Periclase is a

magnesium Magnesium is a chemical element with the symbol Mg and atomic number 12. It is a shiny gray metal having a low density, low melting point and high chemical reactivity. Like the other alkaline earth metals (group 2 of the periodic ta ...

mineral that occurs naturally in contact

metamorphic rock Metamorphic rocks arise from the transformation of existing rock to new types of rock in a process called metamorphism. The original rock ( protolith) is subjected to temperatures greater than and, often, elevated pressure of or more, caus ...

s and is a major component of most basic refractory bricks. It is a cubic form of magnesium oxide ( Mg O). In nature it usually forms a

solid solution A solid solution, a term popularly used for metals, is a homogenous mixture of two different kinds of atoms in solid state and have a single crystal structure. Many examples can be found in metallurgy, geology, and solid-state chemistry. The wor ...

with

wüstite Wüstite ( Fe O) is a mineral form of iron(II) oxide found with meteorites and native iron. It has a grey colour with a greenish tint in reflected light. Wüstite crystallizes in the isometric-hexoctahedral crystal system in opaque to translu ...

(FeO) and is then referred to as ferropericlase or magnesiowüstite. It was first described in 1840 and named from the Greek περικλάω (to break around) in allusion to its cleavage. The type locality is

Monte Somma Mount Somma ( it, Monte Somma) is a mountain located in the Province of Naples, in the Campania region of southern Italy. Mount Somma is an integral part of the Somma–Vesuvius volcanic complex. It is high. Geography Mount Somma is the rem ...

, Somma-

Vesuvius Mount Vesuvius ( ; it, Vesuvio ; nap, 'O Vesuvio , also or ; la, Vesuvius , also , or ) is a somma- stratovolcano located on the Gulf of Naples in Campania, Italy, about east of Naples and a short distance from the shore. It is one of ...

Complex, Naples Province,

Campania (man), it, Campana (woman) , population_note = , population_blank1_title = , population_blank1 = , demographics_type1 = , demographics1_footnotes = , demographics1_title1 = , demographics1_info1 = , demog ...

Italy Italy ( it, Italia ), officially the Italian Republic, ) or the Republic of Italy, is a country in Southern Europe. It is located in the middle of the Mediterranean Sea, and its territory largely coincides with the homonymous geographical ...

. The old term for the mineral is ''magnesia''. Stones from the Magnesia region in ancient

Anatolia Anatolia, tr, Anadolu Yarımadası), and the Anatolian plateau, also known as Asia Minor, is a large peninsula in Western Asia and the westernmost protrusion of the Asian continent. It constitutes the major part of modern-day Turkey. The ...

contained both magnesium oxide and hydrated magnesium carbonate as well as iron oxides (such as magnetite). Thus these stones, called ''Stones from Magnesia'' in antiquity, with their unusual magnetic properties were the reason the terms ''

magnet A magnet is a material or object that produces a magnetic field. This magnetic field is invisible but is responsible for the most notable property of a magnet: a force that pulls on other ferromagnetic materials, such as iron, steel, nicke ...

'' and '' magnetism'' were coined. Periclase is usually found in

marble Marble is a metamorphic rock composed of recrystallized carbonate minerals, most commonly calcite or dolomite. Marble is typically not foliated (layered), although there are exceptions. In geology, the term ''marble'' refers to metamorphose ...

produced by

metamorphism Metamorphism is the transformation of existing rock (the protolith) to rock with a different mineral composition or texture. Metamorphism takes place at temperatures in excess of , and often also at elevated pressure or in the presence of ch ...

of dolomitic

limestones Limestone ( calcium carbonate ) is a type of carbonate sedimentary rock which is the main source of the material lime. It is composed mostly of the minerals calcite and aragonite, which are different crystal forms of . Limestone forms when t ...

