Siderite is a
mineral
In geology and mineralogy, a mineral or mineral species is, broadly speaking, a solid chemical compound with a fairly well-defined chemical composition and a specific crystal structure that occurs naturally in pure form.John P. Rafferty, ed. ( ...
composed of
iron(II) carbonate
Iron(II) carbonate, or ferrous carbonate, is a chemical compound with formula , that occurs naturally as the mineral siderite. At ordinary ambient temperatures, it is a green-brown ionic solid consisting of iron(II) cations and carbonate anions ...
(FeCO
3). It takes its name from the Greek word σίδηρος ''sideros,'' "iron". It is a valuable iron mineral, since it is 48% iron and contains no
sulfur
Sulfur (or sulphur in British English) is a chemical element with the symbol S and atomic number 16. It is abundant, multivalent and nonmetallic. Under normal conditions, sulfur atoms form cyclic octatomic molecules with a chemical formula ...
or
phosphorus
Phosphorus is a chemical element with the symbol P and atomic number 15. Elemental phosphorus exists in two major forms, white phosphorus and red phosphorus, but because it is highly reactive, phosphorus is never found as a free element on Ear ...
.
Zinc
Zinc is a chemical element with the symbol Zn and atomic number 30. Zinc is a slightly brittle metal at room temperature and has a shiny-greyish appearance when oxidation is removed. It is the first element in group 12 (IIB) of the periodi ...
,
magnesium
Magnesium is a chemical element with the symbol Mg and atomic number 12. It is a shiny gray metal having a low density, low melting point and high chemical reactivity. Like the other alkaline earth metals (group 2 of the periodic ta ...
and
manganese
Manganese is a chemical element with the symbol Mn and atomic number 25. It is a hard, brittle, silvery metal, often found in minerals in combination with iron. Manganese is a transition metal with a multifaceted array of industrial alloy use ...
commonly substitute for the iron resulting in the siderite-
smithsonite
Smithsonite, also known as zinc spar, is the mineral form of zinc carbonate ( Zn CO3). Historically, smithsonite was identified with hemimorphite before it was realized that they were two different minerals. The two minerals are very similar in app ...
, siderite-
magnesite
Magnesite is a mineral with the chemical formula (magnesium carbonate). Iron, manganese, cobalt, and nickel may occur as admixtures, but only in small amounts.
Occurrence
Magnesite occurs as veins in and an alteration product of ultramafic ro ...
and siderite-
rhodochrosite
Rhodochrosite is a manganese carbonate mineral with chemical composition MnCO3. In its (rare) pure form, it is typically a rose-red color, but impure specimens can be shades of pink to pale brown. It streaks white, and its Mohs hardness varies bet ...
solid solution
A solid solution, a term popularly used for metals, is a homogenous mixture of two different kinds of atoms in solid state and have a single crystal structure. Many examples can be found in metallurgy, geology, and solid-state chemistry. The word ...
series.
[
Siderite has ]Mohs hardness
The Mohs scale of mineral hardness () is a qualitative ordinal scale, from 1 to 10, characterizing scratch resistance of various minerals through the ability of harder material to scratch softer material.
The scale was introduced in 1812 by th ...
of 3.75-4.25, a specific gravity
Relative density, or specific gravity, is the ratio of the density (mass of a unit volume) of a substance to the density of a given reference material. Specific gravity for liquids is nearly always measured with respect to water (molecule), wa ...
of 3.96, a white streak and a vitreous lustre
Lustre (British English) or luster (American English; see spelling differences) is the way light interacts with the surface of a crystal, rock, or mineral. The word traces its origins back to the Latin ''lux'', meaning "light", and generally imp ...
or pearly luster. Siderite is antiferromagnetic
In materials that exhibit antiferromagnetism, the magnetic moments of atoms or molecules, usually related to the spins of electrons, align in a regular pattern with neighboring spins (on different sublattices) pointing in opposite directions. ...
below its Néel temperature
In physics and materials science, the Curie temperature (''T''C), or Curie point, is the temperature above which certain materials lose their permanent magnetic properties, which can (in most cases) be replaced by induced magnetism. The Cur ...
of 37 K which can assist in its identification.
