Manganese Oxide
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Manganese Oxide
Manganese oxide is any of a variety of manganese oxides and hydroxides.Wells A.F. (1984) ''Structural inorganic chemistry'' 5th edition Oxford Science Publications, . These include * Manganese(II) oxide, MnO * Manganese(II,III) oxide, Mn3O4 * Manganese(III) oxide, Mn2O3 * Manganese dioxide, MnO2 * Manganese(VI) oxide, MnO3 * Manganese(VII) oxide, Mn2O7 Other manganese oxides include Mn5O8, Mn7O12 and Mn7O13. Minerals It may refer more specifically to the following manganese minerals: * Birnessite * Buserite * Hausmannite * Manganite * Manganosite * Psilomelane * Pyrolusite Manganese may also form mixed oxides with other metals : * Bixbyite, a manganese iron oxide mineral * Jacobsite, a manganese iron oxide mineral * Columbite * Tantalite, a mineral group close to columbite * Coltan, a mixture of columbite and tantalite * Galaxite, a spinel mineral * Todorokite Todorokite is a rare complex hydrous manganese oxide mineral with the chemical formula . It was named in 1934 f ...
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Manganese
Manganese is a chemical element with the symbol Mn and atomic number 25. It is a hard, brittle, silvery metal, often found in minerals in combination with iron. Manganese is a transition metal with a multifaceted array of industrial alloy uses, particularly in stainless steels. It improves strength, workability, and resistance to wear. Manganese oxide is used as an oxidising agent; as a rubber additive; and in glass making, fertilisers, and ceramics. Manganese sulfate can be used as a fungicide. Manganese is also an essential human dietary element, important in macronutrient metabolism, bone formation, and free radical defense systems. It is a critical component in dozens of proteins and enzymes. It is found mostly in the bones, but also the liver, kidneys, and brain. In the human brain, the manganese is bound to manganese metalloproteins, most notably glutamine synthetase in astrocytes. Manganese was first isolated in 1774. It is familiar in the laboratory in the form of the ...
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Pyrolusite
Pyrolusite is a mineral consisting essentially of manganese dioxide ( Mn O2) and is important as an ore of manganese.. It is a black, amorphous appearing mineral, often with a granular, fibrous, or columnar structure, sometimes forming reniform crusts. It has a metallic luster, a black or bluish-black streak, and readily soils the fingers. The specific gravity is about 4.8. Its name is from the Greek for ''fire'' and to ''wash'', in reference to its use as a way to remove tints from glass. Occurrence Pyrolusite and romanechite are among the most common manganese minerals. Pyrolusite occurs associated with manganite, hollandite, hausmannite, braunite, chalcophanite, goethite, and hematite under oxidizing conditions in hydrothermal deposits. It also occurs in bogs and often results from alteration of manganite. Use The metal is obtained by reduction of the oxide with sodium, magnesium, aluminium, or by electrolysis. Pyrolusite is extensively used for the manufacture of spi ...
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Manganese Minerals
Manganese is a chemical element with the symbol Mn and atomic number 25. It is a hard, brittle, silvery metal, often found in minerals in combination with iron. Manganese is a transition metal with a multifaceted array of industrial alloy uses, particularly in stainless steels. It improves strength, workability, and resistance to wear. Manganese oxide is used as an oxidising agent; as a rubber additive; and in glass making, fertilisers, and ceramics. Manganese sulfate can be used as a fungicide. Manganese is also an essential human dietary element, important in macronutrient metabolism, bone formation, and free radical defense systems. It is a critical component in dozens of proteins and enzymes. It is found mostly in the bones, but also the liver, kidneys, and brain. In the human brain, the manganese is bound to manganese metalloproteins, most notably glutamine synthetase in astrocytes. Manganese was first isolated in 1774. It is familiar in the laboratory in the form of the ...
