Phonolite is an uncommon
extrusive rock
Extrusive rock refers to the mode of igneous volcanic rock formation in which hot magma from inside the Earth flows out (extrudes) onto the surface as lava or explodes violently into the atmosphere to fall back as pyroclastics or tuff. In ...
, of
intermediate chemical composition between
felsic
In geology, felsic is a modifier describing igneous rocks that are relatively rich in elements that form feldspar and quartz.Marshak, Stephen, 2009, ''Essentials of Geology,'' W. W. Norton & Company, 3rd ed. It is contrasted with mafic rocks, wh ...
and
mafic
A mafic mineral or rock is a silicate mineral or igneous rock rich in magnesium and iron. Most mafic minerals are dark in color, and common rock-forming mafic minerals include olivine, pyroxene, amphibole, and biotite. Common mafic rocks in ...
, with texture ranging from
aphanitic
Aphanites (adj. ''aphanitic''; ) are igneous rocks that are so fine-grained that their component mineral crystals are not visible to the naked eye (in contrast to phanerites, in which the crystals are visible to the unaided eye). This ge ...
(fine-grained) to
porphyritic (mixed fine- and coarse-grained). Phonolite is a variation of the igneous rock
trachyte
Trachyte () is an extrusive igneous rock composed mostly of alkali feldspar. It is usually light-colored and aphanitic (fine-grained), with minor amounts of mafic minerals, and is formed by the rapid cooling of lava enriched with silica and al ...
that contains nepheline or leucite rather than quartz.
Its
intrusive equivalent is
nepheline syenite. Phonolite is typically fine grained and compact.
The name ''phonolite'' comes from the
Ancient Greek
Ancient Greek includes the forms of the Greek language used in ancient Greece and the ancient world from around 1500 BC to 300 BC. It is often roughly divided into the following periods: Mycenaean Greek (), Dark Ages (), the Archaic pe ...
meaning "sounding stone" due to the metallic sound it produces if an unfractured plate is hit; hence, the English name ''clinkstone'' is given as a synonym.
Formation
Unusually, phonolite forms from
magma
Magma () is the molten or semi-molten natural material from which all igneous rocks are formed. Magma is found beneath the surface of the Earth, and evidence of magmatism has also been discovered on other terrestrial planets and some natura ...
with a relatively low
silica
Silicon dioxide, also known as silica, is an oxide of silicon with the chemical formula , most commonly found in nature as quartz and in various living organisms. In many parts of the world, silica is the major constituent of sand. Silica is ...
content, generated by low degrees of
partial melting (less than 10%) of highly aluminous rocks of the lower
crust such as
tonalite,
monzonite and
metamorphic rock
Metamorphic rocks arise from the transformation of existing rock to new types of rock in a process called metamorphism. The original rock (protolith) is subjected to temperatures greater than and, often, elevated pressure of or more, caus ...
s. Melting of such rocks to a very low degree promotes the liberation of aluminium, potassium, sodium and calcium by melting of
feldspar
Feldspars are a group of rock-forming aluminium tectosilicate minerals, also containing other cations such as sodium, calcium, potassium, or barium. The most common members of the feldspar group are the ''plagioclase'' (sodium-calcium) felds ...
, with some involvement of mafic minerals. Because the rock is silica-
undersaturated, it has no
quartz
Quartz is a hard, crystalline mineral composed of silica ( silicon dioxide). The atoms are linked in a continuous framework of SiO4 silicon-oxygen tetrahedra, with each oxygen being shared between two tetrahedra, giving an overall chemical f ...
or
other silica crystals, and is dominated by low-silica
feldspathoid
The feldspathoids are a group of tectosilicate minerals which resemble feldspars but have a different structure and much lower silica content. They occur in rare and unusual types of igneous rocks, and are usually not found in rocks containing ...
minerals more than feldspar minerals.
A few geological processes and tectonic events can melt the necessary precursor rocks to form phonolite. These include intracontinental
hotspot volcanism, such as may form above
mantle plumes covered by thick
continental crust. A-type
granite
Granite () is a coarse-grained ( phaneritic) intrusive igneous rock composed mostly of quartz, alkali feldspar, and plagioclase. It forms from magma with a high content of silica and alkali metal oxides that slowly cools and solidifies un ...
s and alkaline igneous provinces usually occur alongside phonolites. Low-degree partial melting of underplates of granitic material in collisional
orogenic belts may also produce phonolites.
Mineralogy and petrology
Phonolite is a fine-grained equivalent of
nepheline syenite. They are products of partial melting, are silica-undersaturated, and have feldspathoids in their
normative mineralogy.
