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A concretion is a hard, compact mass of matter formed by the precipitation of
mineral In geology and mineralogy, a mineral or mineral species is, broadly speaking, a solid chemical compound with a fairly well-defined chemical composition and a specific crystal structure that occurs naturally in pure form.John P. Rafferty, ed. ( ...
cement within the spaces between particles, and is found in
sedimentary rock Sedimentary rocks are types of rock that are formed by the accumulation or deposition of mineral or organic particles at Earth's surface, followed by cementation. Sedimentation is the collective name for processes that cause these particles ...
or
soil Soil, also commonly referred to as earth or dirt, is a mixture of organic matter, minerals, gases, liquids, and organisms that together support life. Some scientific definitions distinguish ''dirt'' from ''soil'' by restricting the former te ...
. Concretions are often ovoid or spherical in shape, although irregular shapes also occur. The word 'concretion' is derived from the
Latin Latin (, or , ) is a classical language belonging to the Italic branch of the Indo-European languages. Latin was originally a dialect spoken in the lower Tiber area (then known as Latium) around present-day Rome, but through the power of the ...
"(act of) compacting, condensing, congealing, uniting", itself from ''con'' meaning 'together' and ''crescere'' meaning "to grow". Concretions form within layers of sedimentary
strata In geology and related fields, a stratum ( : strata) is a layer of rock or sediment characterized by certain lithologic properties or attributes that distinguish it from adjacent layers from which it is separated by visible surfaces known as ei ...
that have already been deposited. They usually form early in the burial history of the sediment, before the rest of the sediment is hardened into rock. This concretionary cement often makes the concretion harder and more resistant to
weathering Weathering is the deterioration of rocks, soils and minerals as well as wood and artificial materials through contact with water, atmospheric gases, and biological organisms. Weathering occurs ''in situ'' (on site, with little or no movement), ...
than the host
stratum In geology and related fields, a stratum ( : strata) is a layer of rock or sediment characterized by certain lithologic properties or attributes that distinguish it from adjacent layers from which it is separated by visible surfaces known as ei ...
. There is an important distinction to draw between concretions and nodules. Concretions are formed from mineral precipitation around some kind of nucleus while a nodule is a replacement body. Descriptions dating from the 18th century attest to the fact that concretions have long been regarded as geological curiosities. Because of the variety of unusual shapes, sizes and compositions, concretions have been interpreted to be
dinosaur Dinosaurs are a diverse group of reptiles of the clade Dinosauria. They first appeared during the Triassic period, between 243 and 233.23 million years ago (mya), although the exact origin and timing of the evolution of dinosaurs is t ...
eggs, animal and plant
fossil A fossil (from Classical Latin , ) is any preserved remains, impression, or trace of any once-living thing from a past geological age. Examples include bones, shells, exoskeletons, stone imprints of animals or microbes, objects preserved ...
s (called
pseudofossil Pseudofossils are inorganic objects, markings, or impressions that might be mistaken for fossils. Pseudofossils may be misleading, as some types of mineral deposits can mimic lifeforms by forming what appear to be highly detailed or organized str ...
s), extraterrestrial debris or human artifacts.


Origins

Detailed studies have demonstrated that concretions form after sediments are buried but before the sediment is fully lithified during
diagenesis Diagenesis () is the process that describes physical and chemical changes in sediments first caused by water-rock interactions, microbial activity, and compaction after their deposition. Increased pressure and temperature only start to play a ...
. They typically form when a mineral precipitates and cements sediment around a nucleus, which is often organic, such as a leaf, tooth, piece of shell or
fossil A fossil (from Classical Latin , ) is any preserved remains, impression, or trace of any once-living thing from a past geological age. Examples include bones, shells, exoskeletons, stone imprints of animals or microbes, objects preserved ...
. For this reason, fossil collectors commonly break open concretions in their search for fossil animal and plant specimens. Some of the most unusual concretion nuclei are
World War II World War II or the Second World War, often abbreviated as WWII or WW2, was a world war that lasted from 1939 to 1945. It involved the vast majority of the world's countries—including all of the great powers—forming two opposin ...
military shells,
bomb A bomb is an explosive weapon that uses the Exothermic process, exothermic reaction of an explosive material to provide an extremely sudden and violent release of energy. Detonations inflict damage principally through ground- and atmosphere-t ...
s, and
shrapnel Shrapnel may refer to: Military * Shrapnel shell, explosive artillery munitions, generally for anti-personnel use * Shrapnel (fragment), a hard loose material Popular culture * ''Shrapnel'' (Radical Comics) * ''Shrapnel'', a game by Adam C ...
, which are found inside
siderite Siderite is a mineral composed of iron(II) carbonate (FeCO3). It takes its name from the Greek word σίδηρος ''sideros,'' "iron". It is a valuable iron mineral, since it is 48% iron and contains no sulfur or phosphorus. Zinc, magnesium and ...
concretions found in an English coastal
salt marsh A salt marsh or saltmarsh, also known as a coastal salt marsh or a tidal marsh, is a coastal ecosystem in the upper coastal intertidal zone between land and open saltwater or brackish water that is regularly flooded by the tides. It is dominated ...
. Depending on the environmental conditions present at the time of their formation, concretions can be created by either concentric or pervasive growth. In concentric growth, the concretion grows as successive layers of mineral precipitate around a central core. This process results in roughly spherical concretions that grow with time. In the case of pervasive growth, cementation of the host
sediments Sediment is a naturally occurring material that is broken down by processes of weathering and erosion, and is subsequently transported by the action of wind, water, or ice or by the force of gravity acting on the particles. For example, sand a ...
, by infilling of its pore space by precipitated minerals, occurs simultaneously throughout the volume of the area, which in time becomes a concretion. Concretions are often exposed at the surface by subsequent erosion that removes the weaker, uncemented material.


