hydrogen

Hydrogen is the chemical element with the symbol H and atomic number 1. Hydrogen is the lightest element. At standard conditions hydrogen is a gas of diatomic molecules having the formula . It is colorless, odorless, tasteless, non-toxic, and highly combustible. Hydrogen is the most abundant chemical substance in the universe, constituting roughly 75% of all normal matter.However, most of the universe's mass is not in the form of baryons or chemical elements. See dark matter and dark energy. Stars such as the Sun are mainly composed of hydrogen in the plasma state. Most of the hydrogen on Earth exists in molecular forms such as water and organic compounds. For the most common isotope of hydrogen (symbol ¹H) each atom has one proton, one electron, and no neutrons.

In the early universe, the formation of protons, the nuclei of hydrogen, occurred during the first second after the Big Bang. The emergence of neutral hydrogen atoms throughout the universe occurred about 370,000 years later during the recombination epoch, when the plasma had cooled enough for electrons to remain bound to protons.

Hydrogen is nonmetallic (except it becomes metallic at extremely high pressures) and readily forms a single covalent bond with most nonmetallic elements, forming compounds such as water and nearly all organic compounds. Hydrogen plays a particularly important role in acid–base reactions because these reactions usually involve the exchange of protons between soluble molecules. In ionic compounds, hydrogen can take the form of a negative charge (i.e., anion) where it is known as a hydride, or as a positively charged (i.e., cation) species denoted by the symbol . The cation is simply a proton (symbol p) but its behavior in aqueous solutions and in ionic compounds involves screening of its electric charge by nearby polar molecules or anions. Because hydrogen is the only neutral atom for which the Schrödinger equation can be solved analytically, the study of its energetics and chemical bonding has played a key role in the development of quantum mechanics.

Hydrogen gas was first artificially produced in the early 16th century by the reaction of acids on metals. In 1766–1781, Henry Cavendish was the first to recognize that hydrogen gas was a discrete substance, and that it produces water when burned, the property for which it was later named: in Greek, hydrogen means "water-former".

Industrial production is mainly from steam reforming of natural gas, oil reforming, or coal gasification. A small percentage is also produced using more energy-intensive methods such as the electrolysis of water. Most hydrogen is used near the site of its production, the two largest uses being fossil fuel processing (e.g., hydrocracking) and ammonia production, mostly for the fertilizer market. It can be burned to produce heat or combined with oxygen in fuel cells to generate electricity directly, with water being the only emissions at the point of usage. Hydrogen atoms (but not gaseous molecules) are problematic in metallurgy because they can embrittle many metals.

Properties

Combustion

Hydrogen gas (dihydrogen or molecular hydrogen) is highly flammable:
: (572 kJ/2 mol = 286 kJ/mol = 141.865 MJ/kg)286 kJ/mol: energy per mole of the combustible material (molecular hydrogen).
The enthalpy of combustion is −286 kJ/mol.

Hydrogen gas forms explosive mixtures with air in concentrations from 4–74% and with chlorine at 5–95%. The explosive reactions may be triggered by spark, heat, or sunlight. The hydrogen autoignition temperature, the temperature of spontaneous ignition in air, is .

Flame

Pure hydrogen-oxygen flames emit ultraviolet light and with high oxygen mix are nearly invisible to the naked eye, as illustrated by the faint plume of the Space Shuttle Main Engine, compared to the highly visible plume of a Space Shuttle Solid Rocket Booster, which uses an ammonium perchlorate composite. The detection of a burning hydrogen leak may require a flame detector; such leaks can be very dangerous. Hydrogen flames in other conditions are blue, resembling blue natural gas flames. The destruction of the Hindenburg airship was a notorious example of hydrogen combustion and the cause is still debated. The visible flames in the photographs were the result of carbon compounds in the airship skin burning.

Reactants

is unreactive compared to diatomic elements such as halogens or oxygen. The thermodynamic basis of this low reactivity is the very strong H–H bond, with a bond dissociation energy of 435.7 kJ/mol. The kinetic basis of the low reactivity is the nonpolar nature of and its weak polarizability. It spontaneously reacts with chlorine and fluorine to form hydrogen chloride and hydrogen fluoride, respectively. The reactivity of is strongly affected by the presence of metal catalysts. Thus, while mixtures of with or air combust readily when heated to at least 500 °C by a spark or flame, they do not react at room temperature in the absence of a catalyst.

Electron energy levels

The ground state energy level of the electron in a hydrogen atom is −13.6  eV, which is equivalent to an ultraviolet photon of roughly 91  nm wavelength.

