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Spiegeleisen
Spiegeleisen (literally "mirror-iron", —mirror or specular; —iron) is a ferromanganese alloy containing approximately 15% manganese and small quantities of carbon and silicon. Spiegeleisen is sometimes also referred to as ''specular pig iron'', ''Spiegel iron'', just ''Spiegel'', or ''Bisalloy''. Usage Historically, this was the standard form in which manganese was traded and used in steel making. Manganese is useful in steel manufacture because it binds with phosphorus, sulfur, and silica, removing them (to a degree) from the iron. It was much used in conjunction with the Bessemer process both to introduce carbon and manganese, and also to reduce impurities. Manufacture In the 19th-century spiegeleisen was made either by mixing iron ores with appropriate levels of manganese and smelting them directly, or by adding pyrolusite or manganite Manganite is a mineral composed of manganese oxide-hydroxide, MnO(OH), crystallizing in the monoclinic system (pseudo-orthorhombic). ...
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Manganese
Manganese is a chemical element; it has Symbol (chemistry), symbol Mn and atomic number 25. It is a hard, brittle, silvery metal, often found in minerals in combination with iron. Manganese was first isolated in the 1770s. It is a transition metal with a multifaceted array of industrial alloy uses, particularly in stainless steels. It improves strength, workability, and resistance to wear. Manganese oxide is used as an oxidising agent, as a rubber additive, and in glass making, fertilisers, and ceramics. Manganese sulfate can be used as a fungicide. Manganese is also an essential human dietary element, important in macronutrient metabolism, bone formation, and free radical defense systems. It is a critical component in dozens of proteins and enzymes. It is found mostly in the bones, but also the liver, kidneys, and brain. In the human brain, the manganese is bound to manganese metalloproteins, most notably glutamine synthetase in astrocytes. Manganese is commonly found in labo ...
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Ferromanganese
Ferromanganese is an alloy of iron and manganese, with other elements such as silicon, carbon, sulfur, nitrogen and phosphorus. The primary use of ferromanganese is as a type of processed manganese source to add to different types of steel, such as stainless steel. Global production of low-carbon ferromanganese (i.e. alloys with less than 2% carbon content) reached 1.5 megatons in 2010. Physical and chemical properties The properties of ferromanganese vary considerably with the precise type and composition of the alloy. The melting point is generally between and . The density of the alloy depend slightly on the types of impurities present, but is generally around . Production Sources of manganese ore generally also contain iron oxides. As manganese has a more negative free energy of oxidation than iron, i.e. is chemically harder to reduce, during the reduction of manganese ore, iron is also reduced and mixed with the manganese in the melt. This is unlike other oxides such a ...
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Sulfur
Sulfur ( American spelling and the preferred IUPAC name) or sulphur ( Commonwealth spelling) is a chemical element; it has symbol S and atomic number 16. It is abundant, multivalent and nonmetallic. Under normal conditions, sulfur atoms form cyclic octatomic molecules with the chemical formula S8. Elemental sulfur is a bright yellow, crystalline solid at room temperature. Sulfur is the tenth most abundant element by mass in the universe and the fifth most common on Earth. Though sometimes found in pure, native form, sulfur on Earth usually occurs as sulfide and sulfate minerals. Being abundant in native form, sulfur was known in ancient times, being mentioned for its uses in ancient India, ancient Greece, China, and ancient Egypt. Historically and in literature sulfur is also called brimstone, which means "burning stone". Almost all elemental sulfur is produced as a byproduct of removing sulfur-containing contaminants from natural gas and petroleum.. Downloahere Th ...
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Spathic Iron Ore
Siderite is a mineral composed of iron(II) carbonate (FeCO3). Its name comes from the Ancient Greek word (), meaning "iron". A valuable iron ore, it consists of 48% iron and lacks sulfur and phosphorus. Zinc, magnesium, and manganese commonly substitute for the iron, resulting in the siderite-smithsonite, siderite-magnesite, and siderite-rhodochrosite solid solution series. Siderite has Mohs hardness of 3.75 to 4.25, a specific gravity of 3.96, a white streak and a vitreous or pearly luster. Siderite is antiferromagnetic below its Néel temperature of that can assist in its identification. It crystallizes in the trigonal crystal system; crystals are rhombohedral in shape, typically with curved and striated faces. It also occurs in masses. Color ranges from yellow to dark brown or black, the latter being due to the presence of manganese. Siderite is commonly found in hydrothermal veins, and is associated with barite, fluorite, galena, and others. It is also a common diagen ...
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Cupola Furnace
A cupola or cupola furnace is a melting device used in foundries that can be used to melt cast iron, Ni-resist iron and some bronzes. The cupola can be made almost any practical size. The size of a cupola is expressed in diameters and can range from . The overall shape is cylindrical and the equipment is arranged vertically, usually supported by four legs. The overall look is similar to a large smokestack. The bottom of the cylinder is fitted with doors which swing down and out to 'drop bottom'. The top where gases escape can be open or fitted with a cap to prevent rain from entering the cupola. To control emissions a cupola may be fitted with a cap that is designed to pull the gases into a device to cool the gases and remove particulate matter. The shell of the cupola, being usually made of steel, has refractory brick and plastic refractory patching material lining it. The bottom is lined in a similar manner but often a clay and sand mixture ("bod") may be used, as this lin ...