Appearance

Concretions vary in shape, hardness and size, ranging from objects that require a magnifying lens to be clearly visible to huge bodies three meters in diameter and weighing several thousand pounds. The giant, red concretions occurring in
Theodore Roosevelt National Park Theodore Roosevelt National Park is an American national park of the badlands in western North Dakota comprising three geographically separated areas. Honoring U.S. President Theodore Roosevelt, it is the only American national park named direc ...
, in
North Dakota North Dakota () is a U.S. state in the Upper Midwest, named after the Native Americans in the United States, indigenous Dakota people, Dakota Sioux. North Dakota is bordered by the Canadian provinces of Saskatchewan and Manitoba to the north a ...
, are almost in diameter. Spheroidal concretions, as large as in diameter, have been found eroding out of the
Qasr el Sagha Formation The Qasr el Sagha Formation is a geological formation located in Egypt. The formation is part of the Wadi El Hitan World Heritage Site. The Qasr el Sagha Formation overlies the Birket Qarun Formation and is overlain by the Gebel Qatrani Formation ...
within the
Faiyum depression The Faiyum Oasis ( ar, واحة الفيوم ''Waḥet El Fayyum'') is a depression or basin in the desert immediately to the west of the Nile, or just 62 miles south of Cairo in Egypt. The extent of the basin area is estimated at between 1,270 ...
of Egypt. Concretions occur in a wide variety of shapes, including spheres, disks, tubes, and grape-like or soap bubble-like aggregates.


Composition

Concretions are commonly composed of a mineral present as a minor component of the host rock. For example, concretions in
sandstone Sandstone is a clastic sedimentary rock composed mainly of sand-sized (0.0625 to 2 mm) silicate grains. Sandstones comprise about 20–25% of all sedimentary rocks. Most sandstone is composed of quartz or feldspar (both silicates) ...
s or
shale Shale is a fine-grained, clastic sedimentary rock formed from mud that is a mix of flakes of clay minerals (hydrous aluminium phyllosilicates, e.g. kaolin, Al2 Si2 O5( OH)4) and tiny fragments (silt-sized particles) of other minerals, especial ...
s are commonly formed of a
carbonate A carbonate is a salt of carbonic acid (H2CO3), characterized by the presence of the carbonate ion, a polyatomic ion with the formula . The word ''carbonate'' may also refer to a carbonate ester, an organic compound containing the carbonate g ...
mineral such as
calcite Calcite is a Carbonate minerals, carbonate mineral and the most stable Polymorphism (materials science), polymorph of calcium carbonate (CaCO3). It is a very common mineral, particularly as a component of limestone. Calcite defines hardness 3 on ...
; those in
limestone Limestone ( calcium carbonate ) is a type of carbonate sedimentary rock which is the main source of the material lime. It is composed mostly of the minerals calcite and aragonite, which are different crystal forms of . Limestone forms whe ...
s are commonly an amorphous or microcrystalline form of
silica Silicon dioxide, also known as silica, is an oxide of silicon with the chemical formula , most commonly found in nature as quartz and in various living organisms. In many parts of the world, silica is the major constituent of sand. Silica is one ...
such as
chert Chert () is a hard, fine-grained sedimentary rock composed of microcrystalline or cryptocrystalline quartz, the mineral form of silicon dioxide (SiO2). Chert is characteristically of biological origin, but may also occur inorganically as a prec ...
,
flint Flint, occasionally flintstone, is a sedimentary cryptocrystalline form of the mineral quartz, categorized as the variety of chert that occurs in chalk or marly limestone. Flint was widely used historically to make stone tools and start fir ...
, or
jasper Jasper, an aggregate of microgranular quartz and/or cryptocrystalline chalcedony and other mineral phases,Kostov, R. I. 2010. Review on the mineralogical systematics of jasper and related rocks. – Archaeometry Workshop, 7, 3, 209-213PDF/ref> ...
; while those in black shale may be composed of
pyrite The mineral pyrite (), or iron pyrite, also known as fool's gold, is an iron sulfide with the chemical formula Iron, FeSulfur, S2 (iron (II) disulfide). Pyrite is the most abundant sulfide mineral. Pyrite's metallic Luster (mineralogy), lust ...
. Other minerals that form concretions include iron oxides or hydroxides (such as
goethite Goethite (, ) is a mineral of the diaspore group, consisting of iron(III) oxide-hydroxide, specifically the "α" polymorph. It is found in soil and other low-temperature environments such as sediment. Goethite has been well known since ancient t ...
and
hematite Hematite (), also spelled as haematite, is a common iron oxide compound with the formula, Fe2O3 and is widely found in rocks and soils. Hematite crystals belong to the rhombohedral lattice system which is designated the alpha polymorph of . ...
),
dolomite Dolomite may refer to: *Dolomite (mineral), a carbonate mineral *Dolomite (rock), also known as dolostone, a sedimentary carbonate rock *Dolomite, Alabama, United States, an unincorporated community *Dolomite, California, United States, an unincor ...
,
siderite Siderite is a mineral composed of iron(II) carbonate (FeCO3). It takes its name from the Greek word σίδηρος ''sideros,'' "iron". It is a valuable iron mineral, since it is 48% iron and contains no sulfur or phosphorus. Zinc, magnesium and ...
, ankerite,
marcasite The mineral marcasite, sometimes called “white iron pyrite”, is iron sulfide (FeS2) with orthorhombic crystal structure. It is physically and crystallographically distinct from pyrite, which is iron sulfide with cubic crystal structure. Both ...
,
barite Baryte, barite or barytes ( or ) is a mineral consisting of barium sulfate ( Ba S O4). Baryte is generally white or colorless, and is the main source of the element barium. The ''baryte group'' consists of baryte, celestine (strontium sulfate), ...
, and
gypsum Gypsum is a soft sulfate mineral composed of calcium sulfate dihydrate, with the chemical formula . It is widely mined and is used as a fertilizer and as the main constituent in many forms of plaster, blackboard or sidewalk chalk, and drywall. ...
. Although concretions often consist of a single dominant mineral, other minerals can be present depending on the environmental conditions that created them. For example, carbonate concretions, which form in response to the reduction of
sulfates The sulfate or sulphate ion is a polyatomic anion with the empirical formula . Salts, acid derivatives, and peroxides of sulfate are widely used in industry. Sulfates occur widely in everyday life. Sulfates are salts of sulfuric acid and many a ...
by
bacteria Bacteria (; singular: bacterium) are ubiquitous, mostly free-living organisms often consisting of one biological cell. They constitute a large domain of prokaryotic microorganisms. Typically a few micrometres in length, bacteria were among ...
, often contain minor percentages of pyrite. Other concretions, which formed as a result of microbial sulfate reduction, consist of a mixture of calcite, barite, and pyrite.