Mineral assemblages in phonolite occurrences are usually abundant
feldspathoid
The feldspathoids are a group of tectosilicate minerals which resemble feldspars but have a different structure and much lower silica content. They occur in rare and unusual types of igneous rocks, and are usually not found in rocks containing ...
s (
nepheline
Nepheline, also called nephelite (), is a rock-forming mineral in the feldspathoid groupa silica-undersaturated aluminosilicate, Na3 K Al4 Si4 O16, that occurs in intrusive and volcanic rocks with low silica, and in their associated pegmati ...
,
sodalite,
hauyne,
leucite and
analcite
Analcime (; ) or analcite is a white, gray, or colorless tectosilicate mineral. Analcime consists of hydrated sodium aluminium silicate in cubic crystalline form. Its chemical formula is Na Al Si2 O6· H2O. Minor amounts of potassium and cal ...
) and alkali
feldspar
Feldspars are a group of rock-forming aluminium tectosilicate minerals, also containing other cations such as sodium, calcium, potassium, or barium. The most common members of the feldspar group are the ''plagioclase'' (sodium-calcium) felds ...
(
sanidine
Sanidine is the high temperature form of potassium feldspar with a general formula K(AlSi3O8). Sanidine is found most typically in felsic volcanic rocks such as obsidian, rhyolite and trachyte. Sanidine crystallizes in the monoclinic crystal s ...
,
anorthoclase
The mineral anorthoclase ((Na,K)AlSi3O8) is a crystalline solid solution in the alkali feldspar series, in which the sodium-aluminium silicate member exists in larger proportion. It typically consists of between 10 and 36 percent of KAlSi3O8 and ...
or
orthoclase), and rare sodic
plagioclase
Plagioclase is a series of tectosilicate (framework silicate) minerals within the feldspar group. Rather than referring to a particular mineral with a specific chemical composition, plagioclase is a continuous solid solution series, more p ...
.
Biotite, sodium-rich
amphibole
Amphibole () is a group of inosilicate minerals, forming prism or needlelike crystals, composed of double chain tetrahedra, linked at the vertices and generally containing ions of iron and/or magnesium in their structures. Its IMA symbol is ...
s and
pyroxene
The pyroxenes (commonly abbreviated to ''Px'') are a group of important rock-forming inosilicate minerals found in many igneous and metamorphic rocks. Pyroxenes have the general formula , where X represents calcium (Ca), sodium (Na), iron (Fe I ...
s along with iron-rich
olivine
The mineral olivine () is a magnesium iron silicate with the chemical formula . It is a type of nesosilicate or orthosilicate. The primary component of the Earth's upper mantle, it is a common mineral in Earth's subsurface, but weathers qui ...
are common minor minerals. Accessory phases include
titanite
Titanite, or sphene (from the Greek ''sphenos'' (σφηνώ), meaning wedge), is a calcium titanium nesosilicate mineral, Ca Ti Si O5. Trace impurities of iron and aluminium are typically present. Also commonly present are rare earth metals ...
,
apatite
Apatite is a group of phosphate minerals, usually hydroxyapatite, fluorapatite and chlorapatite, with high concentrations of OH−, F− and Cl− ions, respectively, in the crystal. The formula of the admixture of the three most common ...
,
corundum
Corundum is a crystalline form of aluminium oxide () typically containing traces of iron, titanium, vanadium and chromium. It is a rock-forming mineral. It is a naturally transparent material, but can have different colors depending on the pr ...
,
zircon
Zircon () is a mineral belonging to the group of nesosilicates and is a source of the metal zirconium. Its chemical name is zirconium(IV) silicate, and its corresponding chemical formula is Zr SiO4. An empirical formula showing some of t ...
,
magnetite
Magnetite is a mineral and one of the main iron ores, with the chemical formula Fe2+Fe3+2O4. It is one of the oxides of iron, and is ferrimagnetic; it is attracted to a magnet and can be magnetized to become a permanent magnet itself. With ...
and
ilmenite. Phonolite's characteristic dark color comes from its concentration of dark pyroxenes such as aegirine and augite.
Blairmorite is an analcite-rich variety of phonolite.
Occurrence
Nepheline syenites and phonolites occur widely distributed throughout the world in Canada, Norway,
Greenland
Greenland ( kl, Kalaallit Nunaat, ; da, Grønland, ) is an island country in North America that is part of the Kingdom of Denmark. It is located between the Arctic and Atlantic oceans, east of the Canadian Arctic Archipelago. Greenland ...
, Sweden, the
United Kingdom
The United Kingdom of Great Britain and Northern Ireland, commonly known as the United Kingdom (UK) or Britain, is a country in Europe, off the north-western coast of the continental mainland. It comprises England, Scotland, Wales and ...
, the
Ural Mountains
The Ural Mountains ( ; rus, Ура́льские го́ры, r=Uralskiye gory, p=ʊˈralʲskʲɪjə ˈɡorɨ; ba, Урал тауҙары) or simply the Urals, are a mountain range that runs approximately from north to south through western ...
