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The atmosphere of Earth is composed of a layer of gas mixture that surrounds the
Earth Earth is the third planet from the Sun and the only astronomical object known to Planetary habitability, harbor life. This is enabled by Earth being an ocean world, the only one in the Solar System sustaining liquid surface water. Almost all ...
's
planetary surface A planetary surface is where the solid or liquid material of certain types of astronomical objects contacts the atmosphere or outer space. Planetary surfaces are found on solid objects of planetary mass, including terrestrial planets (including ...
(both
land Land, also known as dry land, ground, or earth, is the solid terrestrial surface of Earth not submerged by the ocean or another body of water. It makes up 29.2% of Earth's surface and includes all continents and islands. Earth's land sur ...
s and
ocean The ocean is the body of salt water that covers approximately 70.8% of Earth. The ocean is conventionally divided into large bodies of water, which are also referred to as ''oceans'' (the Pacific, Atlantic, Indian Ocean, Indian, Southern Ocean ...
s), known collectively as air, with variable quantities of suspended
aerosol An aerosol is a suspension (chemistry), suspension of fine solid particles or liquid Drop (liquid), droplets in air or another gas. Aerosols can be generated from natural or Human impact on the environment, human causes. The term ''aerosol'' co ...
s and particulates (which create
weather Weather is the state of the atmosphere, describing for example the degree to which it is hot or cold, wet or dry, calm or stormy, clear or cloud cover, cloudy. On Earth, most weather phenomena occur in the lowest layer of the planet's atmo ...
features such as
cloud In meteorology, a cloud is an aerosol consisting of a visible mass of miniature liquid droplets, frozen crystals, or other particles, suspended in the atmosphere of a planetary body or similar space. Water or various other chemicals may ...
s and hazes), all retained by
Earth's gravity The gravity of Earth, denoted by , is the net acceleration that is imparted to objects due to the combined effect of gravitation (from mass distribution within Earth) and the centrifugal force (from the Earth's rotation). It is a vector qu ...
. The atmosphere serves as a protective buffer between the Earth's surface and outer space, shields the surface from most
meteoroid A meteoroid ( ) is a small rocky or metallic body in outer space. Meteoroids are distinguished as objects significantly smaller than ''asteroids'', ranging in size from grains to objects up to wide. Objects smaller than meteoroids are classifie ...
s and ultraviolet
solar radiation Sunlight is the portion of the electromagnetic radiation which is emitted by the Sun (i.e. solar radiation) and received by the Earth, in particular the visible light perceptible to the human eye as well as invisible infrared (typically p ...
, keeps it warm and reduces
diurnal temperature variation In meteorology, diurnal temperature variation is the variation between a high air temperature and a low temperature that occurs during the same day. Temperature lag Temperature lag, also known as thermal inertia, is an important factor in diur ...
(temperature extremes between
day A day is the time rotation period, period of a full Earth's rotation, rotation of the Earth with respect to the Sun. On average, this is 24 hours (86,400 seconds). As a day passes at a given location it experiences morning, afternoon, evening, ...
and
night Night, or nighttime, is the period of darkness when the Sun is below the horizon. Sunlight illuminates one side of the Earth, leaving the other in darkness. The opposite of nighttime is daytime. Earth's rotation causes the appearance of ...
) through heat retention (
greenhouse effect The greenhouse effect occurs when greenhouse gases in a planet's atmosphere insulate the planet from losing heat to space, raising its surface temperature. Surface heating can happen from an internal heat source (as in the case of Jupiter) or ...
), redistributes heat and moisture among different regions via
air current In meteorology, air currents are concentrated areas of winds. They are mainly due to differences in atmospheric pressure or temperature. They are divided into horizontal and vertical currents; both are present at Mesoscale meteorology, mesoscale w ...
s, and provides the
chemical A chemical substance is a unique form of matter with constant chemical composition and characteristic properties. Chemical substances may take the form of a single element or chemical compounds. If two or more chemical substances can be combin ...
and
climate Climate is the long-term weather pattern in a region, typically averaged over 30 years. More rigorously, it is the mean and variability of meteorological variables over a time spanning from months to millions of years. Some of the meteoro ...
conditions allowing
life Life, also known as biota, refers to matter that has biological processes, such as Cell signaling, signaling and self-sustaining processes. It is defined descriptively by the capacity for homeostasis, Structure#Biological, organisation, met ...
to exist and evolve on Earth. By
mole fraction In chemistry, the mole fraction or molar fraction, also called mole proportion or molar proportion, is a quantity defined as the ratio between the amount of a constituent substance, ''ni'' (expressed in unit of moles, symbol mol), and the to ...
(i.e., by quantity of
molecule A molecule is a group of two or more atoms that are held together by Force, attractive forces known as chemical bonds; depending on context, the term may or may not include ions that satisfy this criterion. In quantum physics, organic chemi ...
s), dry air contains 78.08%
nitrogen Nitrogen is a chemical element; it has Symbol (chemistry), symbol N and atomic number 7. Nitrogen is a Nonmetal (chemistry), nonmetal and the lightest member of pnictogen, group 15 of the periodic table, often called the Pnictogen, pnictogens. ...
, 20.95%
oxygen Oxygen is a chemical element; it has chemical symbol, symbol O and atomic number 8. It is a member of the chalcogen group (periodic table), group in the periodic table, a highly reactivity (chemistry), reactive nonmetal (chemistry), non ...
, 0.93%
argon Argon is a chemical element; it has symbol Ar and atomic number 18. It is in group 18 of the periodic table and is a noble gas. Argon is the third most abundant gas in Earth's atmosphere, at 0.934% (9340 ppmv). It is more than twice as abu ...
, 0.04%
carbon dioxide Carbon dioxide is a chemical compound with the chemical formula . It is made up of molecules that each have one carbon atom covalent bond, covalently double bonded to two oxygen atoms. It is found in a gas state at room temperature and at norma ...
, and small amounts of other trace gases (see Composition below for more detail). Air also contains a variable amount of
water vapor Water vapor, water vapour, or aqueous vapor is the gaseous phase of Properties of water, water. It is one Phase (matter), state of water within the hydrosphere. Water vapor can be produced from the evaporation or boiling of liquid water or from th ...
, on average around 1% at sea level, and 0.4% over the entire atmosphere. Earth's early atmosphere consisted of accreted gases from the
solar nebula There is evidence that the formation of the Solar System began about 4.6 bya, billion years ago with the gravitational collapse of a small part of a giant molecular cloud. Most of the collapsing mass collected in the center, forming the Sun, whil ...
, but the atmosphere changed significantly over time, affected by many factors such as volcanism,
impact event An impact event is a collision between astronomical objects causing measurable effects. Impact events have been found to regularly occur in planetary systems, though the most frequent involve asteroids, comets or meteoroids and have minimal effe ...
s,
weathering Weathering is the deterioration of rocks, soils and minerals (as well as wood and artificial materials) through contact with water, atmospheric gases, sunlight, and biological organisms. It occurs '' in situ'' (on-site, with little or no move ...
and the evolution of life (particularly the photoautotrophs). Recently,
human Humans (''Homo sapiens'') or modern humans are the most common and widespread species of primate, and the last surviving species of the genus ''Homo''. They are Hominidae, great apes characterized by their Prehistory of nakedness and clothing ...
activity has also contributed to atmospheric changes, such as
climate change Present-day climate change includes both global warming—the ongoing increase in Global surface temperature, global average temperature—and its wider effects on Earth's climate system. Climate variability and change, Climate change in ...
(mainly through
deforestation Deforestation or forest clearance is the removal and destruction of a forest or stand of trees from land that is then converted to non-forest use. Deforestation can involve conversion of forest land to farms, ranches, or urban use. Ab ...
and
fossil fuel A fossil fuel is a flammable carbon compound- or hydrocarbon-containing material formed naturally in the Earth's crust from the buried remains of prehistoric organisms (animals, plants or microplanktons), a process that occurs within geolog ...
-related
global warming Present-day climate change includes both global warming—the ongoing increase in global average temperature—and its wider effects on Earth's climate system. Climate change in a broader sense also includes previous long-term changes ...
), ozone depletion and acid deposition. The atmosphere has a mass of about 5.15 kg, three quarters of which is within about of the surface. The atmosphere becomes thinner with increasing altitude, with no definite boundary between the atmosphere and outer space. The
Kármán line The Kármán line (or von Kármán line ) is a conventional definition of the Outer space#Boundary, edge of space; it is widely but not universally accepted. The international record-keeping body Fédération Aéronautique Internationale, FAI ( ...
, at or 1.57% of Earth's radius, is often used as the border between the atmosphere and outer space. Atmospheric effects become noticeable during atmospheric reentry of spacecraft at an altitude of around . Several layers can be distinguished in the atmosphere based on characteristics such as temperature and composition, namely the
troposphere The troposphere is the lowest layer of the atmosphere of Earth. It contains 80% of the total mass of the Atmosphere, planetary atmosphere and 99% of the total mass of water vapor and aerosols, and is where most weather phenomena occur. From the ...
,
stratosphere The stratosphere () is the second-lowest layer of the atmosphere of Earth, located above the troposphere and below the mesosphere. The stratosphere is composed of stratified temperature zones, with the warmer layers of air located higher ...
, mesosphere, thermosphere (formally the
ionosphere The ionosphere () is the ionized part of the upper atmosphere of Earth, from about to above sea level, a region that includes the thermosphere and parts of the mesosphere and exosphere. The ionosphere is ionized by solar radiation. It plays ...
) and
exosphere The exosphere is a thin, atmosphere-like volume surrounding a planet or natural satellite where molecules are gravitationally bound to that body, but where the density is so low that the molecules are essentially collision-less. In the case of ...
. Air composition, temperature and
atmospheric pressure Atmospheric pressure, also known as air pressure or barometric pressure (after the barometer), is the pressure within the atmosphere of Earth. The standard atmosphere (symbol: atm) is a unit of pressure defined as , which is equivalent to 1,013. ...
vary with
altitude Altitude is a distance measurement, usually in the vertical or "up" direction, between a reference datum (geodesy), datum and a point or object. The exact definition and reference datum varies according to the context (e.g., aviation, geometr ...
. Air suitable for use in
photosynthesis Photosynthesis ( ) is a system of biological processes by which photosynthetic organisms, such as most plants, algae, and cyanobacteria, convert light energy, typically from sunlight, into the chemical energy necessary to fuel their metabo ...
by
terrestrial plant A terrestrial plant is a plant that grows on, in or from land. Other types of plants are aquatic plant, aquatic (living in or on water), semiaquatic (living at edge or seasonally in water), epiphyte, epiphytic (living on other plants), and litho ...
s and respiration of
terrestrial animal Terrestrial animals are animals that live predominantly or entirely on land (e.g. cats, chickens, ants, most spiders), as compared with aquatic animals, which live predominantly or entirely in the water (e.g. fish, lobsters, octopuses), ...
s is found within the troposphere. The study of Earth's atmosphere and its processes is called
atmospheric science Atmospheric science is the study of the Atmosphere of Earth, Earth's atmosphere and its various inner-working physical processes. Meteorology includes atmospheric chemistry and atmospheric physics with a major focus on weather forecasting. Clima ...
(aerology), and includes multiple subfields, such as
climatology Climatology (from Greek , ''klima'', "slope"; and , '' -logia'') or climate science is the scientific study of Earth's climate, typically defined as weather conditions averaged over a period of at least 30 years. Climate concerns the atmospher ...
and atmospheric physics. Early pioneers in the field include Léon Teisserenc de Bort and Richard Assmann. The study of historic atmosphere is called
paleoclimatology Paleoclimatology ( British spelling, palaeoclimatology) is the scientific study of climates predating the invention of meteorological instruments, when no direct measurement data were available. As instrumental records only span a tiny part of ...
.


