A pigment is a colored material that is completely or nearly insoluble in water. In contrast,

dye A dye is a colored substance that chemically bonds to the substrate to which it is being applied. This distinguishes dyes from pigments which do not chemically bind to the material they color. Dye is generally applied in an aqueous solution an ...

s are typically soluble, at least at some stage in their use. Generally dyes are often organic compounds whereas pigments are often

inorganic compound In chemistry, an inorganic compound is typically a chemical compound that lacks carbon–hydrogen bonds, that is, a compound that is not an organic compound. The study of inorganic compounds is a subfield of chemistry known as '' inorganic chemist ...

s. Pigments of prehistoric and historic value include

ochre Ochre ( ; , ), or ocher in American English, is a natural clay earth pigment, a mixture of ferric oxide and varying amounts of clay and sand. It ranges in colour from yellow to deep orange or brown. It is also the name of the colours produced ...

charcoal Charcoal is a lightweight black carbon residue produced by strongly heating wood (or other animal and plant materials) in minimal oxygen to remove all water and volatile constituents. In the traditional version of this pyrolysis process, cal ...

, and

lapis lazuli Lapis lazuli (; ), or lapis for short, is a deep-blue metamorphic rock used as a semi-precious stone that has been prized since antiquity for its intense color. As early as the 7th millennium BC, lapis lazuli was mined in the Sar-i Sang mines, ...

Economic impact

In 2006, around 7.4 million tons of inorganic,

organic Organic may refer to: * Organic, of or relating to an organism, a living entity * Organic, of or relating to an anatomical organ Chemistry * Organic matter, matter that has come from a once-living organism, is capable of decay or is the product ...

, and special pigments were marketed worldwide. Estimated at around US$14.86 billion in 2018 and will rise at over 4.9% CAGR from 2019 to 2026. The global demand for pigments was roughly US$20.5 billion in 2009. According to an April 2018 report by '' Bloomberg Businessweek'', the estimated value of the pigment industry globally is $30 billion. The value of titanium dioxide – used to enhance the white brightness of many products – was placed at $13.2 billion per year, while the color

Ferrari Ferrari S.p.A. (; ) is an Italian luxury sports car manufacturer based in Maranello, Italy. Founded by Enzo Ferrari (1898–1988) in 1939 from the Alfa Romeo racing division as ''Auto Avio Costruzioni'', the company built its first car in ...

red is valued at $300 million each year.

Physical principles

Like all materials, the color of pigments arises because they absorb only certain wavelengths of visible light. The bonding properties of the material determine the wavelength and efficiency of light absorption. Light of other wavelengths are reflected or scattered. The reflected light spectrum defines the color that we observe. The appearance of pigments is sensitive to the source light. Sunlight has a high color temperature and a fairly uniform spectrum. Sunlight is considered a standard for white light. Artificial light sources are less uniform. Color spaces used to represent colors numerically must specify their light source. Lab color measurements, unless otherwise noted, assume that the measurement was recorded under a D65 light source, or "Daylight 6500 K", which is roughly the color temperature of sunlight. Complex reflectance

Other properties of a color, such as its saturation or lightness, may be determined by the other substances that accompany pigments. Binders and fillers can affect the color.

History

Minerals have been used as colorants since prehistoric times. Early humans used

paint Paint is any pigmented liquid, liquefiable, or solid mastic composition that, after application to a substrate in a thin layer, converts to a solid film. It is most commonly used to protect, color, or provide texture. Paint can be made in many ...

for aesthetic purposes such as body decoration. Pigments and paint grinding equipment believed to be between 350,000 and 400,000 years old have been reported in a cave at Twin Rivers, near

Lusaka Lusaka (; ) is the Capital city, capital and largest city of Zambia. It is one of the fastest-developing cities in southern Africa. Lusaka is in the southern part of the central plateau at an elevation of about . , the city's population was ab ...

, Zambia.

Ochre Ochre ( ; , ), or ocher in American English, is a natural clay earth pigment, a mixture of ferric oxide and varying amounts of clay and sand. It ranges in colour from yellow to deep orange or brown. It is also the name of the colours produced ...

