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Ethanol fuel is
ethyl alcohol Ethanol (abbr. EtOH; also called ethyl alcohol, grain alcohol, drinking alcohol, or simply alcohol) is an organic compound. It is an alcohol with the chemical formula . Its formula can be also written as or (an ethyl group linked to a hyd ...
, the same type of alcohol found in
alcoholic beverages An alcoholic beverage (also called an alcoholic drink, adult beverage, or a drink) is a drink that contains ethanol, a type of alcohol that acts as a drug and is produced by fermentation of grains, fruits, or other sources of sugar. The cons ...
, used as fuel. It is most often used as a
motor fuel An engine or motor is a machine designed to convert one or more forms of energy into mechanical energy. Available energy sources include potential energy (e.g. energy of the Earth's gravitational field as exploited in hydroelectric power g ...
, mainly as a biofuel additive for
gasoline Gasoline (; ) or petrol (; ) (see ) is a transparent, petroleum-derived flammable liquid that is used primarily as a fuel in most spark-ignited internal combustion engines (also known as petrol engines). It consists mostly of organi ...
. The first production car running entirely on ethanol was the
Fiat 147 The Fiat 147 was a three-door hatchback subcompact car produced by Fiat in the Brazilian state of Minas Gerais from autumn 1976 until 1987, when it was replaced by the Fiat Uno. It was the Brazilian variant of the Fiat 127. Some were also built b ...
, introduced in 1978 in Brazil by Fiat. Ethanol is commonly made from biomass such as corn or sugarcane. World ethanol production for transport fuel tripled between 2000 and 2007 from to more than . From 2007 to 2008, the share of ethanol in global gasoline type fuel use increased from 3.7% to 5.4%. In 2011 worldwide ethanol fuel production reached with the United States of America and Brazil being the top producers, accounting for 62.2% and 25% of global production, respectively. US ethanol production reached in May 2017. Ethanol fuel has a " gasoline gallon equivalency" (GGE) value of 1.5, i.e. to replace the energy of 1 volume of gasoline, 1.5 times the volume of ethanol is needed. Ethanol-blended fuel is widely used in
Brazil Brazil ( pt, Brasil; ), officially the Federative Republic of Brazil (Portuguese: ), is the largest country in both South America and Latin America. At and with over 217 million people, Brazil is the world's fifth-largest country by area ...
, the
United States The United States of America (U.S.A. or USA), commonly known as the United States (U.S. or US) or America, is a country primarily located in North America. It consists of 50 states, a federal district, five major unincorporated territori ...
, and Europe (see also Ethanol fuel by country). Most cars on the road today in the U.S. can run on blends of up to 15% ethanol, and ethanol represented 10% of the U.S. gasoline fuel supply derived from domestic sources in 2011. Some
flexible-fuel vehicle A flexible-fuel vehicle (FFV) or dual-fuel vehicle (colloquially called a flex-fuel vehicle) is an alternative fuel vehicle with an internal combustion engine designed to run on more than one fuel, usually gasoline blended with either ethanol fu ...
s are able to use up to 100% ethanol. Since 1976 the Brazilian government has made it mandatory to blend ethanol with gasoline, and since 2007 the legal blend is around 25% ethanol and 75% gasoline (E25). By December 2011 Brazil had a fleet of 14.8 million flex-fuel automobiles and light trucks pp. 62–63. ''Carta de ANFAVEA 308'' pp. 4. and 1.5 million flex-fuel
motorcycle A motorcycle (motorbike, bike, or trike (if three-wheeled)) is a two or three-wheeled motor vehicle steered by a handlebar. Motorcycle design varies greatly to suit a range of different purposes: long-distance travel, commuting, cruising ...
s that regularly use neat ethanol fuel (known as
E100 E100 or E-100 may refer to: Electronics * Casio Cassiopeia E-100, a pocket of knife PC * iriver E100, a portable media player Vehicles Automobiles * Baojun E100, a Chinese electric microcar * JMEV E100, a Chinese electric city car * Toyota Co ...
). Bioethanol is a form of renewable energy that can be produced from agricultural feedstocks. It can be made from very common crops such as hemp, sugarcane,
potato The potato is a starchy food, a tuber of the plant ''Solanum tuberosum'' and is a root vegetable native to the Americas. The plant is a perennial in the nightshade family Solanaceae. Wild potato species can be found from the southern Unit ...
,
cassava ''Manihot esculenta'', commonly called cassava (), manioc, or yuca (among numerous regional names), is a woody shrub of the spurge family, Euphorbiaceae, native to South America. Although a perennial plant, cassava is extensively cultivated ...
and corn. There has been considerable debate about how useful bioethanol is in replacing gasoline. Concerns about its production and use relate to increased food prices due to the large amount of arable land required for crops, as well as the energy and pollution balance of the whole cycle of ethanol production, especially from corn.


Chemistry

During
ethanol fermentation Ethanol fermentation, also called alcoholic fermentation, is a biological process which converts sugars such as glucose, fructose, and sucrose into cellular energy, producing ethanol and carbon dioxide as by-products. Because yeasts perform this ...
,
glucose Glucose is a simple sugar with the molecular formula . Glucose is overall the most abundant monosaccharide, a subcategory of carbohydrates. Glucose is mainly made by plants and most algae during photosynthesis from water and carbon dioxide, u ...
and other sugars in the corn (or sugarcane or other crops) are converted into ethanol and
carbon dioxide Carbon dioxide ( chemical formula ) is a chemical compound made up of molecules that each have one carbon atom covalently double bonded to two oxygen atoms. It is found in the gas state at room temperature. In the air, carbon dioxide is trans ...
. :C6H12O6 → 2 C2H5OH+ 2 CO2 + heat Ethanol fermentation is not 100% selective with side products such as acetic acid and glycols. They are mostly removed during ethanol purification. Fermentation takes place in an aqueous solution. The resulting solution has an ethanol content of around 15%. Ethanol is subsequently isolated and purified by a combination of adsorption and distillation. During combustion, ethanol reacts with
oxygen Oxygen is the chemical element with the symbol O and atomic number 8. It is a member of the chalcogen group in the periodic table, a highly reactive nonmetal, and an oxidizing agent that readily forms oxides with most elements as ...
to produce carbon dioxide, water, and heat: :C2H5OH + 3 O2 → 2 CO2 + 3 H2O + heat Starch and
cellulose Cellulose is an organic compound with the formula , a polysaccharide consisting of a linear chain of several hundred to many thousands of β(1→4) linked D-glucose units. Cellulose is an important structural component of the primary cell w ...
molecules are strings of glucose molecules. It is also possible to generate ethanol out of cellulosic materials. That, however, requires a pretreatment that splits the cellulose into glucose molecules and other sugars that subsequently can be fermented. The resulting product is called
cellulosic ethanol Cellulosic ethanol is ethanol (ethyl alcohol) produced from cellulose (the stringy fiber of a plant) rather than from the plant's seeds or fruit. It can be produced from grasses, wood, algae, or other plants. It is generally discussed for use as a ...
, indicating its source. Ethanol is also produced industrially from ethylene by
hydration Hydration may refer to: * Hydrate, a substance that contains water * Hydration enthalpy, energy released through hydrating a substance * Hydration reaction, a chemical addition reaction where a hydroxyl group and proton are added to a compound * ...
of the
double bond In chemistry, a double bond is a covalent bond between two atoms involving four bonding electrons as opposed to two in a single bond. Double bonds occur most commonly between two carbon atoms, for example in alkenes. Many double bonds exist betwee ...
in the presence of a catalyst and high temperature. :C2H4 + H2O → C2H5OH Most ethanol is produced by fermentation.


