Properties
Form and structure
Metals are shiny andElectrical and thermal
The electronic structure of metals means they are relatively good conductors of electricity. Electrons in matter can only have fixed rather than variable energy levels, and in a metal the energy levels of the electrons in its electron cloud, at least to some degree, correspond to the energy levels at which electrical conduction can occur. In a semiconductor like silicon or a nonmetal like sulfur there is an energy gap between the electrons in the substance and the energy level at which electrical conduction can occur. Consequently, semiconductors and nonmetals are relatively poor conductors. The elemental metals have electrical conductivity values of from 6.9 × 103 S/cm forChemical
Metals are usually inclined to formPeriodic table distribution
In chemistry, the elements which are usually considered to be metals under ordinary conditions are shown in yellow on the periodic table below. The remaining elements are either metalloids (B, Si, Ge, As, Sb, and Te being commonly recognised as such) or nonmetals. Astatine (At) is usually classified as either a nonmetal or a metalloid, but some predictions expect it to be a metal; as such, it has been left blank due to the inconclusive state of the experimental knowledge. The other elements shown as having unknown properties are likely to be metals, but there is some doubt for copernicium (Cn), flerovium (Fl), and oganesson (Og).Alloys
An alloy is a substance having metallic properties and which is composed of two or more elements at least one of which is a metal. An alloy may have a variable or fixed composition. For example, gold and silver form an alloy in which the proportions of gold or silver can be freely adjusted; titanium and silicon form an alloy Ti2Si in which the ratio of the two components is fixed (also known as anCategories
Metals can be categorised according to their physical or chemical properties. Categories described in the subsections below includeFerrous and non-ferrous metals
The term "ferrous" is derived from theBrittle metal
While nearly all metals are malleable or ductile, a few—beryllium, chromium, manganese, gallium, and bismuth—are brittle. Arsenic and antimony, if admitted as metals, are brittle. Low values of the ratio of bulkRefractory metal
In materials science, metallurgy, and engineering, a refractory metal is a metal that is extraordinarily resistant to heat and wear. Which metals belong to this category varies; the most common definition includes niobium, molybdenum, tantalum, tungsten, and rhenium. They all have melting points above 2000 °C, and a highWhite metal
AHeavy and light metals
A heavy metal is any relatively dense metal orBase, noble, and precious metals
InValve metals
In electrochemistry, a valve metal is a metal which passes current in only one direction.Lifecycle
Formation
:''This sub-section deals with the formation of periodic table elemental metals since these form the basis of metallic materials, as defined in this article.'' Metals up to the vicinity of iron (in the periodic table) are largely made viaAbundance and occurrence
The Earth's crust is made of approximately 25% of metals by weight, of which 80% are light metals such as sodium, magnesium, and aluminium. Nonmetals (~75%) make up the rest of the crust. Despite the overall scarcity of some heavier metals such as copper, they can become concentrated in economically extractable quantities as a result of mountain building, erosion, or other geological processes. Metals are primarily found as lithophiles (rock-loving) or chalcophiles (ore-loving). Lithophile metals are mainly the s-block elements, the more reactive of the d-block elements, and the f-block elements. They have a strong affinity for oxygen and mostly exist as relatively low-density silicate minerals. Chalcophile metals are mainly the less reactive d-block elements, and the period 4–6 p-block metals. They are usually found in (insoluble) sulfide minerals. Being denser than the lithophiles, hence sinking lower into the crust at the time of its solidification, the chalcophiles tend to be less abundant than the lithophiles. On the other hand, gold is a siderophile, or iron-loving element. It does not readily form compounds with either oxygen or sulfur. At the time of the Earth's formation, and as the most noble (inert) of metals, gold sank into the core due to its tendency to form high-density metallic alloys. Consequently, it is a relatively rare metal. Some other (less) noble metals—molybdenum, rhenium, the platinum group metals (ruthenium, rhodium, palladium, osmium, iridium, and platinum), germanium, and tin—can be counted as siderophiles but only in terms of their primary occurrence in the Earth (core, mantle, and crust), rather the crust. These metals otherwise occur in the crust, in small quantities, chiefly as chalcophiles (less so in their native form). The rotating fluid outer core of the Earth's interior, which is composed mostly of iron, is thought to be the source of Earth's protective magnetic field. The core lies above Earth's solid inner core and below its mantle. If it could be rearranged into a column having a footprint it would have a height of nearly 700 light years. The magnetic field shields the Earth from the charged particles of the solar wind, and cosmic rays that would otherwise strip away the upper atmosphere (including the ozone layer that limits the transmission of ultraviolet radiation).Extraction
Metals are often extracted from the Earth by means of mining ores that are rich sources of the requisite elements, such asUses
