Manganite is a

mineral In geology and mineralogy, a mineral or mineral species is, broadly speaking, a solid chemical compound with a fairly well-defined chemical composition and a specific crystal structure that occurs naturally in pure form.John P. Rafferty, ed. ( ...

composed of

manganese Manganese is a chemical element with the symbol Mn and atomic number 25. It is a hard, brittle, silvery metal, often found in minerals in combination with iron. Manganese is a transition metal with a multifaceted array of industrial alloy use ...

oxide An oxide () is a chemical compound that contains at least one oxygen atom and one other element in its chemical formula. "Oxide" itself is the dianion of oxygen, an O2– (molecular) ion. with oxygen in the oxidation state of −2. Most of the E ...

hydroxide Hydroxide is a diatomic anion with chemical formula OH−. It consists of an oxygen and hydrogen atom held together by a single covalent bond, and carries a negative electric charge. It is an important but usually minor constituent of water. I ...

, MnO(OH), crystallizing in the

monoclinic In crystallography, the monoclinic crystal system is one of the seven crystal systems. A crystal system is described by three vectors. In the monoclinic system, the crystal is described by vectors of unequal lengths, as in the orthorhombic s ...

system (pseudo-

orthorhombic In crystallography, the orthorhombic crystal system is one of the 7 crystal systems. Orthorhombic lattices result from stretching a cubic lattice along two of its orthogonal pairs by two different factors, resulting in a rectangular prism with a r ...

). Crystals of manganite are prismatic and deeply striated parallel to their length; they are often grouped together in bundles. The color is dark steel-grey to iron-black, and the luster brilliant and submetallic. The streak is dark reddish brown. The

hardness In materials science, hardness (antonym: softness) is a measure of the resistance to localized plastic deformation induced by either mechanical indentation or abrasion. In general, different materials differ in their hardness; for example hard ...

is 4, and the

specific gravity Relative density, or specific gravity, is the ratio of the density (mass of a unit volume) of a substance to the density of a given reference material. Specific gravity for liquids is nearly always measured with respect to water (molecule), wa ...

is 4.3. There is a perfect cleavage parallel to the brachypinacoid, and less-perfect cleavage parallel to the prism faces. Twinned crystals are not infrequent. The mineral contains 89.7% manganese sesquioxide; it dissolves in

hydrochloric acid Hydrochloric acid, also known as muriatic acid, is an aqueous solution of hydrogen chloride. It is a colorless solution with a distinctive pungent smell. It is classified as a strong acid Acid strength is the tendency of an acid, symbol ...

with evolution of

chlorine Chlorine is a chemical element with the Symbol (chemistry), symbol Cl and atomic number 17. The second-lightest of the halogens, it appears between fluorine and bromine in the periodic table and its properties are mostly intermediate betwee ...

Occurrence

Manganite occurs with other manganese oxides in deposits formed by circulating

meteoric water Meteoric water is the water derived from precipitation (snow and rain). This includes water from lakes, rivers, and icemelts, which all originate from precipitation indirectly. While the bulk of rainwater or meltwater from snow and ice reaches the ...

in the weathering environment in

clay Clay is a type of fine-grained natural soil material containing clay minerals (hydrous aluminium phyllosilicates, e.g. kaolin, Al2 Si2 O5( OH)4). Clays develop plasticity when wet, due to a molecular film of water surrounding the clay par ...

deposits and

laterite Laterite is both a soil and a rock type rich in iron and aluminium and is commonly considered to have formed in hot and wet tropical areas. Nearly all laterites are of rusty-red coloration, because of high iron oxide content. They develop by ...

s. It forms by low temperature

hydrothermal Hydrothermal circulation in its most general sense is the circulation of hot water (Ancient Greek ὕδωρ, ''water'',Liddell, H.G. & Scott, R. (1940). ''A Greek-English Lexicon. revised and augmented throughout by Sir Henry Stuart Jones. with th ...

action in

veins Veins are blood vessels in humans and most other animals that carry blood towards the heart. Most veins carry deoxygenated blood from the tissues back to the heart; exceptions are the pulmonary and umbilical veins, both of which carry oxygenated b ...

in association with

calcite Calcite is a Carbonate minerals, carbonate mineral and the most stable Polymorphism (materials science), polymorph of calcium carbonate (CaCO3). It is a very common mineral, particularly as a component of limestone. Calcite defines hardness 3 on ...

barite Baryte, barite or barytes ( or ) is a mineral consisting of barium sulfate ( Ba S O4). Baryte is generally white or colorless, and is the main source of the element barium. The ''baryte group'' consists of baryte, celestine (strontium sulfate), ...

, and

siderite Siderite is a mineral composed of iron(II) carbonate (FeCO3). It takes its name from the Greek word σίδηρος ''sideros,'' "iron". It is a valuable iron mineral, since it is 48% iron and contains no sulfur or phosphorus. Zinc, magnesium and ...

. Often associated with

pyrolusite Pyrolusite is a mineral consisting essentially of manganese dioxide ( Mn O2) and is important as an ore of manganese.. It is a black, amorphous appearing mineral, often with a granular, fibrous, or columnar structure, sometimes forming reniform ...

braunite Braunite is a silicate mineral containing both di- and tri- valent manganese with the chemical formula: Mn2+Mn3+6 SiO4 Common impurities include iron, calcium, boron, barium, titanium, aluminium, and magnesium. Braunite forms grey/black tetragon ...

hausmannite Hausmannite is a complex oxide of manganese containing both di- and tri-valent manganese. The formula can be represented as Mn2+Mn3+2O4. It belongs to the spinel group and forms tetragonal crystals. Hausmannite is a brown to black metallic minera ...

and

goethite Goethite (, ) is a mineral of the diaspore group, consisting of iron(III) oxide-hydroxide, specifically the "α" polymorph. It is found in soil and other low-temperature environments such as sediment. Goethite has been well known since ancient t ...