, the
Pyrenees
The Pyrenees (; es, Pirineos ; french: Pyrénées ; ca, Pirineu ; eu, Pirinioak ; oc, Pirenèus ; an, Pirineus) is a mountain range straddling the border of France and Spain. It extends nearly from its union with the Cantabrian Mountains to ...
, Italy,
Eifel and
Kaiserstuhl in Germany,
Brazil
Brazil ( pt, Brasil; ), officially the Federative Republic of Brazil (Portuguese: ), is the largest country in both South America and Latin America. At and with over 217 million people, Brazil is the world's fifth-largest country by area ...
, the
Transvaal region, the
Magnet Cove igneous complex of
Arkansas
Arkansas ( ) is a landlocked state in the South Central United States. It is bordered by Missouri to the north, Tennessee and Mississippi to the east, Louisiana to the south, and Texas and Oklahoma to the west. Its name is from the O ...
, the Beemerville Complex of
New Jersey
New Jersey is a state in the Mid-Atlantic and Northeastern regions of the United States. It is bordered on the north and east by the state of New York; on the east, southeast, and south by the Atlantic Ocean; on the west by the Delawa ...
, as well as on oceanic islands such as the
Canary Islands
The Canary Islands (; es, :es:Canarias, Canarias, ), also known informally as the Canaries, are a Spanish Autonomous communities of Spain, autonomous community and archipelago in the Atlantic Ocean, in Macaronesia. At their closest point to ...
.
Phonolite is common across Europe, particularly within the Eifel Plateau and the Laacher See. It is also found in the Czech Republic and the Mediterranean area near Italy. For localities in the United States, phonolite can be found in the Black Hills Forest in South Dakokta. The most well known phonolite-composed natural structure is the
Devil's Tower, found in Wyoming.
Nepheline-normative rocks occur in close association with the
Bushveld Igneous Complex, possibly formed from partial melting of the wall rocks adjacent to that large
ultramafic layered intrusion. Phonolite occurs in the related Pilanesberg Complex and Pienaars River Complex.
Examples
North America
*
Cripple Creek & Victor Gold Mine
The Cripple Creek & Victor Gold Mine, formerly and historically the Cresson Mine, is an active gold mine located near the town of Victor, in the Cripple Creek mining district in the US state of Colorado. The richest gold mine in Colorado histor ...
phonolite pipe in
Colorado
Colorado (, other variants) is a state in the Mountain West subregion of the Western United States. It encompasses most of the Southern Rocky Mountains, as well as the northeastern portion of the Colorado Plateau and the western edge of the ...
*
Baldface Mountain, west-central
British Columbia
British Columbia (commonly abbreviated as BC) is the westernmost province of Canada, situated between the Pacific Ocean and the Rocky Mountains. It has a diverse geography, with rugged landscapes that include rocky coastlines, sandy beaches, for ...
, Canada
*
Devils Tower
Devils Tower (also known as Bear Lodge Butte) is a butte, possibly laccolithic, composed of igneous rock in the Bear Lodge Ranger District of the Black Hills, near Hulett and Sundance in Crook County, northeastern Wyoming, above the Belle ...
,
Wyoming
Wyoming () is a state in the Mountain West subregion of the Western United States. It is bordered by Montana to the north and northwest, South Dakota and Nebraska to the east, Idaho to the west, Utah to the southwest, and Colorado to t ...
, United States, an example of
columnar-jointed phonolite
*
Hoodoo Mountain, northwestern British Columbia, Canada
*
Missouri Buttes,
Crook County, northeast
Wyoming
Wyoming () is a state in the Mountain West subregion of the Western United States. It is bordered by Montana to the north and northwest, South Dakota and Nebraska to the east, Idaho to the west, Utah to the southwest, and Colorado to t ...
, United States
Europe
*
Bass Rock,
North Berwick Law
North Berwick Law, sometimes abbreviated to Berwick Law, is a conical hill which rises conspicuously from the surrounding landscape (this is the definition of the Lowland Scots word "law"). It overlooks the East Lothian town of North Berwick, Sc ...
and
Traprain Law in southeast
Scotland
Scotland (, ) is a country that is part of the United Kingdom. Covering the northern third of the island of Great Britain, mainland Scotland has a border with England to the southeast and is otherwise surrounded by the Atlantic Ocean to ...
, UK
*
Bořeň, northwestern
Czech Republic
The Czech Republic, or simply Czechia, is a landlocked country in Central Europe. Historically known as Bohemia, it is bordered by Austria to the south, Germany to the west, Poland to the northeast, and Slovakia to the southeast. The ...
*
Mont Gerbier de Jonc,
Ardèche, France
*
Montiferru,
Sardinia
Sardinia ( ; it, Sardegna, label=Italian, Corsican and Tabarchino ; sc, Sardigna , sdc, Sardhigna; french: Sardaigne; sdn, Saldigna; ca, Sardenya, label= Algherese and Catalan) is the second-largest island in the Mediterranean Sea, aft ...
