![Sauce boat](https://upload.wikimedia.org/wikipedia/commons/9/91/Sauce_boat.jpg)
A metal (from
Greek
Greek may refer to:
Greece
Anything of, from, or related to Greece, a country in Southern Europe:
*Greeks, an ethnic group.
*Greek language, a branch of the Indo-European language family.
**Proto-Greek language, the assumed last common ancestor ...
μέταλλον ''métallon'', "mine, quarry, metal") is a
material
Material is a substance or mixture of substances that constitutes an object. Materials can be pure or impure, living or non-living matter. Materials can be classified on the basis of their physical and chemical properties, or on their geologi ...
that, when freshly prepared, polished, or fractured, shows a lustrous appearance, and conducts
electricity
Electricity is the set of physical phenomena associated with the presence and motion of matter that has a property of electric charge. Electricity is related to magnetism, both being part of the phenomenon of electromagnetism, as described ...
and
heat
In thermodynamics, heat is defined as the form of energy crossing the boundary of a thermodynamic system by virtue of a temperature difference across the boundary. A thermodynamic system does not ''contain'' heat. Nevertheless, the term is al ...
relatively well. Metals are typically
ductile
Ductility is a mechanical property commonly described as a material's amenability to drawing (e.g. into wire). In materials science, ductility is defined by the degree to which a material can sustain plastic deformation under tensile stres ...
(can be drawn into wires) and
malleable
Ductility is a mechanical property commonly described as a material's amenability to drawing (e.g. into wire). In materials science, ductility is defined by the degree to which a material can sustain plastic deformation under tensile stres ...
(they can be hammered into thin sheets). These properties are the result of the ''
metallic bond
Metallic bonding is a type of chemical bonding that arises from the electrostatic attractive force between conduction electrons (in the form of an electron cloud of delocalized electrons) and positively charged metal ions. It may be descri ...
'' between the atoms or molecules of the metal.
A metal may be a
chemical element
A chemical element is a species of atoms that have a given number of protons in their nuclei, including the pure substance consisting only of that species. Unlike chemical compounds, chemical elements cannot be broken down into simpler sub ...
such as
iron
Iron () is a chemical element with symbol Fe (from la, ferrum) and atomic number 26. It is a metal that belongs to the first transition series and group 8 of the periodic table. It is, by mass, the most common element on Earth, right in f ...
; an
alloy
An alloy is a mixture of chemical elements of which at least one is a metal. Unlike chemical compounds with metallic bases, an alloy will retain all the properties of a metal in the resulting material, such as electrical conductivity, ductility, ...
such as
stainless steel
Stainless steel is an alloy of iron that is resistant to rusting and corrosion. It contains at least 11% chromium and may contain elements such as carbon, other nonmetals and metals to obtain other desired properties. Stainless steel's corros ...
; or a molecular compound such as
polymeric sulfur nitride.
In physics, a metal is generally regarded as any substance capable of conducting electricity at a temperature of
absolute zero
Absolute zero is the lowest limit of the thermodynamic temperature scale, a state at which the enthalpy and entropy of a cooled ideal gas reach their minimum value, taken as zero kelvin. The fundamental particles of nature have minimum vibration ...
. Many elements and compounds that are not normally classified as metals become metallic under high pressures. For example, the nonmetal
iodine
Iodine is a chemical element with the symbol I and atomic number 53. The heaviest of the stable halogens, it exists as a semi-lustrous, non-metallic solid at standard conditions that melts to form a deep violet liquid at , and boils to a vi ...
gradually becomes a metal at a pressure of between 40 and 170 thousand times
atmospheric pressure
Atmospheric pressure, also known as barometric pressure (after the barometer), is the pressure within the atmosphere of Earth. The standard atmosphere (symbol: atm) is a unit of pressure defined as , which is equivalent to 1013.25 millibars, 7 ...
. Equally, some materials regarded as metals can become nonmetals.
Sodium
Sodium is a chemical element with the symbol Na (from Latin ''natrium'') and atomic number 11. It is a soft, silvery-white, highly reactive metal. Sodium is an alkali metal, being in group 1 of the periodic table. Its only stable iso ...
, for example, becomes a nonmetal at pressure of just under two million times atmospheric pressure.
