Carl Paul Gottfried Von Linde
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Carl Paul Gottfried von Linde (11 June 1842 – 16 November 1934) was a German scientist, engineer, and businessman. He discovered a refrigeration cycle and invented the first industrial-scale
air separation An air separation plant separates atmospheric air into its primary components, typically nitrogen and oxygen, and sometimes also argon and other rare inert gases. The most common method for air separation is fractional distillation. Cryogenic air ...
and gas liquefaction processes, which led to the first reliable and efficient compressed-ammonia
refrigerator A refrigerator, colloquially fridge, is a commercial and home appliance consisting of a thermally insulated compartment and a heat pump (mechanical, electronic or chemical) that transfers heat from its inside to its external environment so th ...
in 1876. These breakthroughs laid the backbone for the 1913 Nobel Prize in Physics that was awarded to Heike Kamerlingh Onnes. Linde was a member of scientific and engineering associations, including being on the board of trustees of the
Physikalisch-Technische Reichsanstalt The Physikalisch-Technische Bundesanstalt (PTB) is the national metrology institute of the Federal Republic of Germany, with scientific and technical service tasks. It is a higher federal authority and a public-law institution directly under fed ...
and the
Bavarian Academy of Sciences and Humanities The Bavarian Academy of Sciences and Humanities (german: Bayerische Akademie der Wissenschaften) is an independent public institution, located in Munich. It appoints scholars whose research has contributed considerably to the increase of knowledg ...
. Linde was also the founder of what is now known as Linde plc but formerly known (variously) as the Linde division of Union Carbide,
Linde Linde may refer to: Places *Lindes and Ramsberg Mountain District, a former district in Sweden, see Lindesberg Municipality *Lipka, Złotów County, a village in Poland, called Linde before World War II Rivers *Linde (Tollense), a river of Meckle ...
, Linde Air Products,
Praxair Praxair, Inc. was an American worldwide industrial gases company. Founded in 1907, Praxair was the largest industrial gases company in North and South America, and the third-largest worldwide by revenue. In 2018 it merged with Linde AG to form ...
, and others. Linde is the world's largest producer of industrial gases and ushered in the creation of the global
supply chain In commerce, a supply chain is a network of facilities that procure raw materials, transform them into intermediate goods and then final products to customers through a distribution system. It refers to the network of organizations, people, acti ...
for
industrial gas Industrial gases are the gaseous materials that are manufactured for use in industry. The principal gases provided are nitrogen, oxygen, carbon dioxide, argon, hydrogen, helium and acetylene, although many other gases and mixtures are also avail ...
es. He was knighted in 1897 as Ritter von Linde.


Biography


Early years

Born in , Bavaria as the son of a German-born minister and a Swedish mother, he was expected to follow in his father's footsteps but took another direction entirely. Von Linde's family moved to Munich in 1854, and eight years later he started a course in engineering at the
Swiss Federal Institute of Technology in Zürich (colloquially) , former_name = eidgenössische polytechnische Schule , image = ETHZ.JPG , image_size = , established = , type = Public , budget = CHF 1.896 billion (2021) , rector = Günther Dissertori , president = Joël Mesot , ac ...
, Switzerland, where his teachers included Rudolf Clausius, Gustav Zeuner and Franz Reuleaux. In 1864, he was expelled before graduating for participating in a student protest, but Reuleaux found him a position as an apprentice at the Kottern cotton-spinning plant in Kempten. Linde stayed only a short time before moving first to Borsig in Berlin and then to the new Krauss locomotive factory in Munich, where he worked as head of the technical department. Von Linde married Helene Grimm in September 1866; their marriage lasted 53 years and they had six children. In 1868 Linde learned of a new university opening in Munich (the '' Technische Hochschule'') and immediately applied for a job as a lecturer; he was accepted—at the age of 26—for the position. He became a full professor of mechanical engineering in 1872, and set up an engineering lab where students such as Rudolf Diesel studied.