Composition

The three major constituents of Earth's atmosphere are
nitrogen Nitrogen is a chemical element; it has Symbol (chemistry), symbol N and atomic number 7. Nitrogen is a Nonmetal (chemistry), nonmetal and the lightest member of pnictogen, group 15 of the periodic table, often called the Pnictogen, pnictogens. ...
,
oxygen Oxygen is a chemical element; it has chemical symbol, symbol O and atomic number 8. It is a member of the chalcogen group (periodic table), group in the periodic table, a highly reactivity (chemistry), reactive nonmetal (chemistry), non ...
, and
argon Argon is a chemical element; it has symbol Ar and atomic number 18. It is in group 18 of the periodic table and is a noble gas. Argon is the third most abundant gas in Earth's atmosphere, at 0.934% (9340 ppmv). It is more than twice as abu ...
. Water vapor accounts for roughly 0.25% of the atmosphere by mass. The concentration of water vapor (a greenhouse gas) varies significantly from around 10 ppm by mole fraction in the coldest portions of the atmosphere to as much as 5% by mole fraction in hot, humid air masses, and concentrations of other atmospheric gases are typically quoted in terms of dry air (without water vapor).Wallace, John M. and Peter V. Hobbs
''Atmospheric Science: An Introductory Survey''
. Elsevier. Second Edition, 2006. . Chapter 1
The remaining gases are often referred to as trace gases, among which are other
greenhouse gas Greenhouse gases (GHGs) are the gases in the atmosphere that raise the surface temperature of planets such as the Earth. Unlike other gases, greenhouse gases absorb the radiations that a planet emits, resulting in the greenhouse effect. T ...
es, principally carbon dioxide, methane, nitrous oxide, and ozone. Besides argon, other
noble gas The noble gases (historically the inert gases, sometimes referred to as aerogens) are the members of Group (periodic table), group 18 of the periodic table: helium (He), neon (Ne), argon (Ar), krypton (Kr), xenon (Xe), radon (Rn) and, in some ...
es,
neon Neon is a chemical element; it has symbol Ne and atomic number 10. It is the second noble gas in the periodic table. Neon is a colorless, odorless, inert monatomic gas under standard conditions, with approximately two-thirds the density of ...
,
helium Helium (from ) is a chemical element; it has chemical symbol, symbol He and atomic number 2. It is a colorless, odorless, non-toxic, inert gas, inert, monatomic gas and the first in the noble gas group in the periodic table. Its boiling point is ...
,
krypton Krypton (from 'the hidden one') is a chemical element; it has symbol (chemistry), symbol Kr and atomic number 36. It is a colorless, odorless noble gas that occurs in trace element, trace amounts in the Earth's atmosphere, atmosphere and is of ...
, and
xenon Xenon is a chemical element; it has symbol Xe and atomic number 54. It is a dense, colorless, odorless noble gas found in Earth's atmosphere in trace amounts. Although generally unreactive, it can undergo a few chemical reactions such as the ...
are also present. Filtered air includes trace amounts of many other
chemical compound A chemical compound is a chemical substance composed of many identical molecules (or molecular entities) containing atoms from more than one chemical element held together by chemical bonds. A molecule consisting of atoms of only one element ...
s. Many substances of natural origin may be present in locally and seasonally variable small amounts as
aerosol An aerosol is a suspension (chemistry), suspension of fine solid particles or liquid Drop (liquid), droplets in air or another gas. Aerosols can be generated from natural or Human impact on the environment, human causes. The term ''aerosol'' co ...
s in an unfiltered air sample, including
dust Dust is made of particle size, fine particles of solid matter. On Earth, it generally consists of particles in the atmosphere that come from various sources such as soil lifted by wind (an aeolian processes, aeolian process), Types of volcan ...
of mineral and organic composition,
pollen Pollen is a powdery substance produced by most types of flowers of seed plants for the purpose of sexual reproduction. It consists of pollen grains (highly reduced Gametophyte#Heterospory, microgametophytes), which produce male gametes (sperm ...
and spores, sea spray, and
volcanic ash Volcanic ash consists of fragments of rock, mineral crystals, and volcanic glass, produced during volcanic eruptions and measuring less than 2 mm (0.079 inches) in diameter. The term volcanic ash is also often loosely used to r ...
. Various industrial
pollutant A pollutant or novel entity is a substance or energy introduced into the environment that has undesired effect, or adversely affects the usefulness of a resource. These can be both naturally forming (i.e. minerals or extracted compounds like oi ...
s also may be present as gases or aerosols, such as
chlorine Chlorine is a chemical element; it has Symbol (chemistry), symbol Cl and atomic number 17. The second-lightest of the halogens, it appears between fluorine and bromine in the periodic table and its properties are mostly intermediate between ...
(elemental or in compounds),
fluorine Fluorine is a chemical element; it has Chemical symbol, symbol F and atomic number 9. It is the lightest halogen and exists at Standard temperature and pressure, standard conditions as pale yellow Diatomic molecule, diatomic gas. Fluorine is extre ...
compounds and elemental mercury vapor. Sulfur compounds such as
hydrogen sulfide Hydrogen sulfide is a chemical compound with the formula . It is a colorless chalcogen-hydride gas, and is toxic, corrosive, and flammable. Trace amounts in ambient atmosphere have a characteristic foul odor of rotten eggs. Swedish chemist ...
and
sulfur dioxide Sulfur dioxide (IUPAC-recommended spelling) or sulphur dioxide (traditional Commonwealth English) is the chemical compound with the formula . It is a colorless gas with a pungent smell that is responsible for the odor of burnt matches. It is r ...
(SO2) may be derived from natural sources or from industrial air pollution. The average
molecular weight A molecule is a group of two or more atoms that are held together by Force, attractive forces known as chemical bonds; depending on context, the term may or may not include ions that satisfy this criterion. In quantum physics, organic chemi ...
of dry air, which can be used to calculate densities or to convert between mole fraction and mass fraction, is about 28.946Detlev Möller: ''Luft: Chemie, Physik, Biologie, Reinhaltung, Recht''. Walter de Gruyter, 2003, , S. 173
(View in Google Books)
or 28.964 g/mol. This is decreased when the air is humid. The relative concentration of gases remains constant until about .