In chemistry, two elements that would otherwise qualify (in physics) as brittle metals—
arsenic
Arsenic is a chemical element with the symbol As and atomic number 33. Arsenic occurs in many minerals, usually in combination with sulfur and metals, but also as a pure elemental crystal. Arsenic is a metalloid. It has various allotropes, but ...
and
antimony
Antimony is a chemical element with the symbol Sb (from la, stibium) and atomic number 51. A lustrous gray metalloid, it is found in nature mainly as the sulfide mineral stibnite (Sb2S3). Antimony compounds have been known since ancient time ...
—are commonly instead recognised as
metalloid
A metalloid is a type of chemical element which has a preponderance of material property, properties in between, or that are a mixture of, those of metals and nonmetals. There is no standard definition of a metalloid and no complete agreement on ...
s due to their chemistry (predominantly non-metallic for arsenic, and balanced between metallicity and nonmetallicity for antimony). Around 95 of the 118 elements in the
periodic table
The periodic table, also known as the periodic table of the (chemical) elements, is a rows and columns arrangement of the chemical elements. It is widely used in chemistry, physics, and other sciences, and is generally seen as an icon of ch ...
are metals (or are likely to be such). The number is inexact as the boundaries between metals,
nonmetal
In chemistry, a nonmetal is a chemical element that generally lacks a predominance of metallic properties; they range from colorless gases (like hydrogen) to shiny solids (like carbon, as graphite). The electrons in nonmetals behave differentl ...
s, and
metalloid
A metalloid is a type of chemical element which has a preponderance of material property, properties in between, or that are a mixture of, those of metals and nonmetals. There is no standard definition of a metalloid and no complete agreement on ...
s fluctuate slightly due to a lack of universally accepted definitions of the categories involved.
In
astrophysics
Astrophysics is a science that employs the methods and principles of physics and chemistry in the study of astronomical objects and phenomena. As one of the founders of the discipline said, Astrophysics "seeks to ascertain the nature of the h ...
the term "metal" is cast more widely to refer to all chemical elements in a star that are heavier than
helium
Helium (from el, ἥλιος, helios, lit=sun) is a chemical element with the symbol He and atomic number 2. It is a colorless, odorless, tasteless, non-toxic, inert, monatomic gas and the first in the noble gas group in the periodic table. ...
, and not just traditional metals. In this sense the first four "metals" collecting in stellar cores through nucleosynthesis are
carbon
Carbon () is a chemical element with the symbol C and atomic number 6. It is nonmetallic and tetravalent
In chemistry, the valence (US spelling) or valency (British spelling) of an element is the measure of its combining capacity with o ...
,
nitrogen
Nitrogen is the chemical element with the symbol N and atomic number 7. Nitrogen is a nonmetal and the lightest member of group 15 of the periodic table, often called the pnictogens. It is a common element in the universe, estimated at se ...
,
oxygen
Oxygen is the chemical element with the symbol O and atomic number 8. It is a member of the chalcogen group in the periodic table, a highly reactive nonmetal, and an oxidizing agent that readily forms oxides with most elements as wel ...
, and
neon
Neon is a chemical element with the symbol Ne and atomic number 10. It is a noble gas. Neon is a colorless, odorless, inert monatomic gas under standard conditions, with about two-thirds the density of air. It was discovered (along with krypton ...
, all of which are strictly non-metals in chemistry. A star
fuses
Fuse or FUSE may refer to:
Devices
* Fuse (electrical), a device used in electrical systems to protect against excessive current
** Fuse (automotive), a class of fuses for vehicles
* Fuse (hydraulic), a device used in hydraulic systems to protect ...
lighter atoms, mostly hydrogen and helium, into heavier atoms over its lifetime. Used in that sense, the
metallicity
In astronomy, metallicity is the abundance of elements present in an object that are heavier than hydrogen and helium. Most of the normal physical matter in the Universe is either hydrogen or helium, and astronomers use the word ''"metals"'' as a ...
of an astronomical object is the proportion of its matter made up of the heavier chemical elements.
Metals, as chemical elements, comprise 25% of the Earth's crust and are present in many aspects of modern life. The strength and resilience of some metals has led to their frequent use in, for example, high-rise building and bridge
construction
Construction is a general term meaning the art and science to form objects, systems, or organizations,"Construction" def. 1.a. 1.b. and 1.c. ''Oxford English Dictionary'' Second Edition on CD-ROM (v. 4.0) Oxford University Press 2009 and com ...
