Nickel is a
chemical element
A chemical element is a species of atoms that have a given number of protons in their nuclei, including the pure substance consisting only of that species. Unlike chemical compounds, chemical elements cannot be broken down into simpler sub ...
with
symbol
A symbol is a mark, sign, or word that indicates, signifies, or is understood as representing an idea, object, or relationship. Symbols allow people to go beyond what is known or seen by creating linkages between otherwise very different conc ...
Ni and
atomic number
The atomic number or nuclear charge number (symbol ''Z'') of a chemical element is the charge number of an atomic nucleus. For ordinary nuclei, this is equal to the proton number (''n''p) or the number of protons found in the nucleus of every ...
28. It is a silvery-white lustrous
metal
A metal (from Greek μέταλλον ''métallon'', "mine, quarry, metal") is a material that, when freshly prepared, polished, or fractured, shows a lustrous appearance, and conducts electricity and heat relatively well. Metals are typicall ...
with a slight golden tinge. Nickel is a hard and
ductile
Ductility is a mechanical property commonly described as a material's amenability to drawing (e.g. into wire). In materials science, ductility is defined by the degree to which a material can sustain plastic deformation under tensile stres ...
transition metal
In chemistry, a transition metal (or transition element) is a chemical element in the d-block of the periodic table (groups 3 to 12), though the elements of group 12 (and less often group 3) are sometimes excluded. They are the elements that can ...
. Pure nickel is chemically reactive but large pieces are slow to react with air under
standard conditions
Standard temperature and pressure (STP) are standard sets of conditions for experimental measurements to be established to allow comparisons to be made between different sets of data. The most used standards are those of the International Union ...
because a
passivation layer of
nickel oxide
Nickel oxide may refer to:
* Nickel(II) oxide, NiO, green, well-characterised oxide
* Nickel(III) oxide
Nickel (III) oxide is the inorganic compound
In chemistry, an inorganic compound is typically a chemical compound that lacks carbon–hydr ...
forms on the surface that prevents further corrosion. Even so, pure
native
Native may refer to:
People
* Jus soli, citizenship by right of birth
* Indigenous peoples, peoples with a set of specific rights based on their historical ties to a particular territory
** Native Americans (disambiguation)
In arts and entert ...
nickel is found in Earth's crust only in tiny amounts, usually in
ultramafic rock
Ultramafic rocks (also referred to as ultrabasic rocks, although the terms are not wholly equivalent) are igneous and meta-igneous rocks with a very low silica content (less than 45%), generally >18% MgO, high FeO, low potassium, and are composed ...
s, and in the interiors of larger
nickel–iron meteorites that were not exposed to oxygen when outside Earth's atmosphere.
Meteoric nickel is found in combination with
iron
Iron () is a chemical element with symbol Fe (from la, ferrum) and atomic number 26. It is a metal that belongs to the first transition series and group 8 of the periodic table. It is, by mass, the most common element on Earth, right in f ...
, a reflection of the origin of those elements as major end products of
supernova nucleosynthesis. An iron–nickel mixture is thought to compose
Earth's outer and
inner cores.
Use of nickel (as natural
meteoric nickel–iron alloy) has been traced as far back as 3500 BCE. Nickel was first isolated and classified as an element in 1751 by
Axel Fredrik Cronstedt
Baron Axel Fredrik Cronstedt (''/kroonstet/'' 23 December 1722 – 19 August 1765) was a Swedish mineralogist and chemist who discovered the element nickel in 1751 as a mining expert with the Bureau of Mines.
Cronstedt is considered a founder ...
, who initially mistook the
ore
Ore is natural rock or sediment that contains one or more valuable minerals, typically containing metals, that can be mined, treated and sold at a profit.Encyclopædia Britannica. "Ore". Encyclopædia Britannica Online. Retrieved 7 Apr ...
for a
copper
Copper is a chemical element with the symbol Cu (from la, cuprum) and atomic number 29. It is a soft, malleable, and ductile metal with very high thermal and electrical conductivity. A freshly exposed surface of pure copper has a pinkis ...
mineral
In geology and mineralogy, a mineral or mineral species is, broadly speaking, a solid chemical compound with a fairly well-defined chemical composition and a specific crystal structure that occurs naturally in pure form.John P. Rafferty, ed. ( ...