The energy levels of hydrogen can be calculated fairly accurately using the Bohr model of the atom, which conceptualizes the electron as "orbiting" the proton in analogy to the Earth's orbit of the Sun. However, the atomic electron and proton are held together by electromagnetic force, while planets and celestial objects are held by gravity. Because of the discretization of angular momentum postulated in early quantum mechanics by Bohr, the electron in the Bohr model can only occupy certain allowed distances from the proton, and therefore only certain allowed energies.

A more accurate description of the hydrogen atom comes from a purely quantum mechanical treatment that uses the Schrödinger equation, Dirac equation or Feynman path integral formulation to calculate the probability density of the electron around the proton. The most complicated treatments allow for the small effects of special relativity and vacuum polarization. In the quantum mechanical treatment, the electron in a ground state hydrogen atom has no angular momentum at all—illustrating how the "planetary orbit" differs from electron motion.

Spin isomers

Molecular exists as two spin isomers, i.e. compounds that differ only in the spin states of their nuclei. In the orthohydrogen form, the spins of the two nuclei are parallel, forming a spin triplet state having a total molecular spin $S = 1$; in the parahydrogen form the spins are antiparallel and form a spin singlet state having spin $S = 0$. The equilibrium ratio of ortho- to para-hydrogen depends on temperature. At room temperature or warmer, equilibrium hydrogen gas contains about 25% of the para form and 75% of the ortho form. The ortho form is an excited state, having higher energy than the para form by 1.455 kJ/mol, and it converts to the para form over the course of several minutes when cooled to low temperature. The thermal properties of the forms differ because they differ in their allowed rotational quantum states, resulting in different thermal properties such as the heat capacity.

The ortho-to-para ratio in is an important consideration in the liquefaction and storage of liquid hydrogen: the conversion from ortho to para is exothermic and produces enough heat to evaporate a most of the liquid if not converted first to parahydrogen during the cooling process. Catalysts for the ortho-para interconversion, such as ferric oxide and activated carbon compounds, are used during hydrogen cooling to avoid this loss of liquid.

Phases

* Gaseous hydrogen
* Liquid hydrogen
* Slush hydrogen
* Solid hydrogen
* Metallic hydrogen
* Plasma hydrogen

Compounds

Covalent and organic compounds

While is not very reactive under standard conditions, it does form compounds with most elements. Hydrogen can form compounds with elements that are more electronegative, such as halogens (F, Cl, Br, I), or oxygen; in these compounds hydrogen takes on a partial positive charge. When bonded to a more electronegative element, particularly fluorine, oxygen, or nitrogen, hydrogen can participate in a form of medium-strength noncovalent bonding with another electronegative element with a lone pair, a phenomenon called hydrogen bonding that is critical to the stability of many biological molecules. Hydrogen also forms compounds with less electronegative elements, such as metals and metalloids, where it takes on a partial negative charge. These compounds are often known as hydrides.

Hydrogen forms a vast array of compounds with carbon called the hydrocarbons, and an even vaster array with heteroatoms that, because of their general association with living things, are called organic compounds. The study of their properties is known as organic chemistry and their study in the context of living organisms is known as biochemistry. By some definitions, "organic" compounds are only required to contain carbon. However, most of them also contain hydrogen, and because it is the carbon-hydrogen bond that gives this class of compounds most of its particular chemical characteristics, carbon-hydrogen bonds are required in some definitions of the word "organic" in chemistry. Millions of hydrocarbons are known, and they are usually formed by complicated pathways that seldom involve elemental hydrogen.

Hydrogen is highly soluble in many rare earth and transition metals and is soluble in both nanocrystalline and amorphous metals. Hydrogen solubility in metals is influenced by local distortions or impurities in the crystal lattice. These properties may be useful when hydrogen is purified by passage through hot palladium disks, but the gas's high solubility is a metallurgical problem, contributing to the embrittlement of many metals, complicating the design of pipelines and storage tanks.

Hydrides

Compounds of hydrogen are often called hydrides, a term that is used fairly loosely. The term "hydride" suggests that the H atom has acquired a negative or anionic character, denoted , and is used when hydrogen forms a compound with a more electropositive element. The existence of the hydride anion, suggested by Gilbert N. Lewis in 1916 for group 1 and 2 salt-like hydrides, was demonstrated by Moers in 1920 by the electrolysis of molten lithium hydride (LiH), producing a stoichiometric quantity of hydrogen at the anode. For hydrides other than group 1 and 2 metals, the term is quite misleading, considering the low electronegativity of hydrogen. An exception in group 2 hydrides is , which is polymeric. In lithium aluminium hydride, the anion carries hydridic centers firmly attached to the Al(III).

Although hydrides can be formed with almost all main-group elements, the number and combination of possible compounds varies widely; for example, more than 100 binary borane hydrides are known, but only one binary aluminium hydride. Binary indium hydride has not yet been identified, although larger complexes exist.