It crystallizes in the trigonal crystal system
In crystallography, the hexagonal crystal family is one of the six crystal families, which includes two crystal systems (hexagonal and trigonal) and two lattice systems (hexagonal and rhombohedral). While commonly confused, the trigonal crystal ...
, and are rhombohedral
In geometry, a rhombohedron (also called a rhombic hexahedron or, inaccurately, a rhomboid) is a three-dimensional figure with six faces which are rhombus, rhombi. It is a special case of a parallelepiped where all edges are the same length. It c ...
in shape, typically with curved and striated faces. It also occurs in masses. Color ranges from yellow to dark brown or black, the latter being due to the presence of manganese.
Siderite is commonly found in hydrothermal
Hydrothermal circulation in its most general sense is the circulation of hot water (Ancient Greek ὕδωρ, ''water'',Liddell, H.G. & Scott, R. (1940). ''A Greek-English Lexicon. revised and augmented throughout by Sir Henry Stuart Jones. with th ...
veins
Veins are blood vessels in humans and most other animals that carry blood towards the heart. Most veins carry deoxygenated blood from the tissues back to the heart; exceptions are the pulmonary and umbilical veins, both of which carry oxygenated b ...
, and is associated with barite
Baryte, barite or barytes ( or ) is a mineral consisting of barium sulfate ( Ba S O4). Baryte is generally white or colorless, and is the main source of the element barium. The ''baryte group'' consists of baryte, celestine (strontium sulfate), ...
, fluorite
Fluorite (also called fluorspar) is the mineral form of calcium fluoride, CaF2. It belongs to the halide minerals. It crystallizes in isometric cubic habit, although octahedral and more complex isometric forms are not uncommon.
The Mohs sca ...
, galena
Galena, also called lead glance, is the natural mineral form of lead(II) sulfide (PbS). It is the most important ore of lead and an important source of silver.
Galena is one of the most abundant and widely distributed sulfide minerals. It cryst ...
, and others. It is also a common diagenetic
Diagenesis () is the process that describes physical and chemical changes in sediments first caused by water-rock interactions, microbial activity, and compaction after their deposition. Increased pressure and temperature only start to play a ...
mineral in shale
Shale is a fine-grained, clastic sedimentary rock formed from mud that is a mix of flakes of clay minerals (hydrous aluminium phyllosilicates, e.g. kaolin, Al2 Si2 O5( OH)4) and tiny fragments (silt-sized particles) of other minerals, especial ...
s and sandstone
Sandstone is a clastic sedimentary rock composed mainly of sand-sized (0.0625 to 2 mm) silicate grains. Sandstones comprise about 20–25% of all sedimentary rocks.
Most sandstone is composed of quartz or feldspar (both silicates) ...
s, where it sometimes forms concretion
A concretion is a hard, compact mass of matter formed by the precipitation of mineral cement within the spaces between particles, and is found in sedimentary rock or soil. Concretions are often ovoid or spherical in shape, although irregular ...
s, which can encase three-dimensionally preserved fossils
A fossil (from Classical Latin , ) is any preserved remains, impression, or trace of any once-living thing from a past geological age. Examples include bones, shells, exoskeletons, stone imprints of animals or microbes, objects preserved in ...