Sources

About 5% of the ethanol produced in the world in 2003 was actually a petroleum product. It is made by the catalytic hydration of ethylene with sulfuric acid as the
catalyst Catalysis () is the process of increasing the rate of a chemical reaction by adding a substance known as a catalyst (). Catalysts are not consumed in the reaction and remain unchanged after it. If the reaction is rapid and the catalyst recyc ...
. It can also be obtained via ethylene or acetylene, from
calcium carbide Calcium carbide, also known as calcium acetylide, is a chemical compound with the chemical formula of Ca C2. Its main use industrially is in the production of acetylene and calcium cyanamide. The pure material is colorless, while pieces of te ...
,
coal Coal is a combustible black or brownish-black sedimentary rock, formed as rock strata called coal seams. Coal is mostly carbon with variable amounts of other elements, chiefly hydrogen, sulfur, oxygen, and nitrogen. Coal is formed when ...
, oil gas, and other sources. of petroleum-derived ethanol are produced annually. The principal suppliers are plants in the United States, Europe, and South Africa. Petroleum derived ethanol (synthetic ethanol) is chemically identical to bio-ethanol and can be differentiated only by radiocarbon dating.
Bio-ethanol Ethanol (abbr. EtOH; also called ethyl alcohol, grain alcohol, drinking alcohol, or simply alcohol) is an organic compound. It is an Alcohol (chemistry), alcohol with the chemical formula . Its formula can be also written as or (an ethyl ...
is usually obtained from the conversion of carbon-based feedstock. Agricultural feedstocks are considered renewable because they get energy from the sun using photosynthesis, provided that all minerals required for growth (such as nitrogen and phosphorus) are returned to the land. Ethanol can be produced from a variety of feedstocks such as
sugar cane Sugarcane or sugar cane is a species of (often hybrid) tall, perennial grass (in the genus '' Saccharum'', tribe Andropogoneae) that is used for sugar production. The plants are 2–6 m (6–20 ft) tall with stout, jointed, fibrous stalk ...
,
bagasse Bagasse ( ) is the dry pulpy fibrous material that remains after crushing sugarcane or sorghum stalks to extract their juice. It is used as a biofuel for the production of heat, energy, and electricity, and in the manufacture of pulp and building ...
,
miscanthus ''Miscanthus'', or silvergrass, is a genus of African, Eurasian, and Pacific Island plants in the grass family, Poaceae. ; Species * '' Miscanthus changii'' Y.N.Lee – Korea * '' Miscanthus depauperatus'' Merr. – the Philippines * '' Miscant ...
, sugar beet, sorghum, grain,
switchgrass ''Panicum virgatum'', commonly known as switchgrass, is a perennial warm season bunchgrass native to North America, where it occurs naturally from 55°N latitude in Canada southwards into the United States and Mexico. Switchgrass is one of the ...
,
barley Barley (''Hordeum vulgare''), a member of the grass family, is a major cereal grain grown in temperate climates globally. It was one of the first cultivated grains, particularly in Eurasia as early as 10,000 years ago. Globally 70% of barley p ...
, hemp,
kenaf Kenaf tymology: Persian ''Hibiscus cannabinus'', is a plant in the family Malvaceae also called Deccan hemp and Java jute. ''Hibiscus cannabinus'' is in the genus '' Hibiscus'' and is native to Africa, though its exact origin is unknown. The name ...
,
potato The potato is a starchy food, a tuber of the plant ''Solanum tuberosum'' and is a root vegetable native to the Americas. The plant is a perennial in the nightshade family Solanaceae. Wild potato species can be found from the southern Unit ...
es, sweet potatoes,
cassava ''Manihot esculenta'', commonly called cassava (), manioc, or yuca (among numerous regional names), is a woody shrub of the spurge family, Euphorbiaceae, native to South America. Although a perennial plant, cassava is extensively cultivated ...
, sunflower,
fruit In botany, a fruit is the seed-bearing structure in flowering plants that is formed from the ovary after flowering. Fruits are the means by which flowering plants (also known as angiosperms) disseminate their seeds. Edible fruits in particu ...
, molasses, corn, stover, grain,
wheat Wheat is a grass widely cultivated for its seed, a cereal grain that is a worldwide staple food. The many species of wheat together make up the genus ''Triticum'' ; the most widely grown is common wheat (''T. aestivum''). The archaeologi ...
, straw,
cotton Cotton is a soft, fluffy staple fiber that grows in a boll, or protective case, around the seeds of the cotton plants of the genus '' Gossypium'' in the mallow family Malvaceae. The fiber is almost pure cellulose, and can contain minor pe ...
, other biomass, as well as many types of cellulose waste and harvesting, whichever has the best
well-to-wheel Life cycle assessment or LCA (also known as life cycle analysis) is a methodology for assessing environmental impacts associated with all the stages of the life cycle of a commercial product, process, or service. For instance, in the case of ...
assessment. In 2008 an alternative process to produce bio-ethanol from algae was announced by the company
Algenol Algenol, founded in 2009, headquartered in Fort Myers, Florida, Algenol is an industrial biotechnology company that is commercializing patented algae technology for production of ethanol and other fuels. The technology enables the production of ...
. Rather than grow algae and then harvest and ferment it, the algae grow in sunlight and produce ethanol directly, which is removed without killing the algae. It is claimed the process can produce per year compared with for corn production. In 2015 the project was abandoned. Currently, the first generation processes for the production of ethanol from corn use only a small part of the corn plant: the corn kernels are taken from the corn plant and only the starch, which represents about 50% of the dry kernel mass, is transformed into ethanol. Two types of second generation processes are under development. The first type uses
enzyme Enzymes () are proteins that act as biological catalysts by accelerating chemical reactions. The molecules upon which enzymes may act are called substrates, and the enzyme converts the substrates into different molecules known as products ...
s and
yeast Yeasts are eukaryotic, single-celled microorganisms classified as members of the fungus kingdom. The first yeast originated hundreds of millions of years ago, and at least 1,500 species are currently recognized. They are estimated to constit ...
fermentation to convert the plant cellulose into ethanol while the second type uses
pyrolysis The pyrolysis (or devolatilization) process is the thermal decomposition of materials at elevated temperatures, often in an inert atmosphere. It involves a change of chemical composition. The word is coined from the Greek-derived elements ''py ...
to convert the whole plant to either a liquid
bio-oil Pyrolysis oil, sometimes also known as bio-crude or bio-oil, is a synthetic fuel under investigation as substitute for petroleum. It is obtained by heating dried biomass without oxygen in a reactor at a temperature of about with subsequent cool ...
or a syngas. Second generation processes can also be used with plants such as grasses, wood or agricultural waste material such as straw.


