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Alkalinity
Alkalinity (from ar, القلوي, al-qaly, lit=ashes of the saltwort) is the capacity of water to resist acidification. It should not be confused with basicity, which is an absolute measurement on the pH scale. Alkalinity is the strength of a buffer solution composed of weak acids and their conjugate bases. It is measured by titrating the solution with an acid such as HCl until its pH changes abruptly, or it reaches a known endpoint where that happens. Alkalinity is expressed in units of concentration, such as meq/L (milliequivalents per liter), μeq/kg (microequivalents per kilogram), or mg/L CaCO3 (milligrams per liter of calcium carbonate). Each of these measurements corresponds to an amount of acid added as a titrant. Although alkalinity is primarily a term used by oceanographers, it is also used by hydrologists to describe temporary hardness. Moreover, measuring alkalinity is important in determining a stream's ability to neutralize acidic pollution from rainfall or ...
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Freshwater Acidification
Freshwater acidification occurs when acidic inputs enter a body of fresh water through the weathering of rocks, invasion of acidifying gas (e.g. carbon dioxide), or by the reduction of acid anions, like sulfate and nitrate within the lake. Freshwater acidification is primarily caused by sulfur oxides (SOx) and nitrogen oxides (NOx) entering the water from atmospheric depositions and soil leaching. Carbonic acid and dissolved carbon dioxide can also enter freshwaters in a similar manner associated with runoff through carbon dioxide-rich soils. Runoff that contains these compounds may be accompanied by acidifying hydrogen ions and inorganic aluminum, which can be toxic to marine organisms. Acid rain is also a contributor to freshwater acidification. It is created when SOx and NOx react with water, oxygen, and other oxidants within the clouds. The buffering capacity of soils and bedrocks within the freshwater ecosystem can contribute to the acidity of the water. Each freshwater reserv ...
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Carbonate Alkalinity
Carbonate hardness, is a measure of the water hardness caused by the presence of carbonate () and bicarbonate () anions. Carbonate hardness is usually expressed either in degrees KH (dKH) (from the German ''"Karbonathärte"''), or in ''parts per million calcium carbonate'' ( ppm or grams per litre, mg/L). One dKH is equal to 17.848 mg/L (ppm) , e.g. one dKH corresponds to the carbonate and bicarbonate ions found in a solution of approximately 17.848 milligrams of calcium carbonate() per litre of water (17.848 ppm). Both measurements (mg/L or KH) are usually expressed as mg/L – meaning the concentration of carbonate expressed as if calcium carbonate were the sole source of carbonate ions. An aqueous solution containing 120 mg NaHCO3 (baking soda) per litre of water will contain 1.4285 mmol/l of bicarbonate, since the molar mass of baking soda is 84.007 g/mol. This is equivalent in carbonate hardness to a solution containing 0.71423 mmol/L of (calcium) carb ...
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Temporary Hardness
Hard water is water that has high mineral content (in contrast with "soft water"). Hard water is formed when water percolates through deposits of limestone, chalk or gypsum, which are largely made up of calcium and magnesium carbonates, bicarbonates and sulfates. Hard drinking water may have moderate health benefits. It can pose critical problems in industrial settings, where water hardness is monitored to avoid costly breakdowns in boilers, cooling towers, and other equipment that handles water. In domestic settings, hard water is often indicated by a lack of foam formation when soap is agitated in water, and by the formation of limescale in kettles and water heaters.World Health OrganizatioHardness in Drinking-Water 2003 Wherever water hardness is a concern, water softening is commonly used to reduce hard water's adverse effects. Origins Natural rainwater, snow and other forms of precipitation typically have low concentrations of multivalent cations such as calcium and magnes ...
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WOA05 GLODAP Pd ALK AYool
WOA may refer to: __NOTOC__ Computing * Web-oriented architecture, a computer systems architectural style * Windows on ARM (other), a series of operating systems for ARM architecture computers * WebObjects application, the file system suffix of an application written using the WebObjects framework from NeXT, later Apple Wars * War of Attrition, a conflict between Israel and Egypt * War of aggression Music * Wacken Open Air, the largest exclusively metal music festival in the world * War of Ages, metalcore band from Pennsylvania * W.O.A Records of India and Dubai Sports * World Olympians Association * Welsh Orienteering Association Other uses * World Ocean Atlas * World of Art, a series of books on art * the ICAO airline designator for World Airways World Airways, Inc. was a United States airline headquartered in Peachtree City, Georgia in Greater Atlanta. The company operated mostly non-scheduled services but did fly scheduled passenger services as well ...