, in the cobalt mines of
Los, Hälsingland, Sweden. The element's name comes from a mischievous sprite of German miner mythology, Nickel (similar to
Old Nick), who personified the fact that copper-nickel ores resisted refinement into copper. An economically important source of nickel is the
iron
Iron () is a chemical element with symbol Fe (from la, ferrum) and atomic number 26. It is a metal that belongs to the first transition series and group 8 of the periodic table. It is, by mass, the most common element on Earth, right in f ...
ore
limonite
Limonite () is an iron ore consisting of a mixture of hydrated iron(III) oxide-hydroxides in varying composition. The generic formula is frequently written as FeO(OH)·H2O, although this is not entirely accurate as the ratio of oxide to hydroxid ...
, which is often 1–2% nickel. Other important nickel ore minerals include
pentlandite
Pentlandite is an iron–nickel sulfide with the chemical formula . Pentlandite has a narrow variation range in Ni:Fe but it is usually described as having a Ni:Fe of 1:1. It also contains minor cobalt, usually at low levels as a fraction of wei ...
and a mix of Ni-rich natural silicates known as
garnierite
Garnierite is a general name for a green nickel ore which is found in pockets and veins within weathered and serpentinized ultramafic rocks. It forms by lateritic weathering of ultramafic rocks and occurs in many nickel laterite deposits in the ...
. Major production sites include the
Sudbury region,
Canada
Canada is a country in North America. Its ten provinces and three territories extend from the Atlantic Ocean to the Pacific Ocean and northward into the Arctic Ocean, covering over , making it the world's second-largest country by tot ...
(which is thought to be of
meteoric origin),
New Caledonia
)
, anthem = ""
, image_map = New Caledonia on the globe (small islands magnified) (Polynesia centered).svg
, map_alt = Location of New Caledonia
, map_caption = Location of New Caledonia
, mapsize = 290px
, subdivision_type = Sovereign st ...
in the
Pacific
The Pacific Ocean is the largest and deepest of Earth's five oceanic divisions. It extends from the Arctic Ocean in the north to the Southern Ocean (or, depending on definition, to Antarctica) in the south, and is bounded by the continen ...
, and
Norilsk
Norilsk ( rus, Нори́льск, p=nɐˈrʲilʲsk, ''Norílʹsk'') is a closed city in Krasnoyarsk Krai, Russia, located south of the western Taymyr Peninsula, around 90 km east of the Yenisey River and 1,500 km north of Krasnoyarsk. Norilsk ...
,
Russia
Russia (, , ), or the Russian Federation, is a List of transcontinental countries, transcontinental country spanning Eastern Europe and North Asia, Northern Asia. It is the List of countries and dependencies by area, largest country in the ...
.
Nickel is one of four elements (the others are
iron
Iron () is a chemical element with symbol Fe (from la, ferrum) and atomic number 26. It is a metal that belongs to the first transition series and group 8 of the periodic table. It is, by mass, the most common element on Earth, right in f ...
,
cobalt
Cobalt is a chemical element with the symbol Co and atomic number 27. As with nickel, cobalt is found in the Earth's crust only in a chemically combined form, save for small deposits found in alloys of natural meteoric iron. The free element, pr ...
, and
gadolinium
Gadolinium is a chemical element with the symbol Gd and atomic number 64. Gadolinium is a silvery-white metal when oxidation is removed. It is only slightly malleable and is a ductile rare-earth element. Gadolinium reacts with atmospheric oxygen ...
)
that are
ferromagnetic
Ferromagnetism is a property of certain materials (such as iron) which results in a large observed magnetic permeability, and in many cases a large magnetic coercivity allowing the material to form a permanent magnet. Ferromagnetic materials ...
at about room temperature.