. Manganite occurs in specimens exhibiting good crystal form at

Ilfeld Ilfeld is a village and a former municipality in the district of Nordhausen, in Thuringia, Germany. It is situated at the south foot of the Harz, at the entrance to the Bährethal, north from Nordhausen by the railway to Wernigerode. Since 1 Ja ...

in the

Harz Mountains The Harz () is a highland area in northern Germany. It has the highest elevations for that region, and its rugged terrain extends across parts of Lower Saxony, Saxony-Anhalt, and Thuringia. The name ''Harz'' derives from the Middle High German ...

Germany Germany,, officially the Federal Republic of Germany, is a country in Central Europe. It is the second most populous country in Europe after Russia, and the most populous member state of the European Union. Germany is situated betwe ...

, where the mineral occurs with calcite and barite in veins traversing porphyry. Crystals have also been found at Ilmenau in

Thuringia Thuringia (; german: Thüringen ), officially the Free State of Thuringia ( ), is a state of central Germany, covering , the sixth smallest of the sixteen German states. It has a population of about 2.1 million. Erfurt is the capital and larg ...

, Neukirch near

Sélestat Sélestat (; Alsatian: ''Schlettstàdt''; German: ''Schlettstadt'') is a commune in the Grand Est region of France. An administrative division (Subprefectures in France, sous-préfecture) of the Bas-Rhin Departments of France, department, the tow ...

Alsace Alsace (, ; ; Low Alemannic German/ gsw-FR, Elsàss ; german: Elsass ; la, Alsatia) is a cultural region and a territorial collectivity in eastern France, on the west bank of the upper Rhine next to Germany and Switzerland. In 2020, it had ...

(newkirkite), Granam near

Towie ''The Only Way Is Essex'' (often abbreviated as ''TOWIE'' ) is a British reality television series based in Brentwood, Essex, England. It shows "real people in modified situations, saying unscripted lines but in a structured way." Originally ...

in Aberdeenshire, and in

Upton Pyne Upton Pyne is a parish and village in Devon, England. The parish lies just north west of Exeter, mainly between the River Exe and River Creedy. The village is located north of Cowley and west of Brampford Speke and Stoke Canon. It has a populat ...

near

Exeter Exeter () is a city in Devon, South West England. It is situated on the River Exe, approximately northeast of Plymouth and southwest of Bristol. In Roman Britain, Exeter was established as the base of Legio II Augusta under the personal comm ...

, UK and

Negaunee, Michigan Negaunee ( or ) is a city in Marquette County in the U.S. state of Michigan. The population was 4,568 at the 2010 census. The city is located at the southwest corner of Negaunee Township, which is administratively separate, in the Upper Peni ...

United States The United States of America (U.S.A. or USA), commonly known as the United States (U.S. or US) or America, is a country primarily located in North America. It consists of 50 states, a federal district, five major unincorporated territorie ...

, and in the

Pilbara The Pilbara () is a large, dry, thinly populated region in the north of Western Australia. It is known for its Aboriginal peoples; its ancient landscapes; the red earth; and its vast mineral deposits, in particular iron ore. It is also a glo ...

Western Australia Western Australia (commonly abbreviated as WA) is a state of Australia occupying the western percent of the land area of Australia excluding external territories. It is bounded by the Indian Ocean to the north and west, the Southern Ocean to th ...

. Good crystals have also been found at Atikokan, Ontario and

Nova Scotia Nova Scotia ( ; ; ) is one of the thirteen provinces and territories of Canada. It is one of the three Maritime provinces and one of the four Atlantic provinces. Nova Scotia is Latin for "New Scotland". Most of the population are native Eng ...

, Canada. As an

ore Ore is natural rock or sediment that contains one or more valuable minerals, typically containing metals, that can be mined, treated and sold at a profit.Encyclopædia Britannica. "Ore". Encyclopædia Britannica Online. Retrieved 7 Apr ...

of manganese it is much less abundant than

psilomelane Psilomelane is a group name for hard black manganese oxides including hollandite and romanechite. Psilomelane consists of hydrous manganese oxide with variable amounts of barium and potassium. Psilomelane is erroneously, and uncommonly, known as ...

. Although described with various other names as early as 1772, the name ''manganite'' was first applied in a publication by W. Haidinger in 1827.

Applications

The mineral was used in prehistoric times as a pigment, by humans, and as a fire starter by Neanderthalers. Manganite is believed to have been used in prehistoric times to start a wood fire. Manganite lowers the combustion temperature of wood from 350 degrees Celsius to 250 degrees Celsius. Manganite powder has been a common find in

Neanderthal Neanderthals (, also ''Homo neanderthalensis'' and erroneously ''Homo sapiens neanderthalensis''), also written as Neandertals, are an extinct species or subspecies of archaic humans who lived in Eurasia until about 40,000 years ago. While th ...

archaeological sites.

References

* {{Authority control Manganese(III) minerals Hydroxide minerals Monoclinic minerals Minerals in space group 14

Occurrence

Applications

See also

References