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Manganese Compounds
Manganese is a chemical element with the symbol Mn and atomic number 25. It is a hard, brittle, silvery metal, often found in minerals in combination with iron. Manganese is a transition metal with a multifaceted array of industrial alloy uses, particularly in stainless steels. It improves strength, workability, and resistance to wear. Manganese oxide is used as an oxidising agent; as a rubber additive; and in glass making, fertilisers, and ceramics. Manganese sulfate can be used as a fungicide. Manganese is also an essential human dietary element, important in macronutrient metabolism, bone formation, and free radical defense systems. It is a critical component in dozens of proteins and enzymes. It is found mostly in the bones, but also the liver, kidneys, and brain. In the human brain, the manganese is bound to manganese metalloproteins, most notably glutamine synthetase in astrocytes. Manganese was first isolated in 1774. It is familiar in the laboratory in the form of the ...
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Todorokite
Todorokite is a rare complex hydrous manganese oxide mineral with the chemical formula . It was named in 1934 for the type locality, the Todoroki mine, Hokkaido, Japan. It belongs to the prismatic class 2/m of the monoclinic crystal system, but the angle β between the a and c axes is close to 90°, making it seem orthorhombic. It is a brown to black mineral which occurs in massive or tuberose forms. It is quite soft with a Mohs hardness of 1.5, and a specific gravity of 3.49 - 3.82. It is a component of deep ocean basin manganese nodules. Structure Manganese occurs in different states, including , and . Todorokite is made up of octahedra that share edges to form triple chains. These chains share corners to form roughly square tunnels parallel to the b crystal axis.Burns, Burns and Stockman (1983) American Mineralogist 68:972-980Post and Bish (1988) American Mineralogist 73: 861–869 The tunnels accommodate water molecules and large cations such as potassium , barium , ...
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Galaxite
Galaxite, also known as 'mangan-spinel' is an isometric mineral belonging to the spinel group of oxides with the ideal chemical formula . Galaxite is the manganese (Mn) rich endmember of the aluminium (Al) series of the spinel group. Divalent iron (Fe) and magnesium (Mg) readily substitute for the manganese in the crystal structure. Trivalent iron may also substitute for the aluminium. Thus, reflecting most natural samples, the formula may be better represented as . Galaxite generally occurs as small granular aggregates with a red-brownish tone. It has a vitreous luster and leaves a brownish-red streak. It is rated 7.5 on the Mohs Scale. It was first described in 1932 for an occurrence at Bald Knob, Alleghany County, North Carolina near its namesakes, the town of Galax, Virginia, named after the plant galax or wandflower which grows in the area. It occurs in carbonate-rich metamorphosed manganese ore deposits. It occurs associated with alleghanyite, rhodonite, sonolite, spes ...
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Coltan
Coltan (short for columbite–tantalites and known industrially as tantalite) is a dull black metallic ore from which the elements niobium and tantalum are extracted. The niobium-dominant mineral in coltan is columbite (after niobium's original American name ''columbium''), and the tantalum-dominant mineral is the tantalite. Tantalum from coltan is used to manufacture tantalum capacitors which are used for mobile phones, personal computers, automotive electronics, and cameras. Coltan mining is widespread in the Democratic Republic of Congo. Production and supply Approximately 71% of the global tantalum supply in 2008 was newly mined, 20% was from recycling, and the remainder was from tin slag and inventory. Tantalum minerals are mined in the Democratic Republic of the Congo, Colombia, Rwanda, Australia, Brazil, China, Ethiopia, and Mozambique. Tantalum is also produced in Thailand and Malaysia as a by-product of tin mining and smelting. Potential future mines, in descending ...