Stratification

In general, air pressure and density decrease with altitude in the atmosphere. However, temperature has a more complicated profile with altitude and may remain relatively constant or even increase with altitude in some regions (see the
temperature Temperature is a physical quantity that quantitatively expresses the attribute of hotness or coldness. Temperature is measurement, measured with a thermometer. It reflects the average kinetic energy of the vibrating and colliding atoms making ...
section). Because the general pattern of the temperature/altitude profile, or lapse rate, is constant and measurable by means of instrumented balloon soundings, the temperature behavior provides a useful metric to distinguish atmospheric layers. This ''atmospheric stratification'' divides the Earth's atmosphere into five main layers: * Exosphere: * Thermosphere: * Mesosphere: * Stratosphere: * Troposphere:


Exosphere

The exosphere is the outermost layer of Earth's atmosphere (though it is so tenuous that some scientists consider it to be part of interplanetary space rather than part of the atmosphere). It extends from the
thermopause The thermopause is the atmospheric boundary of Earth's energy system, located at the top of the thermosphere. The temperature of the thermopause could range from nearly absolute zero to . Below this, the atmosphere is defined to be active on the ...
(also known as the "exobase") at the top of the thermosphere to a poorly defined boundary with the
solar wind The solar wind is a stream of charged particles released from the Sun's outermost atmospheric layer, the Stellar corona, corona. This Plasma (physics), plasma mostly consists of electrons, protons and alpha particles with kinetic energy betwee ...
and interplanetary medium. The altitude of the exobase varies from about to about in times of higher incoming solar radiation. The upper limit varies depending on the definition. Various authorities consider it to end at about or about —about halfway to the moon, where the influence of Earth's gravity is about the same as radiation pressure from sunlight. The geocorona visible in the far ultraviolet (caused by neutral hydrogen) extends to at least . This layer is mainly composed of extremely low densities of hydrogen, helium and several heavier molecules including nitrogen, oxygen and carbon dioxide closer to the exobase. The atoms and molecules are so far apart that they can travel hundreds of kilometres without colliding with one another. Thus, the exosphere no longer behaves like a gas, and the particles constantly escape into space. These free-moving particles follow ballistic trajectories and may migrate in and out of the
magnetosphere In astronomy and planetary science, a magnetosphere is a region of space surrounding an astronomical object in which charged particles are affected by that object's magnetic field. It is created by a celestial body with an active interior Dynamo ...
or the solar wind. Every second, the Earth loses about 3 kg of hydrogen, 50 g of helium, and much smaller amounts of other constituents.David C. Catling and Kevin J. Zahnle
The Planetary Air Leak
''Scientific American,'' May 2009, p. 26 (accessed 25 July 2012)
The exosphere is too far above Earth for
meteorological Meteorology is the scientific study of the Earth's atmosphere and short-term atmospheric phenomena (i.e. weather), with a focus on weather forecasting. It has applications in the military, aviation, energy production, transport, agriculture ...
phenomena to be possible. However, Earth's
aurora An aurora ( aurorae or auroras), also commonly known as the northern lights (aurora borealis) or southern lights (aurora australis), is a natural light display in Earth's sky, predominantly observed in high-latitude regions (around the Arc ...
s—the aurora borealis (northern lights) and aurora australis (southern lights)—sometimes occur in the lower part of the exosphere, where they overlap into the thermosphere. The exosphere contains many of the
artificial satellite A satellite or an artificial satellite is an object, typically a spacecraft, placed into orbit around a celestial body. They have a variety of uses, including communication relay, weather forecasting, navigation ( GPS), broadcasting, scienti ...
s that
orbit In celestial mechanics, an orbit (also known as orbital revolution) is the curved trajectory of an object such as the trajectory of a planet around a star, or of a natural satellite around a planet, or of an artificial satellite around an ...
Earth.


Thermosphere

The thermosphere is the second-highest layer of Earth's atmosphere. It extends from the mesopause (which separates it from the mesosphere) at an altitude of about up to the
thermopause The thermopause is the atmospheric boundary of Earth's energy system, located at the top of the thermosphere. The temperature of the thermopause could range from nearly absolute zero to . Below this, the atmosphere is defined to be active on the ...
at an altitude range of . The height of the thermopause varies considerably due to changes in solar activity. Because the thermopause lies at the lower boundary of the exosphere, it is also referred to as the exobase. The lower part of the thermosphere, from above Earth's surface, contains the
ionosphere The ionosphere () is the ionized part of the upper atmosphere of Earth, from about to above sea level, a region that includes the thermosphere and parts of the mesosphere and exosphere. The ionosphere is ionized by solar radiation. It plays ...
. The temperature of the thermosphere gradually increases with height and can rise as high as , though the gas molecules are so far apart that its temperature in the usual sense is not very meaningful. The air is so rarefied that an individual molecule (of
oxygen Oxygen is a chemical element; it has chemical symbol, symbol O and atomic number 8. It is a member of the chalcogen group (periodic table), group in the periodic table, a highly reactivity (chemistry), reactive nonmetal (chemistry), non ...
, for example) travels an average of between collisions with other molecules. Although the thermosphere has a high proportion of molecules with high energy, it would not feel hot to a human in direct contact, because its density is too low to conduct a significant amount of energy to or from the skin. This layer is completely cloudless and free of water vapor. However, non-hydrometeorological phenomena such as the aurora borealis and aurora australis are occasionally seen in the thermosphere. The
International Space Station The International Space Station (ISS) is a large space station that was Assembly of the International Space Station, assembled and is maintained in low Earth orbit by a collaboration of five space agencies and their contractors: NASA (United ...
orbits in this layer, between . It is this layer where many of the satellites orbiting the Earth are present.


Mesosphere

The mesosphere is the third highest layer of Earth's atmosphere, occupying the region above the stratosphere and below the thermosphere. It extends from the stratopause at an altitude of about to the mesopause at above sea level. Temperatures drop with increasing altitude to the mesopause that marks the top of this middle layer of the atmosphere. It is the coldest place on Earth and has an average temperature around . Just below the mesopause, the air is so cold that even the very scarce water vapor at this altitude can condense into polar-mesospheric noctilucent clouds of ice particles. These are the highest clouds in the atmosphere and may be visible to the naked eye if sunlight reflects off them about an hour or two after sunset or similarly before sunrise. They are most readily visible when the Sun is around 4 to 16 degrees below the horizon. Lightning-induced discharges known as transient luminous events (TLEs) occasionally form in the mesosphere above tropospheric thunderclouds. The mesosphere is also the layer where most
meteor A meteor, known colloquially as a shooting star, is a glowing streak of a small body (usually meteoroid) going through Earth's atmosphere, after being heated to incandescence by collisions with air molecules in the upper atmosphere, creating a ...
s burn up upon atmospheric entrance. It is too high above Earth to be accessible to jet-powered aircraft and balloons, and too low to permit orbital spacecraft. The mesosphere is mainly accessed by sounding rockets and rocket-powered aircraft.


Stratosphere

The stratosphere is the second-lowest layer of Earth's atmosphere. It lies above the troposphere and is separated from it by the tropopause. This layer extends from the top of the troposphere at roughly above Earth's surface to the stratopause at an altitude of about . The atmospheric pressure at the top of the stratosphere is roughly 1/1000 the pressure at sea level. It contains the
ozone layer The ozone layer or ozone shield is a region of Earth's stratosphere that absorption (electromagnetic radiation), absorbs most of the Sun's ultraviolet radiation. It contains a high concentration of ozone (O3) in relation to other parts of the a ...
, which is the part of Earth's atmosphere that contains relatively high concentrations of that gas. The stratosphere defines a layer in which temperatures rise with increasing altitude. This rise in temperature is caused by the absorption of
ultraviolet radiation Ultraviolet radiation, also known as simply UV, is electromagnetic radiation of wavelengths of 10–400 nanometers, shorter than that of visible light, but longer than X-rays. UV radiation is present in sunlight and constitutes about 10% of t ...
(UV) from the Sun by the ozone layer, which restricts turbulence and mixing. Although the temperature may be at the tropopause, the top of the stratosphere is much warmer, and may be near 0 °C. The stratospheric temperature profile creates very stable atmospheric conditions, so the stratosphere lacks the weather-producing air turbulence that is so prevalent in the troposphere. Consequently, the stratosphere is almost completely free of clouds and other forms of weather. However, polar stratospheric or nacreous clouds are occasionally seen in the lower part of this layer of the atmosphere where the air is coldest. The stratosphere is the highest layer that can be accessed by jet-powered aircraft.