. In sedimentary rock
Sedimentary rocks are types of rock that are formed by the accumulation or deposition of mineral or organic particles at Earth's surface, followed by cementation. Sedimentation is the collective name for processes that cause these particles ...
s, siderite commonly forms at shallow burial depths and its elemental composition is often related to the depositional environment
In geology, depositional environment or sedimentary environment describes the combination of physical, chemical, and biological processes associated with the deposition of a particular type of sediment and, therefore, the rock types that will be ...
of the enclosing sediments. In addition, a number of recent studies have used the oxygen isotopic composition of sphaerosiderite (a type associated with soil
Soil, also commonly referred to as earth or dirt, is a mixture of organic matter, minerals, gases, liquids, and organisms that together support life. Some scientific definitions distinguish ''dirt'' from ''soil'' by restricting the former te ...
s) as a proxy
Proxy may refer to:
* Proxy or agent (law), a substitute authorized to act for another entity or a document which authorizes the agent so to act
* Proxy (climate), a measured variable used to infer the value of a variable of interest in climate ...
for the isotopic composition of meteoric water
Meteoric water is the water derived from precipitation (snow and rain). This includes water from lakes, rivers, and icemelts, which all originate from precipitation indirectly. While the bulk of rainwater or meltwater from snow and ice reaches the ...
shortly after deposition.
Spathic iron ore
Although spathic (carbonate) iron ores, such as siderite, have been economically important for steel production, they are far from ideal as an ore.
Their hydrothermal mineralisation tends to form them as small ore lenses, often following steeply dipping bedding plane
In geology, a bed is a layer of sediment, sedimentary rock, or pyroclastic material "bounded above and below by more or less well-defined bedding surfaces".Neuendorf, K.K.E., J.P. Mehl, Jr., and J.A. Jackson, eds., 2005. ''Glossary of Geology'' ...
s. This makes them not amenable to opencast working, and increases the cost of working them by mining with horizontal stopes. As the individual ore bodies are small, it may also be necessary to duplicate or relocate the pit head machinery, winding engine
A winding engine is a stationary engine used to control a cable, for example to power a mining hoist at a pit head. Electric hoist controllers have replaced proper winding engines in modern mining, but use electric motors that are also tradition ...
and pumping engine, between these bodies as each is worked out. This makes mining the ore an expensive proposition compared to typical ironstone
Ironstone is a sedimentary rock, either deposited directly as a ferruginous sediment or created by chemical replacement, that contains a substantial proportion of an iron ore compound from which iron (Fe) can be smelted commercially. Not to be con ...
or haematite
Hematite (), also spelled as haematite, is a common iron oxide compound with the formula, Fe2O3 and is widely found in rocks and soils. Hematite crystals belong to the rhombohedral lattice system which is designated the alpha polymorph of . ...
opencasts.
The recovered ore also has drawbacks. The carbonate ore is more difficult to smelt
Smelt may refer to:
* Smelting, chemical process
* The common name of various fish:
** Smelt (fish), a family of small fish, Osmeridae
** Australian smelt in the family Retropinnidae and species ''Retropinna semoni''
** Big-scale sand smelt ''At ...
than a haematite or other oxide ore. Driving off the carbonate as carbon dioxide requires more energy and so the ore 'kills' the blast furnace
A blast furnace is a type of metallurgical furnace used for smelting to produce industrial metals, generally pig iron, but also others such as lead or copper. ''Blast'' refers to the combustion air being "forced" or supplied above atmospheric ...
if added directly. Instead the ore must be given a preliminary roasting step. Developments of specific techniques to deal with these ores began in the early 19th century, largely with the work of Sir Thomas Lethbridge in Somerset
( en, All The People of Somerset)
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. His 'Iron Mill' of 1838 used a three-chambered concentric roasting furnace, before passing the ore to a separate reducing furnace for smelting. Details of this Mill were the invention of Charles Sanderson, a steel maker of Sheffield, who held the patent for it.
These differences between spathic ore and haematite have led to the failure of a number of mining concerns, notably the Brendon Hills Iron Ore Company.