, iron oxide, was the first color of paint. A favored blue pigment was derived from

. Pigments based on minerals and clays often bear the name of the city or region where they were originally mined. Raw Sienna and

Burnt Sienna Sienna (from it, terra di Siena, meaning "Siena earth") is an earth pigment containing iron oxide and manganese oxide. In its natural state, it is yellowish brown and is called raw sienna. When heated, it becomes a reddish brown and is calle ...

came from Siena, Italy, while

Raw Umber Umber is a natural brown earth pigment that contains iron oxide and manganese oxide. In its natural form, it is called raw umber. When calcined, the color becomes warmer and it becomes known as burnt umber. Its name derives from ''terra d'ombra ...

and

Burnt Umber Umber is a natural brown earth pigment that contains iron oxide and manganese oxide. In its natural form, it is called raw umber. When calcined, the color becomes warmer and it becomes known as burnt umber. Its name derives from ''terra d'ombr ...

came from Umbria. These pigments were among the easiest to synthesize, and chemists created modern colors based on the originals. These were more consistent than colors mined from the original ore bodies, but the place names remained. Also found in many

Paleolithic The Paleolithic or Palaeolithic (), also called the Old Stone Age (from Greek: παλαιός ''palaios'', "old" and λίθος ''lithos'', "stone"), is a period in human prehistory that is distinguished by the original development of stone too ...

and Neolithic

cave painting In archaeology, Cave paintings are a type of parietal art (which category also includes petroglyphs, or engravings), found on the wall or ceilings of caves. The term usually implies prehistoric origin, and the oldest known are more than 40,000 ye ...

s are Red Ochre, anhydrous Fe₂O₃, and the hydrated Yellow Ochre (Fe₂O₃^.H₂O). Charcoal—or carbon black—has also been used as a black pigment since prehistoric times. The first known synthetic pigment was Egyptian blue, which is first attested on an alabaster bowl in Egypt dated to Naqada III (''circa'' 3250 BC). Egyptian blue (blue frit), calcium copper silicate CaCuSi₄O₁₀, made by heating a mixture of quartz sand, lime, a

flux Flux describes any effect that appears to pass or travel (whether it actually moves or not) through a surface or substance. Flux is a concept in applied mathematics and vector calculus which has many applications to physics. For transport ph ...

and a copper source, such as malachite. Already invented in the

Predynastic Period of Egypt Prehistoric Egypt and Predynastic Egypt span the period from the earliest human settlement to the beginning of the Early Dynastic Period around 3100 BC, starting with the first Pharaoh, Narmer for some Egyptologists, Hor-Aha for others, with ...

, its use became widespread by the

4th Dynasty The Fourth Dynasty of ancient Egypt (notated Dynasty IV) is characterized as a "golden age" of the Old Kingdom of Egypt. Dynasty IV lasted from to 2494 BC. It was a time of peace and prosperity as well as one during which trade with other ...

. It was the blue pigment par excellence of

Roman antiquity In modern historiography, ancient Rome refers to Roman civilisation from the founding of the city of Rome in the 8th century BC to the collapse of the Western Roman Empire in the 5th century AD. It encompasses the Roman Kingdom (753–509 B ...

; its art technological traces vanished in the course of the Middle Ages until its rediscovery in the context of the Egyptian campaign and the excavations in

Pompeii Pompeii (, ) was an ancient city located in what is now the ''comune'' of Pompei near Naples in the Campania region of Italy. Pompeii, along with Herculaneum and many villas in the surrounding area (e.g. at Boscoreale, Stabiae), was buried ...

and

Herculaneum Herculaneum (; Neapolitan and it, Ercolano) was an ancient town, located in the modern-day ''comune'' of Ercolano, Campania, Italy. Herculaneum was buried under volcanic ash and pumice in the eruption of Mount Vesuvius in AD 79. Like the nea ...

. Later premodern synthetic pigments include white lead (basic lead carbonate, (PbCO₃)₂Pb(OH)₂), vermilion,

verdigris Verdigris is the common name for blue-green, copper-based pigments that form a patina on copper, bronze, and brass. The technical literature is ambiguous as to its chemical composition. Some sources refer to "neutral verdigris" as copper(II) ac ...