Alnico
Alnico is a family of iron alloys which in addition to iron are composed primarily of aluminium (Al), nickel (Ni), and cobalt (Co), hence the acronym ''al-ni-co''. They also include copper, and sometimes titanium. Alnico alloys are ferromagnetic, ...
permanent
magnets
A magnet is a material or object that produces a magnetic field. This magnetic field is invisible but is responsible for the most notable property of a magnet: a force that pulls on other ferromagnetic materials, such as iron, steel, nickel ...
based partly on nickel are of intermediate strength between iron-based permanent magnets and
rare-earth magnets. The metal is used chiefly in
alloy
An alloy is a mixture of chemical elements of which at least one is a metal. Unlike chemical compounds with metallic bases, an alloy will retain all the properties of a metal in the resulting material, such as electrical conductivity, ductility, ...
s and corrosion-resistant plating. About 68% of world production is used in
stainless steel
Stainless steel is an alloy of iron that is resistant to rusting and corrosion. It contains at least 11% chromium and may contain elements such as carbon, other nonmetals and metals to obtain other desired properties. Stainless steel's corros ...
. A further 10% is used for nickel-based and copper-based alloys, 9% for plating, 7% for alloy steels, 3% in foundries, and 4% in other applications such as in rechargeable batteries,
including those in
electric vehicle
An electric vehicle (EV) is a vehicle that uses one or more electric motors for propulsion. It can be powered by a collector system, with electricity from extravehicular sources, or it can be powered autonomously by a battery (sometimes cha ...
s (EVs). Nickel is widely used in
coins
A coin is a small, flat (usually depending on the country or value), round piece of metal or plastic used primarily as a medium of exchange or legal tender. They are standardized in weight, and produced in large quantities at a mint in order to ...
, though nickel-plated objects sometimes provoke
nickel allergy
Nickel allergy or nickel allergic contact dermatitis (Ni-ACD) is a form of allergic contact dermatitis (ACD) caused by exposure to the chemical element nickel. It typically causes a rash that is red and itchy and that may be bumpy or scaly. The ...
. As a compound, nickel has a number of niche chemical manufacturing uses, such as a
catalyst for hydrogenation,
cathode
A cathode is the electrode from which a conventional current leaves a polarized electrical device. This definition can be recalled by using the mnemonic ''CCD'' for ''Cathode Current Departs''. A conventional current describes the direction in whi ...
s for rechargeable batteries, pigments and metal surface treatments. Nickel is an essential nutrient for some microorganisms and plants that have
enzymes
Enzymes () are proteins that act as biological catalysts by accelerating chemical reactions. The molecules upon which enzymes may act are called substrate (chemistry), substrates, and the enzyme converts the substrates into different molecule ...
with nickel as an
active site
In biology and biochemistry, the active site is the region of an enzyme where substrate molecules bind and undergo a chemical reaction. The active site consists of amino acid residues that form temporary bonds with the substrate (binding site) a ...
.
Properties
Atomic and physical properties
![Ni@CNT2](https://upload.wikimedia.org/wikipedia/commons/7/70/Ni%40CNT2.jpg)
Nickel is a silvery-white metal with a slight golden tinge that takes a high polish. It is one of only four elements that are
ferromagnetic
Ferromagnetism is a property of certain materials (such as iron) which results in a large observed magnetic permeability, and in many cases a large magnetic coercivity allowing the material to form a permanent magnet. Ferromagnetic materials ...
at or near room temperature; the others are iron,
cobalt
Cobalt is a chemical element with the symbol Co and atomic number 27. As with nickel, cobalt is found in the Earth's crust only in a chemically combined form, save for small deposits found in alloys of natural meteoric iron. The free element, pr ...
and
gadolinium
Gadolinium is a chemical element with the symbol Gd and atomic number 64. Gadolinium is a silvery-white metal when oxidation is removed. It is only slightly malleable and is a ductile rare-earth element. Gadolinium reacts with atmospheric oxygen ...
. Its
Curie temperature
In physics and materials science, the Curie temperature (''T''C), or Curie point, is the temperature above which certain materials lose their permanent magnetic properties, which can (in most cases) be replaced by induced magnetism. The Cur ...
is , meaning that bulk nickel is non-magnetic above this temperature.
The unit cell of nickel is a
face-centered cube with the lattice parameter of 0.352 nm, giving an
atomic radius
The atomic radius of a chemical element is a measure of the size of its atom, usually the mean or typical distance from the center of the nucleus to the outermost isolated electron. Since the boundary is not a well-defined physical entity, there ...
of 0.124 nm. This crystal structure is stable to pressures of at least 70 GPa. Nickel is hard, malleable and
ductile
Ductility is a mechanical property commonly described as a material's amenability to drawing (e.g. into wire). In materials science, ductility is defined by the degree to which a material can sustain plastic deformation under tensile stres ...