Production

Although there are various ways ethanol fuel can be produced, the most common way is via fermentation. The basic steps for large-scale production of ethanol are: microbial (
yeast Yeasts are eukaryotic, single-celled microorganisms classified as members of the fungus kingdom. The first yeast originated hundreds of millions of years ago, and at least 1,500 species are currently recognized. They are estimated to constit ...
) fermentation of sugars,
distillation Distillation, or classical distillation, is the process of separating the components or substances from a liquid mixture by using selective boiling and condensation, usually inside an apparatus known as a still. Dry distillation is the heat ...
,
dehydration In physiology, dehydration is a lack of total body water, with an accompanying disruption of metabolic processes. It occurs when free water loss exceeds free water intake, usually due to exercise, disease, or high environmental temperature. Mil ...
(requirements vary, see Ethanol fuel mixtures, below), and denaturing (optional). Prior to fermentation, some crops require
saccharification In chemistry, saccharification is a term for denoting any chemical change wherein a monosaccharide molecule remains intact after becoming unbound from another saccharide. For example, when a carbohydrate is broken into its component sugar molecul ...
or
hydrolysis Hydrolysis (; ) is any chemical reaction in which a molecule of water breaks one or more chemical bonds. The term is used broadly for substitution, elimination, and solvation reactions in which water is the nucleophile. Biological hydrolys ...
of carbohydrates such as cellulose and starch into sugars. Saccharification of cellulose is called
cellulolysis Cellulose is an organic compound with the formula , a polysaccharide consisting of a linear chain of several hundred to many thousands of β(1→4) linked D-glucose units. Cellulose is an important structural component of the primary cell wall ...
(see
cellulosic ethanol Cellulosic ethanol is ethanol (ethyl alcohol) produced from cellulose (the stringy fiber of a plant) rather than from the plant's seeds or fruit. It can be produced from grasses, wood, algae, or other plants. It is generally discussed for use as a ...
). Enzymes are used to convert starch into sugar.


Fermentation

Ethanol is produced by
microbial fermentation Fermentation is a metabolic process that produces chemical changes in organic substrates through the action of enzymes. In biochemistry, it is narrowly defined as the extraction of energy from carbohydrates in the absence of oxygen. In food p ...
of the sugar. Microbial fermentation currently only works directly with sugars. Two major components of plants, starch and cellulose, are both made of sugars—and can, in principle, be converted to sugars for fermentation. Currently, only the sugar (e.g., sugar cane) and starch (e.g., corn) portions can be economically converted. There is interest in
cellulosic ethanol Cellulosic ethanol is ethanol (ethyl alcohol) produced from cellulose (the stringy fiber of a plant) rather than from the plant's seeds or fruit. It can be produced from grasses, wood, algae, or other plants. It is generally discussed for use as a ...
obtained from breaking down plant cellulose to sugars and converting the sugars to ethanol. However, cellulosic ethanol is currently uneconomical and not practiced commercially. According to a 2006 International Energy Agency report, cellulosic ethanol could be important in the future.


Distillation

For the ethanol to be usable as a fuel, the yeast solids and the majority of the water must be removed. After fermentation, the mash is heated so that the ethanol evaporates. This process, known as
distillation Distillation, or classical distillation, is the process of separating the components or substances from a liquid mixture by using selective boiling and condensation, usually inside an apparatus known as a still. Dry distillation is the heat ...
, separates the ethanol, but its purity is limited to 95–96% due to the formation of a low-boiling water-ethanol
azeotrope An azeotrope () or a constant heating point mixture is a mixture of two or more liquids whose proportions cannot be altered or changed by simple distillation.Moore, Walter J. ''Physical Chemistry'', 3rd e Prentice-Hall 1962, pp. 140–142 This ...
with maximum (95.6% m/m (96.5% v/v) ethanol and 4.4% m/m (3.5% v/v) water). This mixture is called hydrous ethanol and can be used as a fuel alone, but unlike anhydrous ethanol, hydrous ethanol is not miscible in all ratios with gasoline, so the water fraction is typically removed in further treatment to burn in combination with gasoline in gasoline engines.


Dehydration

There are three dehydration processes to remove the water from an
azeotropic An azeotrope () or a constant heating point mixture is a mixture of two or more liquids whose proportions cannot be altered or changed by simple distillation.Moore, Walter J. ''Physical Chemistry'', 3rd e Prentice-Hall 1962, pp. 140–142 This ...
ethanol/water mixture. The first process, used in many early fuel ethanol plants, is called
azeotropic distillation In chemistry, azeotropic distillation is any of a range of techniques used to break an azeotrope in distillation. In chemical engineering, ''azeotropic distillation'' usually refers to the specific technique of adding another component to gener ...
and consists of adding
benzene Benzene is an organic chemical compound with the molecular formula C6H6. The benzene molecule is composed of six carbon atoms joined in a planar ring with one hydrogen atom attached to each. Because it contains only carbon and hydrogen atoms ...
or cyclohexane to the mixture. When these components are added to the mixture, it forms a heterogeneous azeotropic mixture in vapor–liquid-liquid equilibrium, which when distilled produces anhydrous ethanol in the column bottom, and a vapor mixture of water, ethanol, and cyclohexane/benzene. When condensed, this becomes a two-phase liquid mixture. The heavier phase, poor in the entrainer (benzene or cyclohexane), is stripped of the entrainer and recycled to the feed—while the lighter phase, with condensate from the stripping, is recycled to the second column. Another early method, called
extractive distillation Extractive distillation is defined as distillation in the presence of a miscible, high-boiling, relatively non-volatile component, the solvent, that forms no azeotrope with the other components in the mixture. The method is used for mixtures h ...
, consists of adding a ternary component that increases ethanol's relative volatility. When the ternary mixture is distilled, it produces anhydrous ethanol on the top stream of the column. With increasing attention being paid to saving energy, many methods have been proposed that avoid distillation altogether for dehydration. Of these methods, a third method has emerged and has been adopted by the majority of modern ethanol plants. This new process uses molecular sieves to remove water from fuel ethanol. In this process, ethanol vapor under pressure passes through a bed of molecular sieve beads. The bead's pores are sized to allow
adsorption Adsorption is the adhesion of atoms, ions or molecules from a gas, liquid or dissolved solid to a surface. This process creates a film of the ''adsorbate'' on the surface of the ''adsorbent''. This process differs from absorption, in which ...
of water while excluding ethanol. After a period of time, the bed is regenerated under vacuum or in the flow of inert atmosphere (e.g. N2) to remove the adsorbed water. Two beds are often used so that one is available to adsorb water while the other is being regenerated. This dehydration technology can account for energy saving of 3,000 btus/gallon (840 k J/L) compared to earlier azeotropic distillation. Recent research has demonstrated that complete dehydration prior to blending with gasoline is not always necessary. Instead, the azeotropic mixture can be blended directly with gasoline so that liquid-liquid phase equilibrium can assist in the elimination of water. A two-stage counter-current setup of mixer-settler tanks can achieve complete recovery of ethanol into the fuel phase, with minimal energy consumption.


Post-production water issues

Ethanol is
hygroscopic Hygroscopy is the phenomenon of attracting and holding water molecules via either absorption or adsorption from the surrounding environment, which is usually at normal or room temperature. If water molecules become suspended among the substan ...
, meaning it absorbs water vapor directly from the atmosphere. Because absorbed water dilutes the fuel value of the ethanol and may cause phase separation of ethanol-gasoline blends (which causes engine stall), containers of ethanol fuels must be kept tightly sealed. This high
miscibility Miscibility () is the property of two substances to mix in all proportions (that is, to fully dissolve in each other at any concentration), forming a homogeneous mixture (a solution). The term is most often applied to liquids but also appl ...
with water means that ethanol cannot be efficiently shipped through modern pipelines, like liquid hydrocarbons, over long distances. The fraction of water that an ethanol-gasoline fuel can contain without phase separation increases with the percentage of ethanol. For example, E30 can have up to about 2% water. If there is more than about 71% ethanol, the remainder can be any proportion of water or gasoline and phase separation does not occur. The fuel mileage declines with increased water content. The increased solubility of water with higher ethanol content permits E30 and hydrated ethanol to be put in the same tank since any combination of them always results in a single phase. Somewhat less water is tolerated at lower temperatures. For E10 it is about 0.5% v/v at 21 °C and decreases to about 0.23% v/v at −34 °C.