, and lead-tin-yellow. Vermilion, a

mercury Mercury commonly refers to: * Mercury (planet), the nearest planet to the Sun * Mercury (element), a metallic chemical element with the symbol Hg * Mercury (mythology), a Roman god Mercury or The Mercury may also refer to: Companies * Merc ...

sulfide Sulfide (British English also sulphide) is an inorganic anion of sulfur with the chemical formula S2− or a compound containing one or more S2− ions. Solutions of sulfide salts are corrosive. ''Sulfide'' also refers to chemical compounds lar ...

, was originally made by grinding a powder of natural cinnabar. From the 17th century on, it was also synthesized from the elements. It was favored by old masters such as Titian.

Indian yellow Indian yellow is a complex pigment consisting primarily of euxanthic acid salts (magnesium euxanthate and calcium euxanthate), euxanthone and sulphonated euxanthone. It is also known as purree, snowshoe yellow, gaugoli, gogili, Hardwari peori, M ...

was once produced by collecting the urine of cattle that had been fed only

mango A mango is an edible stone fruit produced by the tropical tree ''Mangifera indica''. It is believed to have originated in the region between northwestern Myanmar, Bangladesh, and northeastern India. ''M. indica'' has been cultivated in South a ...

leaves. Dutch and Flemish painters of the 17th and 18th centuries favored it for its luminescent qualities, and often used it to represent

sunlight Sunlight is a portion of the electromagnetic radiation given off by the Sun, in particular infrared, visible, and ultraviolet light. On Earth, sunlight is scattered and filtered through Earth's atmosphere, and is obvious as daylight when t ...

. Since mango leaves are nutritionally inadequate for cattle, the practice of harvesting Indian yellow was eventually declared to be inhumane. Modern hues of Indian yellow are made from synthetic pigments. Vermillion has been partially replaced in by cadmium reds. Because of the cost of

, substitutes were often used.

Prussian blue Prussian blue (also known as Berlin blue, Brandenburg blue or, in painting, Parisian or Paris blue) is a dark blue pigment produced by oxidation of ferrous ferrocyanide salts. It has the chemical formula Fe CN)">Cyanide.html" ;"title="e(Cyanid ...

, the oldest modern synthetic pigment, was discovered by accident in 1704. By the early 19th century, synthetic and metallic blue pigments included French ultramarine, a synthetic form of

. Ultramarine was manufactured by treating

aluminium silicate Aluminium silicate (or aluminum silicate) is a name commonly applied to chemical compounds which are derived from aluminium oxide, Al2O3 and silicon dioxide, SiO2 which may be anhydrous or hydrated, naturally occurring as minerals or synthetic. ...

with

sulfur Sulfur (or sulphur in British English) is a chemical element with the symbol S and atomic number 16. It is abundant, multivalent and nonmetallic. Under normal conditions, sulfur atoms form cyclic octatomic molecules with a chemical formula ...

. Various forms of Cobalt and

Cerulean blue Cerulean (), also spelled caerulean, is a shade of blue ranging between azure and a darker sky blue. The first recorded use of ''cerulean'' as a colour name in English was in 1590. The word is derived from the Latin word '' caeruleus'', "da ...

were also introduced. In the early 20th century,

Phthalo Blue Copper phthalocyanine (CuPc), also called phthalocyanine blue, phthalo blue and many other names, is a bright, crystalline, synthetic blue pigment from the group of phthalocyanine dyes. Its brilliant blue is frequently used in paints and dyes. ...

, a synthetic metallo-organic pigment was prepared. At the same time, Royal Blue, another name once given to tints produced from lapis lazuli, has evolved to signify a much lighter and brighter color, and is usually mixed from

and titanium dioxide, or from inexpensive synthetic blue dyes. The discovery in 1856 of

mauveine Mauveine, also known as aniline purple and Perkin's mauve, was one of the first synthetic dyes. It was discovered serendipitously by William Henry Perkin in 1856 while he was attempting to synthesise the phytochemical quinine for the treatment of m ...