Occurrence

Concretions are found in a variety of rocks, but are particularly common in
shale Shale is a fine-grained, clastic sedimentary rock formed from mud that is a mix of flakes of clay minerals (hydrous aluminium phyllosilicates, e.g. kaolin, Al2 Si2 O5( OH)4) and tiny fragments (silt-sized particles) of other minerals, especial ...
s,
siltstone Siltstone, also known as aleurolite, is a clastic sedimentary rock that is composed mostly of silt. It is a form of mudrock with a low clay mineral content, which can be distinguished from shale by its lack of fissility.Blatt ''et al.'' 1980, p ...
s, and
sandstone Sandstone is a clastic sedimentary rock composed mainly of sand-sized (0.0625 to 2 mm) silicate grains. Sandstones comprise about 20–25% of all sedimentary rocks. Most sandstone is composed of quartz or feldspar (both silicates) ...
s. They often outwardly resemble fossils or rocks that look as if they do not belong to the stratum in which they were found. Occasionally, concretions contain a fossil, either as its nucleus or as a component that was incorporated during its growth but concretions are not fossils themselves. They appear in nodular patches, concentrated along bedding planes, or protruding from weathered cliffsides. Small hematite concretions or
Martian spherules Martian spherules (also known as hematite spherules, blueberries, & Martian blueberries) are small spherules (roughly spherical pebbles) that are rich in an iron oxide (grey hematite, α-Fe2O3) and are found at Meridiani Planum (a large plain on ...
have been observed by the ''Opportunity'' rover in the
Eagle Crater Eagle is a 22-metre long impact crater located on the Meridiani Planum extraterrestrial plain, situated within the Margaritifer Sinus quadrangle (MC-19) portion of the planet Mars. The Opportunity rover, ''Opportunity'' rover came to rest insid ...
on Mars.


Types of concretion

Concretions vary considerably in their compositions, shapes, sizes and modes of origin.