, and has a relatively high
electrical
Electricity is the set of physical phenomena associated with the presence and motion of matter that has a property of electric charge. Electricity is related to magnetism, both being part of the phenomenon of electromagnetism, as described ...
and
thermal conductivity
The thermal conductivity of a material is a measure of its ability to conduct heat. It is commonly denoted by k, \lambda, or \kappa.
Heat transfer occurs at a lower rate in materials of low thermal conductivity than in materials of high thermal ...
for transition metals.
The high
compressive strength
In mechanics, compressive strength or compression strength is the capacity of a material or structure to withstand loads tending to reduce size (as opposed to tensile strength which withstands loads tending to elongate). In other words, compre ...
of 34 GPa, predicted for ideal crystals, is never obtained in the real bulk material due to formation and movement of
dislocation
In materials science, a dislocation or Taylor's dislocation is a linear crystallographic defect or irregularity within a crystal structure that contains an abrupt change in the arrangement of atoms. The movement of dislocations allow atoms to sl ...
s. However, it has been reached in Ni
nanoparticle
A nanoparticle or ultrafine particle is usually defined as a particle of matter that is between 1 and 100 nanometres (nm) in diameter. The term is sometimes used for larger particles, up to 500 nm, or fibers and tubes that are less than 1 ...
s.
Electron configuration dispute
Nickel has two atomic
electron configurations,
r3d 4s and
r3d 4s, which are very close in energy;
rdenotes the complete
argon
Argon is a chemical element with the symbol Ar and atomic number 18. It is in group 18 of the periodic table and is a noble gas. Argon is the third-most abundant gas in Earth's atmosphere, at 0.934% (9340 ppmv). It is more than twice as abu ...
core structure. There is some disagreement on which configuration has the lower energy.
Chemistry textbooks quote nickel's electron configuration as
r4s 3d, also written
r3d 4s. This configuration agrees with the
Madelung energy ordering rule, which predicts that 4s is filled before 3d. It is supported by the experimental fact that the lowest energy state of the nickel atom is a 3d 4s energy level, specifically the 3d(F) 4s F, ''J'' = 4 level.
[NIST Atomic Spectrum Database](_blank)
To read the nickel atom levels, type "Ni I" in the Spectrum box and click on Retrieve data.
However, each of these two configurations splits into several energy levels due to
fine structure,
and the two sets of energy levels overlap. The average energy of states with
r3d 4s is actually lower than the average energy of states with
r3d 4s. Therefore, the research literature on atomic calculations quotes the ground state configuration as
r3d 4s.
Isotopes
The isotopes of nickel range in
atomic weight
Relative atomic mass (symbol: ''A''; sometimes abbreviated RAM or r.a.m.), also known by the deprecated synonym atomic weight, is a dimensionless physical quantity defined as the ratio of the average mass of atoms of a chemical element in a giv ...
from 48
u () to 78 u ().
Natural nickel is composed of five stable
isotope
Isotopes are two or more types of atoms that have the same atomic number (number of protons in their nuclei) and position in the periodic table (and hence belong to the same chemical element), and that differ in nucleon numbers (mass numbers) ...
s, , , , and , of which is the most abundant (68.077%
natural abundance
In physics, natural abundance (NA) refers to the abundance of isotopes of a chemical element as naturally found on a planet. The relative atomic mass (a weighted average, weighted by mole-fraction abundance figures) of these isotopes is the atomi ...
).
Nickel-62
Nickel-62 is an isotope of nickel having 28 protons and 34 neutrons.
It is a stable isotope, with the highest binding energy per nucleon of any known nuclide (8.7945 MeV). It is often stated that 56Fe is the "most stable nucleus", but only beca ...
has the highest
binding energy
In physics and chemistry, binding energy is the smallest amount of energy required to remove a particle from a system of particles or to disassemble a system of particles into individual parts. In the former meaning the term is predominantly use ...
per nucleon of any
nuclide: 8.7946 MeV/nucleon. Its binding energy is greater than both
and
, more abundant nuclides often incorrectly cited as having the highest binding energy.