, the first aniline dye, was a forerunner for the development of hundreds of

synthetic dye A dye is a colored substance that chemically bonds to the substrate to which it is being applied. This distinguishes dyes from pigments which do not chemically bind to the material they color. Dye is generally applied in an aqueous solution and ...

s and pigments like azo and

diazo The diazo group is an organic moiety consisting of two linked nitrogen atoms ( azo) at the terminal position. Overall charge neutral organic compounds containing the diazo group bound to a carbon atom are called diazo compounds or diazoalkanes ...

compounds. These dyes ushered in the flourishing of organic chemistry, including systematic designs of colorants. The development of organic chemistry diminished the dependence on inorganic pigments. File:Johannes Vermeer - Het melkmeisje - Google Art Project.jpg, ''The Milkmaid'' by Johannes Vermeer (c. 1658). Vermeer was lavish in his choice of expensive pigments, including lead-tin-yellow, natural ultramarine, and madder lake, as shown in the vibrant painting. File:Tizian 041.jpg, Titian used the historic pigment Vermilion to create the reds in the oil painting of Assunta, completed c. 1518. File:Accademia - Miracle of the Slave by Tintoretto.jpg, ''Miracle of the Slave'' by Tintoretto (c. 1548). The son of a master

r, Tintoretto used Carmine Red Lake pigment, derived from the cochineal insect, to achieve dramatic color effects. File:Paul Cézanne 160.jpg, ''Self Portrait'' by

Paul Cézanne Paul Cézanne ( , , ; ; 19 January 1839 – 22 October 1906) was a French artist and Post-Impressionism, Post-Impressionist painter whose work laid the foundations of the transition from the 19th-century conception of artistic endeavour to a ...

. Working in the late 19th century, Cézanne had a much broader palette of colors than his predecessors.

Manufacturing and industrial standards

Before the development of synthetic pigments, and the refinement of techniques for extracting mineral pigments, batches of color were often inconsistent. With the development of a modern color industry, manufacturers and professionals have cooperated to create international standards for identifying, producing, measuring, and testing colors. First published in 1905, the Munsell color system became the foundation for a series of color models, providing objective methods for the measurement of color. The Munsell system describes a color in three dimensions, hue,

value Value or values may refer to: Ethics and social * Value (ethics) wherein said concept may be construed as treating actions themselves as abstract objects, associating value to them ** Values (Western philosophy) expands the notion of value beyo ...

(lightness), and chroma (color purity), where chroma is the difference from gray at a given hue and value. By the middle 20th century, standardized methods for pigment chemistry were available, part of an international movement to create such standards in industry. The International Organization for Standardization (ISO) develops technical standards for the manufacture of pigments and dyes. ISO standards define various industrial and chemical properties, and how to test for them. The principal ISO standards that relate to all pigments are as follows: * ISO-787 General methods of test for pigments and extenders. * ISO-8780 Methods of dispersion for assessment of dispersion characteristics. Other ISO standards pertain to particular classes or categories of pigments, based on their chemical composition, such as ultramarine pigments, titanium dioxide, iron oxide pigments, and so forth. Many manufacturers of paints, inks, textiles, plastics, and colors have voluntarily adopted the Colour Index International (CII) as a standard for identifying the pigments that they use in manufacturing particular colors. First published in 1925—and now published jointly on the web by the Society of Dyers and Colourists ( United Kingdom) and the American Association of Textile Chemists and Colorists (USA)—this index is recognized internationally as the authoritative reference on colorants. It encompasses more than 27,000 products under more than 13,000 generic color index names. In the CII schema, each pigment has a generic index number that identifies it chemically, regardless of proprietary and historic names. For example, Phthalocyanine Blue BN has been known by a variety of generic and proprietary names since its discovery in the 1930s. In much of Europe, phthalocyanine blue is better known as Helio Blue, or by a proprietary name such as Winsor Blue. An American paint manufacturer, Grumbacher, registered an alternate spelling (Thanos Blue) as a trademark. Colour Index International resolves all these conflicting historic, generic, and proprietary names so that manufacturers and consumers can identify the pigment (or dye) used in a particular color product. In the CII, all phthalocyanine blue pigments are designated by a generic color index number as either PB15 or PB16, short for pigment blue 15 and pigment blue 16; these two numbers reflect slight variations in molecular structure, which produce a slightly more greenish or reddish blue.