Spathic iron ores are rich in manganese and have negligible phosphorus. This led to their one major benefit, connected with the Bessemer steel-making process. Although the first demonstrations by Bessemer in 1856 had been successful, later attempts to reproduce this were infamously failures. Work by the metallurgist Robert Forester Mushet
Robert Forester Mushet (8 April 1811 – 29 January 1891) was a British metallurgist and businessman, born on 8 April 1811, in Coleford, in the Forest of Dean, Gloucestershire, England. He was the youngest son of Scottish parents, Agnes Wilson ...
discovered that the reason for this was the nature of the Swedish ores that Bessemer had innocently used, being very low in phosphorus. Using a typical European high-phosphorus ore in Bessemer's converter gave a poor quality steel. To produce high quality steel from a high-phosphorus ore, Mushet realised that he could operate the Bessemer converter for longer, burning off all the steel's impurities including the unwanted phosphorus and the essential carbon, but then re-adding carbon, with manganese, in the form of a previously obscure ferromanganese ore with no phosphorus, spiegeleisen
Spiegeleisen (literally "mirror-iron", —mirror or specular; —iron) is a ferromanganese alloy containing approximately 15% manganese and small quantities of carbon and silicon. Spiegeleisen is sometimes also referred to as ''specular pig iron' ...
. This created a sudden demand for spiegeleisen. Although it was not available in sufficient quantity as a mineral, steelworks such as that at Ebbw Vale
Ebbw Vale (; cy, Glynebwy) is a town at the head of the valley formed by the Ebbw Fawr tributary of the Ebbw River in Wales. It is the largest town and the administrative centre of Blaenau Gwent county borough. The Ebbw Vale and Brynmawr con ...
in South Wales soon learned to make it from the spathic siderite ores. For a few decades, spathic ores were now in demand and this encouraged their mining. In time though, the original 'acidic' liner, made from siliceous sandstone or ganister
A ganister (or sometimes gannister ) is hard, fine-grained quartzose sandstone, or orthoquartzite,Jackson, J. A., 1997, ''Glossary of geology'', 4th ed. American Geological Institute, Alexandria. used in the manufacture of silica brick typically ...
, of the Bessemer converter was replaced by a 'basic' liner in the developed Gilchrist Thomas process. This removed the phosphorus impurities as slag
Slag is a by-product of smelting (pyrometallurgical) ores and used metals. Broadly, it can be classified as ferrous (by-products of processing iron and steel), ferroalloy (by-product of ferroalloy production) or non-ferrous/base metals (by-prod ...
, produced by chemical reaction with the liner, and no longer required spiegeleisen. From the 1880s demand for the ores fell once again and many of their mines, including those of the Brendon Hills
The Brendon Hills are a range of hills in west Somerset, England. The hills merge level into the eastern side of Exmoor and are included within the Exmoor National Park. The highest point of the range is Lype Hill at above sea level with a secon ...
, closed soon after.
Gallery
Siderite late 1800s Redruth.jpg, Siderite - Redruth
Redruth ( , kw, Resrudh) is a town and civil parishes in Cornwall, civil parish in Cornwall, England. The population of Redruth was 14,018 at the 2011 census. In the same year the population of the Camborne-Redruth urban area, which also inc ...
, Cornwall, England
Galena-Quartz-Siderite-oldeuro-56c.jpg, Siderite crystals with galena and quartz (size: 6.2 x 4.1 x 3.6 cm)
Chalcopyrite-Siderite-gha7a.jpg, Disc-shaped, brown siderite crystals perched upon chalcopyrites
SideriteTaillée.jpg, Cut siderite from Minas Gerais, Brazil (size : 5 x 3.2 mm)
Siderite-64328.jpg, Colorado siderite, with sharp blades of olive-brown and minor accenting quartz
Siderite Concretion Carboniferous.JPG, Fossiliferous siderite concretion from the Lower Carboniferous.
Notes
References
{{Commons category, Siderite
Iron(II) minerals
Carbonate minerals
Calcite group
Carbonates
Trigonal minerals
Minerals in space group 167
Iron ores