Consumer production systems

While
biodiesel Biodiesel is a form of diesel fuel derived from plants or animals and consisting of long-chain fatty acid esters. It is typically made by chemically reacting lipids such as animal fat ( tallow), soybean oil, or some other vegetable oil ...
production systems have been marketed to home and business users for many years, commercialized ethanol production systems designed for end-consumer use have lagged in the marketplace. In 2008, two different companies announced home-scale ethanol production systems. The AFS125 Advanced Fuel System from Allard Research and Development is capable of producing both ethanol and biodiesel in one machine, while the E-100 MicroFueler from E-Fuel Corporation is dedicated to ethanol only.


Engines


Fuel economy

Ethanol contains approximately 34% less energy per unit volume than gasoline, and therefore in theory, burning pure ethanol in a vehicle reduces range per unit measure by 34%, given the same fuel economy, compared to burning pure gasoline. However, since ethanol has a higher octane rating, the engine can be made more efficient by raising its compression ratio. For E10 (10% ethanol and 90% gasoline), the effect is small (~3%) when compared to conventional gasoline, and even smaller (1–2%) when compared to oxygenated and reformulated blends. For E85 (85% ethanol), the effect becomes significant. E85 produces lower mileage than gasoline, and requires more frequent refueling. Actual performance may vary depending on the vehicle. Based on EPA tests for all 2006 E85 models, the average fuel economy for E85 vehicles was 25.56% lower than unleaded gasoline. The EPA-rated mileage of current United States flex-fuel vehicles should be considered when making price comparisons, but E85 is a high performance fuel, with an octane rating of about 94–96, and should be compared to premium. Ethanol is not suitable for most aircraft, according to the
RACQ The Royal Automobile Club of Queensland Limited (RACQ) is a mutual organisation and Queensland’s largest Club, providing services including roadside assistance, insurance, banking and travel to its approximately 1.75 million members. RACQ i ...
, as well as some motorbikes and small engines, though the
Embraer EMB 202 Ipanema The Embraer EMB 202 Ipanema is a Brazilian agricultural aircraft used for aerial application, particularly crop dusting. It is produced by Indústria Aeronáutica Neiva, a subsidiary of Embraer located in Botucatu, Brazil. The latest version of ...
is an example of an aircraft that has been specifically designed for use with ethanol fuel in some variants.


Cold start during the winter

High ethanol blends present a problem to achieve enough
vapor pressure Vapor pressure (or vapour pressure in English-speaking countries other than the US; see spelling differences) or equilibrium vapor pressure is defined as the pressure exerted by a vapor in thermodynamic equilibrium with its condensed phas ...
for the fuel to evaporate and spark the ignition during cold weather (since ethanol tends to increase fuel
enthalpy of vaporization The enthalpy of vaporization (symbol ), also known as the (latent) heat of vaporization or heat of evaporation, is the amount of energy (enthalpy) that must be added to a liquid substance to transform a quantity of that substance into a gas. T ...
). When vapor pressure is below 45
kPa KPA may refer to: * Keele Postgraduate Association, Keele University, UK, formerly Keele Research Association (KRA) * Kensington (Olympia) station, London, England, National Rail station code * Kenya Ports Authority * ''Kiln phosphoric acid'', a ...
starting a cold engine becomes difficult. To avoid this problem at temperatures below , and to reduce ethanol higher emissions during cold weather, both the US and the European markets adopted E85 as the maximum blend to be used in their flexible fuel vehicles, and they are optimized to run at such a blend. At places with harsh cold weather, the ethanol blend in the US has a seasonal reduction to E70 for these very cold regions, though it is still sold as E85. At places where temperatures fall below during the winter, it is recommended to install an engine heater system, both for gasoline and E85 vehicles. Sweden has a similar seasonal reduction, but the ethanol content in the blend is reduced to E75 during the winter months. Brazilian flex fuel vehicles can operate with ethanol mixtures up to
E100 E100 or E-100 may refer to: Electronics * Casio Cassiopeia E-100, a pocket of knife PC * iriver E100, a portable media player Vehicles Automobiles * Baojun E100, a Chinese electric microcar * JMEV E100, a Chinese electric city car * Toyota Co ...
, which is
hydrous In chemistry, a hydrate is a substance that contains water or its constituent elements. The chemical state of the water varies widely between different classes of hydrates, some of which were so labeled before their chemical structure was underst ...
ethanol (with up to 4% water), which causes vapor pressure to drop faster as compared to E85 vehicles. As a result, Brazilian flex vehicles are built with a small secondary gasoline reservoir located near the engine. During a cold start pure gasoline is injected to avoid starting problems at low temperatures. This provision is particularly necessary for users of Brazil's southern and central regions, where temperatures normally drop below during the winter. An improved flex engine generation was launched in 2009 that eliminates the need for the secondary gas storage tank. Ano 2, No. 3 (every article is presented in both English and Portuguese) In March 2009
Volkswagen do Brasil Volkswagen do Brasil Ltda. is a subsidiary arm of Volkswagen Group, established in 1953 with local assembly of the Volkswagen Type 1 from parts imported from Germany. It produced over 20 million vehicles in Brazil, having been market leader for th ...
launched the Polo E-Flex, the first Brazilian flex fuel model without an auxiliary tank for cold start.