Figures of merit

The following are some of the attributes of pigments that determine their suitability for particular manufacturing processes and applications: * Lightfastness and sensitivity for damage from ultraviolet light *

Heat stability In materials science and molecular biology, thermostability is the ability of a substance to resist irreversible change in its chemical or physical structure, often by resisting decomposition or polymerization, at a high relative temperature. ...

* Toxicity * Tinting strength *

Staining Staining is a technique used to enhance contrast in samples, generally at the microscopic level. Stains and dyes are frequently used in histology (microscopic study of biological tissues), in cytology (microscopic study of cells), and in the ...

* Dispersion (which can be measured with a

Hegman gauge A Hegman gauge, sometimes referred to as a grind gauge, grind gage, or grindometer, is an instrument which indicates the fineness of grind or the presence of coarse particles and agglomeration in a dispersion. It is commonly used to determine how fi ...

) *

Opacity Opacity or opaque may refer to: * Impediments to (especially, visible) light: ** Opacities, absorption coefficients ** Opacity (optics), property or degree of blocking the transmission of light * Metaphors derived from literal optics: ** In lingu ...

or transparency * Resistance to alkalis and acids * Reactions and interactions between pigments

Swatches

Swatches are used to communicate colors accurately. The types of swatches are dictated by the media, i.e., printing, computers, plastics, and textiles. Generally, the medium that offers the broadest gamut of color shades is widely used across diverse media.

Printed swatches

Reference standards are provided by printed swatches of color shades. PANTONE, RAL,

Munsell Munsell may refer to: * Albert Henry Munsell (1858–1918), American painter, teacher of art, and the inventor of the Munsell color system * Harvey M. Munsell, American soldier in the Civil War. *Munsell Color Company *Munsell color system In c ...

, etc. are widely used standards of color communication across diverse media like printing, plastics, and

textiles Textile is an umbrella term that includes various fiber-based materials, including fibers, yarns, filaments, threads, different fabric types, etc. At first, the word "textiles" only referred to woven fabrics. However, weaving is not the ...

Plastic swatches

Companies manufacturing color masterbatches and pigments for plastics offer plastic swatches in injection molded color chips. These color chips are supplied to the designer or customer to choose and select the color for their specific plastic products. Plastic swatches are available in various special effects like pearl, metallic, fluorescent, sparkle, mosaic etc. However, these effects are difficult to replicate on other media like print and computer display. Plastic swatches have been created by 3D modelling to including various special effects.

Computer swatches

The appearance of pigments in natural light is difficult to replicate on a computer display. Approximations are required. The Munsell Color System provides an objective measure of color in three dimensions: hue, value (or lightness), and chroma. Computer displays in general fail to show the true chroma of many pigments, but the hue and lightness can be reproduced with relative accuracy. However, when the gamma of a computer display deviates from the reference value, the hue is also systematically biased. The following approximations assume a display device at

gamma Gamma (uppercase , lowercase ; ''gámma'') is the third letter of the Greek alphabet. In the system of Greek numerals it has a value of 3. In Ancient Greek, the letter gamma represented a voiced velar stop . In Modern Greek, this letter re ...

