Suess Effect
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Suess Effect
The Suess effect, also referred to as the 13C Suess effect, is a change in the ratio of the atmospheric concentrations of heavy isotopes of carbon (13C and 14C) by the wikt:admixture, admixture of large amounts of fossil-fuel derived CO2, which is depleted in 13CO2 and contains no 14CO2. It is named for the Austrian chemist Hans Suess, who noted the influence of this effect on the accuracy of radiocarbon dating. More recently, the Suess effect has been used in studies of climate change. The term originally referred only to dilution of atmospheric 14CO2. The concept was later extended to dilution of 13CO2 and to other reservoirs of carbon such as the oceans and soils. Carbon isotopes Carbon has three naturally occurring isotopes. About 99% of carbon on Earth is carbon-12 (Carbon-12, 12C), about 1% is carbon-13 (Carbon-13, 13C), and a trace amount is carbon-14 (Carbon-14, 14C). The 12C and 13C isotopes are stable, while 14C decays radioactively to nitrogen-14 (Nitrogen-14, 14N) wi ...
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Atmospheric
An atmosphere () is a layer of gas or layers of gases that envelop a planet, and is held in place by the gravity of the planetary body. A planet retains an atmosphere when the gravity is great and the temperature of the atmosphere is low. A stellar atmosphere is the outer region of a star, which includes the layers above the opacity (optics), opaque photosphere; stars of low temperature might have outer atmospheres containing compound molecules. The atmosphere of Earth is composed of nitrogen (78%), oxygen (21%), argon (0.9%), Carbon dioxide in Earth's atmosphere, carbon dioxide (0.04%) and trace gases. Most organisms use oxygen for respiration (physiology), respiration; lightning and bacteria perform nitrogen fixation to produce ammonia that is used to make nucleotides and amino acids; plants, algae, and cyanobacteria use carbon dioxide for photosynthesis. The layered composition of the atmosphere minimises the harmful effects of sunlight, ultraviolet radiation, the solar win ...
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Limited Test Ban Treaty
The Partial Test Ban Treaty (PTBT) is the abbreviated name of the 1963 Treaty Banning Nuclear Weapon Tests in the Atmosphere, in Outer Space and Under Water, which prohibited all test detonations of nuclear weapons except for those conducted underground. It is also abbreviated as the Limited Test Ban Treaty (LTBT) and Nuclear Test Ban Treaty (NTBT), though the latter may also refer to the Comprehensive Nuclear-Test-Ban Treaty (CTBT), which succeeded the PTBT for ratifying parties. Negotiations initially focused on a comprehensive ban, but that was abandoned because of technical questions surrounding the detection of underground tests and Soviet concerns over the intrusiveness of proposed verification methods. The impetus for the test ban was provided by rising public anxiety over the magnitude of nuclear tests, particularly tests of new thermonuclear weapons (hydrogen bombs), and the resulting nuclear fallout. A test ban was also seen as a means of slowing nuclear proliferation ...
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Petroleum
Petroleum, also known as crude oil, or simply oil, is a naturally occurring yellowish-black liquid mixture of mainly hydrocarbons, and is found in geological formations. The name ''petroleum'' covers both naturally occurring unprocessed crude oil and petroleum products that consist of refined crude oil. A fossil fuel, petroleum is formed when large quantities of dead organisms, mostly zooplankton and algae, are buried underneath sedimentary rock and subjected to both prolonged heat and pressure. Petroleum is primarily recovered by oil drilling. Drilling is carried out after studies of structural geology, sedimentary basin analysis, and reservoir characterisation. Recent developments in technologies have also led to exploitation of other unconventional reserves such as oil sands and oil shale. Once extracted, oil is refined and separated, most easily by distillation, into innumerable products for direct use or use in manufacturing. Products include fuels such as gasol ...