Septarian concretions

Septarian concretions (or septarian nodules) are
carbonate A carbonate is a salt of carbonic acid (H2CO3), characterized by the presence of the carbonate ion, a polyatomic ion with the formula . The word ''carbonate'' may also refer to a carbonate ester, an organic compound containing the carbonate g ...
-rich concretions containing angular cavities or cracks (septaria; ', from the Latin "partition, separating element", referring to the cracks or cavities separating polygonal blocks of hardened material). Septarian nodules are characteristically found in carbonate-rich mudrock. They typically show an internal structure of polyhedral blocks (the ''matrix'') separated by mineral-filled radiating cracks (the septaria) which taper towards the rim of the concretion. The radiating cracks sometimes intersect a second set of concentric cracks. However, the cracks can be highly variable in shape and volume, as well as the degree of shrinkage they indicate. The matrix is typically composed of argillaceous carbonate, such as clay ironstone, while the crack filling is usually calcite. The calcite often contains significant iron (ferroan calcite) and may have inclusions of pyrite and clay minerals. The brown calcite common in septaria may also be colored by organic compounds produced by bacterial decay of organic matter in the original sediments. Septarian concretions are found in many kinds of mudstone, including
lacustrine A lake is an area filled with water, localized in a basin, surrounded by land, and distinct from any river or other outlet that serves to feed or drain the lake. Lakes lie on land and are not part of the ocean, although, like the much larger ...
siltstone Siltstone, also known as aleurolite, is a clastic sedimentary rock that is composed mostly of silt. It is a form of mudrock with a low clay mineral content, which can be distinguished from shale by its lack of fissility.Blatt ''et al.'' 1980, p ...
s such as the Beaufort Group of northwest Mozambique, but are most commonly found in marine
shale Shale is a fine-grained, clastic sedimentary rock formed from mud that is a mix of flakes of clay minerals (hydrous aluminium phyllosilicates, e.g. kaolin, Al2 Si2 O5( OH)4) and tiny fragments (silt-sized particles) of other minerals, especial ...
s, such as the
Staffin Shale Formation Staffin ( gd, Stafain) is a district with the Gaelic name ''An Taobh Sear'', which translates as "the East Side", on the northeast coast of the Trotternish peninsula of the island of Skye. It is located on the A855 road about north of Portre ...
of Skye, the
Kimmeridge Clay The Kimmeridge Clay is a sedimentary deposit of fossiliferous marine clay which is of Late Jurassic to lowermost Cretaceous age and occurs in southern and eastern England and in the North Sea. This rock formation is the major source rock for North ...
of England, or the
Mancos Group The Mancos Shale or Mancos Group is a Late Cretaceous (Upper Cretaceous) Formation (stratigraphy), geologic formation of the Western United States. The Mancos Shale was first described by Cross and Purington in 1899 and was named for exposure ...
of North America. It is commonly thought that concretions grew incrementally from the inside outwards. Chemical and textural zoning in many concretions are consistent with this ''concentric'' model of formation. However, the evidence is ambiguous, and many or most concretions may have formed by ''pervasive'' cementation of the entire volume of the concretion at the same time. For example, if the porosity after early cementation varies across the concretion, then later cementation filling this porosity would produce compositional zoning even with uniform pore water composition. Whether the initial cementation was concentric or pervasive, there is considerable evidence that it occurred quickly and at shallow depth of burial. In many cases, there is clear evidence that the initial concretion formed around some kind of organic nucleus. The origin of the carbonate-rich septaria is still debated. One possibility is that dehydration hardens the outer shell of the concretion while causing the interior matrix to shrink until it cracks. Shrinkage of a still-wet matrix may also take place through syneresis, in which the particles of colloidal material in the interior of the concretion become gradually more tightly bound while expelling water. Another possibility is that early cementation reduces the permeability of the concretion, trapping pore fluids and creating excess pore pressure during continued burial. This could crack the interior at depths as shallow as . A more speculative theory is that the septaria form by brittle fracturing resulting from
earthquake An earthquake (also known as a quake, tremor or temblor) is the shaking of the surface of the Earth resulting from a sudden release of energy in the Earth's lithosphere that creates seismic waves. Earthquakes can range in intensity, from ...
s. Regardless of the mechanism of crack formation, the septaria, like the concretion itself, likely form at a relatively shallow depth of burial of less than and possibly as little as . Geologically young concretions of the Errol Beds of Scotland show texture consistent with formation from flocculated sediments containing organic matter, whose decay left tiny gas bubbles (30 to 35 microns in diameter) and a soap of calcium fatty acids salts. The conversion of these fatty acids to calcium carbonate may have promoted shrinkage and fracture of the matrix. One model for the formation of septarian concretions in the Staffin Shales suggests that the concretions started as remirigid masses of flocculated clay. The individual colloidal clay particles were bound by
extracellular polymeric substance Extracellular polymeric substances (EPSs) are natural polymers of high molecular weight secreted by microorganisms into their environment. EPSs establish the functional and structural integrity of biofilms, and are considered the fundamental comp ...
s or EPS produced by colonizing bacteria. The decay of these substances, together with syneresis of the host mud, produced stresses that fractured the interiors of the concretions while still at shallow burial depth. This was possible only with the bacterial colonization and the right sedimentation rate. Additional fractures formed during subsequent episodes of shallow burial (during the Cretaceous) or uplift (during the Paleogene). Water derived from rain and snow (meteoric water) later infiltrated the beds and deposited ferroan calcite in the cracks. Septarian concretions often record a complex history of formation that provides geologists with information on early
diagenesis Diagenesis () is the process that describes physical and chemical changes in sediments first caused by water-rock interactions, microbial activity, and compaction after their deposition. Increased pressure and temperature only start to play a ...
, the initial stages of the formation of sedimentary rock from unconsolidated sediments. Most concretions appear to have formed at depths of burial where
sulfate-reducing microorganisms Sulfate-reducing microorganisms (SRM) or sulfate-reducing prokaryotes (SRP) are a group composed of sulfate-reducing bacteria (SRB) and sulfate-reducing archaea (SRA), both of which can perform anaerobic respiration utilizing sulfate () as termina ...
are active. This corresponds to burial depths of , and is characterized by generation of carbon dioxide, increased
alkalinity Alkalinity (from ar, القلوي, al-qaly, lit=ashes of the saltwort) is the capacity of water to resist acidification. It should not be confused with basicity, which is an absolute measurement on the pH scale. Alkalinity is the strength of ...
and precipitation of calcium carbonate. However, there is some evidence that formation continues well into the methanogenic zone beneath the sulfate reduction zone. A spectacular example of
boulder In geology, a boulder (or rarely bowlder) is a rock fragment with size greater than in diameter. Smaller pieces are called cobbles and pebbles. While a boulder may be small enough to move or roll manually, others are extremely massive. In c ...
septarian concretions, which are as much as in diameter, are the Moeraki Boulders. These concretions are found eroding out of
Paleocene The Paleocene, ( ) or Palaeocene, is a geological epoch (geology), epoch that lasted from about 66 to 56 mya (unit), million years ago (mya). It is the first epoch of the Paleogene Period (geology), Period in the modern Cenozoic Era (geology), E ...
mudstone of the Moeraki Formation exposed along the coast near
Moeraki Moeraki is a small fishing village on the east coast of the South Island of New Zealand. It was once the location of a whaling station. In the 1870s, local interests believed it could become the main port for the north Otago area and a railwa ...
,
South Island The South Island, also officially named , is the larger of the two major islands of New Zealand in surface area, the other being the smaller but more populous North Island. It is bordered to the north by Cook Strait, to the west by the Tasman ...
,
New Zealand New Zealand ( mi, Aotearoa ) is an island country in the southwestern Pacific Ocean. It consists of two main landmasses—the North Island () and the South Island ()—and over 700 smaller islands. It is the sixth-largest island count ...
. They are composed of calcite-cemented mud with septarian veins of calcite and rare late-stage
quartz Quartz is a hard, crystalline mineral composed of silica (silicon dioxide). The atoms are linked in a continuous framework of SiO4 silicon-oxygen tetrahedra, with each oxygen being shared between two tetrahedra, giving an overall chemical form ...
and
ferrous In chemistry, the adjective Ferrous indicates a compound that contains iron(II), meaning iron in its +2 oxidation state, possibly as the divalent cation Fe2+. It is opposed to "ferric" or iron(III), meaning iron in its +3 oxidation state, such a ...
dolomite Dolomite may refer to: *Dolomite (mineral), a carbonate mineral *Dolomite (rock), also known as dolostone, a sedimentary carbonate rock *Dolomite, Alabama, United States, an unincorporated community *Dolomite, California, United States, an unincor ...
.Fordyce, E., and P. Maxwell, 2003, ''Canterbury Basin Paleontology and Stratigraphy, Geological Society of New Zealand Annual Field Conference 2003 Field Trip 8'', Miscellaneous Publication 116B, Geological Society of New Zealand, Dunedin, New Zealand. Forsyth, P.J., and G. Coates, 1992, ''The Moeraki boulders''. Institute of Geological & Nuclear Sciences, Information Series no. 1, (Lower Hutt, New Zealand)Thyne, G.D., and J.R. Boles, 1989
''Isotopic evidence for origin of the Moeraki septarian concretions, New Zealand''
Journal of Sedimentary Petrology. v. 59, n. 2, p. 272-279.
The much smaller septarian concretions found in the
Kimmeridge Clay The Kimmeridge Clay is a sedimentary deposit of fossiliferous marine clay which is of Late Jurassic to lowermost Cretaceous age and occurs in southern and eastern England and in the North Sea. This rock formation is the major source rock for North ...
exposed in
cliff In geography and geology, a cliff is an area of rock which has a general angle defined by the vertical, or nearly vertical. Cliffs are formed by the processes of weathering and erosion, with the effect of gravity. Cliffs are common on co ...
s along the
Wessex la, Regnum Occidentalium Saxonum , conventional_long_name = Kingdom of the West Saxons , common_name = Wessex , image_map = Southern British Isles 9th century.svg , map_caption = S ...
coast of England are more typical examples of septarian concretions.