2.2, using the sRGB color space. The further a display device deviates from these standards, the less accurate these swatches will be. Swatches are based on the average measurements of several lots of single-pigment watercolor paints, converted from

Lab color space The CIELAB color space, also referred to as ''L*a*b*'' , is a color space defined by the International Commission on Illumination (abbreviated CIE) in 1976. (Referring to CIELAB as "Lab" without asterisks should be avoided to prevent confusion ...

to sRGB color space for viewing on a computer display. The appearance of a pigment may depend on the brand and even the batch. Furthermore, pigments have inherently complex reflectance spectra that will render their color appearance greatly different depending on the spectrum of the source illumination, a property called metamerism. Averaged measurements of pigment samples will only yield approximations of their true appearance under a specific source of illumination. Computer display systems use a technique called chromatic adaptation transforms to emulate the correlated color temperature of illumination sources, and cannot perfectly reproduce the intricate spectral combinations originally seen. In many cases, the perceived color of a pigment falls outside of the gamut of computer displays and a method called

gamut mapping In digital imaging systems, color management (or colour management) is the controlled conversion between the color representations of various devices, such as image scanners, digital cameras, monitors, TV screens, film printers, computer printe ...

is used to approximate the true appearance. Gamut mapping trades off any one of

lightness Lightness is a visual perception of the luminance (L) of an object. It is often judged relative to a similarly lit object. In colorimetry and color appearance models, lightness is a prediction of how an illuminated color will appear to a stan ...

, hue, or saturation accuracy to render the color on screen, depending on the priority chosen in the conversion's ICC

rendering intent In digital imaging systems, color management (or colour management) is the controlled conversion between the color representations of various devices, such as image scanners, digital cameras, monitors, TV screens, film printers, computer printe ...

Biological pigments

In biology, a pigment is any colored material of plant or animal cells. Many biological structures, such as skin,

eye Eyes are organs of the visual system. They provide living organisms with vision, the ability to receive and process visual detail, as well as enabling several photo response functions that are independent of vision. Eyes detect light and conv ...

s, fur, and

hair Hair is a protein filament that grows from follicles found in the dermis. Hair is one of the defining characteristics of mammals. The human body, apart from areas of glabrous skin, is covered in follicles which produce thick terminal and f ...

contain pigments (such as melanin). Animal skin coloration often comes about through specialized cells called chromatophores, which animals such as the

octopus An octopus ( : octopuses or octopodes, see below for variants) is a soft-bodied, eight- limbed mollusc of the order Octopoda (, ). The order consists of some 300 species and is grouped within the class Cephalopoda with squids, cuttle ...

and

chameleon Chameleons or chamaeleons (family Chamaeleonidae) are a distinctive and highly specialized clade of Old World lizards with 202 species described as of June 2015. The members of this family are best known for their distinct range of colors, bein ...

can control to vary the animal's color. Many conditions affect the levels or nature of pigments in plant, animal, some

protista A protist () is any eukaryotic organism (that is, an organism whose cells contain a cell nucleus) that is not an animal, plant, or fungus. While it is likely that protists share a common ancestor (the last eukaryotic common ancestor), the excl ...

, or fungus cells. For instance, the disorder called albinism affects the level of melanin production in animals. Pigmentation in organisms serves many biological purposes, including camouflage,

mimicry In evolutionary biology, mimicry is an evolved resemblance between an organism and another object, often an organism of another species. Mimicry may evolve between different species, or between individuals of the same species. Often, mimicry f ...

aposematism Aposematism is the advertising by an animal to potential predators that it is not worth attacking or eating. This unprofitability may consist of any defences which make the prey difficult to kill and eat, such as toxicity, venom, foul taste or ...

(warning), sexual selection and other forms of signalling, photosynthesis (in plants), as well as basic physical purposes such as protection from sunburn. Pigment color differs from structural color in that pigment color is the same for all viewing angles, whereas structural color is the result of selective reflection or

iridescence Iridescence (also known as goniochromism) is the phenomenon of certain surfaces that appear to gradually change color as the angle of view or the angle of illumination changes. Examples of iridescence include soap bubbles, feathers, butterfl ...

, usually because of multilayer structures. For example, butterfly wings typically contain structural color, although many butterflies have cells that contain pigment as well.

Pigments by chemical composition

* Cadmium pigments:

cadmium yellow Cadmium pigments are a class of pigments that contain cadmium. Most of the cadmium produced worldwide has been for use in rechargeable nickel–cadmium batteries, which have been replaced by other rechargeable nickel-chemistry cell varieties ...