Fuel mixtures

In many countries cars are mandated to run on mixtures of ethanol. All Brazilian light-duty vehicles are built to operate for an ethanol blend of up to 25% ( E25), and since 1993 a federal law requires mixtures between 22% and 25% ethanol, with 25% required as of mid July 2011. PhD Dissertation Thesis, pp. 81–82 In the United States all light-duty vehicles are built to operate normally with an ethanol blend of 10% ( E10). At the end of 2010 over 90 percent of all gasoline sold in the U.S. was blended with ethanol.''See pages 2–3, 10–11, 19–20, and 26–27''. In January 2011 the
U.S. Environmental Protection Agency The Environmental Protection Agency (EPA) is an Independent agencies of the United States government, independent executive agency of the United States federal government tasked with environmental protection matters. President Richard Nixon pro ...
(EPA) issued a waiver to authorize up to 15% of ethanol blended with gasoline ( E15) to be sold only for cars and light pickup trucks with a
model year The model year (sometimes abbreviated "MY") is a method of describing the version of a product which has been produced over multiple years. The model year may or may not be the same as the calendar year in which the product was manufactured. ...
of 2001 or newer. Beginning with the model year 1999, an increasing number of vehicles in the world are manufactured with engines that can run on any fuel from 0% ethanol up to 100% ethanol without modification. Many cars and
light truck Light truck or light-duty truck is a US classification for vehicles with a gross vehicle weight up to and a payload capacity up to 4,000 pounds (1,815 kg). Similar goods vehicle classes in the European Union, Canada, Australia, and New Zeala ...
s (a class containing
minivan Minivan (sometimes called simply as van) is a North American car classification for vehicles designed to transport passengers in the rear seating row(s), with reconfigurable seats in two or three rows. The equivalent classification in Europe is ...
s,
SUV A sport utility vehicle (SUV) is a car classification that combines elements of road-going passenger cars with features from off-road vehicles, such as raised ground clearance and four-wheel drive. There is no commonly agreed-upon definiti ...
s and pickup trucks) are designed to be flexible-fuel vehicles using ethanol blends up to 85% (
E85 E85 is an abbreviation typically referring to an ethanol fuel blend of 85% ethanol fuel and 15% gasoline or other hydrocarbon by volume. In the United States, the exact ratio of fuel ethanol to hydrocarbon may vary according to ASTM 5798 that ...
) in North America and Europe, and up to 100% (E100) in Brazil. In older model years, their engine systems contained alcohol sensors in the fuel and/or oxygen sensors in the exhaust that provide input to the engine control computer to adjust the fuel injection to achieve
stochiometric Stoichiometry refers to the relationship between the quantities of reactants and Product (chemistry), products before, during, and following chemical reactions. Stoichiometry is founded on the law of conservation of mass where the total mass of ...
(no residual fuel or free oxygen in the exhaust) air-to-fuel ratio for any fuel mix. In newer models, the alcohol sensors have been removed, with the computer using only oxygen and airflow sensor feedback to estimate alcohol content. The engine control computer can also adjust (advance) the ignition timing to achieve a higher output without pre-ignition when it predicts that higher alcohol percentages are present in the fuel being burned. This method is backed up by advanced knock sensors – used in most high performance gasoline engines regardless of whether they are designed to use ethanol or not – that detect pre-ignition and detonation. In June 2021, India brought forward to 2025 its target to implement a 20% ethanol-blended auto fuel. India's ethanol blending rate in fuel (at the time of this target revision) is 8%, which is set to increase to 10% by 2022 based on the 'Roadmap for ethanol blending in India 2020-25' released on 5 June (
World Environment Day World Environment Day (WED) is celebrated annually on 5 June and encourages awareness and action for the protection of the environment. It is supported by many non-governmental organizations, businesses, government entities, and represents the ...
) by Prime Minister
Narendra Modi Narendra Damodardas Modi (; born 17 September 1950) is an Indian politician serving as the 14th and current Prime Minister of India since 2014. Modi was the Chief Minister of Gujarat from 2001 to 2014 and is the Member of Parliament fro ...
. The government expects oil marketing companies such as Indian Oil Corp (IOC) and Hindustan Petroleum Corp Ltd (HPCL) to provide 20% ethanol-blended fuel from April 2023 onward. States like Maharashtra and Uttar Pradesh, where ethanol is in surplus, are expected to be the first to adopt the higher ethanol fuel blending rate. India is also prioritizing roll-out of vehicles compatible with ethanol-blended fuel. From March 2021, auto manufacturers are required to indicate the ethanol compatibility of new vehicles and engines must be optimally designed to use 20% ethanol-blended fuel. The government expects automakers to begin production of ethanol-blended fuel compliant vehicles before April 2022. However, environmentalists worry that India's increased target for ethanol blending could incentivise water-intensive crops such as sugarcane and rice, and suggest that the government should focus on lower-water intensity crops such as millets since India is already facing an acute water shortage.


Other engine configurations

;ED95 engines Since 1989 there have also been ethanol engines based on the diesel principle operating in Sweden.
Scania PRESSInfo, 21 May 2007
They are used primarily in city buses, but also in distribution trucks and waste collectors. The engines, made by Scania AB, Scania, have a modified compression ratio, and the fuel (known as ED95) used is a mix of 93.6% ethanol and 3.6% ignition improver, and 2.8% denaturants. The ignition improver makes it possible for the fuel to ignite in the diesel combustion cycle. It is then also possible to use the energy efficiency of the diesel principle with ethanol. These engines have been used in the United Kingdom by
Reading Buses Reading Buses is a bus operator serving the towns of Reading, Bracknell, Newbury, Slough, Windsor, Maidenhead, Wokingham and the surrounding areas in the counties of Berkshire, Oxfordshire, and Hampshire, England, as well as parts of Greater L ...
but the use of bioethanol fuel is now being phased out. ;Dual-fuel direct-injection A 2004
MIT The Massachusetts Institute of Technology (MIT) is a private land-grant research university in Cambridge, Massachusetts. Established in 1861, MIT has played a key role in the development of modern technology and science, and is one of the m ...
study and an earlier paper published by the Society of Automotive Engineers identified a method to exploit the characteristics of fuel ethanol substantially more efficiently than mixing it with gasoline. The method presents the possibility of leveraging the use of alcohol to achieve definite improvement over the cost-effectiveness of hybrid electric. The improvement consists of using dual-fuel direct-injection of pure alcohol (or the azeotrope or E85) and gasoline, in any ratio up to 100% of either, in a turbocharged, high compression-ratio, small-displacement engine having performance similar to an engine having twice the displacement. Each fuel is carried separately, with a much smaller tank for alcohol. The high-compression (for higher efficiency) engine runs on ordinary gasoline under low-power cruise conditions. Alcohol is directly injected into the cylinders (and the gasoline injection simultaneously reduced) only when necessary to suppress 'knock' such as when significantly accelerating. Direct cylinder injection raises the already high octane rating of ethanol up to an effective 130. The calculated over-all reduction of gasoline use and CO2 emission is 30%. The consumer cost payback time shows a 4:1 improvement over turbo-diesel and a 5:1 improvement over hybrid. The problems of water absorption into pre-mixed gasoline (causing phase separation), supply issues of multiple mix ratios and cold-weather starting are also avoided. ;Increased thermal efficiency In a 2008 study, complex engine controls and increased
exhaust gas recirculation In internal combustion engines, exhaust gas recirculation (EGR) is a nitrogen oxide () emissions reduction technique used in petrol/gasoline, diesel engines and some hydrogen engines. EGR works by recirculating a portion of an engine's exhaust ...
allowed a compression ratio of 19.5 with fuels ranging from neat ethanol to E50. Thermal efficiency up to approximately that for a diesel was achieved. This would result in the fuel economy of a neat ethanol vehicle to be about the same as one burning gasoline. ;Fuel cells powered by an ethanol reformer In June 2016, Nissan announced plans to develop
fuel cell vehicle A fuel cell vehicle (FCV) or fuel cell electric vehicle (FCEV) is an electric vehicle that uses a fuel cell, sometimes in combination with a small battery or supercapacitor, to power its onboard electric motor. Fuel cells in vehicles generate e ...
s powered by ethanol rather than
hydrogen Hydrogen is the chemical element with the symbol H and atomic number 1. Hydrogen is the lightest element. At standard conditions hydrogen is a gas of diatomic molecules having the formula . It is colorless, odorless, tasteless, non-toxic ...
, the fuel of choice by the other car manufacturers that have developed and commercialized fuel cell vehicles, such as the
Hyundai Tucson FCEV The Hyundai ix35 FCEV or Tucson FCEV is a fuel cell vehicle, hydrogen fuel cell electric vehicle developed by Hyundai Motor Company, Hyundai. The model is a left-hand drive only conversion to the SUV platform it is based on and was the first of it ...
,
Toyota Mirai The (from , Japanese for 'future') is a mid-size hydrogen fuel cell vehicle (FCV) manufactured by Toyota, and is one of the first FCV automobiles to be mass-produced and sold commercially. The Mirai was unveiled at the November 2014 Los Angel ...
, and
Honda FCX Clarity The Honda Clarity is a nameplate used by Honda on alternative fuel vehicles. It was initially used only on hydrogen fuel-cell electric vehicles such as the 2008 Honda FCX Clarity, but in 2017 the nameplate was expanded to include the battery-elec ...
. The main advantage of this technical approach is that it would be cheaper and easier to deploy the fueling infrastructure than setting up the one required to deliver hydrogen at high pressures, as each hydrogen fueling station cost to to build. Nissan plans to create a technology that uses liquid ethanol fuel as a source to generate hydrogen within the vehicle itself. The technology uses heat to reform ethanol into hydrogen to feed what is known as a solid oxide fuel cell (SOFC). The fuel cell generates electricity to supply power to the electric motor driving the wheels, through a battery that handles peak power demands and stores regenerated energy. The vehicle would include a tank for a blend of water and ethanol, which is fed into an onboard reformer that splits it into pure hydrogen and carbon dioxide. According to Nissan, the liquid fuel could be an ethanol-water blend at a 55:45 ratio. Nissan expects to commercialize its technology by 2020.


