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Material Properties (thermodynamics)
The thermodynamic properties of materials are intensive thermodynamic parameters which are specific to a given material. Each is directly related to a second order differential of a thermodynamic potential. Examples for a simple 1-component system are: * Compressibility (or its inverse, the bulk modulus) :* Isothermal compressibility ::\kappa_T=-\frac\left(\frac\right)_T \quad = -\frac\,\frac :* Adiabatic compressibility ::\kappa_S=-\frac\left(\frac\right)_S \quad = -\frac\,\frac * Specific heat (Note - the extensive analog is the heat capacity) :* Specific heat at constant pressure ::c_P=\frac\left(\frac\right)_P \quad = -\frac\,\frac :* Specific heat at constant volume ::c_V=\frac\left(\frac\right)_V \quad = -\frac\,\frac * Coefficient of thermal expansion ::\alpha=\frac\left(\frac\right)_P \quad = \frac\,\frac where ''P'' is pressure, ''V'' is volume, ''T'' is temperature, ''S'' is entropy, and ''N'' is the number of particles. For a single comp ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Thermodynamic Potential
A thermodynamic potential (or more accurately, a thermodynamic potential energy)ISO/IEC 80000-5, Quantities an units, Part 5 - Thermodynamics, item 5-20.4 Helmholtz energy, Helmholtz functionISO/IEC 80000-5, Quantities an units, Part 5 - Thermodynamics, item 5-20.5, Gibbs energy, Gibbs function is a scalar quantity used to represent the thermodynamic state of a system. The concept of thermodynamic potentials was introduced by Pierre Duhem in 1886. Josiah Willard Gibbs in his papers used the term ''fundamental functions''. One main thermodynamic potential that has a physical interpretation is the internal energy . It is the energy of configuration of a given system of conservative forces (that is why it is called potential) and only has meaning with respect to a defined set of references (or data). Expressions for all other thermodynamic energy potentials are derivable via Legendre transforms from an expression for . In thermodynamics, external forces, such as gravity, are c ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
List Of Materials Properties
A materials property is an intensive property of a material, i.e., a physical property that does not depend on the amount of the material. These quantitative properties may be used as a metric by which the benefits of one material versus another can be compared, thereby aiding in materials selection. A property may be a constant or may be a function of one or more independent variables, such as temperature. Materials properties often vary to some degree according to the direction in the material in which they are measured, a condition referred to as anisotropy. Materials properties that relate to different physical phenomena often behave linearly (or approximately so) in a given operating range. Modeling them as linear functions can significantly simplify the differential constitutive equations that are used to describe the property. Equations describing relevant materials properties are often used to predict the attributes of a system. The properties are measured by standardi ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Thermal Mass
In building design, thermal mass is a property of the mass of a building that enables it to store heat and provide inertia against temperature fluctuations. It is sometimes known as the thermal flywheel effect. The thermal mass of heavy structural elements can be designed to work alongside a construction's lighter thermal resistance components to create energy efficient buildings. For example, when outside temperatures are fluctuating throughout the day, a large thermal mass within the insulated portion of a house can serve to "flatten out" the daily temperature fluctuations, since the thermal mass will absorb thermal energy when the surroundings are higher in temperature than the mass, and give thermal energy back when the surroundings are cooler, without reaching thermal equilibrium. This is distinct from a material's insulative value, which reduces a building's thermal conductivity, allowing it to be heated or cooled relatively separately from the outside, or even just retain ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Enthalpy Of Vaporization
The enthalpy of vaporization (symbol ), also known as the (latent) heat of vaporization or heat of evaporation, is the amount of energy (enthalpy) that must be added to a liquid substance to transform a quantity of that substance into a gas. The enthalpy of vaporization is a function of the pressure at which that transformation takes place. The enthalpy of vaporization is often quoted for the normal boiling temperature of the substance. Although tabulated values are usually corrected to 298 K, that correction is often smaller than the uncertainty in the measured value. The heat of vaporization is temperature-dependent, though a constant heat of vaporization can be assumed for small temperature ranges and for reduced temperature T_r \ll 1. The heat of vaporization diminishes with increasing temperature and it vanishes completely at a certain point called the critical temperature (T_r = 1). Above the critical temperature, the liquid and vapor phases are indistinguishabl ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Enthalpy Of Fusion
In thermodynamics, the enthalpy of fusion of a substance, also known as (latent) heat of fusion, is the change in its enthalpy resulting from providing energy, typically heat, to a specific quantity of the substance to change its state from a solid to a liquid, at constant pressure. It is the amount of energy required to convert one mole of solid into liquid For example, when melting 1 kg of ice (at 0 °C under a wide range of pressures), 333.55 kJ of energy is absorbed with no temperature change. The heat of solidification (when a substance changes from liquid to solid) is equal and opposite. This energy includes the contribution required to make room for any associated change in volume by displacing its environment against ambient pressure. The temperature at which the phase transition occurs is the melting point or the freezing point, according to context. By convention, the pressure is assumed to be unless otherwise specified. Overview The 'enthalpy' of fusi ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Latent Heat