, cadmium red, cadmium green,

cadmium orange Cadmium pigments are a class of pigments that contain cadmium. Most of the cadmium produced worldwide has been for use in rechargeable nickel–cadmium batteries, which have been replaced by other rechargeable nickel-chemistry cell varieties ...

, cadmium sulfoselenide *

Chromium Chromium is a chemical element with the symbol Cr and atomic number 24. It is the first element in group 6. It is a steely-grey, lustrous, hard, and brittle transition metal. Chromium metal is valued for its high corrosion resistance and hardne ...

pigments: chrome yellow and chrome green (viridian) * Cobalt pigments:

cobalt violet Cobalt phosphate is the inorganic compound with the formula Co3(PO4)2. It is a commercial inorganic pigment known as cobalt violet.Hugo Müller, Wolfgang Müller, Manfred Wehner, Heike Liewald "Artists' Colors" in Ullmann's Encyclopedia of Indust ...

cobalt blue Cobalt blue is a blue pigment made by sintering cobalt(II) oxide with aluminum(III) oxide (alumina) at 1200 °C. Chemically, cobalt blue pigment is cobalt(II) oxide-aluminium oxide, or cobalt(II) aluminate, CoAl2O4. Cobalt blue is lighter ...

cerulean blue Cerulean (), also spelled caerulean, is a shade of blue ranging between azure and a darker sky blue. The first recorded use of ''cerulean'' as a colour name in English was in 1590. The word is derived from the Latin word '' caeruleus'', "da ...

, aureolin (cobalt yellow) * Copper pigments: Azurite,

Han purple Han purple and Han blue (also called Chinese purple and Chinese blue) are synthetic barium copper silicate pigments developed in China and used in ancient and imperial China from the Western Zhou period (1045–771 BC) until the end of the Han dy ...

Han blue Han purple and Han blue (also called Chinese purple and Chinese blue) are synthetic barium copper silicate pigments developed in China and used in ancient and imperial China from the Western Zhou period (1045–771 BC) until the end of the Han ...

, Egyptian blue, Malachite, Paris green, Phthalocyanine Blue BN,

Phthalocyanine Green G Phthalocyanine green G, which has many commercial names, is a synthetic green pigment from the group of phthalocyanine dyes, a complex of copper(II) with chlorinated phthalocyanine. It is a soft green powder, which is insoluble in water.. It is ...

Iron oxide Iron oxides are chemical compounds composed of iron and oxygen. Several iron oxides are recognized. All are black magnetic solids. Often they are non-stoichiometric. Oxyhydroxides are a related class of compounds, perhaps the best known of whic ...

pigments: sanguine, caput mortuum, oxide red, red ochre, yellow ochre, Venetian red,

, raw sienna,

burnt sienna Sienna (from it, terra di Siena, meaning "Siena earth") is an earth pigment containing iron oxide and manganese oxide. In its natural state, it is yellowish brown and is called raw sienna. When heated, it becomes a reddish brown and is calle ...

raw umber Umber is a natural brown earth pigment that contains iron oxide and manganese oxide. In its natural form, it is called raw umber. When calcined, the color becomes warmer and it becomes known as burnt umber. Its name derives from ''terra d'ombra ...

burnt umber Umber is a natural brown earth pigment that contains iron oxide and manganese oxide. In its natural form, it is called raw umber. When calcined, the color becomes warmer and it becomes known as burnt umber. Its name derives from ''terra d'ombr ...

* Lead pigments: lead white, cremnitz white, Naples yellow, red lead, lead-tin-yellow * Manganese pigments:

manganese violet Manganese violet is the common name for ammonium manganese(III) pyrophosphate, an inorganic compound composed of ammonium (), manganese in the +3 oxidation state, and the pyrophosphate anion (). It is prepared by heating a mixture of manganese(I ...

