most populous county in Pennsylvania and the urban core of the Delaware Valley, the nation's seventh-largest and one of world's largest metropolitan regions, with 6.245 million residents . The city's population at the 2020 census was 1,603,797, and over 56 million people live within of Philadelphia. Philadelphia was founded in 1682 by William Penn, an English Quaker. The city served as capital of the Pennsylvania Colony during the British colonial era and went on to play a historic and vital role as the central meeting place for the nation's founding fathers whose plans and actions in Philadelphia ultimately inspired the American Revolution and the nation's inde ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Priestley Medal
The Priestley Medal is the highest honor conferred by the American Chemical Society (ACS) and is awarded for distinguished service in the field of chemistry. Established in 1922, the award is named after Joseph Priestley, the discoverer of oxygen who immigrated to the United States of America in 1794. The ACS formed in 1876, spearheaded by a group of chemists who had met two years previously in Priestley's home. The Priestley Medal is commonly awarded to scientists who are advanced in their fields, as it is intended to commemorate lifetime achievement. When the ACS started presenting the Priestley Medal in 1923, they intended to award it every three years. This continued until 1944, when it became an annual award. Recipients ;1920s * 1923 Ira Remsen * 1926 Edgar Fahs Smith * 1929 Francis P. Garvan ;1930s * 1932 Charles L. Parsons * 1935 William A. Noyes * 1938 Marston T. Bogert ;1940s * 1941 Thomas Midgley, Jr. * 1944 James Bryant Conant * 1945 Ian Heilbron * 1946 Roger ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Potassium Octachlorodirhenate
Potassium octachlorodirhenate(III) is an inorganic compound with the formula K2 Re2 Cl8. This dark blue salt is well known as an early example of a compound featuring quadruple bond between its metal centers. Although the compound has no practical value, its characterization was significant in opening a new field of research into complexes with quadruple bonds. Synthesis and reactions Soviet chemists first reported K2 e2Cl8in 1954, but it was not until 1964 that Cotton and Harris characterized the compound as featuring a short Re–Re bond, the first of its kind discovered. The results of this classic study subsequently led to new work into other metals capable of forming metal–metal bonds, such as chromium, molybdenum, tungsten, and technetium. A high-yield synthesis of the tetrabutylammonium salt involves treating the perrhenate salt with benzoyl chloride followed by HCl: :2 ''n''-C4H9)4N">n-Butyl">''n''-C4H9)4N ReO4 + 8 C6H5COCl → ''n''-C4H9)4Nsub>2 e2Cl8+ ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Quadruple Bond
A quadruple bond is a type of chemical bond between two atoms involving eight electrons. This bond is an extension of the more familiar types double bonds and triple bonds. Stable quadruple bonds are most common among the transition metals in the middle of the , such as rhenium, tungsten, technetium, molybdenum and chromium. Typically the ligands that support quadruple bonds are π-donors, not π-acceptors. History Chromium(II) acetate, Cr2(''μ''-O2CCH3)4(H2O)2, was the first chemical compound containing a quadruple bond to be synthesized. It was described in 1844 by E. Peligot, although its distinctive bonding was not recognized for more than a century. The first crystallographic study of a compound with a quadruple bond was provided by Soviet chemists for salts of . The very short Re–Re distance was noted. This short distance (and the salt's diamagnetism) indicated Re–Re bonding. These researchers however misformulated the anion as a derivative of Re(II), i.e., . Soon ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Rhenium
Rhenium is a chemical element with the symbol Re and atomic number 75. It is a silvery-gray, heavy, third-row transition metal in group 7 of the periodic table. With an estimated average concentration of 1 part per billion (ppb), rhenium is one of the rarest elements in the Earth's crust. Rhenium has the third-highest melting point and highest boiling point of any stable element at 5869 K. Rhenium resembles manganese and technetium chemically and is mainly obtained as a by-product of the extraction and refinement of molybdenum and copper ores. Rhenium shows in its compounds a wide variety of oxidation states ranging from −1 to +7. Discovered by Walter Noddack, Ida Tacke and Otto Berg in 1925, rhenium was the last stable element to be discovered. It was named after the river Rhine in Europe, from which the earliest samples had been obtained and worked commercially. Nickel-based superalloys of rhenium are used in combustion chambers, turbine blades, and exhaust nozzles ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Metallocene
A metallocene is a compound typically consisting of two cyclopentadienyl anions (, abbreviated Cp) bound to a metallic element, metal center (M) in the oxidation state II, with the resulting general formula Closely related to the metallocenes are the metallocene derivatives, e.g. titanocene dichloride, vanadocene dichloride. Certain metallocenes and their derivatives exhibit catalysis, catalytic properties, although metallocenes are rarely used industrially. Cationic group 4 metallocene derivatives related to [Cp2ZrCH3]+ catalyze Ziegler–Natta catalyst, olefin polymerization. Some metallocenes consist of metal plus two cyclooctatetraenide anions (, abbreviated cot2−), namely the lanthanocenes and the actinocenes (uranocene and others). Metallocenes are a subset of a broader class of compounds called sandwich compounds. In the structure shown at right, the two pentagons are the cyclopentadienyl anions with circles inside them indicating they are aromaticity, aromatically st ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Sir Geoffrey Wilkinson