, as well as most vehicles, many
home appliance
A home appliance, also referred to as a domestic appliance, an electric appliance or a household appliance, is a machine which assists in household functions such as cooking, cleaning and food preservation.
Appliances are divided into three ty ...
s, tools, pipes, and railroad tracks.
Precious metal
Precious metals are rare, naturally occurring metallic chemical elements of high economic value.
Chemically, the precious metals tend to be less reactive than most elements (see noble metal). They are usually ductile and have a high lustre. ...
s were historically used as
coin
A coin is a small, flat (usually depending on the country or value), round piece of metal or plastic used primarily as a medium of exchange or legal tender. They are standardized in weight, and produced in large quantities at a mint in order t ...
age, but in the modern era,
coinage metals
The coinage metals comprise, at a minimum, those metallic chemical elements which have historically been used as components in alloys used to mint coins. The term is not perfectly defined, however, since a number of metals have been used to mak ...
have extended to at least 23 of the chemical elements.
The history of refined metals is thought to begin with the use of copper about 11,000 years ago. Gold, silver, iron (as meteoric iron), lead, and brass were likewise in use before the first known appearance of bronze in the fifth millennium BCE. Subsequent developments include the production of early forms of steel; the discovery of
sodium
Sodium is a chemical element with the symbol Na (from Latin ''natrium'') and atomic number 11. It is a soft, silvery-white, highly reactive metal. Sodium is an alkali metal, being in group 1 of the periodic table. Its only stable iso ...
—the first
light metal
A light metal is any metal of relatively low density. More specific definitions have been proposed; none have obtained widespread acceptance. Magnesium, aluminium and titanium are light metals of significant commercial importance. Their densities ...
—in 1809; the rise of modern
alloy steel
Alloy steel is steel that is alloyed with a variety of elements in total amounts between 1.0% and 50% by weight to improve its mechanical properties. Alloy steels are broken down into two groups: low alloy steels and high alloy steels. The differe ...
s; and, since the end of World War II, the development of more sophisticated alloys.
Properties
Form and structure
![Gallium crystals](https://upload.wikimedia.org/wikipedia/commons/9/92/Gallium_crystals.jpg)
Metals are shiny and
lustrous
Lustre (British English) or luster (American English; see spelling differences) is the way light interacts with the surface of a crystal, rock, or mineral. The word traces its origins back to the Latin ''lux'', meaning "light", and generally imp ...
, at least when freshly prepared, polished, or fractured. Sheets of metal thicker than a few micrometres appear opaque, but
gold leaf
Gold leaf is gold that has been hammered into thin sheets (usually around 0.1 µm thick) by goldbeating and is often used for gilding. Gold leaf is available in a wide variety of karats and shades. The most commonly used gold is 22-kara ...
transmits green light.
The solid or liquid state of metals largely originates in the capacity of the metal atoms involved to readily lose their outer shell electrons. Broadly, the forces holding an individual atom's outer shell electrons in place are weaker than the attractive forces on the same electrons arising from interactions between the atoms in the solid or liquid metal. The electrons involved become delocalised and the atomic structure of a metal can effectively be visualised as a collection of atoms embedded in a cloud of relatively mobile electrons. This type of interaction is called a
metallic bond
Metallic bonding is a type of chemical bonding that arises from the electrostatic attractive force between conduction electrons (in the form of an electron cloud of delocalized electrons) and positively charged metal ions. It may be descri ...
.
The strength of metallic bonds for different elemental metals reaches a maximum around the center of the
transition metal
In chemistry, a transition metal (or transition element) is a chemical element in the d-block of the periodic table (groups 3 to 12), though the elements of group 12 (and less often group 3) are sometimes excluded. They are the elements that can ...
series, as these elements have large numbers of delocalized electrons.
