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Ratio Of Specific Heats
In thermal physics and thermodynamics, the heat capacity ratio, also known as the adiabatic index, the ratio of specific heats, or Laplace's coefficient, is the ratio of the heat capacity at constant pressure () to heat capacity at constant volume (). It is sometimes also known as the ''isentropic expansion factor'' and is denoted by (gamma) for an ideal gasγ first appeared in an article by the French mathematician, engineer, and physicist Siméon Denis Poisson: * On p. 332, Poisson defines γ merely as a small deviation from equilibrium which causes small variations of the equilibrium value of the density ρ. In Poisson's article of 1823 – * γ was expressed as a function of density D (p. 8) or of pressure P (p. 9). Meanwhile, in 1816 the French mathematician and physicist Pierre-Simon Laplace had found that the speed of sound depends on the ratio of the specific heats. * However, he didn't denote the ratio as γ. In 1825, Laplace stated that the speed of sound is ...
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Material Properties (thermodynamics)
The thermodynamic properties of materials are intensive thermodynamic parameters which are specific to a given material. Each is directly related to a second order differential of a thermodynamic potential. Examples for a simple 1-component system are: * Compressibility (or its inverse, the bulk modulus) :* Isothermal compressibility ::\kappa_T=-\frac\left(\frac\right)_T \quad = -\frac\,\frac :* Adiabatic compressibility ::\kappa_S=-\frac\left(\frac\right)_S \quad = -\frac\,\frac * Specific heat (Note - the extensive analog is the heat capacity) :* Specific heat at constant pressure ::c_P=\frac\left(\frac\right)_P \quad = -\frac\,\frac :* Specific heat at constant volume ::c_V=\frac\left(\frac\right)_V \quad = -\frac\,\frac * Coefficient of thermal expansion ::\alpha=\frac\left(\frac\right)_P \quad = \frac\,\frac where ''P''  is pressure, ''V''  is volume, ''T''  is temperature, ''S''  is entropy, and ''N''  is the number of particles. For a single comp ...
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Krypton
Krypton (from grc, κρυπτός, translit=kryptos 'the hidden one') is a chemical element with the symbol Kr and atomic number 36. It is a colorless, odorless, tasteless noble gas that occurs in trace amounts in the atmosphere and is often used with other rare gases in fluorescent lamps. With rare exceptions, krypton is chemically inert. Krypton, like the other noble gases, is used in lighting and photography. Krypton light has many spectral lines, and krypton plasma is useful in bright, high-powered gas lasers (krypton ion and excimer lasers), each of which resonates and amplifies a single spectral line. Krypton fluoride also makes a useful laser medium. From 1960 to 1983, the official definition of meter was based on the wavelength of one spectral line of krypton-86, because of the high power and relative ease of operation of krypton discharge tubes. History Krypton was discovered in Britain in 1898 by William Ramsay, a Scottish chemist, and Morris Travers, an Engli ...
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Kappa
Kappa (uppercase Κ, lowercase κ or cursive ; el, κάππα, ''káppa'') is the 10th letter of the Greek alphabet, representing the voiceless velar plosive sound in Ancient and Modern Greek. In the system of Greek numerals, has a value of 20. It was derived from the Phoenician letter kaph . Letters that arose from kappa include the Roman K and Cyrillic К. The uppercase form is identical to the Latin K. Greek proper names and placenames containing kappa are often written in English with "c" due to the Romans' transliterations into the Latin alphabet: Constantinople, Corinth, Crete. All formal modern romanizations of Greek now use the letter "k", however. The cursive form is generally a simple font variant of lower-case kappa, but it is encoded separately in Unicode for occasions where it is used as a separate symbol in math and science. In mathematics, the kappa curve is named after this letter; the tangents of this curve were first calculated by Isaac Barrow in the ...
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William John Macquorn Rankine
William John Macquorn Rankine (; 5 July 1820 – 24 December 1872) was a Scottish mechanical engineer who also contributed to civil engineering, physics and mathematics. He was a founding contributor, with Rudolf Clausius and William Thomson (Lord Kelvin), to the science of thermodynamics, particularly focusing on the first of the three thermodynamic laws. He developed the Rankine scale, an equivalent to the Kelvin scale of temperature, but in degrees Fahrenheit rather than Celsius. Rankine developed a complete theory of the steam engine and indeed of all heat engines. His manuals of engineering science and practice were used for many decades after their publication in the 1850s and 1860s. He published several hundred papers and notes on science and engineering topics, from 1840 onwards, and his interests were extremely varied, including, in his youth, botany, music theory and number theory, and, in his mature years, most major branches of science, mathematics and engineering. ...
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Pierre-Simon Laplace
Pierre-Simon, marquis de Laplace (; ; 23 March 1749 – 5 March 1827) was a French scholar and polymath whose work was important to the development of engineering, mathematics, statistics, physics, astronomy, and philosophy. He summarized and extended the work of his predecessors in his five-volume ''Mécanique céleste'' (''Celestial Mechanics'') (1799–1825). This work translated the geometric study of classical mechanics to one based on calculus, opening up a broader range of problems. In statistics, the Bayesian interpretation of probability was developed mainly by Laplace. Laplace formulated Laplace's equation, and pioneered the Laplace transform which appears in many branches of mathematical physics, a field that he took a leading role in forming. The Laplacian differential operator, widely used in mathematics, is also named after him. He restated and developed the nebular hypothesis of the origin of the Solar System and was one of the first scientists to sugges ...