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Tantalite
The mineral group tantalite Fe,_manganese.html"_;"title="iron.html"_;"title="iron">Fe,_manganese">Mn)Tantalum">Ta2oxygen.html" ;"title="manganese">Mn)Tantalum.html" ;"title="iron">Fe,_manganese.html" ;"title="iron.html" ;"title="iron">Fe, manganese">Mn)Tantalum">Ta2oxygen">O6] is the primary source of the chemical element tantalum, a corrosion (heat and acid) resistant metal. It is chemically similar to ''columbite'', and the two are often grouped together as a semi-singular mineral called coltan or "columbite-tantalite" in many mineral guides. However, tantalite has a much greater specific gravity than columbite (8.0+ compared to columbite's 5.2). Iron-rich tantalite is the mineral tantalite-(Fe) or ''ferrotantalite'' and manganese-rich is tantalite-(Mn) or ''manganotantalite''. Tantalite is also very close to ''tapiolite''. Those minerals have the same chemical composition, but different crystal symmetry: orthorhombic for tantalite and tetragonal for tapiolite. Tantalite is b ...
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Columbite
Columbite, also called niobite, niobite-tantalite and columbate [], is a black mineral group that is an ore of niobium. It has a submetallic Lustre (mineralogy), luster and a high density and is a niobate of iron and manganese. This mineral group was first found in Haddam, Connecticut, in the United States. It forms a series with the tantalum-dominant analogue ferrotantalite and one with the manganese-dominant analogue manganocolumbite. The iron-rich member of the columbite group is ferrocolumbite. Some tin and tungsten may be present in the mineral. Yttrocolumbite is the yttrium-rich columbite with the formula . It is a radioactive mineral found in Mozambique. Columbite has the same composition and crystal symmetry (orthorhombic) as tantalite. In fact, the two are often grouped together as a semi-singular mineral series called columbite-tantalite or coltan in many mineral guides. However, tantalite has a much greater specific gravity than columbite, more than 8.0 compared to colum ...
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Jacobsite
Jacobsite is a manganese iron oxide mineral. It is in the spinel group and forms a solid solution series with magnetite. The chemical formula is (Mn,Mg)Fe2O4 or with oxidation states and substitutions: (Mn2+,Fe2+,Mg)(Fe3+,Mn3+)2O4. is a Nordic country located on .... References National Pollutant Inventory - Manganese and compounds Fact Sheet Spinel group Iron(II,III) minerals Manganese(II,III) minerals Magnesium minerals Magnetic minerals Cubic minerals Minerals in space group 227 Minerals described in 1869 {{Manganese minerals ...
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Bixbyite
Bixbyite is a manganese iron oxide mineral with chemical formula: (Mn,Fe)2O3. The iron/manganese ratio is quite variable and many specimens have almost no iron. It is a metallic dark black with a Mohs hardness of 6.0 - 6.5. It is a somewhat rare mineral sought after by collectors as it typically forms euhedral isometric crystals exhibiting various cubes, octahedra, and dodecahedra. It is commonly associated with beryl, quartz, spessartine, hematite, pseudobrookite, hausmannite, braunite and topaz in pneumatolytic or hydrothermal veins and cavities and in metamorphic rocks. It can also be found in lithophysal cavities in rhyolite. Typical localities are Jhabua and Chhindwara districts, India and the Thomas Range in Juab County, Utah. It is also reported from San Luis Potosi, Mexico; northern Patagonia, Argentina; Girona, Catalonia, Spain; Sweden, Germany, Namibia, Zimbabwe, and South Africa. Bixbyite was named for the American mineralogist Maynard Bixby (1853–1935), ...
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Psilomelane
Psilomelane is a group name for hard black manganese oxides including hollandite and romanechite. Psilomelane consists of hydrous manganese oxide with variable amounts of barium and potassium. Psilomelane is erroneously, and uncommonly, known as black hematite, despite not being related to true hematite, which is an iron oxide. Formula Generalized formula may be represented as or as . It is sometimes considered to be a hydrous manganese manganate, but of doubtful composition. The amount of manganese present corresponds to 70-80% of manganous oxide with 10-15% of available oxygen. Characteristics Psilomelane has no definite chemical composition and occurs as botryoidal and stalactitic masses with a smooth shining surface and submetallic lustre. The mineral is readily distinguished from other hydrous manganese oxides (manganite and wad) by its greater hardness 5 to 6; the specific gravity varies from 3.7 to 4.7. The streak is brownish black and the fracture smooth. The mineral ...
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