Although most elemental metals have higher
densities
Density (volumetric mass density or specific mass) is the substance's mass per unit of volume. The symbol most often used for density is ''ρ'' (the lower case Greek language, Greek letter Rho (letter), rho), although the Latin letter ''D'' ca ...
than most
nonmetal
In chemistry, a nonmetal is a chemical element that generally lacks a predominance of metallic properties; they range from colorless gases (like hydrogen) to shiny solids (like carbon, as graphite). The electrons in nonmetals behave differentl ...
s,
there is a wide variation in their densities,
lithium
Lithium (from el, λίθος, lithos, lit=stone) is a chemical element with the symbol Li and atomic number 3. It is a soft, silvery-white alkali metal. Under standard conditions, it is the least dense metal and the least dense solid el ...
being the least dense (0.534 g/cm
3) and
osmium
Osmium (from Greek grc, ὀσμή, osme, smell, label=none) is a chemical element with the symbol Os and atomic number 76. It is a hard, brittle, bluish-white transition metal in the platinum group that is found as a trace element in alloys, mos ...
(22.59 g/cm
3) the most dense. Magnesium, aluminum and titanium are
light metal
A light metal is any metal of relatively low density. More specific definitions have been proposed; none have obtained widespread acceptance. Magnesium, aluminium and titanium are light metals of significant commercial importance. Their densities ...
s of significant commercial importance. Their respective densities of 1.7, 2.7, and 4.5 g/cm
3 can be compared to those of the older structural metals, like iron at 7.9 and copper at 8.9 g/cm
3. An iron ball would thus weigh about as much as three aluminum balls of equal volume.
![Hot metalwork](https://upload.wikimedia.org/wikipedia/commons/a/a9/Hot_metalwork.jpg)
Metals are typically malleable and ductile, deforming under stress without
cleaving.
The nondirectional nature of metallic bonding is thought to contribute significantly to the ductility of most metallic solids. In contrast, in an ionic compound like table salt, when the planes of an
ionic bond
Ionic bonding is a type of chemical bonding that involves the electrostatic attraction between oppositely charged ions, or between two atoms with sharply different electronegativities, and is the primary interaction occurring in ionic compounds. ...
slide past one another, the resultant change in location shifts ions of the same charge closer, resulting in the
cleavage of the crystal. Such a shift is not observed in a
covalently bonded
A covalent bond is a chemical bond that involves the sharing of electrons to form electron pairs between atoms. These electron pairs are known as shared pairs or bonding pairs. The stable balance of attractive and repulsive forces between atoms ...
crystal, such as a diamond, where fracture and crystal fragmentation occurs. Reversible
elastic deformation
In engineering, deformation refers to the change in size or shape of an object. ''Displacements'' are the ''absolute'' change in position of a point on the object. Deflection is the relative change in external displacements on an object. Strain ...
in metals can be described by
Hooke's Law
In physics, Hooke's law is an empirical law which states that the force () needed to extend or compress a spring (device), spring by some distance () Proportionality (mathematics)#Direct_proportionality, scales linearly with respect to that ...
for restoring forces, where the
stress
Stress may refer to:
Science and medicine
* Stress (biology), an organism's response to a stressor such as an environmental condition
* Stress (linguistics), relative emphasis or prominence given to a syllable in a word, or to a word in a phrase ...
is linearly proportional to the
strain
Strain may refer to:
Science and technology
* Strain (biology), variants of plants, viruses or bacteria; or an inbred animal used for experimental purposes
* Strain (chemistry), a chemical stress of a molecule
* Strain (injury), an injury to a mu ...
.
Heat or forces larger than a metal's
elastic limit
In materials science and engineering, the yield point is the point on a stress-strain curve that indicates the limit of elastic behavior and the beginning of plastic behavior. Below the yield point, a material will deform elastically and wi ...
may cause a permanent (irreversible) deformation, known as
plastic deformation
In engineering, deformation refers to the change in size or shape of an object. ''Displacements'' are the ''absolute'' change in position of a point on the object. Deflection is the relative change in external displacements on an object. Strain ...
or
plasticity
Plasticity may refer to:
Science
* Plasticity (physics), in engineering and physics, the propensity of a solid material to undergo permanent deformation under load
* Neuroplasticity, in neuroscience, how entire brain structures, and the brain it ...
. An applied force may be a
tensile
In physics, tension is described as the pulling force transmitted axially by the means of a string, a rope, chain, or similar object, or by each end of a rod, truss member, or similar three-dimensional object; tension might also be described as t ...