Cannonball concretions

Cannonball concretions are large spherical concretions, which resemble cannonballs. These are found along the Cannonball River within Morton and Sioux Counties,
North Dakota North Dakota () is a U.S. state in the Upper Midwest, named after the Native Americans in the United States, indigenous Dakota people, Dakota Sioux. North Dakota is bordered by the Canadian provinces of Saskatchewan and Manitoba to the north a ...
, and can reach in diameter. They were created by early cementation of sand and silt by
calcite Calcite is a Carbonate minerals, carbonate mineral and the most stable Polymorphism (materials science), polymorph of calcium carbonate (CaCO3). It is a very common mineral, particularly as a component of limestone. Calcite defines hardness 3 on ...
. Similar cannonball concretions, which are as much as in diameter, are found associated with sandstone outcrops of the Frontier Formation in northeast
Utah Utah ( , ) is a state in the Mountain West subregion of the Western United States. Utah is a landlocked U.S. state bordered to its east by Colorado, to its northeast by Wyoming, to its north by Idaho, to its south by Arizona, and to it ...
and central
Wyoming Wyoming () is a U.S. state, state in the Mountain states, Mountain West subregion of the Western United States. It is bordered by Montana to the north and northwest, South Dakota and Nebraska to the east, Idaho to the west, Utah to the south ...
. They formed by the early cementation of sand by calcite. Somewhat weathered and eroded giant cannonball concretions, as large as in diameter, occur in abundance at " Rock City" in
Ottawa County, Kansas Ottawa County (standard abbreviation: OT) is a county located in the U.S. state of Kansas. As of the 2020 census, the county population was 5,735. The largest city and county seat is Minneapolis. History Early history For many millennia, ...
. Large and spherical boulders are also found along Koekohe beach near
Moeraki Moeraki is a small fishing village on the east coast of the South Island of New Zealand. It was once the location of a whaling station. In the 1870s, local interests believed it could become the main port for the north Otago area and a railwa ...
on the east coast of the South Island of
New Zealand New Zealand ( mi, Aotearoa ) is an island country in the southwestern Pacific Ocean. It consists of two main landmasses—the North Island () and the South Island ()—and over 700 smaller islands. It is the sixth-largest island count ...
. The Moeraki Boulders, Ward Beach boulders and
Koutu Boulders Koutu is a suburb of Rotorua in the Bay of Plenty Region of New Zealand's North Island. Koutu was originally a home for the people of Ngati Whakaue and Ngāti Uenukukopako and has been in existence since before the establishment of Rotorua Town ...
of New Zealand are examples of septarian concretions, which are also cannonball concretions. Large spherical rocks, which are found on the shore of
Lake Huron Lake Huron ( ) is one of the five Great Lakes of North America. Hydrology, Hydrologically, it comprises the easterly portion of Lake Michigan–Huron, having the same surface elevation as Lake Michigan, to which it is connected by the , Strait ...
near
Kettle Point, Ontario Kettle & Stony Point First Nation ( oj, Wiiwkwedong Anishinaabek, meaning: "in/at the bay") comprises the Kettle Point reserve and Stony Point Reserve (which is under remedial cleanup after over 50 years of occupation by the Canadian Armed Forces), ...
, and locally known as "kettles", are typical cannonball concretions. Cannonball concretions have also been reported from
Van Mijenfjorden Van Mijenfjorden is the third-longest fjord in Norway's Svalbard archipelago. It lies in the southern portion of Spitsbergen island, south of Nordenskiöld Land and north of Nathorst Land. The fjord is long, being separated from Bellsund further ...
,
Spitsbergen Spitsbergen (; formerly known as West Spitsbergen; Norwegian: ''Vest Spitsbergen'' or ''Vestspitsbergen'' , also sometimes spelled Spitzbergen) is the largest and the only permanently populated island of the Svalbard archipelago in northern Norw ...
; near
Haines Junction Haines Junction is a village in Yukon, Canada. It is at Kilometre 1,632 (historical mile 1016) of the Alaska Highway at its junction with the Haines Highway, hence the name of the community. According to the 2021 Census, the population was 688. ...
,
Yukon Territory Yukon (; ; formerly called Yukon Territory and also referred to as the Yukon) is the smallest and westernmost of Canada's three territories. It also is the second-least populated province or territory in Canada, with a population of 43,964 as ...
,
Canada Canada is a country in North America. Its ten provinces and three territories extend from the Atlantic Ocean to the Pacific Ocean and northward into the Arctic Ocean, covering over , making it the world's second-largest country by tot ...
;
Jameson Land Jameson Land is a peninsula in eastern Greenland. Geography Jameson Land is bounded to the southwest by Scoresby Sound (the world's largest fjord), to the northwest by the Stauning Alps, to the north by Scoresby Land, to the northeast by the Fle ...
, East
Greenland Greenland ( kl, Kalaallit Nunaat, ; da, Grønland, ) is an island country in North America that is part of the Kingdom of Denmark. It is located between the Arctic and Atlantic oceans, east of the Canadian Arctic Archipelago. Greenland is t ...
; near Mecevici, Ozimici, and Zavidovici in Bosnia-Herzegovina; in Alaska in the
Kenai Peninsula The Kenai Peninsula ( Dena'ina: ''Yaghenen'') is a large peninsula jutting from the coast of Southcentral Alaska. The name Kenai (, ) is derived from the word "Kenaitze" or "Kenaitze Indian Tribe", the name of the Native Athabascan Alaskan trib ...
Captain Cook State Park on north of
Cook Inlet Cook Inlet ( tfn, Tikahtnu;  Sugpiaq: ''Cungaaciq'') stretches from the Gulf of Alaska to Anchorage in south-central Alaska. Cook Inlet branches into the Knik Arm and Turnagain Arm at its northern end, almost surrounding Anchorage. On its so ...
beach and on
Kodiak Island Kodiak Island (Alutiiq: ''Qikertaq''), is a large island on the south coast of the U.S. state of Alaska, separated from the Alaska mainland by the Shelikof Strait. The largest island in the Kodiak Archipelago, Kodiak Island is the second larges ...
northeast of Fossil Beach;


