Garnierite
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Garnierite
Garnierite is a general name for a green nickel ore which is found in pockets and veins within weathered and serpentinized ultramafic rocks. It forms by lateritic weathering of ultramafic rocks and occurs in many nickel laterite deposits in the world. It is an important nickel ore, having a large weight percent NiO.Pecora, W.T., Hobbs, S.W. and Murata, J.K. (1949) Variations in garnierite from the nickel deposit near Riddle, Oregon. Economic Geology, 44, 13-23.Roqué-Rosell, J., Villanova-de-Benavent, C., Proenza, J.A., Tauler, E. and Galí,S. (2011) Distribution and speciation of Ni in sepiolite-falcondoite-type “garnierite” by EXAFS. Macla, 15, 183-184. As garnierite is not a valid mineral name according to the Commission on New Minerals, Nomenclature and Classification (CNMNC), no definite composition or formula has been universally adopted. Some of the proposed compositions are all hydrous Ni-Mg silicates,Faust, G.T. (1966) The hydrous nickel-magnesium silicates – The ga ...
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Népouite
Népouite is a rare nickel silicate mineral which has the apple green colour typical of such compounds. It was named by the French mining engineer Edouard Glasser in 1907 after the place where it was first described (the type locality), the Népoui Mine, , Poya Commune, North Province, New Caledonia. The ideal formula is , but most specimens contain some magnesium, and is more realistic. There is a similar mineral called lizardite (named after the Lizard Complex in Cornwall, England) in which all of the nickel is replaced by magnesium, formula . These two minerals form a series; intermediate compositions are possible, with varying proportions of nickel to magnesium. Pecoraite is another rare mineral with the same chemical formula as népouite, but a different structure; such minerals are said to be dimorphs of each other, in the same way as graphite is a dimorph of diamond. Népouite, lizardite and pecoraite are all members of the kaolinite-serpentine group. Garnie ...
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Nontronite
Nontronite is the iron(III) rich member of the smectite group of clay minerals. Nontronites typically have a chemical composition consisting of more than ~30% Fe2 O3 and less than ~12% Al2O3 (ignited basis). Nontronite has very few economic deposits like montmorillonite. Like montmorillonite, nontronite can have variable amounts of adsorbed water associated with the interlayer surfaces and the exchange cations. A typical structural formula for nontronite is Ca.5( Si7Al.8Fe.2)(Fe3.5Al.4 Mg.1)O20(O H)4. The dioctahedral sheet of nontronite is composed mainly of trivalent iron (Fe3+) cations, although some substitution by trivalent aluminium (Al3+) and divalent magnesium (Mg2+) does occur. The tetrahedral sheet is composed mainly of silicon (Si4+), but can have substantial (about 1 in 8) substitution of either Fe3+ or Al3+, or combinations of these two cations. Thus, nontronite typically is characterised by having most (usually greater than 60%) of the layer charge located in the ...
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Palygorskite
Palygorskite or attapulgite is a magnesium aluminium phyllosilicate with the chemical formula ) that occurs in a type of clay soil common to the Southeastern United States. It is one of the types of fuller's earth. Some smaller deposits of this mineral can be found in Mexico, where its use is tied to the manufacture of Maya blue in pre-Columbian times. Name Palygorskite was first described in 1862 for a deposit at Palygorskaya on the Popovka River, Middle Urals, Permskaya Oblast, Russia. The synonym ''attapulgite'' is derived from the U.S. town of Attapulgus, in the extreme southwest corner of the state of Georgia, where the mineral is abundant and surface-mined. Mining and usage Mineral deposit in the US Two companies are involved in the industrial extraction and processing of gellant-grade attapulgite clay within the same Attapulgus deposit: Active Minerals International, LLC, and BASF Corp. In 2008, BASF acquired the assets of Zemex Attapulgite, leaving only two gellan ...
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Chlorite Group
The chlorites are the group of phyllosilicate minerals common in low-grade metamorphic rocks and in altered igneous rocks. Greenschist, formed by metamorphism of basalt or other low-silica volcanic rock, typically contains significant amounts of chlorite. Chlorite minerals show a wide variety of compositions, in which magnesium, iron, aluminium, and silicon substitute for each other in the crystal structure. A complete solid solution series exists between the two most common end members, magnesium-rich clinochlore and iron-rich chamosite. In addition, manganese, zinc, lithium, and calcium species are known. The great range in composition results in considerable variation in physical, optical, and X-ray properties. Similarly, the range of chemical composition allows chlorite group minerals to exist over a wide range of temperature and pressure conditions. For this reason chlorite minerals are ubiquitous minerals within low and medium temperature metamorphic rocks, some igneous r ...