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Siméon Denis Poisson
Baron Siméon Denis Poisson FRS FRSE (; 21 June 1781 – 25 April 1840) was a French mathematician and physicist who worked on statistics, complex analysis, partial differential equations, the calculus of variations, analytical mechanics, electricity and magnetism, thermodynamics, elasticity, and fluid mechanics. Moreover, he predicted the Poisson spot in his attempt to disprove the wave theory of Augustin-Jean Fresnel, which was later confirmed. Biography Poisson was born in Pithiviers, Loiret district in France, the son of Siméon Poisson, an officer in the French army. In 1798, he entered the École Polytechnique in Paris as first in his year, and immediately began to attract the notice of the professors of the school, who left him free to make his own decisions as to what he would study. In his final year of study, less than two years after his entry, he published two memoirs, one on Étienne Bézout's method of elimination, the other on the number of integrals of a finite di ...
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Gamma (letter)
Gamma (uppercase , lowercase ; ''gámma'') is the third letter of the Greek alphabet. In the system of Greek numerals it has a value of 3. In Ancient Greek, the letter gamma represented a voiced velar stop . In Modern Greek, this letter represents either a voiced velar fricative or a voiced palatal fricative (while /g/ in foreign words is instead commonly transcribed as γκ). In the International Phonetic Alphabet and other modern Latin-alphabet based phonetic notations, it represents the voiced velar fricative. History The Greek letter Gamma Γ is a grapheme derived from the Phoenician letter (''gīml'') which was rotated from the right-to-left script of Canaanite to accommodate the Greek language's writing system of left-to-right. The Canaanite grapheme represented the /g/ phoneme in the Canaanite language, and as such is cognate with ''gimel'' ג of the Hebrew alphabet. Based on its name, the letter has been interpreted as an abstract representation of a camel' ...
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Isentropic
In thermodynamics, an isentropic process is an idealized thermodynamic process that is both adiabatic and reversible. The work transfers of the system are frictionless, and there is no net transfer of heat or matter. Such an idealized process is useful in engineering as a model of and basis of comparison for real processes. This process is idealized because reversible processes do not occur in reality; thinking of a process as both adiabatic and reversible would show that the initial and final entropies are the same, thus, the reason it is called isentropic (entropy does not change). Thermodynamic processes are named based on the effect they would have on the system (ex. isovolumetric: constant volume, isenthalpic: constant enthalpy). Even though in reality it is not necessarily possible to carry out an isentropic process, some may be approximated as such. The word "isentropic" can be interpreted in another way, since its meaning is deducible from its etymology. It means a pr ...
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Heat Capacity
Heat capacity or thermal capacity is a physical property of matter, defined as the amount of heat to be supplied to an object to produce a unit change in its temperature. The SI unit of heat capacity is joule per kelvin (J/K). Heat capacity is an extensive property. The corresponding intensive property is the specific heat capacity, found by dividing the heat capacity of an object by its mass. Dividing the heat capacity by the amount of substance in moles yields its molar heat capacity. The volumetric heat capacity measures the heat capacity per volume. In architecture and civil engineering, the heat capacity of a building is often referred to as its thermal mass. Definition Basic definition The heat capacity of an object, denoted by C, is the limit : C = \lim_\frac, where \Delta Q is the amount of heat that must be added to the object (of mass ''M'') in order to raise its temperature by \Delta T. The value of this parameter usually varies considerably depending on the ...
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Thermodynamics
Thermodynamics is a branch of physics that deals with heat, work, and temperature, and their relation to energy, entropy, and the physical properties of matter and radiation. The behavior of these quantities is governed by the four laws of thermodynamics which convey a quantitative description using measurable macroscopic physical quantities, but may be explained in terms of microscopic constituents by statistical mechanics. Thermodynamics applies to a wide variety of topics in science and engineering, especially physical chemistry, biochemistry, chemical engineering and mechanical engineering, but also in other complex fields such as meteorology. Historically, thermodynamics developed out of a desire to increase the efficiency of early steam engines, particularly through the work of French physicist Sadi Carnot (1824) who believed that engine efficiency was the key that could help France win the Napoleonic Wars. Scots-Irish physicist Lord Kelvin was the first to formulate a ...
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Thermal Physics
Thermal physics is the combined study of thermodynamics, statistical mechanics, and kinetic theory of gases. This umbrella-subject is typically designed for physics students and functions to provide a general introduction to each of three core heat-related subjects. Other authors, however, define thermal physics loosely as a summation of only thermodynamics and statistical mechanics. Thermal physics can be seen as the study of system with larger number of atom, it unites thermodynamics to statistical mechanics. Overview Thermal physics, generally speaking, is the study of the statistical nature of physical systems from an energetic perspective. Starting with the basics of heat and temperature, thermal physics analyzes the first law of thermodynamics and second law of thermodynamics from the statistical perspective, in terms of the number of microstate (statistical mechanics), microstates corresponding to a given macrostate. In addition, the concept of entropy is studied via Qu ...
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Propane
Propane () is a three-carbon alkane with the molecular formula . It is a gas at standard temperature and pressure, but compressible to a transportable liquid. A by-product of natural gas processing and petroleum refining, it is commonly used as a fuel in domestic and industrial applications and in low-emissions public transportation. Discovered in 1857 by the French chemist Marcellin Berthelot, it became commercially available in the US by 1911. Propane is one of a group of liquefied petroleum gases (LP gases). The others include butane, propylene, butadiene, butylene, isobutylene, and mixtures thereof. Propane has lower volumetric energy density, but higher gravimetric energy density and burns more cleanly than gasoline and coal. Propane gas has become a popular choice for barbecues and portable stoves because its low −42 °C boiling point makes it vaporise inside pressurised liquid containers (2 phases). Propane powers buses, forklifts, taxis, outboard boat motors, and ic ...
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