Metals are present in nearly all aspects of modern life. Iron, a heavy metal, may be the most common as it accounts for 90% of all refined metals; aluminum, aRecycling
Demand for metals is closely linked to economic growth given their use in infrastructure, construction, manufacturing, and consumer goods. During the 20th century, the variety of metals used in society grew rapidly. Today, the development of major nations, such as China and India, and technological advances, are fuelling ever more demand. The result is that mining activities are expanding, and more and more of the world's metal stocks are above ground in use, rather than below ground as unused reserves. An example is the in-use stock ofBiological interactions
The role of metallic elements in the evolution of cell biochemistry has been reviewed, including a detailed section on the role ofHistory
Prehistory
Copper, which occurs in native form, may have been the first metal discovered given its distinctive appearance, heaviness, and malleability compared to other stones or pebbles. Gold, silver, and iron (as meteoric iron), and lead were likewise discovered in prehistory. Forms ofAntiquity
The discovery ofMiddle Ages
Arabic and medievalThe Renaissance
The first systematic text on the arts of mining and metallurgy was ''De la Pirotechnia'' (1540) byPlatinum, the third precious metal after gold and silver, was discovered in Ecuador during the period 1736 to 1744, by the Spanish astronomer Antonio de Ulloa and his colleague the mathematician Jorge Juan y Santacilia. Ulloa was the first person to write a scientific description of the metal, in 1748. In 1789, the German chemist Martin Heinrich Klaproth isolated an oxide of uranium, which he thought was the metal itself. Klaproth was subsequently credited as the discoverer of uranium. It was not until 1841, that the French chemist Eugène-Melchior Péligot, prepared the first sample of uranium metal. Henri Becquerel subsequently discovered radioactivity in 1896 by using uranium. In the 1790s, Joseph Priestley and the Dutch chemist Martinus van Marum observed the transformative action of metal surfaces on the dehydrogenation of alcohol, a development which subsequently led, in 1831, to the industrial scale synthesis of sulphuric acid using a platinum catalyst. In 1803, cerium was the first of the lanthanide metals to be discovered, in Bastnäs, Sweden by Jöns Jakob Berzelius and Wilhelm Hisinger, and independently by Martin Heinrich Klaproth in Germany. The lanthanide metals were largely regarded as oddities until the 1960s when methods were developed to more efficiently separate them from one another. They have subsequently found uses in cell phones, magnets, lasers, lighting, batteries, catalytic converters, and in other applications enabling modern technologies. Other metals discovered and prepared during this time were cobalt, nickel, manganese, molybdenum, tungsten, and chromium; and some of theMetal is a mineral body, by nature either liquid or somewhat hard. The latter may be melted by the heat of the fire, but when it has cooled down again and lost all heat, it becomes hard again and resumes its proper form. In this respect it differs from the stone which melts in the fire, for although the latter regain its hardness, yet it loses its pristine form and properties. Traditionally there are six different kinds of metals, namely gold, silver, copper, iron, tin, and lead. There are really others, for quicksilver is a metal, although the Alchemists disagree with us on this subject, andbismuth Bismuth is a chemical element with the Symbol (chemistry), symbol Bi and atomic number 83. It is a post-transition metal and one of the pnictogens, with chemical properties resembling its lighter group 15 siblings arsenic and antimony. Elemental ...is also. The ancient Greek writers seem to have been ignorant of bismuth, wherefore Ammonius rightly states that there are many species of metals, animals, and plants which are unknown to us.Stibium Antimony is a chemical element with the symbol Sb (from la, stibium) and atomic number 51. A lustrous gray metalloid, it is found in nature mainly as the sulfide mineral stibnite (Sb2S3). Antimony compounds have been known since ancient time ...when smelted in the crucible and refined has as much right to be regarded as a proper metal as is accorded to lead by writers. If when smelted, a certain portion be added to tin, a bookseller's alloy is produced from which the type is made that is used by those who print books on paper. Each metal has its own form which it preserves when separated from those metals which were mixed with it. Therefore neitherelectrum Electrum is a naturally occurring alloy of gold and silver, with trace amounts of copper and other metals. Its color ranges from pale to bright yellow, depending on the proportions of gold and silver. It has been produced artificially, and ...nor Stannum ot meaning our tinis of itself a real metal, but rather an alloy of two metals. Electrum is an alloy of gold and silver, Stannum of lead and silver. And yet if silver be parted from the electrum, then gold remains and not electrum; if silver be taken away from Stannum, then lead remains and not Stannum. Whether brass, however, is found as a native metal or not, cannot be ascertained with any surety. We only know of the artificial brass, which consists of copper tinted with the colour of the mineralcalamine Calamine, also known as calamine lotion, is a medication used to treat mild itchiness. This includes from sunburn, insect bites, poison ivy, poison oak, and other mild skin conditions. It may also help dry out skin irritation. It is applied .... And yet if any should be dug up, it would be a proper metal. Black and white copper seem to be different from the red kind. Metal, therefore, is by nature either solid, as I have stated, or fluid, as in the unique case of quicksilver. But enough now concerning the simple kinds.Georgius Agricola