Troposphere

The troposphere is the lowest layer of Earth's atmosphere. It extends from Earth's surface to an average height of about , although this
altitude Altitude is a distance measurement, usually in the vertical or "up" direction, between a reference datum (geodesy), datum and a point or object. The exact definition and reference datum varies according to the context (e.g., aviation, geometr ...
varies from about at the geographic poles to at the
Equator The equator is the circle of latitude that divides Earth into the Northern Hemisphere, Northern and Southern Hemisphere, Southern Hemispheres of Earth, hemispheres. It is an imaginary line located at 0 degrees latitude, about in circumferen ...
, with some variation due to weather. The troposphere is bounded above by the tropopause, a boundary marked in most places by a temperature inversion (i.e. a layer of relatively warm air above a colder one), and in others by a zone that is isothermal with height. Although variations do occur, the temperature usually declines with increasing altitude in the troposphere because the troposphere is mostly heated through energy transfer from the surface. Thus, the lowest part of the troposphere (i.e. Earth's surface) is typically the warmest section of the troposphere. This promotes vertical mixing (hence, the origin of its name in the Greek word τρόπος, ''tropos'', meaning "turn"). The troposphere contains roughly 80% of the
mass Mass is an Intrinsic and extrinsic properties, intrinsic property of a physical body, body. It was traditionally believed to be related to the physical quantity, quantity of matter in a body, until the discovery of the atom and particle physi ...
of Earth's atmosphere. The troposphere is denser than all its overlying layers because a larger atmospheric weight sits on top of the troposphere and causes it to be most severely compressed. Fifty percent of the total mass of the atmosphere is located in the lower of the troposphere. Nearly all atmospheric water vapor or moisture is found in the troposphere, so it is the layer where most of Earth's weather takes place. It has basically all the weather-associated cloud genus types generated by active wind circulation, although very tall cumulonimbus thunder clouds can penetrate the tropopause from below and rise into the lower part of the stratosphere. Most conventional
aviation Aviation includes the activities surrounding mechanical flight and the aircraft industry. ''Aircraft'' include fixed-wing and rotary-wing types, morphable wings, wing-less lifting bodies, as well as lighter-than-air aircraft such as h ...
activity takes place in the troposphere, and it is the only layer accessible by propeller-driven aircraft.


Other layers

Within the five principal layers above, which are largely determined by temperature, several secondary layers may be distinguished by other properties: * The
ozone layer The ozone layer or ozone shield is a region of Earth's stratosphere that absorption (electromagnetic radiation), absorbs most of the Sun's ultraviolet radiation. It contains a high concentration of ozone (O3) in relation to other parts of the a ...
is contained within the stratosphere. In this layer
ozone Ozone () (or trioxygen) is an Inorganic compound, inorganic molecule with the chemical formula . It is a pale blue gas with a distinctively pungent smell. It is an allotrope of oxygen that is much less stable than the diatomic allotrope , break ...
concentrations are about 2 to 8 parts per million, which is much higher than in the lower atmosphere but still very small compared to the main components of the atmosphere. It is mainly located in the lower portion of the stratosphere from about , though the thickness varies seasonally and geographically. About 90% of the ozone in Earth's atmosphere is contained in the stratosphere. * The
ionosphere The ionosphere () is the ionized part of the upper atmosphere of Earth, from about to above sea level, a region that includes the thermosphere and parts of the mesosphere and exosphere. The ionosphere is ionized by solar radiation. It plays ...
is a region of the atmosphere that is ionized by solar radiation. It is responsible for auroras. During daytime hours, it stretches from and includes the mesosphere, thermosphere, and parts of the exosphere. However, ionization in the mesosphere largely ceases during the night, so auroras are normally seen only in the thermosphere and lower exosphere. The ionosphere forms the inner edge of the
magnetosphere In astronomy and planetary science, a magnetosphere is a region of space surrounding an astronomical object in which charged particles are affected by that object's magnetic field. It is created by a celestial body with an active interior Dynamo ...
. It has practical importance because it influences, for example, radio propagation on Earth. * The homosphere and heterosphere are defined by whether the atmospheric gases are well mixed. The surface-based homosphere includes the troposphere, stratosphere, mesosphere, and the lowest part of the thermosphere, where the chemical composition of the atmosphere does not depend on molecular weight because the gases are mixed by turbulence. This relatively homogeneous layer ends at the '' turbopause'' found at about , the very edge of space itself as accepted by the FAI, which places it about above the mesopause. :Above this altitude lies the heterosphere, which includes the exosphere and most of the thermosphere. Here, the chemical composition varies with altitude. This is because the distance that particles can move without colliding with one another is large compared with the size of motions that cause mixing. This allows the gases to stratify by molecular weight, with the heavier ones, such as oxygen and nitrogen, present only near the bottom of the heterosphere. The upper part of the heterosphere is composed almost completely of hydrogen, the lightest element. * The planetary boundary layer is the part of the troposphere that is closest to Earth's surface and is directly affected by it, mainly through turbulent diffusion. During the day the planetary boundary layer usually is well-mixed, whereas at night it becomes stably stratified with weak or intermittent mixing. The depth of the planetary boundary layer ranges from as little as about on clear, calm nights to or more during the afternoon in dry regions. The average temperature of the atmosphere at Earth's surface is or , depending on the reference.


Physical properties


Pressure and thickness

The average atmospheric pressure at sea level is defined by the International Standard Atmosphere as . This is sometimes referred to as a unit of standard atmospheres (atm). Total atmospheric mass is , about 2.5% less than would be inferred from the average sea-level pressure and Earth's area of 51007.2 megahectares, this portion being displaced by Earth's mountainous terrain. Atmospheric pressure is the total weight of the air above unit area at the point where the pressure is measured. Thus air pressure varies with location and
weather Weather is the state of the atmosphere, describing for example the degree to which it is hot or cold, wet or dry, calm or stormy, clear or cloud cover, cloudy. On Earth, most weather phenomena occur in the lowest layer of the planet's atmo ...
. If the entire mass of the atmosphere had a uniform density equal to sea-level density (about 1.2 kg/m3) from sea level upwards, it would terminate abruptly at an altitude of . Air pressure actually decreases exponentially with altitude, for altitudes up to around , dropping by half every , or by a factor of 1/ e ≈ 0.368 every , which is called the scale height. However, the atmosphere is more accurately modeled with a customized equation for each layer that takes gradients of temperature, molecular composition, solar radiation and gravity into account. At heights over 100 km, an atmosphere may no longer be well mixed. Then each chemical species has its own scale height. In summary, the mass of Earth's atmosphere is distributed approximately as follows: * 50% is below * 90% is below * 99.99997% is below , the
Kármán line The Kármán line (or von Kármán line ) is a conventional definition of the Outer space#Boundary, edge of space; it is widely but not universally accepted. The international record-keeping body Fédération Aéronautique Internationale, FAI ( ...
. By international convention, this marks the beginning of space where human travelers are considered
astronaut An astronaut (from the Ancient Greek (), meaning 'star', and (), meaning 'sailor') is a person trained, equipped, and deployed by a List of human spaceflight programs, human spaceflight program to serve as a commander or crew member of a spa ...
s. By comparison, the summit of
Mount Everest Mount Everest (), known locally as Sagarmatha in Nepal and Qomolangma in Tibet, is Earth's highest mountain above sea level. It lies in the Mahalangur Himal sub-range of the Himalayas and marks part of the China–Nepal border at it ...
is at ; commercial airliners typically cruise between , where the lower density and temperature of the air improve fuel economy; weather balloons reach and above; and the highest
X-15 The North American X-15 is a Hypersonic speed, hypersonic rocket-powered aircraft which was operated by the United States Air Force and the National Aeronautics and Space Administration (NASA) as part of the List of X-planes, X-plane series of ...
flight in 1963 reached . Even above the Kármán line, significant atmospheric effects such as auroras still occur. Meteors begin to glow in this region, though the larger ones may not burn up until they penetrate more deeply. The various layers of Earth's
ionosphere The ionosphere () is the ionized part of the upper atmosphere of Earth, from about to above sea level, a region that includes the thermosphere and parts of the mesosphere and exosphere. The ionosphere is ionized by solar radiation. It plays ...
, important to HF radio propagation, begin below 100 km and extend beyond 500 km. By comparison, the
International Space Station The International Space Station (ISS) is a large space station that was Assembly of the International Space Station, assembled and is maintained in low Earth orbit by a collaboration of five space agencies and their contractors: NASA (United ...
and
Space Shuttle The Space Shuttle is a retired, partially reusable launch system, reusable low Earth orbital spacecraft system operated from 1981 to 2011 by the U.S. National Aeronautics and Space Administration (NASA) as part of the Space Shuttle program. ...
typically orbit at 350–400 km, within the F-layer of the ionosphere, where they encounter enough
atmospheric drag In fluid dynamics, drag, sometimes referred to as fluid resistance, is a force acting opposite to the direction of motion of any object moving with respect to a surrounding fluid. This can exist between two fluid layers, two solid surfaces, or b ...
to require reboosts every few months, otherwise orbital decay will occur, resulting in a return to Earth. Depending on solar activity, satellites can experience noticeable atmospheric drag at altitudes as high as 700–800 km.