, YInMn blue *

Mercury Mercury commonly refers to: * Mercury (planet), the nearest planet to the Sun * Mercury (element), a metallic chemical element with the symbol Hg * Mercury (mythology), a Roman god Mercury or The Mercury may also refer to: Companies * Merc ...

pigments: vermilion * Titanium pigments:

titanium yellow Titanium yellow, also nickel antimony titanium yellow, nickel antimony titanium yellow rutile, CI Pigment Yellow 53, or C.I. 77788, is a yellow pigment with the chemical composition of NiO· Sb2O3·20 TiO2. It is a complex inorganic compound. Its ...

titanium beige Titanium is a chemical element with the symbol Ti and atomic number 22. Found in nature only as an oxide, it can be reduced to produce a lustrous transition metal with a silver color, low density, and high strength, resistant to corrosion in s ...

, titanium white,

titanium black Titanium is a chemical element with the Symbol (chemistry), symbol Ti and atomic number 22. Found in nature only as an oxide, it can be reduced to produce a lustrous transition metal with a silver color, low density, and high strength, resista ...

* Zinc pigments: zinc white,

zinc ferrite Zinc ferrites are a series of synthetic inorganic compounds of zinc and iron (ferrite) with the general formula of ZnxFe3−xO4. Zinc ferrite compounds can be prepared by aging solutions of Zn(NO3)2, Fe(NO3)3, and triethanolamine in the presence ...

zinc yellow Chromate conversion coating or alodine coating is a type of conversion coating used to passivate steel, aluminium, zinc, cadmium, copper, silver, titanium, magnesium, and tin alloys. The coating serves as a corrosion inhibitor, as a primer ...

* Aluminum pigment:

Aluminum powder Aluminium powder is powdered aluminium. This was originally produced by mechanical means using a stamp mill to create flakes. Subsequently, a process of spraying molten aluminium to create a powder of droplets was developed by E. J. Hall in the ...

* Carbon pigments: carbon black (including vine black, lamp black), ivory black (bone charcoal) * Ultramarine pigments (based on sulfur): ultramarine,

ultramarine green shade Ultramarine is a deep blue color pigment which was originally made by grinding lapis lazuli into a powder. The name comes from the Latin ''ultramarinus'', literally 'beyond the sea', because the pigment was imported into Europe from mines in Afg ...

Barium Barium is a chemical element with the symbol Ba and atomic number 56. It is the fifth element in group 2 and is a soft, silvery alkaline earth metal. Because of its high chemical reactivity, barium is never found in nature as a free element. Th ...

: barium white ( lithopone)

Biological and organic

* Biological origins: alizarin, gamboge, cochineal red,

rose madder Rose madder (also known as madder) is a red paint made from the pigment madder lake, a traditional lake pigment extracted from the common madder plant '' Rubia tinctorum''. Madder lake contains two organic red dyes: alizarin and purpurin. ...

, indigo,

, Tyrian purple * Non biological

quinacridone Quinacridone is an organic compound used as a pigment. Numerous derivatives constitute the quinacridone pigment family, which finds extensive use in industrial colorant applications such as robust outdoor paints, inkjet printer ink, tattoo inks, ...

, magenta,

phthalo green Phthalocyanine green G, which has many commercial names, is a synthetic green pigment from the group of phthalocyanine dyes, a complex of copper(II) with chlorinated phthalocyanine. It is a soft green powder, which is insoluble in water.. It is a ...

phthalo blue Copper phthalocyanine (CuPc), also called phthalocyanine blue, phthalo blue and many other names, is a bright, crystalline, synthetic blue pigment from the group of phthalocyanine dyes. Its brilliant blue is frequently used in paints and dyes. ...

, pigment red 170,

diarylide yellow Diarylide pigments are organic compounds that are used as pigments in inks and related materials. They often are yellow or yellow-green. To some extent, these organic compounds have displaced cadmium sulfide from the market. They exist as yellow ...

Notes

References

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External links

Pigments through the ages

ColourLex Pigment Lexicon

Earliest evidence of art found
* Sarah Lowengar
The Creation of Color in Eighteenth-century Europe
Columbia University Press, 2006 * ,

Chemical Heritage Foundation The Science History Institute is an institution that preserves and promotes understanding of the history of science. Located in Philadelphia, Pennsylvania, it includes a library, museum, archive, research center and conference center. It was fo ...

* ,

The Quest for the Next Billion-Dollar Color
{{Authority control Painting materials