''De Re Metallica''
(1556) Tr. Herbert Clark Hoover & Lou Henry Hoover (1912); Footnote quoting ''De Natura Fossilium'' (1546), p. 180
Light metals
All metals discovered until 1809 had relatively high densities; their heaviness was regarded as a singularly distinguishing criterion. From 1809 onward, light metals such as sodium, potassium, and strontium were isolated. Their low densities challenged conventional wisdom as to the nature of metals. They behaved chemically as metals however, and were subsequently recognised as such. Aluminum was discovered in 1824 but it was not until 1886 that an industrial large-scale production method was developed. Prices of aluminum dropped and aluminum became widely used in jewelry, everyday items, eyeglass frames, optical instruments, tableware, and foil in the 1890s and early 20th century. Aluminum's ability to form hard yet light alloys with other metals provided the metal many uses at the time. During World War I, major governments demanded large shipments of aluminum for light strong airframes. The most common metal in use for electric power transmission today is aluminum-conductor steel-reinforced. Also seeing much use is all-aluminum-alloy conductor. Aluminum is used because it has about half the weight of a comparable resistance copper cable (though larger diameter due to lowerThe age of steel
The modern era inThe last stable metallic elements
By 1900 three metals withPost-World War II developments
Superalloys
Transcurium metals
The successful development of the atomic bomb at the end of World War II sparked further efforts to synthesize new elements, nearly all of which are, or are expected to be, metals, and all of which are radioactive. It was not until 1949 that element 97 (berkelium), next after element 96 (curium), was synthesized by firing alpha particles at an americium target. In 1952, element 100 (fermium) was found in the debris of the first hydrogen bomb explosion; hydrogen, a nonmetal, had been identified as an element nearly 200 years earlier. Since 1952, elements 101 (mendelevium) to 118 (oganesson) have been synthesized.Bulk metallic glasses
A metallic glass (also known as an amorphous or glassy metal) is a solid metallic material, usually an alloy, with a disordered atomic-scale structure. Most pure and alloyed metals, in their solid state, have atoms arranged in a highly ordered crystalline structure. Amorphous metals have a non-crystalline glass-like structure. But unlike common glasses, such as window glass, which are typically electrical insulators, amorphous metals have good electrical conductivity. Amorphous metals are produced in several ways, including extremely rapid cooling, physical vapor deposition, solid-state reaction, ion irradiation, and mechanical alloying. The first reported metallic glass was an alloy (Au75Si25) produced atShape-memory alloys
A shape-memory alloy (SMA) is an alloy that "remembers" its original shape and when deformed returns to its pre-deformed shape when heated. While the shape memory effect had been first observed in 1932, in an Au-Cd alloy, it was not until 1962, with the accidental discovery of the effect in a Ni-Ti alloy that research began in earnest, and another ten years before commercial applications emerged. SMA's have applications in robotics and automotive, aerospace, and biomedical industries. There is another type of SMA, called a ferromagnetic shape-memory alloy (FSMA), that changes shape under strong magnetic fields. These materials are of particular interest as the magnetic response tends to be faster and more efficient than temperature-induced responses.Quasicyrstalline alloys
In 1984, Israeli chemist Dan Shechtman found an aluminum-manganese alloy having five-fold symmetry, in breach of crystallographic convention at the time which said that crystalline structures could only have two-, three-, four-, or six-fold symmetry. Due to fear of the scientific community's reaction, it took him two years to publish the results for which he was awarded the Nobel Prize in Chemistry in 2011. Since this time, hundreds of quasicrystals have been reported and confirmed. They exist in many metallic alloys (and some polymers). Quasicrystals are found most often in aluminum alloys (Al-Li-Cu, Al-Mn-Si, Al-Ni-Co, Al-Pd-Mn, Al-Cu-Fe, Al-Cu-V, etc.), but numerous other compositions are also known (Cd-Yb, Ti-Zr-Ni, Zn-Mg-Ho, Zn-Mg-Sc, In-Ag-Yb, Pd-U-Si, etc.). Quasicrystals effectively have infinitely large unit cells.Complex metallic alloys
High-entropy alloys
MAX phase alloys
In a MAX phase alloy, M is an early transition metal, A is an A group element (mostly group IIIA and IVA, or groups 13 and 14), and X is either carbon or nitrogen. Examples are Hf2SnC and Ti4AlN3. Such alloys have some of the best properties of metals and ceramics. These properties include high electrical and thermal conductivity, thermal shock resistance, damage tolerance, machinability, high elastic stiffness, and low thermal expansion coefficients.Max phase compositesSee also
*Notes
References
Further reading
* Choptuik M. W., Lehner L. & Pretorias F. 2015, "Probing strong-field gravity through numerical simulation", in A. Ashtekar, B. K. Berger, J. Isenberg & M. MacCallum (eds), ''General Relativity and Gravitation: A Centennial Perspective'', Cambridge University Press, Cambridge, . * * Crow J. M. 2016,External links