Temperature

The division of the atmosphere into layers mostly by reference to temperature is discussed above. Temperature decreases with altitude starting at sea level, but variations in this trend begin above 11 km, where the temperature stabilizes over a large vertical distance through the rest of the troposphere. In the
stratosphere The stratosphere () is the second-lowest layer of the atmosphere of Earth, located above the troposphere and below the mesosphere. The stratosphere is composed of stratified temperature zones, with the warmer layers of air located higher ...
, starting above about 20 km, the temperature increases with height, due to heating within the ozone layer caused by the capture of significant
ultraviolet Ultraviolet radiation, also known as simply UV, is electromagnetic radiation of wavelengths of 10–400 nanometers, shorter than that of visible light, but longer than X-rays. UV radiation is present in sunlight and constitutes about 10% of ...
radiation from the Sun by the dioxygen and ozone gas in this region. Still another region of increasing temperature with altitude occurs at very high altitudes, in the aptly-named thermosphere above 90 km.


Speed of sound

Because in an
ideal gas An ideal gas is a theoretical gas composed of many randomly moving point particles that are not subject to interparticle interactions. The ideal gas concept is useful because it obeys the ideal gas law, a simplified equation of state, and is ...
of constant composition the
speed of sound The speed of sound is the distance travelled per unit of time by a sound wave as it propagates through an elasticity (solid mechanics), elastic medium. More simply, the speed of sound is how fast vibrations travel. At , the speed of sound in a ...
depends only on temperature and not on pressure or density, the speed of sound in the atmosphere with altitude takes on the form of the complicated temperature profile (see illustration to the right), and does not mirror altitudinal changes in density or pressure.


Density and mass

The density of air at sea level is about 1.2 kg/m3 (1.2 g/L, 0.0012 g/cm3). Density is not measured directly but is calculated from measurements of temperature, pressure and humidity using the equation of state for air (a form of the
ideal gas law The ideal gas law, also called the general gas equation, is the equation of state of a hypothetical ideal gas. It is a good approximation of the behavior of many gases under many conditions, although it has several limitations. It was first stat ...
). Atmospheric density decreases as the altitude increases. This variation can be approximately modeled using the barometric formula. More sophisticated models are used to predict the orbital decay of satellites. The average mass of the atmosphere is about 5 quadrillion (5)
tonne The tonne ( or ; symbol: t) is a unit of mass equal to 1,000  kilograms. It is a non-SI unit accepted for use with SI. It is also referred to as a metric ton in the United States to distinguish it from the non-metric units of the s ...
s or 1/1,200,000 the mass of Earth. According to the American
National Center for Atmospheric Research The US National Center for Atmospheric Research (NCAR ) is a US federally funded research and development center (FFRDC) managed by the nonprofit University Corporation for Atmospheric Research (UCAR) and funded by the National Science Foundat ...
, "The total mean mass of the atmosphere is 5.1480 kg with an annual range due to water vapor of 1.2 or 1.5 kg, depending on whether surface pressure or water vapor data are used; somewhat smaller than the previous estimate. The mean mass of water vapor is estimated as 1.27 kg and the dry air mass as 5.1352 ±0.0003 kg."


Tabulated properties


Optical properties

Solar
radiation In physics, radiation is the emission or transmission of energy in the form of waves or particles through space or a material medium. This includes: * ''electromagnetic radiation'' consisting of photons, such as radio waves, microwaves, infr ...
(or sunlight) is the energy Earth receives from the Sun. Earth also emits radiation back into space, but at longer wavelengths that humans cannot see. Part of the incoming and emitted radiation is absorbed or reflected by the atmosphere. In May 2017, glints of light, seen as twinkling from an orbiting satellite a million miles away, were found to be reflected light from
ice crystals Ice crystals are solid water (known as ice) in crystal structure, symmetrical shapes including hexagonal crystal family, hexagonal columns, hexagonal plates, and dendrite (crystal), dendritic crystals. Ice crystals are responsible for various at ...
in the atmosphere.


Scattering

When light passes through Earth's atmosphere,
photon A photon () is an elementary particle that is a quantum of the electromagnetic field, including electromagnetic radiation such as light and radio waves, and the force carrier for the electromagnetic force. Photons are massless particles that can ...
s interact with it through ''scattering''. If the light does not interact with the atmosphere, it is called ''direct radiation'' and is what you see if you were to look directly at the Sun. ''Indirect radiation'' is light that has been scattered in the atmosphere. For example, on an overcast day when you cannot see your shadow, there is no direct radiation reaching you, it has all been scattered. As another example, due to a phenomenon called
Rayleigh scattering Rayleigh scattering ( ) is the scattering or deflection of light, or other electromagnetic radiation, by particles with a size much smaller than the wavelength of the radiation. For light frequencies well below the resonance frequency of the scat ...
, shorter (blue) wavelengths scatter more easily than longer (red) wavelengths. This is why the sky looks blue; you are seeing scattered blue light. This is also why sunsets are red. Because the Sun is close to the horizon, the Sun's rays pass through more atmosphere than normal before reaching your eye. Much of the blue light has been scattered out, leaving the red light in a sunset.


Absorption

Different molecules absorb different wavelengths of radiation. For example, O2 and O3 absorb almost all radiation with wavelengths shorter than 300
nanometre 330px, Different lengths as in respect to the Molecule">molecular scale. The nanometre (international spelling as used by the International Bureau of Weights and Measures; SI symbol: nm), or nanometer (American spelling), is a unit of length ...
s. Water (H2O) absorbs at many wavelengths above 700 nm. When a molecule absorbs a photon, it increases the energy of the molecule. This heats the atmosphere, but the atmosphere also cools by emitting radiation, as discussed below. The combined absorption spectra of the gases in the atmosphere leave "windows" of low opacity, allowing the transmission of only certain bands of light. The
optical window The optical window is the portion of the optical spectrum that is blocked by the Earth's atmosphere. The window runs from around 300 nanometers ( ultraviolet-B) up into the range the human eye can detect, roughly 400–700 nm and continues up ...
runs from around 300 nm (
ultraviolet Ultraviolet radiation, also known as simply UV, is electromagnetic radiation of wavelengths of 10–400 nanometers, shorter than that of visible light, but longer than X-rays. UV radiation is present in sunlight and constitutes about 10% of ...
-C) up into the range humans can see, the
visible spectrum The visible spectrum is the spectral band, band of the electromagnetic spectrum that is visual perception, visible to the human eye. Electromagnetic radiation in this range of wavelengths is called ''visible light'' (or simply light). The optica ...
(commonly called light), at roughly 400–700 nm and continues to the
infrared Infrared (IR; sometimes called infrared light) is electromagnetic radiation (EMR) with wavelengths longer than that of visible light but shorter than microwaves. The infrared spectral band begins with the waves that are just longer than those ...
to around 1100 nm. There are also
infrared Infrared (IR; sometimes called infrared light) is electromagnetic radiation (EMR) with wavelengths longer than that of visible light but shorter than microwaves. The infrared spectral band begins with the waves that are just longer than those ...
and
radio window The radio window is the region of the radio spectrum that penetrate the Earth's atmosphere. Typically, the lower limit of the radio window's range has a value of about 10 MHz (λ ≈ 30 m); the best upper limit achievable from optimal terrestria ...
s that transmit some infrared and
radio waves Radio waves (formerly called Hertzian waves) are a type of electromagnetic radiation with the lowest frequencies and the longest wavelengths in the electromagnetic spectrum, typically with frequencies below 300 gigahertz (GHz) and wavelengths ...
at longer wavelengths. For example, the radio window runs from about one centimetre to about eleven-metre waves.