Experience by country

The world's top ethanol fuel producers in 2011 were the United States with and Brazil with , accounting together for 87.1% of world production of . Strong incentives, coupled with other industry development initiatives, are giving rise to fledgling ethanol industries in countries such as Germany, Spain, France, Sweden, China, Thailand, Canada, Colombia, India, Australia, and some Central American countries.


Environment


Energy balance

† experimental, not in commercial production †† depending on production method
All biomass goes through at least some of these steps: it needs to be grown, collected, dried, fermented, distilled, and burned. All of these steps require resources and an infrastructure. The total amount of energy input into the process compared to the energy released by burning the resulting ethanol fuel is known as the energy balance (or "
energy returned on energy invested In energy economics and ecological energetics, energy return on investment (EROI), also sometimes called energy returned on energy invested (ERoEI), is the ratio of the amount of usable energy (the ''exergy'') delivered from a particular energy re ...
"). Figures compiled in a 2007 report by '' National Geographic'' point to modest results for corn ethanol produced in the US: one unit of fossil-fuel energy is required to create 1.3 energy units from the resulting ethanol. The energy balance for sugarcane ethanol produced in Brazil is more favorable, with one unit of fossil-fuel energy required to create 8 from the ethanol. Energy balance estimates are not easily produced, thus numerous such reports have been generated that are contradictory. For instance, a separate survey reports that production of ethanol from sugarcane, which requires a tropical climate to grow productively, returns from 8 to 9 units of energy for each unit expended, as compared to corn, which only returns about 1.34 units of fuel energy for each unit of energy expended.
A 2006 University of California Berkeley study, after analyzing six separate studies, concluded that producing ethanol from corn uses much less petroleum than producing gasoline.
Carbon dioxide Carbon dioxide ( chemical formula ) is a chemical compound made up of molecules that each have one carbon atom covalently double bonded to two oxygen atoms. It is found in the gas state at room temperature. In the air, carbon dioxide is trans ...
, a greenhouse gas, is emitted during fermentation and combustion. This is canceled out by the greater uptake of carbon dioxide by the plants as they grow to produce the biomass. When produced by certain methods, ethanol releases less greenhouse gases than gasoline does.


Air pollution

Compared with conventional
unleaded gasoline Gasoline (; ) or petrol (; ) (see ) is a transparent, petroleum-derived flammable liquid that is used primarily as a fuel in most spark-ignited internal combustion engines (also known as petrol engines). It consists mostly of organic com ...
, ethanol is a particulate-free burning fuel source that combusts with oxygen to form carbon dioxide, carbon monoxide, water and
aldehydes In organic chemistry, an aldehyde () is an organic compound containing a functional group with the structure . The functional group itself (without the "R" side chain) can be referred to as an aldehyde but can also be classified as a formyl grou ...
. The Clean Air Act requires the addition of
oxygenate Oxygenated chemical compounds contain oxygen as a part of their chemical structure. The term usually refers to oxygenated chemical compounds added to fuels. Oxygenates are usually employed as gasoline additives to reduce carbon monoxide and soot ...
s to reduce carbon monoxide emissions in the United States. The additive
MTBE Methyl ''tertiary''-butyl ether (MTBE), also known as methyl tert-butyl ether and ''tert''-butyl methyl ether, is an organic compound with a structural formula (CH3)3COCH3. MTBE is a volatile, flammable, and colorless liquid that is sparingly sol ...
is currently being phased out due to ground water contamination, hence ethanol becomes an attractive alternative additive. Current production methods include air pollution from the manufacturer of macronutrient
fertilizer A fertilizer (American English) or fertiliser (British English; see spelling differences) is any material of natural or synthetic origin that is applied to soil or to plant tissues to supply plant nutrients. Fertilizers may be distinct from ...
s such as ammonia. A study by atmospheric scientists at Stanford University found that E85 fuel would increase the risk of air pollution deaths relative to gasoline by 9% in Los Angeles, US: a very large, urban, car-based metropolis that is a worst-case scenario.
Ozone Ozone (), or trioxygen, is an inorganic molecule with the chemical formula . It is a pale blue gas with a distinctively pungent smell. It is an allotrope of oxygen that is much less stable than the diatomic allotrope , breaking down in the lo ...
levels are significantly increased, thereby increasing photochemical smog and aggravating medical problems such as asthma. Brazil burns significant amounts of ethanol biofuel. Gas
chromatograph In chemical analysis, chromatography is a laboratory technique for the separation of a mixture into its components. The mixture is dissolved in a fluid solvent (gas or liquid) called the ''mobile phase'', which carries it through a system (a ...
studies were performed of ambient air in São Paulo, Brazil, and compared to Osaka, Japan, which does not burn ethanol fuel. Atmospheric
Formaldehyde Formaldehyde ( , ) (systematic name methanal) is a naturally occurring organic compound with the formula and structure . The pure compound is a pungent, colourless gas that polymerises spontaneously into paraformaldehyde (refer to section ...
was 160% higher in Brazil, and Acetaldehyde was 260% higher.


Carbon dioxide

of exactly how much carbon dioxide is produced in the manufacture of bioethanol is a complex and inexact process, and is highly dependent on the method by which the ethanol is produced and the assumptions made in the calculation. A calculation should include: *The cost of growing the feedstock *The cost of transporting the feedstock to the factory *The cost of processing the feedstock into bioethanol Such a calculation may or may not consider the following effects: *The cost of the change in land use of the area where the fuel feedstock is grown. *The cost of transportation of the bioethanol from the factory to its point of use *The efficiency of the bioethanol compared with standard gasoline *The amount of carbon dioxide produced at the tail pipe. *The benefits due to the production of useful bi-products, such as cattle feed or electricity. The graph on the right shows figures calculated by the UK government for the purposes of the
Renewable transport fuel obligation The Renewable Transport Fuel Obligation (RTFO) in the United Kingdom is a requirement on transport fuel suppliers to ensure that 5 per cent of all road vehicle fuel is supplied from sustainable renewable sources by 2010. The Government intend ...
. The January 2006 Science article from UC Berkeley's ERG, estimated reduction from corn ethanol in GHG to be 13% after reviewing a large number of studies. In a correction to that article released shortly after publication, they reduce the estimated value to 7.4%. A '' National Geographic'' overview article (2007) puts the figures at 22% less CO2 emissions in production and use for corn ethanol compared to gasoline and a 56% reduction for cane ethanol. Carmaker Ford reports a 70% reduction in CO2 emissions with bioethanol compared to petrol for one of their flexible-fuel vehicles. An additional complication is that production requires tilling new soil which produces a one-off release of GHG that it can take decades or centuries of production reductions in GHG emissions to equalize. As an example, converting grass lands to corn production for ethanol takes about a century of annual savings to make up for the GHG released from the initial tilling.