Though this would seem to predict nickel as the most abundant heavy element in the universe, the high rate of
photodisintegration
Photodisintegration (also called phototransmutation, or a photonuclear reaction) is a nuclear process in which an atomic nucleus absorbs a high-energy gamma ray, enters an excited state, and immediately decays by emitting a subatomic particle. The ...
of nickel in stellar interiors causes iron to be by far the most abundant.
Nickel-60 is the daughter product of the
extinct radionuclide
An extinct radionuclide is a radionuclide that was formed by nucleosynthesis before the formation of the Solar System, about 4.6 billion years ago, but has since decayed to virtually zero abundance and is no longer detectable as a primordial nuc ...
(half-life 2.6 million years). Due to the long half-life of , its persistence in materials in the
Solar System
The Solar SystemCapitalization of the name varies. The International Astronomical Union, the authoritative body regarding astronomical nomenclature, specifies capitalizing the names of all individual astronomical objects but uses mixed "Solar S ...
may generate observable variations in the isotopic composition of . Therefore, the abundance of in extraterrestrial material may give insight into the origin of the Solar System and its early history.
At least 26 nickel
radioisotope
A radionuclide (radioactive nuclide, radioisotope or radioactive isotope) is a nuclide that has excess nuclear energy, making it unstable. This excess energy can be used in one of three ways: emitted from the nucleus as gamma radiation; transferr ...
s have been characterized; the most stable are with
half-life
Half-life (symbol ) is the time required for a quantity (of substance) to reduce to half of its initial value. The term is commonly used in nuclear physics to describe how quickly unstable atoms undergo radioactive decay or how long stable ato ...
76,000 years, (100 years), and (6 days). All other radioisotopes have half-lives less than 60 hours and most these have half-lives less than 30 seconds. This element also has one
meta state
A nuclear isomer is a metastable state of an atomic nucleus, in which one or more nucleons (protons or neutrons) occupy higher energy levels than in the ground state of the same nucleus. "Metastable" describes nuclei whose excited states have ...
.
Radioactive nickel-56 is produced by the
silicon burning process
In astrophysics, silicon burning is a very brief sequence of nuclear fusion reactions that occur in massive stars with a minimum of about 8–11 solar masses. Silicon burning is the final stage of fusion for massive stars that have run out of the f ...
and later set free in large amounts in
type Ia
A Type Ia supernova (read: "type one-A") is a type of supernova that occurs in binary systems (two stars orbiting one another) in which one of the stars is a white dwarf. The other star can be anything from a giant star to an even smaller whi ...
supernova
A supernova is a powerful and luminous explosion of a star. It has the plural form supernovae or supernovas, and is abbreviated SN or SNe. This transient astronomical event occurs during the last evolutionary stages of a massive star or when ...
e. The shape of the
light curve
In astronomy, a light curve is a graph of light intensity of a celestial object or region as a function of time, typically with the magnitude of light received on the y axis and with time on the x axis. The light is usually in a particular frequ ...
of these supernovae at intermediate to late-times corresponds to the decay via
electron capture
Electron capture (K-electron capture, also K-capture, or L-electron capture, L-capture) is a process in which the proton-rich nucleus of an electrically neutral atom absorbs an inner atomic electron, usually from the K or L electron shells. Thi ...
of to
cobalt
Cobalt is a chemical element with the symbol Co and atomic number 27. As with nickel, cobalt is found in the Earth's crust only in a chemically combined form, save for small deposits found in alloys of natural meteoric iron. The free element, pr ...
-56 and ultimately to iron-56.
Nickel-59 is a long-lived
cosmogenic
Cosmogenic nuclides (or cosmogenic isotopes) are rare nuclides (isotopes) created when a high-energy cosmic ray interacts with the nucleus of an ''in situ'' Solar System atom, causing nucleons (protons and neutrons) to be expelled from the atom ...
radionuclide
A radionuclide (radioactive nuclide, radioisotope or radioactive isotope) is a nuclide that has excess nuclear energy, making it unstable. This excess energy can be used in one of three ways: emitted from the nucleus as gamma radiation; transfer ...