. It readily alters to brucite under near surface conditions. In addition to its type locality, it is reported from Predazzo,

Trentino Trentino ( lld, Trentin), officially the Autonomous Province of Trento, is an autonomous province of Italy, in the country's far north. The Trentino and South Tyrol constitute the region of Trentino-Alto Adige/Südtirol, an autonomous region ...

;

Carlingford, County Louth Carlingford (; ga, Cairlinn) is a coastal town and civil parish in northern County Louth, Ireland. For the purposes of local government, the town is part of the Dundalk Municipal District. It is situated on the southern shore of Carlingford ...

, Ireland;

Broadford, Skye Broadford ( gd, An t-Àth Leathann), together with nearby Harrapool, is the second-largest settlement on the Isle of Skye, Scotland. Lying in the shadow of the Red Cuillin mountains, Broadford is within the parish of Strath. A long meandering vi ...

and the island of Muck, Scotland; León, Spain; the Bellerberg Volcano, Eifel district, Germany; Nordmark and

Långban Långban is a mining area in Värmland in Sweden. It belongs to Filipstad Municipality, with the nearest city being Filipstad, 21 km south. It was systematically mined through 1711-1972, but has traces from the 15th century. It is the birthp ...

, Varmland, Sweden; and

Kopeysk Kopeysk (russian: Копе́йск) is a city in Chelyabinsk Oblast, Russia, located southeast of Chelyabinsk. Population: The population growth between 2002 and 2010 was caused by the annexation of surrounding settlements. History Prior to 19 ...

, southern

Ural Mountains The Ural Mountains ( ; rus, Ура́льские го́ры, r=Uralskiye gory, p=ʊˈralʲskʲɪjə ˈɡorɨ; ba, Урал тауҙары) or simply the Urals, are a mountain range that runs approximately from north to south through western ...

, Russia. In the US it occurs at the Crestmore quarry, Riverside County, California; Tombstone, Arizona; Gabbs district, Nye County, Nevada. In

Canada Canada is a country in North America. Its ten provinces and three territories extend from the Atlantic Ocean to the Pacific Ocean and northward into the Arctic Ocean, covering over , making it the world's second-largest country by tot ...

, it occurs at Oka,

Quebec Quebec ( ; )According to the Canadian government, ''Québec'' (with the acute accent) is the official name in Canadian French and ''Quebec'' (without the accent) is the province's official name in Canadian English is one of the thirtee ...

and in Australia, west of Cowell, Eyre Peninsula,

South Australia South Australia (commonly abbreviated as SA) is a state in the southern central part of Australia. It covers some of the most arid parts of the country. With a total land area of , it is the fourth-largest of Australia's states and territories ...

. The

crystal structure In crystallography, crystal structure is a description of the ordered arrangement of atoms, ions or molecules in a crystalline material. Ordered structures occur from the intrinsic nature of the constituent particles to form symmetric patterns ...

of periclase corresponds to that of halite and has been studied extensively due to its simplicity. As a consequence, the physical properties of periclase are well known, which makes the mineral a popular standard in experimental work. The mineral has been shown to remain stable at pressures up to at least 360

GPa Grading in education is the process of applying standardized measurements for varying levels of achievements in a course. Grades can be assigned as letters (usually A through F), as a range (for example, 1 to 6), as a percentage, or as a numbe ...

Mantle occurrence

Ferropericlase makes up about 20% of the volume of the lower mantle of the Earth, which makes it the second most abundant mineral phase in that region after silicate perovskite ; it also is the major host for iron in the lower mantle.Researchers locate mantle’s spin transition zone, leading to clues about earth’s structure
At the bottom of the transition zone of the mantle, the reaction : γ– transforms γ-olivine into a mixture of perovskite and ferropericlase and ''vice versa''. In the literature, this mineral phase of the lower mantle is also often called magnesiowüstite.

References

{{reflist Magnesium minerals Oxide minerals Cubic minerals Minerals in space group 225 Luminescent minerals Rocksalt group