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Manganite
Manganite is a mineral composed of manganese oxide-hydroxide, MnO(OH), crystallizing in the monoclinic system (pseudo-orthorhombic). Crystals of manganite are prismatic and deeply striated parallel to their length; they are often grouped together in bundles. The color is dark steel-grey to iron-black, and the Lustre (mineralogy), luster brilliant and submetallic. The streak is dark reddish brown. The Mohs hardness, hardness is 4, and the specific gravity is 4.3. There is a perfect cleavage parallel to the brachypinacoid, and less-perfect cleavage parallel to the prism faces. Crystal twinning, Twinned crystals are not infrequent. The mineral contains 89.7% manganese sesquioxide; it dissolves in hydrochloric acid with evolution of chlorine. Occurrence Manganite occurs with other manganese oxides in deposits formed by circulating meteoric water in the weathering environment in Clay mineral, clay deposits and laterites. It forms by low temperature hydrothermal action in Vein (geolo ...
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Pyrolusite
Pyrolusite is a mineral consisting essentially of manganese dioxide ( Mn O2) and is important as an ore of manganese.. It is a black, amorphous appearing mineral, often with a granular, fibrous, or columnar structure, sometimes forming reniform crusts. It has a metallic luster, a black or bluish-black streak, and readily soils the fingers. The specific gravity is about 4.8. Its name is from the Greek for ''fire'' and to ''wash'', in reference to its use as a way to remove tints from glass. Occurrence Pyrolusite and romanechite are among the most common manganese minerals. Pyrolusite occurs associated with manganite, hollandite, hausmannite, braunite, cryptomelane, chalcophanite, goethite, and hematite under oxidizing conditions in hydrothermal deposits. It also occurs in bogs and often results from alteration of manganite. Use The metal is obtained by reduction of the oxide with sodium, magnesium, aluminium, or by electrolysis. Pyrolusite is extensively used for the ...
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Bessemer Process
The Bessemer process was the first inexpensive industrial process for the mass production of steel from molten pig iron before the development of the open hearth furnace. The key principle is steelmaking, removal of impurities and undesired elements, primarily excess carbon contained in the pig iron by oxidation with air being blown through the molten iron. Oxidation of the excess carbon also raises the temperature of the iron mass and keeps it molten. Virtually all the pig iron carbon is removed by the converter and so carbon must be added at the end of the process to create steel, 0.25% carbon content is a typical value for low carbon steel which is used in construction and other low-stress applications. The modern process is named after its inventor, the Englishman Henry Bessemer, who took out a patent on the process in 1856. The process was said to be independently discovered in 1851 by the American inventor William Kelly (inventor), William Kelly though the claim is con ...
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Silica
Silicon dioxide, also known as silica, is an oxide of silicon with the chemical formula , commonly found in nature as quartz. In many parts of the world, silica is the major constituent of sand. Silica is one of the most complex and abundant families of materials, existing as a compound of several minerals and as a synthetic product. Examples include fused quartz, fumed silica, opal, and aerogels. It is used in structural materials, microelectronics, and as components in the food and pharmaceutical industries. All forms are white or colorless, although impure samples can be colored. Silicon dioxide is a common fundamental constituent of glass. Structure In the majority of silicon dioxides, the silicon atom shows Tetrahedral molecular geometry, tetrahedral coordination, with four oxygen atoms surrounding a central Si atomsee 3-D Unit Cell. Thus, SiO2 forms 3-dimensional network solids in which each silicon atom is covalently bonded in a tetrahedral manner to 4 oxygen atoms. ...
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Steel Making
Steelmaking is the process of producing steel from iron ore and/or scrap. Steel has been made for millennia, and was commercialized on a massive scale in the 1850s and 1860s, using the Bessemer and Siemens-Martin processes. Currently, two major commercial processes are used. Basic oxygen steelmaking (BOS) uses liquid pig-iron from a blast furnace and scrap steel as the main feed materials. Electric arc furnace (EAF) steelmaking uses scrap steel or direct reduced iron (DRI). Oxygen steelmaking has become more popular over time. Steelmaking is one of the most carbon emission-intensive industries. In 2020, the steelmaking industry was reported to be responsible for 7% of energy sector greenhouse gas emissions. The industry is seeking significant emission reductions. Steel Steel is made from iron and carbon. Cast iron is a hard, brittle material that is difficult to work, whereas steel is malleable, relatively easily formed and versatile. On its own, iron is not strong, but ...
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Phosphorus
Phosphorus is a chemical element; it has Chemical symbol, symbol P and atomic number 15. All elemental forms of phosphorus are highly Reactivity (chemistry), reactive and are therefore never found in nature. They can nevertheless be prepared artificially, the two most common allotropes being white phosphorus and red phosphorus. With as its only stable isotope, phosphorus has an occurrence in Earth's crust of about 0.1%, generally as phosphate rock. A member of the pnictogen family, phosphorus readily forms a wide variety of organic compound, organic and inorganic compound, inorganic compounds, with as its main oxidation states +5, +3 and −3. The isolation of white phosphorus in 1669 by Hennig Brand marked the scientific community's first discovery since Antiquity of an element. The name phosphorus is a reference to the Phosphorus (morning star), god of the Morning star in Greek mythology, inspired by the faint glow of white phosphorus when exposed to oxygen. This property is ...
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