; half-life 76,000 years. has found many applications in
isotope geology
Isotope geochemistry is an aspect of geology based upon the study of natural variations in the relative abundances of isotopes of various elements. Variations in isotopic abundance are measured by isotope ratio mass spectrometry, and can reveal ...
. has been used to date the terrestrial age of
meteorite
A meteorite is a solid piece of debris from an object, such as a comet, asteroid, or meteoroid, that originates in outer space and survives its passage through the atmosphere to reach the surface of a planet or Natural satellite, moon. When the ...
s and to determine abundances of extraterrestrial dust in ice and
sediment
Sediment is a naturally occurring material that is broken down by processes of weathering and erosion, and is subsequently transported by the action of wind, water, or ice or by the force of gravity acting on the particles. For example, sand an ...
. The half-life of nickel-78 was recently measured at 110 milliseconds, and is believed an important isotope in
supernova nucleosynthesis of elements heavier than iron. Ni, discovered in 1999, is the most proton-rich heavy element isotope known. With 28
proton
A proton is a stable subatomic particle, symbol , H+, or 1H+ with a positive electric charge of +1 ''e'' elementary charge. Its mass is slightly less than that of a neutron and 1,836 times the mass of an electron (the proton–electron mass ...
s and 20
neutron
The neutron is a subatomic particle, symbol or , which has a neutral (not positive or negative) charge, and a mass slightly greater than that of a proton. Protons and neutrons constitute the nuclei of atoms. Since protons and neutrons beh ...
s, Ni is "
doubly magic
In nuclear physics, a magic number is a number of nucleons (either protons or neutrons, separately) such that they are arranged into complete shells within the atomic nucleus. As a result, atomic nuclei with a 'magic' number of protons or neutron ...
", as is Ni with 28 protons and 50 neutrons. Both are therefore unusually stable for nuclei with so large a
proton–neutron imbalance.
Nickel-63 is a contaminant found in the support structure of nuclear reactors. It is produced through neutron capture by nickel-62. Small amounts have also been found near nuclear weapon test sites in the South Pacific.
Occurrence
![Widmanstatten hand](https://upload.wikimedia.org/wikipedia/commons/3/36/Widmanstatten_hand.jpg)
On Earth, nickel occurs most often in combination with
sulfur
Sulfur (or sulphur in British English) is a chemical element with the symbol S and atomic number 16. It is abundant, multivalent and nonmetallic. Under normal conditions, sulfur atoms form cyclic octatomic molecules with a chemical formula ...
and iron in
pentlandite
Pentlandite is an iron–nickel sulfide with the chemical formula . Pentlandite has a narrow variation range in Ni:Fe but it is usually described as having a Ni:Fe of 1:1. It also contains minor cobalt, usually at low levels as a fraction of wei ...
, with
sulfur
Sulfur (or sulphur in British English) is a chemical element with the symbol S and atomic number 16. It is abundant, multivalent and nonmetallic. Under normal conditions, sulfur atoms form cyclic octatomic molecules with a chemical formula ...
in
millerite
Millerite is a nickel sulfide mineral, Ni S. It is brassy in colour and has an acicular habit, often forming radiating masses and furry aggregates. It can be distinguished from pentlandite by crystal habit, its duller colour, and general la ...
, with
arsenic
Arsenic is a chemical element with the symbol As and atomic number 33. Arsenic occurs in many minerals, usually in combination with sulfur and metals, but also as a pure elemental crystal. Arsenic is a metalloid. It has various allotropes, but ...
in the mineral
nickeline
Nickeline or niccolite is a mineral consisting primarily of nickel arsenide (NiAs). The naturally-occurring mineral contains roughly 43.9% nickel and 56.1% arsenic by mass, but composition of the mineral may vary slightly.
Small quantities of ...
, and with arsenic and
sulfur
Sulfur (or sulphur in British English) is a chemical element with the symbol S and atomic number 16. It is abundant, multivalent and nonmetallic. Under normal conditions, sulfur atoms form cyclic octatomic molecules with a chemical formula ...
in nickel
galena
Galena, also called lead glance, is the natural mineral form of lead(II) sulfide (PbS). It is the most important ore of lead and an important source of silver.
Galena is one of the most abundant and widely distributed sulfide minerals. It cryst ...