Middle years

In 1870 and 1871, Linde published articles in the ''Bavarian Industry and Trade Journal'' describing his research findings in the area of refrigeration. Linde's first refrigeration plants were commercially successful, and development began to take up increasing amounts of his time. In 1879, he gave up his professorship and founded the ''Gesellschaft für Lindes Eismaschinen Aktiengesellschaft'' ("Linde's Ice Machine Company"), now ''Linde plc'', in Wiesbaden, Germany. After a slow start in a difficult German economy, business picked up quickly in the 1880s. The efficient new refrigeration technology offered big benefits to the breweries, and by 1890 Linde had sold 747 machines. In addition to the breweries, other uses for the new technology were found in slaughterhouses and cold storage facilities all over Europe. In 1888, Linde moved back to Munich where he took up his professorship once more but was soon back at work developing new refrigeration cycles. In 1892, an order from the
Guinness Guinness () is an Irish dry stout that originated in the brewery of Arthur Guinness at St. James's Gate, Dublin, Ireland, in 1759. It is one of the most successful alcohol brands worldwide, brewed in almost 50 countries, and available in ove ...
brewery in Dublin for a carbon dioxide liquefaction plant drove Linde's research into the area of low-temperature refrigeration, and in 1894 he started work on a process for the
liquefaction In materials science, liquefaction is a process that generates a liquid from a solid or a gas or that generates a non-liquid phase which behaves in accordance with fluid dynamics. It occurs both naturally and artificially. As an example of the ...
of air. In 1895, Linde first achieved success, and filed for patent protection of his process (not approved in the US until 1903). In 1901, Linde began work on a technique to obtain pure oxygen and nitrogen based on the
fractional distillation Fractional distillation is the separation of a mixture into its component parts, or fractions. Chemical compounds are separated by heating them to a temperature at which one or more fractions of the mixture will vaporize. It uses distillation to ...
of liquefied air. By 1910, coworkers including Carl's son Friedrich had developed the ''Linde double-column'' process, variants of which are still in common use today. After a decade, Linde withdrew from managerial activities to refocus on research, and in 1895 he succeeded in liquefying air by first compressing it and then letting it expand rapidly, thereby cooling it. He then obtained oxygen and nitrogen from the liquid air by slow warming. In the early days of oxygen production, the biggest use by far for the gas was the
oxyacetylene torch Principle of burn cutting Oxy-fuel welding (commonly called oxyacetylene welding, oxy welding, or gas welding in the United States) and oxy-fuel cutting are processes that use fuel gases (or liquid fuels such as gasoline or petrol, diesel, ...
, invented in France in 1903, which revolutionized metal cutting and welding in the construction of ships,
skyscraper A skyscraper is a tall continuously habitable building having multiple floors. Modern sources currently define skyscrapers as being at least or in height, though there is no universally accepted definition. Skyscrapers are very tall high-ris ...
s, and other iron and steel structures. In 1897, Linde was appointed to the
Order of Merit of the Bavarian Crown The Order of Merit of the Bavarian Crown (german: Verdienstorden der Bayerischen Krone) was an order of merit of the Kingdom of Bavaria established by King Maximilian Joseph I on 19 March 1808. The motto of the order is Virtus et Honos ('Courage ...
and ennobled in accordance with its statutes. In addition to Linde's technical and engineering abilities, he was a successful entrepreneur. He formed many successful partnerships in Germany and internationally, working effectively to exploit the value of his patents and knowledge through licensing arrangements. In 1906, Linde negotiated a stake in Brin's Oxygen Company, renamed The BOC Group. in exchange for rights to Linde's patents in the UK and other countries, and held a board position until 1914. Linde also formed the Linde Air Products Company in the USA in 1907, a company that passed through US Government control to Union Carbide in the 1940s and on to form
Praxair Praxair, Inc. was an American worldwide industrial gases company. Founded in 1907, Praxair was the largest industrial gases company in North and South America, and the third-largest worldwide by revenue. In 2018 it merged with Linde AG to form ...
. In 2005 ''Linde, plc'' bought the BOC Group, and in 2019 ''Linde plc'' merged with Praxair, thus combining all three companies founded by Linde.


Later years and death

From around 1910, Linde started transferring responsibility for the company's operation to his sons Friedrich and Richard and to his son-in-law Rudolf Wucherer. He continued with supervisory board and advisory duties until his death. Carl von Linde died in Munich in November 1934 at the age of 92.