In inorganic chemistry, hydrides can also serve as bridging ligands that link two metal centers in a coordination complex. This function is particularly common in group 13 elements, especially in boranes ( boron hydrides) and aluminium complexes, as well as in clustered carboranes.

Protons and acids

Oxidation of hydrogen removes its electron and gives , which contains no electrons and a nucleus which is usually composed of one proton. That is why is often called a proton. This species is central to discussion of acids. Under the Brønsted–Lowry acid–base theory, acids are proton donors, while bases are proton acceptors.

A bare proton, , cannot exist in solution or in ionic crystals because of its unstoppable attraction to other atoms or molecules with electrons. Except at the high temperatures associated with plasmas, such protons cannot be removed from the electron clouds of atoms and molecules, and will remain attached to them. However, the term 'proton' is sometimes used loosely and metaphorically to refer to positively charged or cationic hydrogen attached to other species in this fashion, and as such is denoted "" without any implication that any single protons exist freely as a species.

To avoid the implication of the naked "solvated proton" in solution, acidic aqueous solutions are sometimes considered to contain a less unlikely fictitious species, termed the " hydronium ion" (). However, even in this case, such solvated hydrogen cations are more realistically conceived as being organized into clusters that form species closer to . Other oxonium ions are found when water is in acidic solution with other solvents.

Although exotic on Earth, one of the most common ions in the universe is the ion, known as protonated molecular hydrogen or the trihydrogen cation.

Isotopes

Hydrogen has three naturally occurring isotopes, denoted , and . Other, highly unstable nuclei ( to ) have been synthesized in the laboratory but not observed in nature.
* is the most common hydrogen isotope, with an abundance of more than 99.98%. Because the nucleus of this isotope consists of only a single proton, it is given the descriptive but rarely used formal name '' protium''. It is unique among all stable isotopes in having no neutrons; see diproton for a discussion of why others do not exist.
* , the other stable hydrogen isotope, is known as '' deuterium'' and contains one proton and one neutron in the nucleus. All deuterium in the universe is thought to have been produced at the time of the Big Bang, and has endured since that time. Deuterium is not radioactive, and does not represent a significant toxicity hazard. Water enriched in molecules that include deuterium instead of normal hydrogen is called heavy water. Deuterium and its compounds are used as a non-radioactive label in chemical experiments and in solvents for - NMR spectroscopy. Heavy water is used as a neutron moderator and coolant for nuclear reactors. Deuterium is also a potential fuel for commercial nuclear fusion.
* is known as ''tritium'' and contains one proton and two neutrons in its nucleus. It is radioactive, decaying into helium-3 through beta decay with a half-life of 12.32 years. It is so radioactive that it can be used in luminous paint, making it useful in such things as watches. The glass prevents the small amount of radiation from getting out. Small amounts of tritium are produced naturally by the interaction of cosmic rays with atmospheric gases; tritium has also been released during nuclear weapons tests. It is used in nuclear fusion reactions, as a tracer in isotope geochemistry, and in specialized self-powered lighting devices. Tritium has also been used in chemical and biological labeling experiments as a radiolabel.

Unique among the elements, distinct names are assigned to its isotopes in common use today. During the early study of radioactivity, various heavy radioactive isotopes were given their own names, but such names are no longer used, except for deuterium and tritium. The symbols D and T (instead of and ) are sometimes used for deuterium and tritium, but the symbol P is already in use for phosphorus and thus is not available for protium. In its nomenclatural guidelines, the International Union of Pure and Applied Chemistry (IUPAC) allows any of D, T, , and to be used, although and are preferred.

The exotic atom muonium (symbol Mu), composed of an antimuon and an electron, can also be considered a light radioisotope of hydrogen. Because muons decay with lifetime , muonium is too unstable to exhibit observable chemistry. Nevertheless, muonium compounds are important test cases for quantum simulation, due to the mass difference between the antimuon and the proton, and IUPAC nomenclature incorporates such hypothetical compounds as muonium chloride (MuCl) and sodium muonide (NaMu), analogous to hydrogen chloride and sodium hydride respectively.

Thermal and physical properties

Table of thermal and physical properties of hydrogen (H2) at atmospheric pressure:

History

Discovery and use

In 1671, Robert Boyle discovered and described the reaction between iron filings and dilute acids, which results in the production of hydrogen gas.

In 1766, Henry Cavendish was the first to recognize hydrogen gas as a discrete substance, by naming the gas from a metal-acid reaction "inflammable air". He speculated that "inflammable air" was in fact identical to the hypothetical substance called " phlogiston" and further finding in 1781 that the gas produces water when burned. He is usually given credit for the discovery of hydrogen as an element. In 1783, Antoine Lavoisier