Change in land use

Large-scale farming is necessary to produce agricultural alcohol and this requires substantial amounts of cultivated land. University of Minnesota researchers report that if all corn grown in the U.S. were used to make ethanol it would displace 12% of current U.S. gasoline consumption. There are claims that land for ethanol production is acquired through deforestation, while others have observed that areas currently supporting forests are usually not suitable for growing crops. In any case, farming may involve a decline in soil fertility due to reduction of organic matter, a decrease in water availability and quality, an increase in the use of pesticides and fertilizers, and potential dislocation of local communities. New technology enables farmers and processors to increasingly produce the same output using less inputs. Cellulosic ethanol production is a new approach that may alleviate land use and related concerns. Cellulosic ethanol can be produced from any plant material, potentially doubling yields, in an effort to minimize conflict between food needs vs. fuel needs. Instead of utilizing only the starch by-products from grinding wheat and other crops, cellulosic ethanol production maximizes the use of all plant materials, including gluten. This approach would have a smaller carbon footprint because the amount of energy-intensive fertilisers and fungicides remain the same for higher output of usable material. The technology for producing cellulosic ethanol is currently in the commercialization stage.


Using biomass for electricity instead of ethanol

Converting biomass to electricity for charging electric vehicles may be a more "climate-friendly" transportation option than using biomass to produce ethanol fuel, according to an analysis published in Science in May 2009 Researchers continue to search for more cost-effective developments in both cellulosic ethanol and advanced vehicle batteries.


Health costs of ethanol emissions

For each billion ethanol-equivalent gallons of fuel produced and combusted in the US, the combined climate-change and health costs are $469million for gasoline, $472–952million for corn ethanol depending on biorefinery heat source (natural gas, corn stover, or coal) and technology, but only $123–208million for cellulosic ethanol depending on feedstock (prairie biomass, Miscanthus, corn stover, or switchgrass).


Efficiency of common crops

As ethanol yields improve or different feedstocks are introduced, ethanol production may become more economically feasible in the US. Currently, research on improving ethanol yields from each unit of corn is underway using biotechnology. Also, as long as oil prices remain high, the economical use of other feedstocks, such as
cellulose Cellulose is an organic compound with the formula , a polysaccharide consisting of a linear chain of several hundred to many thousands of β(1→4) linked D-glucose units. Cellulose is an important structural component of the primary cell w ...
, become viable. By-products such as straw or wood chips can be converted to ethanol. Fast growing species like
switchgrass ''Panicum virgatum'', commonly known as switchgrass, is a perennial warm season bunchgrass native to North America, where it occurs naturally from 55°N latitude in Canada southwards into the United States and Mexico. Switchgrass is one of the ...
can be grown on land not suitable for other cash crops and yield high levels of ethanol per unit area.


Reduced petroleum imports and costs

One rationale given for extensive ethanol production in the U.S. is its benefit to
energy security Energy security is the association between national security and the availability of natural resources for energy consumption. Access to (relatively) cheap energy has become essential to the functioning of modern economies. However, the uneven d ...
, by shifting the need for some foreign-produced oil to domestically produced energy sources. Production of ethanol requires significant energy, but current U.S. production derives most of that energy from coal, natural gas and other sources, rather than oil. Because 66% of oil consumed in the U.S. is imported, compared to a net surplus of coal and just 16% of natural gas (figures from 2006), the displacement of oil-based fuels to ethanol produces a net shift from foreign to domestic U.S. energy sources. According to a 2008 analysis by Iowa State University, the growth in US ethanol production has caused retail gasoline prices to be US$0.29 to US$0.40 per gallon lower than would otherwise have been the case.


Motorsport

Leon Duray qualified third for the
1927 Indianapolis 500 The 15th International 500-Mile Sweepstakes Race was held at the Indianapolis Motor Speedway on Monday, May 30, 1927. First-time starter George Souders won by eight laps, the largest margin since 1913. Souders became the first driver to win the ...
auto race with an ethanol-fueled car. The
IndyCar Series The IndyCar Series, currently known as the NTT IndyCar Series under sponsorship, is the highest class of regional North American open-wheel single-seater formula racing cars in the United States, which has been conducted under the auspices o ...
adopted a 10% ethanol blend for the 2006 season, and a 98% blend in 2007. The
American Le Mans Series The American Le Mans Series (ALMS) was a sports car racing series based in the United States and Canada. It consisted of a series of endurance and sprint races, and was created in the spirit of the 24 Hours of Le Mans. The American Le Mans' hea ...
sports car championship introduced E10 in the 2007 season to replace pure gasoline. In the 2008 season, E85 was allowed in the GT class and teams began switching to it. In 2011, the three national
NASCAR The National Association for Stock Car Auto Racing, LLC (NASCAR) is an American auto racing sanctioning and operating company that is best known for stock car racing. The privately owned company was founded by Bill France Sr. in 1948, and ...
stock car series mandated a switch from gasoline to E15, a blend of Sunoco GTX unleaded racing fuel and 15% ethanol. Australia's
V8 Supercar The Supercars Championship is a touring car racing category in Australia, running as an International Series under Fédération Internationale de l'Automobile (FIA) regulations, governing the sport. Supercars events take place in all Australian ...
championship uses Shell E85 for its racing fuel.
Stock Car Brasil Stock Car Pro Series, formerly known as Stock Car Brasil, is a touring car auto racing series based in Brazil organized by Vicar. It is considered the major Brazilian and South American motorsports series. Starting in 1979 with Chevrolet as the ...
Championship runs on neat ethanol, E100. Ethanol fuel may also be utilized as a
rocket fuel Rocket propellant is the reaction mass of a rocket. This reaction mass is ejected at the highest achievable velocity from a rocket engine to produce thrust. The energy required can either come from the propellants themselves, as with a chemical ...
. , small quantities of ethanol are used in
lightweight Lightweight is a weight class in combat sports and rowing. Boxing Professional boxing The lightweight division is over 130 pounds (59 kilograms) and up to 135 pounds (61.2 kilograms) weight class in the sport of boxing. Notable lightweight ...
rocket-racing aircraft.