Latent heat (also known as latent energy or heat of transformation) is energy released or absorbed, by a body or a thermodynamic system, during a constant-temperature process — usually a first-order phase transition. Latent heat can be understood as energy in hidden form which is supplied or extracted to change the state of a substance without changing its temperature. Examples are latent heat of fusion and latent heat of vaporization involved in phase changes, i.e. a substance condensing or vaporizing at a specified temperature and pressure. The term was introduced around 1762 by Scottish chemist Joseph Black. It is derived from the Latin ''latere'' (''to lie hidden''). Black used the term in the context of calorimetry where a heat transfer caused a volume change in a body while its temperature was constant. In contrast to latent heat, sensible heat is energy transferred as heat, with a resultant temperature change in a body. Usage The terms ″sensible heat″ and ″laten ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Heat Transfer Coefficient
In thermodynamics, the heat transfer coefficient or film coefficient, or film effectiveness, is the proportionality constant between the heat flux and the thermodynamic driving force for the flow of heat (i.e., the temperature difference, ). It is used in calculating the heat transfer, typically by convection or phase transition between a fluid and a solid. The heat transfer coefficient has SI units in watts per square meter kelvin (W/m2/K). The overall heat transfer rate for combined modes is usually expressed in terms of an overall conductance or heat transfer coefficient, . In that case, the heat transfer rate is: :\dot=hA(T_2-T_1) where (in SI units): *: surface area where the heat transfer takes place (m2) *: temperature of the surrounding fluid (K) *: temperature of the solid surface (K) The general definition of the heat transfer coefficient is: :h = \frac where: *: heat flux (W/m2); i.e., thermal power per unit area, q = d\dot/dA *: difference in temperature bet ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Thermodynamic Databases For Pure Substances
Thermodynamic databases contain information about thermodynamic properties for substances, the most important being enthalpy, entropy, and Gibbs free energy. Numerical values of these thermodynamic properties are collected as tables or are calculated from thermodynamic datafiles. Data is expressed as temperature-dependent values for one mole of substance at the standard pressure of 101.325 kPa (1 atm), or 100 kPa (1 bar). Unfortunately, both of these definitions for the standard condition for pressure are in use. Thermodynamic data Thermodynamic data is usually presented as a table or chart of function values for one mole of a substance (or in the case of the steam tables, one kg). A thermodynamic datafile is a set of equation parameters from which the numerical data values can be calculated. Tables and datafiles are usually presented at a standard pressure of 1 bar or 1 atm, but in the case of steam and other industrially important gases, pressure may be included as a varia ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Thermodynamic Equations
Thermodynamics is expressed by a mathematical framework of ''thermodynamic equations'' which relate various thermodynamic quantities and physical properties measured in a laboratory or production process. Thermodynamics is based on a fundamental set of postulates, that became the laws of thermodynamics. Introduction One of the fundamental thermodynamic equations is the description of thermodynamic work in analogy to mechanical work, or weight lifted through an elevation against gravity, as defined in 1824 by French physicist Sadi Carnot. Carnot used the phrase motive power for work. In the footnotes to his famous ''On the Motive Power of Fire'', he states: “We use here the expression ''motive power'' to express the useful effect that a motor is capable of producing. This effect can always be likened to the elevation of a weight to a certain height. It has, as we know, as a measure, the product of the weight multiplied by the height to which it is raised.” With the inc ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Statistical Mechanics
In physics, statistical mechanics is a mathematical framework that applies statistical methods and probability theory to large assemblies of microscopic entities. It does not assume or postulate any natural laws, but explains the macroscopic behavior of nature from the behavior of such ensembles. Statistical mechanics arose out of the development of classical thermodynamics, a field for which it was successful in explaining macroscopic physical properties—such as temperature, pressure, and heat capacity—in terms of microscopic parameters that fluctuate about average values and are characterized by probability distributions. This established the fields of statistical thermodynamics and statistical physics. The founding of the field of statistical mechanics is generally credited to three physicists: *Ludwig Boltzmann, who developed the fundamental interpretation of entropy in terms of a collection of microstates *James Clerk Maxwell, who developed models of probability distr ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Heat Capacity Ratio
In thermal physics and thermodynamics, the heat capacity ratio, also known as the adiabatic index, the ratio of specific heats, or Laplace's coefficient, is the ratio of the heat capacity at constant pressure () to heat capacity at constant volume (). It is sometimes also known as the ''isentropic expansion factor'' and is denoted by ( gamma) for an ideal gasγ first appeared in an article by the French mathematician, engineer, and physicist Siméon Denis Poisson: * On p. 332, Poisson defines γ merely as a small deviation from equilibrium which causes small variations of the equilibrium value of the density ρ. In Poisson's article of 1823 – * γ was expressed as a function of density D (p. 8) or of pressure P (p. 9). Meanwhile, in 1816 the French mathematician and physicist Pierre-Simon Laplace had found that the speed of sound depends on the ratio of the specific heats. * However, he didn't denote the ratio as γ. In 1825, Laplace stated that the speed of sound is ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Gibbs Free Energy
In thermodynamics, the Gibbs free energy (or Gibbs energy; symbol G) is a thermodynamic potential that can be used to calculate the maximum amount of work that may be performed by a thermodynamically closed system at constant temperature and pressure. It also provides a necessary condition for processes such as chemical reactions that may occur under these conditions. The Gibbs free energy change , measured in joules in SI) is the ''maximum'' amount of non-expansion work that can be extracted from a closed system (one that can exchange heat and work with its surroundings, but not matter) at fixed temperature and pressure. This maximum can be attained only in a completely reversible process. When a system transforms reversibly from an initial state to a final state under these conditions, the decrease in Gibbs free energy equals the work done by the system to its surroundings, minus the work of the pressure forces. The Gibbs energy is the thermodynamic potential that is minim ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