Emission

''Emission'' is the opposite of absorption, it is when an object emits radiation. Objects tend to emit amounts and wavelengths of radiation depending on their " black body" emission curves, therefore hotter objects tend to emit more radiation, with shorter wavelengths. Colder objects emit less radiation, with longer wavelengths. For example, the Sun is approximately , its radiation peaks near 500 nm, and is visible to the human eye. Earth is approximately , so its radiation peaks near 10,000 nm, and is much too long to be visible to humans. Because of its temperature, the atmosphere emits infrared radiation. For example, on clear nights Earth's surface cools down faster than on cloudy nights. This is because clouds (H2O) are strong absorbers and emitters of infrared radiation. This is also why it becomes colder at night at higher elevations. The
greenhouse effect The greenhouse effect occurs when greenhouse gases in a planet's atmosphere insulate the planet from losing heat to space, raising its surface temperature. Surface heating can happen from an internal heat source (as in the case of Jupiter) or ...
is directly related to this absorption and emission effect. Some gases in the atmosphere absorb and emit infrared radiation, but do not interact with sunlight in the visible spectrum. Common examples of these are and H2O.


Refractive index

The
refractive index In optics, the refractive index (or refraction index) of an optical medium is the ratio of the apparent speed of light in the air or vacuum to the speed in the medium. The refractive index determines how much the path of light is bent, or refrac ...
of air is close to, but just greater than, 1. Systematic variations in the refractive index can lead to the bending of light rays over long optical paths. One example is that, under some circumstances, observers on board ships can see other vessels just over the
horizon The horizon is the apparent curve that separates the surface of a celestial body from its sky when viewed from the perspective of an observer on or near the surface of the relevant body. This curve divides all viewing directions based on whethe ...
because light is refracted in the same direction as the
curvature In mathematics, curvature is any of several strongly related concepts in geometry that intuitively measure the amount by which a curve deviates from being a straight line or by which a surface deviates from being a plane. If a curve or su ...
of Earth's surface. The refractive index of air depends on temperature, giving rise to refraction effects when the temperature gradient is large. An example of such effects is the mirage.


Circulation

''Atmospheric circulation'' is the large-scale movement of air through the troposphere, and the means (with ocean circulation) by which heat is distributed around Earth. The large-scale structure of the atmospheric circulation varies from year to year, but the basic structure remains fairly constant because it is determined by Earth's rotation rate and the difference in solar radiation between the equator and poles.


Evolution of Earth's atmosphere


Earliest atmosphere

The first atmosphere, during the Early Earth's Hadean eon, consisted of gases in the
solar nebula There is evidence that the formation of the Solar System began about 4.6 bya, billion years ago with the gravitational collapse of a small part of a giant molecular cloud. Most of the collapsing mass collected in the center, forming the Sun, whil ...
, primarily
hydrogen Hydrogen is a chemical element; it has chemical symbol, symbol H and atomic number 1. It is the lightest and abundance of the chemical elements, most abundant chemical element in the universe, constituting about 75% of all baryon, normal matter ...
, and probably simple
hydride In chemistry, a hydride is formally the anion of hydrogen (H−), a hydrogen ion with two electrons. In modern usage, this is typically only used for ionic bonds, but it is sometimes (and has been more frequently in the past) applied to all che ...
s such as those now found in the
gas giant A gas giant is a giant planet composed mainly of hydrogen and helium. Jupiter and Saturn are the gas giants of the Solar System. The term "gas giant" was originally synonymous with "giant planet". However, in the 1990s, it became known that Uranu ...
s (
Jupiter Jupiter is the fifth planet from the Sun and the List of Solar System objects by size, largest in the Solar System. It is a gas giant with a Jupiter mass, mass more than 2.5 times that of all the other planets in the Solar System combined a ...
and
Saturn Saturn is the sixth planet from the Sun and the second largest in the Solar System, after Jupiter. It is a gas giant, with an average radius of about 9 times that of Earth. It has an eighth the average density of Earth, but is over 95 tim ...
), notably
water vapor Water vapor, water vapour, or aqueous vapor is the gaseous phase of Properties of water, water. It is one Phase (matter), state of water within the hydrosphere. Water vapor can be produced from the evaporation or boiling of liquid water or from th ...
,
methane Methane ( , ) is a chemical compound with the chemical formula (one carbon atom bonded to four hydrogen atoms). It is a group-14 hydride, the simplest alkane, and the main constituent of natural gas. The abundance of methane on Earth makes ...
and
ammonia Ammonia is an inorganic chemical compound of nitrogen and hydrogen with the chemical formula, formula . A Binary compounds of hydrogen, stable binary hydride and the simplest pnictogen hydride, ammonia is a colourless gas with a distinctive pu ...
. During this earliest era, the Moon-forming collision and numerous impacts with large
meteorite A meteorite is a rock (geology), rock that originated in outer space and has fallen to the surface of a planet or Natural satellite, moon. When the original object enters the atmosphere, various factors such as friction, pressure, and chemical ...
s heated the atmosphere, driving off the most volatile gases. The collision with Theia, in particular, melted and ejected large portions of Earth's mantle and crust and outgassed significant amounts of
steam Steam is water vapor, often mixed with air or an aerosol of liquid water droplets. This may occur due to evaporation or due to boiling, where heat is applied until water reaches the enthalpy of vaporization. Saturated or superheated steam is inv ...
which eventually cooled and condensed to contribute to ocean water at the end of the Hadean.


Second atmosphere

The increasing
solidification Freezing is a phase transition in which a liquid turns into a solid when its temperature is lowered below its freezing point. For most substances, the melting and freezing points are the same temperature; however, certain substances possess dif ...
of
Earth's crust Earth's crust is its thick outer shell of rock, referring to less than one percent of the planet's radius and volume. It is the top component of the lithosphere, a solidified division of Earth's layers that includes the crust and the upper ...
at the end of the Hadean closed off most of the advective
heat transfer Heat transfer is a discipline of thermal engineering that concerns the generation, use, conversion, and exchange of thermal energy (heat) between physical systems. Heat transfer is classified into various mechanisms, such as thermal conduction, ...
to the surface, causing the atmosphere to cool, which condensed most of the water vapor out of the air precipitating into a superocean. Further
outgassing Outgassing (sometimes called offgassing, particularly when in reference to indoor air quality) is the release of a gas that was dissolved, trapped, frozen, or absorbed in some material. Outgassing can include sublimation and evaporation (whic ...
from volcanism, supplemented by gases introduced by huge
asteroid An asteroid is a minor planet—an object larger than a meteoroid that is neither a planet nor an identified comet—that orbits within the Solar System#Inner Solar System, inner Solar System or is co-orbital with Jupiter (Trojan asteroids). As ...
s during the Late Heavy Bombardment, created the subsequent
Archean The Archean ( , also spelled Archaean or Archæan), in older sources sometimes called the Archaeozoic, is the second of the four geologic eons of Earth's history of Earth, history, preceded by the Hadean Eon and followed by the Proterozoic and t ...
atmosphere, which consisted largely of
nitrogen Nitrogen is a chemical element; it has Symbol (chemistry), symbol N and atomic number 7. Nitrogen is a Nonmetal (chemistry), nonmetal and the lightest member of pnictogen, group 15 of the periodic table, often called the Pnictogen, pnictogens. ...
plus
carbon dioxide Carbon dioxide is a chemical compound with the chemical formula . It is made up of molecules that each have one carbon atom covalent bond, covalently double bonded to two oxygen atoms. It is found in a gas state at room temperature and at norma ...
,
methane Methane ( , ) is a chemical compound with the chemical formula (one carbon atom bonded to four hydrogen atoms). It is a group-14 hydride, the simplest alkane, and the main constituent of natural gas. The abundance of methane on Earth makes ...
and
inert gas An inert gas is a gas that does not readily undergo chemical reactions with other chemical substances and therefore does not readily form chemical compounds. Though inert gases have a variety of applications, they are generally used to prevent u ...
es. A major part of carbon dioxide emissions dissolved in water and reacted with metals such as
calcium Calcium is a chemical element; it has symbol Ca and atomic number 20. As an alkaline earth metal, calcium is a reactive metal that forms a dark oxide-nitride layer when exposed to air. Its physical and chemical properties are most similar to it ...
and
magnesium Magnesium is a chemical element; it has Symbol (chemistry), symbol Mg and atomic number 12. It is a shiny gray metal having a low density, low melting point and high chemical reactivity. Like the other alkaline earth metals (group 2 ...
during
weathering Weathering is the deterioration of rocks, soils and minerals (as well as wood and artificial materials) through contact with water, atmospheric gases, sunlight, and biological organisms. It occurs '' in situ'' (on-site, with little or no move ...
of crustal rocks to form
carbonate A carbonate is a salt of carbonic acid, (), characterized by the presence of the carbonate ion, a polyatomic ion with the formula . The word "carbonate" may also refer to a carbonate ester, an organic compound containing the carbonate group ...
s that were deposited as
sediment Sediment is a solid material that is transported to a new location where it is deposited. It occurs naturally and, through the processes of weathering and erosion, is broken down and subsequently sediment transport, transported by the action of ...
s. Water-related sediments have been found that date from as early as 3.8 billion years ago. About 3.4 billion years ago, nitrogen formed the major component of the then-stable "second atmosphere". The influence of the evolution of life has to be taken into account rather soon in the history of the atmosphere because hints of earliest life forms appeared as early as 3.5 billion years ago. How Earth at that time maintained a climate warm enough for liquid water and life, if the early Sun put out 30% lower solar radiance than today, is a puzzle known as the " faint young Sun paradox". The geological record however shows a continuous relatively warm surface during the complete early temperature record of Earth – with the exception of one cold glacial phase about 2.4 billion years ago. In the late Neoarchean, an oxygen-containing atmosphere began to develop, apparently due to a billion years of
cyanobacteria Cyanobacteria ( ) are a group of autotrophic gram-negative bacteria that can obtain biological energy via oxygenic photosynthesis. The name "cyanobacteria" () refers to their bluish green (cyan) color, which forms the basis of cyanobacteri ...
l
photosynthesis Photosynthesis ( ) is a system of biological processes by which photosynthetic organisms, such as most plants, algae, and cyanobacteria, convert light energy, typically from sunlight, into the chemical energy necessary to fuel their metabo ...
(see Great Oxygenation Event), which have been found as
stromatolite Stromatolites ( ) or stromatoliths () are layered Sedimentary rock, sedimentary formation of rocks, formations (microbialite) that are created mainly by Photosynthesis, photosynthetic microorganisms such as cyanobacteria, sulfate-reducing micr ...
fossil A fossil (from Classical Latin , ) is any preserved remains, impression, or trace of any once-living thing from a past geological age. Examples include bones, shells, exoskeletons, stone imprints of animals or microbes, objects preserve ...
s from 2.7 billion years ago. The early basic carbon isotopy ( isotope ratio proportions) strongly suggests conditions similar to the current, and that the fundamental features of the
carbon cycle The carbon cycle is a part of the biogeochemical cycle where carbon is exchanged among the biosphere, pedosphere, geosphere, hydrosphere, and atmosphere of Earth. Other major biogeochemical cycles include the nitrogen cycle and the water cycl ...
became established as early as 4 billion years ago. Ancient sediments in the
Gabon Gabon ( ; ), officially the Gabonese Republic (), is a country on the Atlantic coast of Central Africa, on the equator, bordered by Equatorial Guinea to the northwest, Cameroon to the north, the Republic of the Congo to the east and south, and ...
dating from between about 2.15 and 2.08 billion years ago provide a record of Earth's dynamic oxygenation evolution. These fluctuations in oxygenation were likely driven by the Lomagundi carbon isotope excursion.