. Nickel is commonly found in
iron meteorite
Iron meteorites, also known as siderites, or ferrous meteorites, are a type of meteorite that consist overwhelmingly of an iron–nickel alloy known as meteoric iron that usually consists of two mineral phases: kamacite and taenite. Most iron ...
s as the alloys
kamacite
Kamacite is an alloy of iron and nickel, which is found on Earth only in meteorites. According to the International Mineralogical Association (IMA) it is considered a proper nickel-rich variety of the mineral native iron. The proportion iron:ni ...
and
taenite
Taenite is a mineral found naturally on Earth mostly in iron meteorites. It is an alloy of iron and nickel, with a chemical formula of and nickel proportions of 20% up to 65%.
The name is derived from the Greek ταινία for "band, ribbon" ...
. Nickel in meteorites was first detected in 1799 by
Joseph-Louis Proust
Joseph Louis Proust (26 September 1754 – 5 July 1826) was a French chemist. He was best known for his discovery of the law of definite proportions in 1794, stating that chemical compounds always combine in constant proportions.
Life
Joseph L. ...
, a French chemist who then worked in Spain. Proust analyzed samples of the meteorite from
Campo del Cielo
Campo del Cielo refers to a group of iron meteorites and the area in Argentina where they were found. The site straddles the provinces of Chaco and Santiago del Estero, located north-northwest of Buenos Aires, Argentina and approximately south ...
(Argentina), which had been obtained in 1783 by Miguel Rubín de Celis, discovering the presence in them of nickel (about 10%) along with iron.
The bulk of nickel is
mined from two types of
ore
Ore is natural rock or sediment that contains one or more valuable minerals, typically containing metals, that can be mined, treated and sold at a profit.Encyclopædia Britannica. "Ore". Encyclopædia Britannica Online. Retrieved 7 Apr ...
deposits. The first is
laterite, where the principal ore mineral mixtures are nickeliferous
limonite
Limonite () is an iron ore consisting of a mixture of hydrated iron(III) oxide-hydroxides in varying composition. The generic formula is frequently written as FeO(OH)·H2O, although this is not entirely accurate as the ratio of oxide to hydroxid ...
, (Fe,Ni)O(OH), and
garnierite
Garnierite is a general name for a green nickel ore which is found in pockets and veins within weathered and serpentinized ultramafic rocks. It forms by lateritic weathering of ultramafic rocks and occurs in many nickel laterite deposits in the ...
(a mixture of various hydrous nickel and nickel-rich silicates). The second is magmatic
sulfide
Sulfide (British English also sulphide) is an inorganic anion of sulfur with the chemical formula S2− or a compound containing one or more S2− ions. Solutions of sulfide salts are corrosive. ''Sulfide'' also refers to chemical compounds lar ...
deposits, where the principal ore mineral is
pentlandite
Pentlandite is an iron–nickel sulfide with the chemical formula . Pentlandite has a narrow variation range in Ni:Fe but it is usually described as having a Ni:Fe of 1:1. It also contains minor cobalt, usually at low levels as a fraction of wei ...
: .
Indonesia
Indonesia, officially the Republic of Indonesia, is a country in Southeast Asia and Oceania between the Indian and Pacific oceans. It consists of over 17,000 islands, including Sumatra, Java, Sulawesi, and parts of Borneo and New Guine ...
and
Australia
Australia, officially the Commonwealth of Australia, is a Sovereign state, sovereign country comprising the mainland of the Australia (continent), Australian continent, the island of Tasmania, and numerous List of islands of Australia, sma ...
have the biggest estimated reserves, at 43.6% of world total.
Identified land-based resources throughout the world averaging 1% nickel or greater comprise at least 130 million tons of nickel (about the double of known reserves). About 60% is in
laterites
Laterite is both a soil and a rock type rich in iron and aluminium and is commonly considered to have formed in hot and wet tropical areas. Nearly all laterites are of rusty-red coloration, because of high iron oxide content. They develop by ...
and 40% in sulfide deposits.
On
geophysical
Geophysics () is a subject of natural science concerned with the physical processes and physical properties of the Earth and its surrounding space environment, and the use of quantitative methods for their analysis. The term ''geophysics'' some ...
evidence, most of the nickel on Earth is believed to be in Earth's
outer
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