Sir Geoffrey Wilkinson FRS (14 July 1921 – 26 September 1996) was a Nobel laureate English chemist who pioneered inorganic chemistry and homogeneous transition metal catalysis. Education and early life Wilkinson was born at Springside, Todmorden, in the West Riding of Yorkshire. His father, Henry Wilkinson, was a master house painter and decorator; his mother, Ruth, worked in a local cotton mill. One of his uncles, an organist and choirmaster, had married into a family that owned a small chemical company making Epsom and Glauber's salts for the pharmaceutical industry; this is where he first developed an interest in chemistry. He was educated at the local council primary school and, after winning a County Scholarship in 1932, went to Todmorden Grammar School. His physics teacher there, Luke Sutcliffe, had also taught Sir John Cockcroft, who received a Nobel Prize for "splitting the atom". In 1939 he obtained a Royal Scholarship for study at Imperial College London, from wh ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Temple University
Temple University (Temple or TU) is a public state-related research university in Philadelphia, Pennsylvania. It was founded in 1884 by the Baptist minister Russell Conwell and his congregation Grace Baptist Church of Philadelphia then called Baptist Temple. On May 12, 1888, it was renamed the Temple College of Philadelphia. By 1907, the institution revised its institutional status and was incorporated as a research university. As of 2020, about 37,289 undergraduate, graduate and professional students were enrolled at the university. Temple is among the world's largest providers of professional education (law, medicine, podiatry, pharmacy, dentistry, engineering and architecture), preparing the largest body of professional practitioners in Pennsylvania. History Temple University was founded in 1884 by Grace Baptist Church of Philadelphia and its pastor Russell Conwell, a Yale-educated Boston lawyer, orator, and ordained Baptist minister, who had served in the Union Army d ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Drexel University
Drexel University is a private research university with its main campus in Philadelphia, Pennsylvania. Drexel's undergraduate school was founded in 1891 by Anthony J. Drexel, a financier and philanthropist. Founded as Drexel Institute of Art, Science and Industry, it was renamed Drexel Institute of Technology in 1936, before assuming its current name in 1970. , more than 24,000 students were enrolled in over 70 undergraduate programs and more than 100 master's, doctoral, and professional programs at the university. Drexel's cooperative education program (co-op) is a prominent aspect of the school's degree programs, offering students the opportunity to gain up to 18 months of paid, full-time work experience in a field relevant to their undergraduate major or graduate degree program prior to graduation. History Drexel University was founded in 1891 as the Drexel Institute of Art, Science and Industry, by Philadelphia financier and philanthropist Anthony J. Drexel. The orig ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Philadelphia, Pennsylvania
Philadelphia, often called Philly, is the largest city in the Commonwealth of Pennsylvania, the sixth-largest city in the U.S., the second-largest city in both the Northeast megalopolis and Mid-Atlantic regions after New York City. Since 1854, the city has been coextensive with Philadelphia County, the most populous county in Pennsylvania and the urban core of the Delaware Valley, the nation's seventh-largest and one of world's largest metropolitan regions, with 6.245 million residents . The city's population at the 2020 census was 1,603,797, and over 56 million people live within of Philadelphia. Philadelphia was founded in 1682 by William Penn, an English Quaker. The city served as capital of the Pennsylvania Colony during the British colonial era and went on to play a historic and vital role as the central meeting place for the nation's founding fathers whose plans and actions in Philadelphia ultimately inspired the American Revolution and the nation's inde ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Transition Metal
In chemistry, a transition metal (or transition element) is a chemical element in the d-block of the periodic table (groups 3 to 12), though the elements of group 12 (and less often group 3) are sometimes excluded. They are the elements that can use d orbitals as valence orbitals to form chemical bonds. The lanthanide and actinide elements (the f-block) are called inner transition metals and are sometimes considered to be transition metals as well. Since they are metals, they are lustrous and have good electrical and thermal conductivity. Most (with the exception of group 11 and group 12) are hard and strong, and have high melting and boiling temperatures. They form compounds in any of two or more different oxidation states and bind to a variety of ligands to form coordination complexes that are often coloured. They form many useful alloys and are often employed as catalysts in elemental form or in compounds such as coordination complexes and oxides. Most are strongly param ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Biographical Memoirs Of Fellows Of The Royal Society
The ''Biographical Memoirs of Fellows of the Royal Society'' is an academic journal on the history of science published annually by the Royal Society. It publishes obituaries of Fellows of the Royal Society. It was established in 1932 as ''Obituary Notices of Fellows of the Royal Society'' and obtained its current title in 1955, with volume numbering restarting at 1. Prior to 1932, obituaries were published in the ''Proceedings of the Royal Society''. The memoirs are a significant historical record and most include a full bibliography of works by the subjects. The memoirs are often written by a scientist of the next generation, often one of the subject's own former students, or a close colleague. In many cases the author is also a Fellow. Notable biographies published in this journal include Albert Einstein, Alan Turing, Bertrand Russell, Claude Shannon, Clement Attlee, Ernst Mayr, and Erwin Schrödinger. Each year around 40 to 50 memoirs of deceased Fellows of the Royal Soci ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
2Re2Cl8.jpg "Click for more on -> Potassium Octachlorodirhenate")
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