Third atmosphere

The constant re-arrangement of
continent A continent is any of several large geographical regions. Continents are generally identified by convention (norm), convention rather than any strict criteria. A continent could be a single large landmass, a part of a very large landmass, as ...
s by
plate tectonics Plate tectonics (, ) is the scientific theory that the Earth's lithosphere comprises a number of large tectonic plates, which have been slowly moving since 3–4 billion years ago. The model builds on the concept of , an idea developed durin ...
influences the long-term evolution of the atmosphere by transferring carbon dioxide to and from large continental
carbonate A carbonate is a salt of carbonic acid, (), characterized by the presence of the carbonate ion, a polyatomic ion with the formula . The word "carbonate" may also refer to a carbonate ester, an organic compound containing the carbonate group ...
stores. Free oxygen did not exist in the atmosphere until about 2.4 billion years ago during the Great Oxygenation Event and its appearance is indicated by the end of
banded iron formation Banded iron formations (BIFs; also called banded ironstone formations) are distinctive units of sedimentary rock consisting of alternating layers of iron oxides and iron-poor chert. They can be up to several hundred meters in thickness and e ...
s (which signals the depletion of substrates that can react with oxygen to produce
ferric In chemistry, iron(III) or ''ferric'' refers to the chemical element, element iron in its +3 oxidation number, oxidation state. ''Ferric chloride'' is an alternative name for iron(III) chloride (). The adjective ''ferrous'' is used instead for i ...
deposits) during the early
Proterozoic The Proterozoic ( ) is the third of the four geologic eons of Earth's history, spanning the time interval from 2500 to 538.8 Mya, and is the longest eon of Earth's geologic time scale. It is preceded by the Archean and followed by the Phanerozo ...
eon. Before this time, any oxygen produced by cyanobacterial photosynthesis would be readily removed by the
oxidation Redox ( , , reduction–oxidation or oxidation–reduction) is a type of chemical reaction in which the oxidation states of the reactants change. Oxidation is the loss of electrons or an increase in the oxidation state, while reduction is ...
of reducing substances on the Earth's surface, notably ferrous iron,
sulfur Sulfur ( American spelling and the preferred IUPAC name) or sulphur ( Commonwealth spelling) is a chemical element; it has symbol S and atomic number 16. It is abundant, multivalent and nonmetallic. Under normal conditions, sulfur atoms ...
and atmospheric methane. Free oxygen molecules did not start to accumulate in the atmosphere until the rate of production of oxygen began to exceed the availability of reductant materials that removed oxygen. This point signifies a shift from a reducing atmosphere to an oxidizing atmosphere. O2 showed major variations during the Proterozoic, including a billion-year period of euxinia, until reaching a steady state of more than 15% by the end of the
Precambrian The Precambrian ( ; or pre-Cambrian, sometimes abbreviated pC, or Cryptozoic) is the earliest part of Earth's history, set before the current Phanerozoic Eon. The Precambrian is so named because it preceded the Cambrian, the first period of t ...
. The rise of the more robust
eukaryotic The eukaryotes ( ) constitute the Domain (biology), domain of Eukaryota or Eukarya, organisms whose Cell (biology), cells have a membrane-bound cell nucleus, nucleus. All animals, plants, Fungus, fungi, seaweeds, and many unicellular organisms ...
photoautotrophs (
green Green is the color between cyan and yellow on the visible spectrum. It is evoked by light which has a dominant wavelength of roughly 495570 nm. In subtractive color systems, used in painting and color printing, it is created by a com ...
and
red algae Red algae, or Rhodophyta (, ; ), make up one of the oldest groups of eukaryotic algae. The Rhodophyta comprises one of the largest Phylum, phyla of algae, containing over 7,000 recognized species within over 900 Genus, genera amidst ongoing taxon ...
) injected further oxygenation into the air, especially after the end of the
Cryogenian The Cryogenian (from , meaning "cold" and , romanized: , meaning "birth") is a geologic period that lasted from . It is the second of the three periods of the Neoproterozoic era, preceded by the Tonian and followed by the Ediacaran. The Cryoge ...
global glaciation, which was followed by an
evolutionary radiation An evolutionary radiation is an increase in taxonomic diversity that is caused by elevated rates of speciation, that may or may not be associated with an increase in morphological disparity. A significantly large and diverse radiation within ...
event during the
Ediacaran The Ediacaran ( ) is a geological period of the Neoproterozoic geologic era, Era that spans 96 million years from the end of the Cryogenian Period at 635 Million years ago, Mya to the beginning of the Cambrian Period at 538.8 Mya. It is the last ...
period known as the Avalon explosion, where complex metazoan life forms (including the earliest
cnidarian Cnidaria ( ) is a phylum under kingdom Animalia containing over 11,000 species of aquatic invertebrates found both in fresh water, freshwater and marine environments (predominantly the latter), including jellyfish, hydroid (zoology), hydroids, ...
s,
placozoa Placozoa ( ; ) is a phylum of free-living (non-parasitic) marine invertebrates. They are blob-like animals composed of aggregations of cells. Moving in water by ciliary motion, eating food by Phagocytosis, engulfment, reproducing by Fission (biol ...
ns and
bilaterian Bilateria () is a large clade of animals characterised by bilateral symmetry during embryonic development. This means their body plans are laid around a longitudinal axis with a front (or "head") and a rear (or "tail") end, as well as a left–r ...
s) first proliferated. The following time span from 539 million years ago to the present day is the
Phanerozoic The Phanerozoic is the current and the latest of the four eon (geology), geologic eons in the Earth's geologic time scale, covering the time period from 538.8 million years ago to the present. It is the eon during which abundant animal and ...
eon, during the earliest period of which, the
Cambrian The Cambrian ( ) is the first geological period of the Paleozoic Era, and the Phanerozoic Eon. The Cambrian lasted 51.95 million years from the end of the preceding Ediacaran period 538.8 Ma (million years ago) to the beginning of the Ordov ...
, more actively moving metazoan life began to appear and rapidly diversify in another radiation event called the Cambrian explosion, whose
locomotive A locomotive is a rail transport, rail vehicle that provides the motive power for a train. Traditionally, locomotives pulled trains from the front. However, Push–pull train, push–pull operation has become common, and in the pursuit for ...
metabolism Metabolism (, from ''metabolē'', "change") is the set of life-sustaining chemical reactions in organisms. The three main functions of metabolism are: the conversion of the energy in food to energy available to run cellular processes; the co ...
was fuelled by the rising oxygen level. The amount of oxygen in the atmosphere has fluctuated over the last 600 million years, reaching a peak of about 30% around 280 million years ago during the
Carboniferous The Carboniferous ( ) is a Geologic time scale, geologic period and System (stratigraphy), system of the Paleozoic era (geology), era that spans 60 million years, from the end of the Devonian Period Ma (million years ago) to the beginning of the ...
period, significantly higher than today's 21%. Two main processes govern changes in the atmosphere: the evolution of
plant Plants are the eukaryotes that form the Kingdom (biology), kingdom Plantae; they are predominantly Photosynthesis, photosynthetic. This means that they obtain their energy from sunlight, using chloroplasts derived from endosymbiosis with c ...
s and their increasing role in
carbon fixation Biological carbon fixation, or сarbon assimilation, is the Biological process, process by which living organisms convert Total inorganic carbon, inorganic carbon (particularly carbon dioxide, ) to Organic compound, organic compounds. These o ...
, and the consumption of oxygen by rapidly diversifying
animal Animals are multicellular, eukaryotic organisms in the Biology, biological Kingdom (biology), kingdom Animalia (). With few exceptions, animals heterotroph, consume organic material, Cellular respiration#Aerobic respiration, breathe oxygen, ...
fauna Fauna (: faunae or faunas) is all of the animal life present in a particular region or time. The corresponding terms for plants and fungi are ''flora'' and '' funga'', respectively. Flora, fauna, funga and other forms of life are collectively ...
e and also by plants for photorespiration and their own metabolic needs at night. Breakdown of
pyrite The mineral pyrite ( ), or iron pyrite, also known as fool's gold, is an iron sulfide with the chemical formula Fe S2 (iron (II) disulfide). Pyrite is the most abundant sulfide mineral. Pyrite's metallic luster and pale brass-yellow hue ...
and
volcanic eruption A volcanic eruption occurs when material is expelled from a volcanic vent or fissure. Several types of volcanic eruptions have been distinguished by volcanologists. These are often named after famous volcanoes where that type of behavior h ...
s release sulfur into the atmosphere, which reacts and hence reduces oxygen in the atmosphere. However, volcanic eruptions also release carbon dioxide, which can fuel oxygenic photosynthesis by terrestrial and
aquatic plant Aquatic plants, also referred to as hydrophytes, are vascular plants and Non-vascular plant, non-vascular plants that have adapted to live in aquatic ecosystem, aquatic environments (marine ecosystem, saltwater or freshwater ecosystem, freshwater ...
s. The cause of the variation of the amount of oxygen in the atmosphere is not precisely understood. Periods with more oxygen in the atmosphere were often associated with more rapid development of animals.