Key inventions

Linde's first refrigeration system used
dimethyl ether Dimethyl ether (DME; also known as methoxymethane) is the organic compound with the formula CH3OCH3, (sometimes ambiguously simplified to C2H6O as it is an isomer of ethanol). The simplest ether, it is a colorless gas that is a useful precursor ...
as the refrigerant and was built by ''Maschinenfabrik Augsburg'' (now MAN AG) for the Spaten Brewery in 1873. He quickly moved on to develop more reliable ammonia-based cycles. These were early examples of vapor-compression refrigeration machines, and ammonia is still in wide use as a
refrigerant A refrigerant is a working fluid used in the heat pump and refrigeration cycle, refrigeration cycle of air conditioning systems and heat pumps where in most cases they undergo a repeated phase transition from a liquid to a gas and back again. Ref ...
in industrial applications. His apparatus for the liquefaction of air combined the cooling effect achieved by allowing a compressed gas to expand (the
Joule–Thomson effect In thermodynamics, the Joule–Thomson effect (also known as the Joule–Kelvin effect or Kelvin–Joule effect) describes the temperature change of a ''real'' gas or liquid (as differentiated from an ideal gas) when it is forced through a valv ...
first observed by James Prescott Joule and Lord Kelvin) with a counter-current heat exchange technique that used the cold air produced by expansion to chill ambient air entering the apparatus. Over a period of time this effect gradually cooled the apparatus and air within it to the point of liquefaction. Linde followed development of air liquefaction equipment with equipment that also separated air into its constituent parts using distillation processes. Linde's inventions and developments spurred development in many areas of cryogenics, physics,
chemistry Chemistry is the science, scientific study of the properties and behavior of matter. It is a natural science that covers the Chemical element, elements that make up matter to the chemical compound, compounds made of atoms, molecules and ions ...
and engineering.


Patents


CH10704
– 31 January 1896 – ''Gasverflüssigungs-maschine (Machine for the liquefaction of gas)'' (in German) – Switzerland
GB189512528
– 16 May 1896 – ''Process and Apparatus for Liquefying Gases or Gaseous Mixtures, and for Producing Cold, more particularly applicable for Separating Oxygen from Atmospheric Air'' – UK * – 12 May 1903 – ''Linde oxygen process'' – US * – 12 May 1903 – ''Equipment for Linde oxygen process'' – US * – 25 July 1905 – ''Equipment for Linde oxygen and nitrogen process'' – US


Awards

* Wilhelm Exner Medal, 1922


See also

*
Air separation An air separation plant separates atmospheric air into its primary components, typically nitrogen and oxygen, and sometimes also argon and other rare inert gases. The most common method for air separation is fractional distillation. Cryogenic air ...
*
Cryogenic nitrogen plant A cryogenic gas plant is an industrial facility that creates molecular oxygen, molecular nitrogen, argon, krypton Helium and Xenon at relatively high purity. As air is made up of nitrogen, the most common gas in the atmosphere, at 78%, with Oxyge ...
*
Industrial gas Industrial gases are the gaseous materials that are manufactured for use in industry. The principal gases provided are nitrogen, oxygen, carbon dioxide, argon, hydrogen, helium and acetylene, although many other gases and mixtures are also avail ...
*
Timeline of low-temperature technology The following is a timeline of low-temperature technology and cryogenic technology (refrigeration down to –273.15 °C, –459.67 °F or 0 K). It also lists important milestones in thermometry, thermodynamics, statistical physics and ca ...
* German inventors and discoverers


References


Further reading

* Carl von Linde: "''Aus meinem Leben und von meiner Arbeit''" (Memoirs: "From my life and about my work"), first published 1916, reprinted by Springer 1984, . *


External links

*
Linde AG
' (Homepage) * {{DEFAULTSORT:Linde, Carl von 1842 births 1934 deaths Burials at Munich Waldfriedhof ETH Zurich alumni German company founders German industrialists German chemical industry people 19th-century German businesspeople 20th-century German businesspeople German mechanical engineers Engineers from Bavaria 19th-century German inventors Industrial gases People from the Kingdom of Bavaria People from Kulmbach (district) Technical University of Munich faculty Werner von Siemens Ring laureates Recipients of the Pour le Mérite (civil class) Linde plc people