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Lizardite
Lizardite is a mineral from the serpentine group with formula , and the most common type of mineral in the group. It is also a member of the kaolinite-serpentine group. Népouite and lizardite form a series; intermediate compositions are possible, with varying proportions of nickel to magnesium. Lizardite, which is much more common, forms a solid solution series with népouite. Lizardite may form a solid solution series with népouite. Extremely fine-grained, scaly lizardite (also called orthoantigorite) comprises much of the serpentine present in serpentine marbles. It is triclinic, has one direction of perfect cleavage, and may be white, yellow or green. Lizardite is translucent and soft, and may be pseudomorphous after enstatite, olivine or pyroxene, in which case the name bastite is sometimes applied. Bastite may have a silky lustre. Name Lizardite was named by Eric James William Whittaker and Jack Zussman in 1955 after the place it was first reported, the Lizard Penin ...
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Chrysotile
Chrysotile or white asbestos is the most commonly encountered form of asbestos, accounting for approximately 95% of the asbestos in the United StatesOccupational Safety and Health Administration, U.S. Department of Labor (2007)29 C.F.R. 1910.1001 Appendix J. and a similar proportion in other countries.Institut national de recherche sur la sécurité (1997).Amiante." ''Fiches toxicologiques.'' n° 167. (in French) It is a soft, fibrous silicate mineral in the serpentine subgroup of phyllosilicates; as such, it is distinct from other asbestiform minerals in the amphibole group. Its idealized chemical formula is Mg( Si O)( OH). The material has physical properties which make it desirable for inclusion in building materials, but poses serious health risks when dispersed into air and inhaled. Polytypes Three polytypes of chrysotile are known. These are very difficult to distinguish in hand specimens, and polarized light microscopy must normally be used. Some older publica ...
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Pecoraite
Pecoraite is a nickel silicate mineral and a member of the serpentine group. It was named after geologist William Thomas Pecora. It is monoclinic and has a chemical composition of Ni3(Si2O5)(OH)4. It is associated with the weathering-and-or oxidation of meteorites or nickel sulfide minerals such as millerite. It is also found in altered ultramafic rocks Ultramafic rocks (also referred to as ultrabasic rocks, although the terms are not wholly equivalent) are igneous and meta-igneous rocks with a very low silica content (less than 45%), generally >18% MgO, high FeO, low potassium, and are compos .... Pecoriate is typically a green, lime green, or bluegreen mineral with a waxy, or earthy luster and a mohs hardness of 2.5. Common textural habits associated with Pecoraite are curved plates, spirals and tubes. It can also be granular and massive. References Nickel minerals Monoclinic minerals Serpentine group {{silicate-mineral-stub ...
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Ural Mountains
The Ural Mountains ( ; rus, Ура́льские го́ры, r=Uralskiye gory, p=ʊˈralʲskʲɪjə ˈɡorɨ; ba, Урал тауҙары) or simply the Urals, are a mountain range that runs approximately from north to south through western Russia, from the coast of the Arctic Ocean to the river Ural and northwestern Kazakhstan.Ural Mountains
Encyclopædia Britannica on-line
The mountain range forms part of the conventional boundary between the regions of and

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Solid Solution
A solid solution, a term popularly used for metals, is a homogenous mixture of two different kinds of atoms in solid state and have a single crystal structure. Many examples can be found in metallurgy, geology, and solid-state chemistry. The word "solution" is used to describe the intimate mixing of components at the atomic level and distinguishes these homogeneous materials from physical mixtures of components. Two terms are mainly associated with solid solutions - ''solvents'' and ''solutes,'' depending on the relative abundance of the atomic species. In general if two compounds are isostructural then a solid solution will exist between the end members (also known as parents). For example sodium chloride and potassium chloride have the same cubic crystal structure so it is possible to make a pure compound with any ratio of sodium to potassium (Na1-xKx)Cl by dissolving that ratio of NaCl and KCl in water and then evaporating the solution. A member of this family is sold under t ...
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EXAFS
Extended X-ray absorption fine structure (EXAFS), along with X-ray absorption near edge structure (XANES), is a subset of X-ray absorption spectroscopy (XAS). Like other absorption spectroscopies, XAS techniques follow Beer's law. The X-ray absorption coefficient of a material as a function of energy is obtained using X-rays of a narrow energy resolution are directed at a sample and the incident and transmitted x-ray intensity is recorded as the incident x-ray energy is incremented. When the incident x-ray energy matches the binding energy of an electron of an atom within the sample, the number of x-rays absorbed by the sample increases dramatically, causing a drop in the transmitted x-ray intensity. This results in an absorption edge. Every element has a set of unique absorption edges corresponding to different binding energies of its electrons, giving XAS element selectivity. XAS spectra are most often collected at synchrotrons because of the high intensity of synchrotron X- ...
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