Hiatus concretions

Hiatus concretions are distinguished by their stratigraphic history of exhumation, exposure and reburial. They are found where submarine erosion has concentrated early diagenetic concretions as lag surfaces by washing away surrounding fine-grained sediments. Their significance for stratigraphy, sedimentology and paleontology was first noted by Voigt who referred to them as ''Hiatus-Konkretionen''. "Hiatus" refers to the break in sedimentation that allowed this erosion and exposure. They are found throughout the fossil record but are most common during periods in which calcite sea conditions prevailed, such as the
Ordovician The Ordovician ( ) is a geologic period and System (geology), system, the second of six periods of the Paleozoic Era (geology), Era. The Ordovician spans 41.6 million years from the end of the Cambrian Period million years ago (Mya) to the start ...
,
Jurassic The Jurassic ( ) is a Geological period, geologic period and System (stratigraphy), stratigraphic system that spanned from the end of the Triassic Period million years ago (Mya) to the beginning of the Cretaceous Period, approximately Mya. The J ...
and
Cretaceous The Cretaceous ( ) is a geological period that lasted from about 145 to 66 million years ago (Mya). It is the third and final period of the Mesozoic Era, as well as the longest. At around 79 million years, it is the longest geological period of th ...
. Most are formed from the cemented infillings of burrow systems in siliciclastic or carbonate sediments. A distinctive feature of hiatus concretions separating them from other types is that they were often encrusted by marine organisms including
bryozoans Bryozoa (also known as the Polyzoa, Ectoprocta or commonly as moss animals) are a phylum of simple, aquatic invertebrate animals, nearly all living in sedentary colonies. Typically about long, they have a special feeding structure called a l ...
, echinoderms and
tube worms A tubeworm is any worm-like sessility (zoology), sessile invertebrate that anchors its tail to an underwater surface and secretes around its body a mineral tube, into which it can withdraw its entire body. Tubeworms are found among the following t ...
in the Paleozoic and bryozoans, oysters and tube worms in the Mesozoic and Cenozoic. Hiatus concretions are also often significantly bored by worms and bivalves.


Elongate concretions

Elongate concretions form parallel to sedimentary strata and have been studied extensively due to the inferred influence of
phreatic ''Phreatic'' is a term used in hydrology to refer to aquifers, in speleology to refer to cave passages, and in volcanology to refer to a type of volcanic eruption. Hydrology The term phreatic (the word originates from the Greek , meaning "well" ...
(saturated) zone
groundwater Groundwater is the water present beneath Earth's surface in rock and soil pore spaces and in the fractures of rock formations. About 30 percent of all readily available freshwater in the world is groundwater. A unit of rock or an unconsolidate ...
flow direction on the orientation of the axis of elongation. In addition to providing information about the orientation of past fluid flow in the host rock, elongate concretions can provide insight into local permeability trends (i.e., permeability correlation structure; variation in groundwater velocity, and the types of geological features that influence flow. Elongate concretions are well known in the
Kimmeridge Clay The Kimmeridge Clay is a sedimentary deposit of fossiliferous marine clay which is of Late Jurassic to lowermost Cretaceous age and occurs in southern and eastern England and in the North Sea. This rock formation is the major source rock for North ...
formation of northwest Europe. In outcrops, where they have acquired the name "doggers", they are typically only a few meters across, but in the subsurface they can be seen to penetrate up to tens of meters of along-hole dimension. Unlike limestone beds, however, it is impossible to consistently correlate them between even closely spaced wells.


Moqui Marbles

Moqui Marbles, also called Moqui balls or "Moki marbles", are iron oxide concretions which can be found eroding in great abundance out of outcrops of the
Navajo Sandstone The Navajo Sandstone is a geological formation in the Glen Canyon Group that is spread across the U.S. states of southern Nevada, northern Arizona, northwest Colorado, and Utah as part of the Colorado Plateau province of the United States.Anonymo ...
within south-central and southeastern Utah. These concretions range in shape from spheres to discs, buttons, spiked balls, cylindrical forms, and other odd shapes. They range from pea-size to baseball-size. The concretions were created by the precipitation of iron, which was dissolved in groundwater. The iron was originally present as a thin film of iron oxide surrounding sand grains in the Navajo Sandstone. Groundwater containing
methane Methane ( , ) is a chemical compound with the chemical formula (one carbon atom bonded to four hydrogen atoms). It is a group-14 hydride, the simplest alkane, and the main constituent of natural gas. The relative abundance of methane on Eart ...
or
petroleum Petroleum, also known as crude oil, or simply oil, is a naturally occurring yellowish-black liquid mixture of mainly hydrocarbons, and is found in geological formations. The name ''petroleum'' covers both naturally occurring unprocessed crud ...
from underlying rock beds reacted with the iron oxide, converting it to soluble
reduced iron In chemistry, iron(II) refers to the element iron in its +2 oxidation state. In ionic compounds (salts), such an atom may occur as a separate cation (positive ion) denoted by Fe2+. The adjective ferrous or the prefix ferro- is often used to sp ...
. When the iron-bearing groundwater came into contact with more oxygen-rich groundwater, the reduced iron was converted back to insoluble iron oxide, which formed the concretions. It is possible that reduced iron first formed
siderite Siderite is a mineral composed of iron(II) carbonate (FeCO3). It takes its name from the Greek word σίδηρος ''sideros,'' "iron". It is a valuable iron mineral, since it is 48% iron and contains no sulfur or phosphorus. Zinc, magnesium and ...
concretions that were subsequently oxidized.
Iron-oxidizing bacteria Iron-oxidizing bacteria are chemotrophic bacteria that derive energy by oxidizing dissolved ferrous iron. They are known to grow and proliferate in waters containing iron concentrations as low as 0.1 mg/L. However, at least 0.3 ppm of dissolved ox ...
may have played a role.