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Coal
Coal is a combustible black or brownish-black sedimentary rock, formed as rock strata called coal seams. Coal is mostly carbon with variable amounts of other elements, chiefly hydrogen, sulfur, oxygen, and nitrogen. Coal is formed when dead plant matter decays into peat and is converted into coal by the heat and pressure of deep burial over millions of years. Vast deposits of coal originate in former wetlands called coal forests that covered much of the Earth's tropical land areas during the late Carboniferous ( Pennsylvanian) and Permian times. Many significant coal deposits are younger than this and originate from the Mesozoic and Cenozoic eras. Coal is used primarily as a fuel. While coal has been known and used for thousands of years, its usage was limited until the Industrial Revolution. With the invention of the steam engine, coal consumption increased. In 2020, coal supplied about a quarter of the world's primary energy and over a third of its electricity. Some iron ...
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Carboniferous
The Carboniferous ( ) is a geologic period and system of the Paleozoic that spans 60 million years from the end of the Devonian Period million years ago ( Mya), to the beginning of the Permian Period, million years ago. The name ''Carboniferous'' means "coal-bearing", from the Latin '' carbō'' ("coal") and '' ferō'' ("bear, carry"), and refers to the many coal beds formed globally during that time. The first of the modern 'system' names, it was coined by geologists William Conybeare and William Phillips in 1822, based on a study of the British rock succession. The Carboniferous is often treated in North America as two geological periods, the earlier Mississippian and the later Pennsylvanian. Terrestrial animal life was well established by the Carboniferous Period. Tetrapods (four limbed vertebrates), which had originated from lobe-finned fish during the preceding Devonian, became pentadactylous in and diversified during the Carboniferous, including early amphibian line ...
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Lepidodendron
''Lepidodendron'' is an extinct genus of primitive vascular plants belonging to the family Lepidodendraceae, part of a group of Lycopodiopsida known as scale trees or arborescent lycophytes, related to Isoetes, quillworts and Lycopodiopsida, lycopsids (club mosses). They were part of the coal forest flora. They sometimes reached heights of , and the trunks were often over in diameter. They thrived during the Carboniferous Period (358.9 to 298.9 million years ago). Sometimes erroneously called "giant club mosses", the genus was actually more closely related to modern quillworts than to modern club mosses. Within the form classification system used within paleobotany, ''Lepidodendron'' is both used for the whole plant as well as specifically the stems and leaves. Etymology The name ''Lepidodendron'' comes from the Greek language, Greek wikt:λεπίς, λεπίς ', scale, and wikt:δένδρον, δένδρον ''dendron'', tree. Growth During the early stages of growth, ''L ...
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Isoetes
''Isoetes'', commonly known as the quillworts, is the only extant genus of plants in the family Isoetaceae, which is in the class of lycopods. There are currently 192 recognized species, with a cosmopolitan distribution but with the individual species often scarce to rare. Some botanists split the genus, separating two South American species into the genus ''Stylites'', although molecular data place these species among other species of ''Isoetes'', so that ''Stylites'' does not warrant taxonomic recognition. Species of ''Isoetes'' virtually identical to modern forms have existed since the Jurassic epoch. The name of the genus may also be spelled ''Isoëtes''. The diaeresis (two dots over the e) indicates that the o and the e are to be pronounced in two distinct syllables. Including this in print is optional; either spelling (''Isoetes'' or ''Isoëtes'') is correct. Description Quillworts are mostly aquatic or semi-aquatic in clear ponds and slow-moving streams, though several ( ...
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Crassulacean Acid Metabolism
Crassulacean acid metabolism, also known as CAM photosynthesis, is a carbon fixation pathway that evolved in some plants as an adaptation to arid conditions that allows a plant to photosynthesize during the day, but only exchange gases at night. In a plant using full CAM, the stomata in the leaves remain shut during the day to reduce evapotranspiration, but they open at night to collect carbon dioxide () and allow it to diffuse into the mesophyll cells. The is stored as four-carbon malic acid in vacuoles at night, and then in the daytime, the malate is transported to chloroplasts where it is converted back to , which is then used during photosynthesis. The pre-collected is concentrated around the enzyme RuBisCO, increasing photosynthetic efficiency. This mechanism of acid metabolism was first discovered in plants of the family Crassulaceae. Historical background Observations relating to CAM were first made by de Saussure in 1804 in his ''Recherches Chimiques sur la Végétatio ...