Air pollution

is the introduction of airborne
chemical A chemical substance is a unique form of matter with constant chemical composition and characteristic properties. Chemical substances may take the form of a single element or chemical compounds. If two or more chemical substances can be combin ...
s,
particulate matter Particulate matter (PM) or particulates are microscopic particles of solid or liquid matter suspended in the air. An ''aerosol'' is a mixture of particulates and air, as opposed to the particulate matter alone, though it is sometimes defin ...
or biological materials that cause harm or discomfort to organisms. The
population growth Population growth is the increase in the number of people in a population or dispersed group. The World population, global population has grown from 1 billion in 1800 to 8.2 billion in 2025. Actual global human population growth amounts to aroun ...
,
industrialization Industrialisation (British English, UK) American and British English spelling differences, or industrialization (American English, US) is the period of social and economic change that transforms a human group from an agrarian society into an i ...
and motorization of
human Humans (''Homo sapiens'') or modern humans are the most common and widespread species of primate, and the last surviving species of the genus ''Homo''. They are Hominidae, great apes characterized by their Prehistory of nakedness and clothing ...
societies A society () is a group of individuals involved in persistent social interaction or a large social group sharing the same spatial or social territory, typically subject to the same political authority and dominant cultural expectations. ...
have significantly increased the amount of airborne
pollutant A pollutant or novel entity is a substance or energy introduced into the environment that has undesired effect, or adversely affects the usefulness of a resource. These can be both naturally forming (i.e. minerals or extracted compounds like oi ...
s in the Earth's atmosphere, causing noticeable problems such as
smog Smog, or smoke fog, is a type of intense air pollution. The word "smog" was coined in the early 20th century, and is a portmanteau of the words ''smoke'' and ''fog'' to refer to smoky fog due to its opacity, and odour. The word was then inte ...
s,
acid rain Acid rain is rain or any other form of Precipitation (meteorology), precipitation that is unusually acidic, meaning that it has elevated levels of hydrogen ions (low pH). Most water, including drinking water, has a neutral pH that exists b ...
s and pollution-related diseases. The depletion of stratospheric
ozone layer The ozone layer or ozone shield is a region of Earth's stratosphere that absorption (electromagnetic radiation), absorbs most of the Sun's ultraviolet radiation. It contains a high concentration of ozone (O3) in relation to other parts of the a ...
, which shields the surface from harmful ionizing
ultraviolet Ultraviolet radiation, also known as simply UV, is electromagnetic radiation of wavelengths of 10–400 nanometers, shorter than that of visible light, but longer than X-rays. UV radiation is present in sunlight and constitutes about 10% of ...
radiations, is also caused by air pollution, chiefly from chlorofluorocarbons and other ozone-depleting substances. Since 1750, human activity, especially after the
Industrial Revolution The Industrial Revolution, sometimes divided into the First Industrial Revolution and Second Industrial Revolution, was a transitional period of the global economy toward more widespread, efficient and stable manufacturing processes, succee ...
, has increased the concentrations of various
greenhouse gas Greenhouse gases (GHGs) are the gases in the atmosphere that raise the surface temperature of planets such as the Earth. Unlike other gases, greenhouse gases absorb the radiations that a planet emits, resulting in the greenhouse effect. T ...
es, most importantly carbon dioxide, methane and
nitrous oxide Nitrous oxide (dinitrogen oxide or dinitrogen monoxide), commonly known as laughing gas, nitrous, or factitious air, among others, is a chemical compound, an Nitrogen oxide, oxide of nitrogen with the Chemical formula, formula . At room te ...
.
Greenhouse gas emissions Greenhouse gas (GHG) emissions from human activities intensify the greenhouse effect. This contributes to climate change. Carbon dioxide (), from burning fossil fuels such as coal, petroleum, oil, and natural gas, is the main cause of climate chan ...
, coupled with
deforestation Deforestation or forest clearance is the removal and destruction of a forest or stand of trees from land that is then converted to non-forest use. Deforestation can involve conversion of forest land to farms, ranches, or urban use. Ab ...
and destruction of
wetland A wetland is a distinct semi-aquatic ecosystem whose groundcovers are flooded or saturated in water, either permanently, for years or decades, or only seasonally. Flooding results in oxygen-poor ( anoxic) processes taking place, especially ...
s via
logging Logging is the process of cutting, processing, and moving trees to a location for transport. It may include skidder, skidding, on-site processing, and loading of trees or trunk (botany), logs onto logging truck, trucksland developments, have caused an observed rise in global temperatures, with the global average surface temperatures being higher in the 2011–2020 decade than they were in 1850. It has raised concerns of man-made
climate change Present-day climate change includes both global warming—the ongoing increase in Global surface temperature, global average temperature—and its wider effects on Earth's climate system. Climate variability and change, Climate change in ...
, which can have significant environmental impacts such as
sea level rise The sea level has been rising from the end of the last ice age, which was around 20,000 years ago. Between 1901 and 2018, the average sea level rose by , with an increase of per year since the 1970s. This was faster than the sea level had e ...
,
ocean acidification Ocean acidification is the ongoing decrease in the pH of the Earth's ocean. Between 1950 and 2020, the average pH of the ocean surface fell from approximately 8.15 to 8.05. Carbon dioxide emissions from human activities are the primary cause of ...
, glacial retreat (which threatens water security), increasing extreme weather events and wildfires, ecological collapse and Holocene extinction, mass dying of wildlife.


See also

* Aerial perspective * Air (classical element) * Biosphere * Hydrosphere * Lithosphere * Airglow * Airshed * Atmospheric dispersion modeling * Atmospheric electricity * Climate system * COSPAR International Reference Atmosphere (CIRA) * Environmental impact of aviation * Global dimming * Global surface temperature * Reference atmospheric model


References


External links

*
Interactive global map of current atmospheric and ocean surface conditions.
{{Authority control Atmosphere of Earth, Atmospheric thermodynamics Articles containing video clips Breathing gases, Air Climate, Environments