Kansas pop rocks

Kansas pop rocks are concretions of either iron sulfide, ''i.e.''
pyrite The mineral pyrite (), or iron pyrite, also known as fool's gold, is an iron sulfide with the chemical formula Iron, FeSulfur, S2 (iron (II) disulfide). Pyrite is the most abundant sulfide mineral. Pyrite's metallic Luster (mineralogy), lust ...
and
marcasite The mineral marcasite, sometimes called “white iron pyrite”, is iron sulfide (FeS2) with orthorhombic crystal structure. It is physically and crystallographically distinct from pyrite, which is iron sulfide with cubic crystal structure. Both ...
, or in some cases
jarosite Jarosite is a basic hydrous sulfate of potassium and ferric iron (Fe-III) with a chemical formula of KFe3(SO4)2(OH)6. This sulfate mineral is formed in ore deposits by the oxidation of iron sulfides. Jarosite is often produced as a byproduct du ...
, which are found in outcrops of the Smoky Hill Chalk Member of the Niobrara Formation within
Gove County, Kansas Gove County (county code GO) is a county in the U.S. state of Kansas. As of the 2020 census, the county population was 2,718. Its county seat is Gove City, and its most populous city is Quinter. History Early history Eighty (80) million y ...
. They are typically associated with thin layers of altered volcanic ash, called
bentonite Bentonite () is an absorbent swelling clay consisting mostly of montmorillonite (a type of smectite) which can either be Na-montmorillonite or Ca-montmorillonite. Na-montmorillonite has a considerably greater swelling capacity than Ca-mon ...
, that occur within the
chalk Chalk is a soft, white, porous, sedimentary carbonate rock. It is a form of limestone composed of the mineral calcite and originally formed deep under the sea by the compression of microscopic plankton that had settled to the sea floor. Chalk ...
comprising the Smoky Hill Chalk Member. A few of these concretions enclose, at least in part, large flattened valves of inoceramid
bivalve Bivalvia (), in previous centuries referred to as the Lamellibranchiata and Pelecypoda, is a class of marine and freshwater molluscs that have laterally compressed bodies enclosed by a shell consisting of two hinged parts. As a group, bival ...
s. These concretions range in size from a few millimeters to as much as in length and in thickness. Most of these concretions are oblate spheroids. Other "pop rocks" are small polycuboidal pyrite concretions, which are as much as in diameter. These concretions are called "pop rocks" because they explode if thrown in a fire. Also, when they are either cut or hammered, they produce sparks and a burning sulfur smell. Contrary to what has been published on the Internet, none of the iron sulfide concretions, which are found in the Smoky Hill Chalk Member were created by either the replacement of fossils or by metamorphic processes. In fact,
metamorphic rocks Metamorphic rocks arise from the transformation of existing rock to new types of rock in a process called metamorphism. The original rock (protolith) is subjected to temperatures greater than and, often, elevated pressure of or more, caus ...
are completely absent from the Smoky Hill Chalk Member. Instead, all of these iron sulfide concretions were created by the precipitation of iron sulfides within anoxic marine
calcareous ooze Calcareous () is an adjective meaning "mostly or partly composed of calcium carbonate", in other words, containing lime or being chalky. The term is used in a wide variety of scientific disciplines. In zoology ''Calcareous'' is used as an adje ...
after it had accumulated and before it had
lithified Lithification (from the Ancient Greek word ''lithos'' meaning 'rock' and the Latin-derived suffix ''-ific'') is the process in which sediments compact under pressure, expel connate fluids, and gradually become solid rock. Essentially, lithificatio ...
into chalk. Iron sulfide concretions, such as the Kansas Pop rocks, consisting of either
pyrite The mineral pyrite (), or iron pyrite, also known as fool's gold, is an iron sulfide with the chemical formula Iron, FeSulfur, S2 (iron (II) disulfide). Pyrite is the most abundant sulfide mineral. Pyrite's metallic Luster (mineralogy), lust ...
and
marcasite The mineral marcasite, sometimes called “white iron pyrite”, is iron sulfide (FeS2) with orthorhombic crystal structure. It is physically and crystallographically distinct from pyrite, which is iron sulfide with cubic crystal structure. Both ...
, are nonmagnetic. On the other hand, iron sulfide concretions, which either are composed of or contain either
pyrrhotite Pyrrhotite is an iron sulfide mineral with the formula Fe(1-x)S (x = 0 to 0.2). It is a nonstoichiometric variant of FeS, the mineral known as troilite. Pyrrhotite is also called magnetic pyrite, because the color is similar to pyrite and it is ...
or smythite, will be magnetic to varying degrees. Prolonged heating of either a pyrite or marcasite concretion will convert portions of either mineral into pyrrhotite causing the concretion to become slightly magnetic.