*
Wolf Rock,
Cornwall
Cornwall (; kw, Kernow ) is a Historic counties of England, historic county and Ceremonial counties of England, ceremonial county in South West England. It is recognised as one of the Celtic nations, and is the homeland of the Cornish people ...
Other
*
Jebel Nefusa,
Libya
Libya (; ar, ليبيا, Lībiyā), officially the State of Libya ( ar, دولة ليبيا, Dawlat Lībiyā), is a country in the Maghreb region in North Africa. It is bordered by the Mediterranean Sea to the north, Egypt to the east, Suda ...
*
Dunedin
Dunedin ( ; mi, Ōtepoti) is the second-largest city in the South Island of New Zealand (after Christchurch), and the principal city of the Otago region. Its name comes from , the Scottish Gaelic name for Edinburgh, the capital of Scotland. Th ...
, New Zealand
*
Teide
Teide, or Mount Teide, ( es, El Teide, Pico del Teide, , "Peak of Teide") is a volcano on Tenerife in the Canary Islands, Spain. Its summit (at ) is the highest point in Spain and the highest point above sea level in the islands of the A ...
, a
stratovolcano on the island of
Tenerife
Tenerife (; ; formerly spelled ''Teneriffe'') is the largest and most populous island of the Canary Islands. It is home to 43% of the total population of the Archipelago, archipelago. With a land area of and a population of 978,100 inhabitant ...
* The phonolitic
lava lake
Lava lakes are large volumes of molten lava, usually basaltic, contained in a volcanic vent, crater, or broad depression. The term is used to describe both lava lakes that are wholly or partly molten and those that are solidified (someti ...
in
Mount Erebus
Mount Erebus () is the second-highest volcano in Antarctica (after Mount Sidley), the highest active volcano in Antarctica, and the southernmost active volcano on Earth. It is the sixth-highest ultra mountain on the continent.
With a sum ...
,
Ross Island,
Antarctica
Antarctica () is Earth's southernmost and least-populated continent. Situated almost entirely south of the Antarctic Circle and surrounded by the Southern Ocean, it contains the geographic South Pole. Antarctica is the fifth-largest cont ...
* The 'Bellstone' in
Saint Helena
Saint Helena () is a British overseas territory located in the South Atlantic Ocean. It is a remote volcanic tropical island west of the coast of south-western Africa, and east of Rio de Janeiro in South America. It is one of three constit ...
Economic importance
Phonolites can be of interest as
dimension stone or as aggregate for gravels.
Rarely, economically mineralised phonolite-nepheline syenite alkaline complexes can be associated with
rare-earth mineralisation,
uranium
Uranium is a chemical element with the symbol U and atomic number 92. It is a silvery-grey metal in the actinide series of the periodic table. A uranium atom has 92 protons and 92 electrons, of which 6 are valence electrons. Uranium is weak ...
mineralisation and
phosphate
In chemistry, a phosphate is an anion, salt, functional group or ester derived from a phosphoric acid. It most commonly means orthophosphate, a derivative of orthophosphoric acid .
The phosphate or orthophosphate ion is derived from phosph ...
s, such as at
Phalaborwa, South Africa.
Phonolite
tuff
Tuff is a type of rock made of volcanic ash ejected from a vent during a volcanic eruption. Following ejection and deposition, the ash is lithified into a solid rock. Rock that contains greater than 75% ash is considered tuff, while rock ...
was used as a source of
flint
Flint, occasionally flintstone, is a sedimentary cryptocrystalline form of the mineral quartz, categorized as the variety of chert that occurs in chalk or marly limestone. Flint was widely used historically to make stone tools and start ...
for
adze heads and such by prehistoric people from
Hohentwiel and
Hegau
The Hegau is an extinct volcanic landscape in southern Germany extending around the industrial city of Singen (Hohentwiel), between Lake Constance in the east, the Rhine River in the south, the Danube River in the north and the Randen—as the s ...
, Germany.
[Affolter, J., 2002, '' Provenance des silex préhistoriques du Jura et des régions limitrophes'', Archéologie neuchâteloise, 28.]
Phonolites can be separated into slabs of appropriate dimensions to be used as roofing tiles in place of roofing slate. One such occurrence is in the French
Massif Central
The (; oc, Massís Central, ; literally ''"Central Massif"'') is a highland region in south-central France, consisting of mountains and plateaus. It covers about 15% of mainland France.
Subject to volcanism that has subsided in the last 10,0 ...
region such as the
Haute Loire département.
References
External links
Woolley, A.R., Alkaline rocks and carbonatites of the world
{{Authority control
Igneous petrology
Volcanic rocks
Intermediate rocks