Replacement cooking fuel

Project Gaia Project Gaia is a U.S. non-governmental, non-profit organization involved in the creation of a commercially viable household market for alcohol-based fuels in Ethiopia and other countries in the developing world.
is a U.S.
non-governmental A non-governmental organization (NGO) or non-governmental organisation (see spelling differences) is an organization that generally is formed independent from government. They are typically nonprofit entities, and many of them are active in ...
,
non-profit A nonprofit organization (NPO) or non-profit organisation, also known as a non-business entity, not-for-profit organization, or nonprofit institution, is a legal entity organized and operated for a collective, public or social benefit, in co ...
organization involved in the creation of a commercially viable household market for alcohol-based fuels in Ethiopia and other countries in the developing world. The project considers alcohol fuels to be a solution to fuel shortages, environmental damage, and public health issues caused by traditional cooking in the developing world. Targeting poor and marginalized communities that face health issues from cooking over polluting fires, Gaia currently works in
Ethiopia Ethiopia, , om, Itiyoophiyaa, so, Itoobiya, ti, ኢትዮጵያ, Ítiyop'iya, aa, Itiyoppiya officially the Federal Democratic Republic of Ethiopia, is a landlocked country in the Horn of Africa. It shares borders with Eritrea to the ...
,
Nigeria Nigeria ( ), , ig, Naìjíríyà, yo, Nàìjíríà, pcm, Naijá , ff, Naajeeriya, kcg, Naijeriya officially the Federal Republic of Nigeria, is a country in West Africa. It is situated between the Sahel to the north and the Gulf o ...
,
Brazil Brazil ( pt, Brasil; ), officially the Federative Republic of Brazil (Portuguese: ), is the largest country in both South America and Latin America. At and with over 217 million people, Brazil is the world's fifth-largest country by area ...
, Haiti, and
Madagascar Madagascar (; mg, Madagasikara, ), officially the Republic of Madagascar ( mg, Repoblikan'i Madagasikara, links=no, ; french: République de Madagascar), is an island country in the Indian Ocean, approximately off the coast of East Africa ...
, and is in the planning stage of projects in several other countries."Impact of Improved Stoves and Fuels on IAP"
, CEIHD Center for Entrepreneurship in International Health and Development. Retrieved 30 May 2010.


Research

Ethanol research focuses on alternative sources, novel catalysts and production processes.
INEOS INEOS Group Limited is a British multinational chemicals company headquartered and registered in London. , it is the fourth largest chemical company in the world. Ineos is organised into about 20 standalone business units, each with its own b ...
produced ethanol from vegetative material and wood waste. The
bacterium Bacteria (; singular: bacterium) are ubiquitous, mostly free-living organisms often consisting of one biological cell. They constitute a large domain of prokaryotic microorganisms. Typically a few micrometres in length, bacteria were amon ...
E.coli ''Escherichia coli'' (),Wells, J. C. (2000) Longman Pronunciation Dictionary. Harlow ngland Pearson Education Ltd. also known as ''E. coli'' (), is a Gram-negative, facultative anaerobic, rod-shaped, coliform bacterium of the genus ''Esche ...
when
genetically engineered Genetic engineering, also called genetic modification or genetic manipulation, is the modification and manipulation of an organism's genes using technology. It is a set of technologies used to change the genetic makeup of cells, including t ...
with cow
rumen The rumen, also known as a paunch, is the largest stomach compartment in ruminants and the larger part of the reticulorumen, which is the first chamber in the alimentary canal of ruminant animals. The rumen's microbial favoring environment al ...
genes and
enzyme Enzymes () are proteins that act as biological catalysts by accelerating chemical reactions. The molecules upon which enzymes may act are called substrates, and the enzyme converts the substrates into different molecules known as products ...
s can produce ethanol from corn stover. Other potential feedstocks are municipal waste, recycled products,
rice hull Rice hulls (or rice husks) are the hard protecting coverings of grains of rice. In addition to protecting rice during the growing season, rice hulls can be put to use as building material, fertilizer, insulation material, or fuel. Rice hulls are p ...
s, sugarcane
bagasse Bagasse ( ) is the dry pulpy fibrous material that remains after crushing sugarcane or sorghum stalks to extract their juice. It is used as a biofuel for the production of heat, energy, and electricity, and in the manufacture of pulp and building ...
, wood chips,
switchgrass ''Panicum virgatum'', commonly known as switchgrass, is a perennial warm season bunchgrass native to North America, where it occurs naturally from 55°N latitude in Canada southwards into the United States and Mexico. Switchgrass is one of the ...
and
carbon dioxide Carbon dioxide ( chemical formula ) is a chemical compound made up of molecules that each have one carbon atom covalently double bonded to two oxygen atoms. It is found in the gas state at room temperature. In the air, carbon dioxide is trans ...
.


Bibliography

* * *


See also

* Alcohol fuel * Biobutanol, a gasoline replacement *
Bioconversion of biomass to mixed alcohol fuels The bioconversion of biomass to mixed alcohol fuels can be accomplished using the MixAlco process. Through bioconversion of biomass to a mixed alcohol fuel, more energy from the biomass will end up as liquid fuels than in converting biomass to etha ...
*
Biodiesel Biodiesel is a form of diesel fuel derived from plants or animals and consisting of long-chain fatty acid esters. It is typically made by chemically reacting lipids such as animal fat ( tallow), soybean oil, or some other vegetable oil ...
* Biomass *
Cellulosic ethanol Cellulosic ethanol is ethanol (ethyl alcohol) produced from cellulose (the stringy fiber of a plant) rather than from the plant's seeds or fruit. It can be produced from grasses, wood, algae, or other plants. It is generally discussed for use as a ...
* Common ethanol fuel mixtures * Corn ethanol * DMF (potential ethanol competitor biofuel) *
Dimethyl ether Dimethyl ether (DME; also known as methoxymethane) is the organic compound with the formula CH3OCH3, (sometimes ambiguously simplified to C2H6O as it is an isomer of ethanol). The simplest ether, it is a colorless gas that is a useful precursor ...
* Energy crop * Ethanol effect * Ethanol from coal *
Flexible-fuel vehicle A flexible-fuel vehicle (FFV) or dual-fuel vehicle (colloquially called a flex-fuel vehicle) is an alternative fuel vehicle with an internal combustion engine designed to run on more than one fuel, usually gasoline blended with either ethanol fu ...
* Food vs. fuel *
Gasoline gallon equivalent Gasoline gallon equivalent (GGE) or gasoline-equivalent gallon (GEG) is the amount of an alternative fuel it takes to equal the energy content of one liquid gallon of gasoline. GGE allows consumers to compare the energy content of competing fu ...
*
Hydrogen fuel Hydrogen fuel refers to hydrogen which is burned as fuel with oxygen. It is zero-carbon, provided that it is created in a process that does not involve carbon. It can be used in fuel cells or internal combustion engines (see HICEV). Regarding hydr ...
*
Issues relating to biofuels There are various social, economic, environmental and technical issues with biofuel production and use, which have been discussed in the popular media and scientific journals. These include: the effect of moderating oil prices, the "food vs fuel" de ...
*
Liquid fuels Liquid fuels are combustible or energy-generating molecules that can be harnessed to create mechanical energy, usually producing kinetic energy; they also must take the shape of their container. It is the fumes of liquid fuels that are flammable ...
*
Low-carbon fuel standard A low-carbon fuel standard (LCFS) is an emissions trading rule designed to reduce the average carbon intensity of transportation fuels in a given jurisdiction, as compared to conventional petroleum fuels, such as gasoline and diesel. The most co ...
*
Methanol fuel Methanol fuel is an alternative biofuel for internal combustion and other engines, either in combination with gasoline or independently. Methanol ( C H3 O H) is less expensive to produce sustainably than ethanol fuel, although it produces more ...
*
P-series fuels P-series fuels are a family of renewable, non-petroleum, liquid fuels that can substitute for gasoline. The blend of methyl tetrahydrofuran (MTHF), ethanol, and hydrocarbon In organic chemistry, a hydrocarbon is an organic compound consisti ...
* Renewable energy * Timeline of alcohol fuel *
United States energy law United States energy law is a function of the federal government, states, and local governments. At the federal level, it is regulated extensively through the United States Department of Energy. Every state, the federal government, and the Distric ...


References


External links

* {{DEFAULTSORT:Ethanol Fuel