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C3 Carbon Fixation
carbon fixation is the most common of three metabolic pathways for carbon fixation in photosynthesis, along with and CAM. This process converts carbon dioxide and ribulose bisphosphate (RuBP, a 5-carbon sugar) into two molecules of 3-phosphoglycerate through the following reaction: :CO2 + H2O + RuBP → (2) 3-phosphoglycerate This reaction was first discovered by Melvin Calvin, Andrew Benson and James Bassham in 1950. C3 carbon fixation occurs in all plants as the first step of the Calvin–Benson cycle. (In and CAM plants, carbon dioxide is drawn out of malate and into this reaction rather than directly from the air.) Plants that survive solely on fixation ( plants) tend to thrive in areas where sunlight intensity is moderate, temperatures are moderate, carbon dioxide concentrations are around 200 ppm or higher, and groundwater is plentiful. The plants, originating during Mesozoic and Paleozoic eras, predate the plants and still represent approximately 95% of Eart ...
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C4 Carbon Fixation
carbon fixation or the Hatch–Slack pathway is one of three known photosynthetic processes of carbon fixation in plants. It owes the names to the 1960's discovery by Marshall Davidson Hatch and Charles Roger Slack that some plants, when supplied with 14, incorporate the 14C label into four-carbon molecules first. fixation is an addition to the ancestral and more common carbon fixation. The main carboxylating enzyme in photosynthesis is called RuBisCO, which catalyses two distinct reactions using either (carboxylation) or oxygen (oxygenation) as a substrate. The latter process, oxygenation, gives rise to the wasteful process of photorespiration. photosynthesis reduces photorespiration by concentrating around RuBisCO. To ensure that RuBisCO works in an environment where there is a lot of carbon dioxide and very little oxygen, leaves generally differentiate two partially isolated compartments called mesophyll cells and bundle-sheath cells. is initially fixed in the ...
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Kinetic Isotope Effect
In physical organic chemistry, a kinetic isotope effect (KIE) is the change in the reaction rate of a chemical reaction when one of the atoms in the reactants is replaced by one of its isotopes. Formally, it is the ratio of rate constants for the reactions involving the light (''kL'') and the heavy (''kH'') isotopically substituted reactants (isotopologues): :\text=\frac This change in reaction rate is a quantum mechanical effect that primarily results from heavier isotopologues having lower vibrational frequencies compared to their lighter counterparts. In most cases, this implies a greater energetic input needed for heavier isotopologues to reach the transition state (or, in rare cases, the dissociation limit), and consequently, a slower reaction rate. The study of kinetic isotope effects can help the elucidation of the reaction mechanism of certain chemical reactions and is occasionally exploited in drug development to improve unfavorable pharmacokinetics by protecting m ...
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Fractionation Of Carbon Isotopes In Oxygenic Photosynthesis
Photosynthesis converts carbon dioxide to carbohydrates via several metabolic pathways that provide energy to an organism and preferentially react with certain stable isotopes of carbon. The selective enrichment of one stable isotope over another creates distinct isotopic fractionations that can be measured and correlated among oxygenic phototrophs. The degree of carbon isotope fractionation is influenced by several factors, including the metabolism, anatomy, growth rate, and environmental conditions of the organism. Understanding these variations in carbon fractionation across species is useful for biogeochemical studies, including the reconstruction of paleoecology, plant evolution, and the characterization of food chains. Oxygenic photosynthesis is a metabolic pathway facilitated by autotrophs, including plants, algae, and cyanobacteria. This pathway converts inorganic carbon dioxide from the atmosphere or aquatic environment into carbohydrates, using water and energy from ligh ...
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