Claystones, clay dogs, and fairy stones

Disc concretions composed of calcium carbonate are often found eroding out of exposures of interlaminated
silt Silt is granular material of a size between sand and clay and composed mostly of broken grains of quartz. Silt may occur as a soil (often mixed with sand or clay) or as sediment mixed in suspension with water. Silt usually has a floury feel when ...
and
clay Clay is a type of fine-grained natural soil material containing clay minerals (hydrous aluminium phyllosilicates, e.g. kaolin, Al2 Si2 O5( OH)4). Clays develop plasticity when wet, due to a molecular film of water surrounding the clay par ...
,
varve A varve is an annual layer of sediment or sedimentary rock. The word 'varve' derives from the Swedish word ''varv'' whose meanings and connotations include 'revolution', 'in layers', and 'circle'. The term first appeared as ''Hvarfig lera'' (va ...
d,
proglacial lake In geology, a proglacial lake is a lake formed either by the damming action of a moraine during the retreat of a melting glacier, a glacial ice dam, or by meltwater trapped against an ice sheet due to isostatic depression of the crust around th ...
deposits. For example, great numbers of strikingly symmetrical concretions have been found eroding out of outcrops of
Quaternary The Quaternary ( ) is the current and most recent of the three periods of the Cenozoic Era in the geologic time scale of the International Commission on Stratigraphy (ICS). It follows the Neogene Period and spans from 2.58 million years ...
proglacial lake
sediment Sediment is a naturally occurring material that is broken down by processes of weathering and erosion, and is subsequently transported by the action of wind, water, or ice or by the force of gravity acting on the particles. For example, sand an ...
s along and in the
gravel Gravel is a loose aggregation of rock fragments. Gravel occurs naturally throughout the world as a result of sedimentary and erosive geologic processes; it is also produced in large quantities commercially as crushed stone. Gravel is classifi ...
s of the
Connecticut River The Connecticut River is the longest river in the New England region of the United States, flowing roughly southward for through four states. It rises 300 yards (270 m) south of the U.S. border with Quebec, Canada, and discharges at Long Island ...
and its tributaries in
Massachusetts Massachusetts (Massachusett language, Massachusett: ''Muhsachuweesut assachusett writing systems, məhswatʃəwiːsət'' English: , ), officially the Commonwealth of Massachusetts, is the most populous U.S. state, state in the New England ...
and
Vermont Vermont () is a state in the northeast New England region of the United States. Vermont is bordered by the states of Massachusetts to the south, New Hampshire to the east, and New York to the west, and the Canadian province of Quebec to ...
. Depending the specific source of these concretions, they vary in an infinite variety of forms that include disc-shapes; crescent-shapes; watch-shapes; cylindrical or club-shapes; botryoidal masses; and animal-like forms. They can vary in length from to over and often exhibit concentric grooves on their surfaces. In the
Connecticut River Valley The Connecticut River is the longest river in the New England region of the United States, flowing roughly southward for through four states. It rises 300 yards (270 m) south of the U.S. border with Quebec, Canada, and discharges at Long Island ...
, these concretions are often called "claystones" because the concretions are harder than the clay enclosing them. In local brickyards, they were called "clay-dogs" either because of their animal-like forms or the concretions were nuisances in molding bricks. Similar disc-shaped calcium carbonate concretions have also been found in the
Harricana River The Harricana River (french: Rivière Harricana) (also known as Harricanaw River) is a river in western Quebec and northeastern Ontario, Canada. It is long, has a drainage area of , and has a mean discharge of . While 80% of its drainage area is ...
valley in the
Abitibi-Témiscamingue Abitibi-Témiscamingue () is an List of regions of Quebec, administrative region located in western Québec, Canada, along the border with Ontario. It became part of the province in 1898. It has a land area of and its population was 146,717 peo ...
administrative region of
Quebec Quebec ( ; )According to the Canadian government, ''Québec'' (with the acute accent) is the official name in Canadian French and ''Quebec'' (without the accent) is the province's official name in Canadian English is one of the thirtee ...
, and in Östergötland county, Sweden. In
Scandinavia Scandinavia; Sámi languages: /. ( ) is a subregion#Europe, subregion in Northern Europe, with strong historical, cultural, and linguistic ties between its constituent peoples. In English usage, ''Scandinavia'' most commonly refers to Denmark, ...
, they are known as "marlekor" ("fairy stones").Warkentin, B.P., 1967. ''Carbonate content of concretions in varved sediments''. ''Canadian Journal of Earth Sciences'', 4(2), pp.333-333.


Gogottes

are sandstone concretions found in
Oligocene The Oligocene ( ) is a geologic epoch of the Paleogene Period and extends from about 33.9 million to 23 million years before the present ( to ). As with other older geologic periods, the rock beds that define the epoch are well identified but the ...
(~30 million years) aged sediments near Fontainebleau, France. Gogottes have fetched high prices at auction due to their sculpture-like quality.


See also

* * in arid and semi-arid soils * * * in the Natural History Museum, London * * . CaSO4 concretions in arid and semi-arid soils * * * * * , a ''replacement body'', not to be confused with a concretion * * . CaCO3


References


External links

* Dietrich, R.V., 2002
''Carbonate Concretions--A Bibliography''
The Wayback Machine. an
PDF file of ''Carbonate Concretions--A Bibliography''
, CMU Online Digital Object Repository, Central Michigan University, Mount Pleasant, Michigan. * Biek, B., 2002
''Concretions and Nodules in North Dakota''
North Dakota Geological Survey, Bismarck, North Dakota. * Everhart, M., 2004

Part of the ttp://www.oceansofkansas.com Oceans of Kansasweb site. * Hansen, M.C., 1994
''Ohio Shale Concretions'' PDF version, 270 KB
Ohio Division of Geological Survey GeoFacts n. 4, pp. 1–2. * Hanson, W.D., and J.M. Howard, 2005
''Spherical Boulders in North-Central Arkansas'' PDF version, 2.8 MB
Arkansas Geological Commission Miscellaneous Publication n. 22, pp. 1–23. * Heinrich, P.V., 2007
''The Giant Concretions of Rock City Kansas'' PDF version, 836 KB
BackBender's Gazette. vol. 38, no. 8, pp. 6–12. * Hokianga Tourism Association, nd
''Koutu Boulders ANY ONE FOR A GAME OF BOWLS?''
an

High-quality pictures of cannonball concretions. * Irna, 2006

* Irna, 2007a

* Irna, 2007b

* Katz, B., 1998

Digital West Media, Inc. * Kuban, Glen J., 2006–2008

* McCollum, A., nd

a collection of articles maintained by an American artist. * Mozley, P.S.

on-line version of an overview paper originally published by the New Mexico Bureau of Geology and Mineral Resources. * United States Geological Survey, nd

* University of Utah, 2004
''Earth Has 'Blueberries' Like Mars 'Moqui Marbles' Formed in Groundwater in Utah's National Parks''
{{Webarchive, url=https://web.archive.org/web/20150802011237/http://unews.utah.edu/news_releases/earth-has-039blueberries039-like-mars/ , date=2015-08-02 press release about iron oxide and Martian concretions * Tessa Koumoundouros
These Eerie 'Living Stones' in Romania Are Fantastical, And Totally Real
On: sciencealert. 25 December 2020: About Trovants in
Costești Costești () is a town in Argeș County, Muntenia, Romania Romania ( ; ro, România ) is a country located at the crossroads of Central, Eastern, and Southeastern Europe. It borders Bulgaria to the south, Ukraine to the north, Hung ...
, Ulmet and other locations in
Romania Romania ( ; ro, România ) is a country located at the crossroads of Central Europe, Central, Eastern Europe, Eastern, and Southeast Europe, Southeastern Europe. It borders Bulgaria to the south, Ukraine to the north, Hungary to the west, S ...
Sedimentary rocks Minerals Petrology Mineralogy Pseudofossils Stones