(pulling) force, a
compressive
In continuum mechanics, stress is a physical quantity. It is a quantity that describes the magnitude of forces that cause deformation. Stress is defined as ''force per unit area''. When an object is pulled apart by a force it will cause elonga ...
(pushing) force, or a
shear
Shear may refer to:
Textile production
*Animal shearing, the collection of wool from various species
**Sheep shearing
*The removal of nap during wool cloth production
Science and technology Engineering
*Shear strength (soil), the shear strength ...
,
bending
In applied mechanics, bending (also known as flexure) characterizes the behavior of a slender structural element subjected to an external load applied perpendicularly to a longitudinal axis of the element.
The structural element is assumed to ...
, or
torsion
Torsion may refer to:
Science
* Torsion (mechanics), the twisting of an object due to an applied torque
* Torsion of spacetime, the field used in Einstein–Cartan theory and
** Alternatives to general relativity
* Torsion angle, in chemistry
Bio ...
(twisting) force. A temperature change may affect the movement or displacement of
structural defects in the metal such as
grain boundaries
In materials science, a grain boundary is the interface between two grains, or crystallites, in a polycrystalline material. Grain boundaries are two-dimensional crystallographic defect, defects in the crystal structure, and tend to decrease the ...
,
point vacancies,
line and screw dislocations,
stacking fault
In crystallography, a stacking fault is a planar defect that can occur in crystalline materials.Fine, Morris E. (1921). "Introduction to Chemical and Structural Defects in Crystalline Solids", in ''Treatise on Solid State Chemistry Volume 1'', Spr ...
s and
twins
Twins are two offspring produced by the same pregnancy.MedicineNet > Definition of TwinLast Editorial Review: 19 June 2000 Twins can be either ''monozygotic'' ('identical'), meaning that they develop from one zygote, which splits and forms two em ...
in both
crystalline
A crystal or crystalline solid is a solid material whose constituents (such as atoms, molecules, or ions) are arranged in a highly ordered microscopic structure, forming a crystal lattice that extends in all directions. In addition, macrosc ...
and
non-crystalline metals. Internal
slip
Slip or SLIP may refer to:
Science and technology Biology
* Slip (fish), also known as Black Sole
* Slip (horticulture), a small cutting of a plant as a specimen or for grafting
* Muscle slip, a branching of a muscle, in anatomy
Computing and ...
,
creep
Creep, Creeps or CREEP may refer to:
People
* Creep, a creepy person
Politics
* Committee for the Re-Election of the President (CRP), mockingly abbreviated as CREEP, an fundraising organization for Richard Nixon's 1972 re-election campaign
Art ...
, and
metal fatigue
In materials science, fatigue is the initiation and propagation of cracks in a material due to cyclic loading. Once a fatigue crack has initiated, it grows a small amount with each loading cycle, typically producing striations on some parts o ...
may ensue.
The atoms of metallic substances are
typically arranged in one of three common
crystal structure
In crystallography, crystal structure is a description of the ordered arrangement of atoms, ions or molecules in a crystal, crystalline material. Ordered structures occur from the intrinsic nature of the constituent particles to form symmetric pat ...
s, namely
body-centered cubic
In crystallography, the cubic (or isometric) crystal system is a crystal system where the unit cell is in the shape of a cube. This is one of the most common and simplest shapes found in crystals and minerals.
There are three main varieties of ...
(bcc),
face-centered cubic
In crystallography, the cubic (or isometric) crystal system is a crystal system where the unit cell is in the shape of a cube. This is one of the most common and simplest shapes found in crystals and minerals.
There are three main varieties of ...
(fcc), and
hexagonal close-packed
In geometry, close-packing of equal spheres is a dense arrangement of congruent spheres in an infinite, regular arrangement (or lattice). Carl Friedrich Gauss proved that the highest average density – that is, the greatest fraction of space occu ...
(hcp). In bcc, each atom is positioned at the center of a cube of eight others. In fcc and hcp, each atom is surrounded by twelve others, but the stacking of the layers differs. Some metals adopt different structures depending on the temperature.
File:Cubic-body-centered.svg, Body-centered cubic crystal structure, with a 2-atom unit cell, as found in e.g. chromium, iron, and tungsten
File:Cubic-face-centered.svg, Face-centered cubic crystal structure, with a 4-atom unit cell, as found in e.g. aluminum, copper, and gold