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Challenger Expedition
The ''Challenger'' expedition of 1872–1876 was a scientific program that made many discoveries to lay the foundation of oceanography. The expedition was named after the naval vessel that undertook the trip, . The expedition, initiated by William Benjamin Carpenter, was placed under the scientific supervision of Sir Charles Wyville Thomson—of the University of Edinburgh and Merchiston Castle School—assisted by five other scientists, including Sir John Murray, a secretary-artist and a photographer. The Royal Society of London obtained the use of ''Challenger'' from the Royal Navy and in 1872 modified the ship for scientific tasks, equipping it with separate laboratories for natural history and chemistry. The expedition, led by Captain George Nares, sailed from Portsmouth, England, on 21 December 1872. Other naval officers included Commander John Maclear. – pages 19 and 20 list the civilian staff and naval officers and crew, along with changes that took place during the ...
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Carbon Dioxide
Carbon dioxide (chemical formula ) is a chemical compound made up of molecules that each have one carbon atom covalently double bonded to two oxygen atoms. It is found in the gas state at room temperature. In the air, carbon dioxide is transparent to visible light but absorbs infrared radiation, acting as a greenhouse gas. It is a trace gas in Earth's atmosphere at 421 parts per million (ppm), or about 0.04% by volume (as of May 2022), having risen from pre-industrial levels of 280 ppm. Burning fossil fuels is the primary cause of these increased CO2 concentrations and also the primary cause of climate change.IPCC (2022Summary for policy makersiClimate Change 2022: Mitigation of Climate Change. Contribution of Working Group III to the Sixth Assessment Report of the Intergovernmental Panel on Climate Change Cambridge University Press, Cambridge, United Kingdom and New York, NY, USA Carbon dioxide is soluble in water and is found in groundwater, lakes, ice caps, ...
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Carbonate
A carbonate is a salt of carbonic acid (H2CO3), characterized by the presence of the carbonate ion, a polyatomic ion with the formula . The word ''carbonate'' may also refer to a carbonate ester, an organic compound containing the carbonate group C(=O)(O–)2. The term is also used as a verb, to describe carbonation: the process of raising the concentrations of carbonate and bicarbonate ions in water to produce carbonated water and other carbonated beverageseither by the addition of carbon dioxide gas under pressure or by dissolving carbonate or bicarbonate salts into the water. In geology and mineralogy, the term "carbonate" can refer both to carbonate minerals and carbonate rock (which is made of chiefly carbonate minerals), and both are dominated by the carbonate ion, . Carbonate minerals are extremely varied and ubiquitous in chemically precipitated sedimentary rock. The most common are calcite or calcium carbonate, CaCO3, the chief constituent of limestone (as well a ...
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Stoichiometric
Stoichiometry refers to the relationship between the quantities of reactants and products before, during, and following chemical reactions. Stoichiometry is founded on the law of conservation of mass where the total mass of the reactants equals the total mass of the products, leading to the insight that the relations among quantities of reactants and products typically form a ratio of positive integers. This means that if the amounts of the separate reactants are known, then the amount of the product can be calculated. Conversely, if one reactant has a known quantity and the quantity of the products can be empirically determined, then the amount of the other reactants can also be calculated. This is illustrated in the image here, where the balanced equation is: : Here, one molecule of methane reacts with two molecules of oxygen gas to yield one molecule of carbon dioxide and two molecules of water. This particular chemical equation is an example of complete combustion. St ...
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Equivalence Point
The equivalence point, or stoichiometric point, of a chemical reaction is the point at which chemically equivalent quantities of reactants have been mixed. For an acid-base reaction the equivalence point is where the moles of acid and the moles of base would neutralize each other according to the chemical reaction. This does not necessarily imply a 1:1 molar ratio of acid:base, merely that the ratio is the same as in the chemical reaction. It can be found by means of an indicator, for example phenolphthalein or methyl orange. The endpoint (related to, but not the same as the equivalence point) refers to the point at which the indicator changes color in a colorimetric titration. Methods to determine the equivalence point Different methods to determine the equivalence point include: ;pH indicator: A pH indicator is a substance that changes color in response to a chemical change. An acid-base indicator (e.g., phenolphthalein) changes color depending on the pH. Redox indicators are a ...
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Acid
In computer science, ACID ( atomicity, consistency, isolation, durability) is a set of properties of database transactions intended to guarantee data validity despite errors, power failures, and other mishaps. In the context of databases, a sequence of database operations that satisfies the ACID properties (which can be perceived as a single logical operation on the data) is called a ''transaction''. For example, a transfer of funds from one bank account to another, even involving multiple changes such as debiting one account and crediting another, is a single transaction. In 1983, Andreas Reuter and Theo Härder coined the acronym ''ACID'', building on earlier work by Jim Gray who named atomicity, consistency, and durability, but not isolation, when characterizing the transaction concept. These four properties are the major guarantees of the transaction paradigm, which has influenced many aspects of development in database systems. According to Gray and Reuter, the IBM Informa ...
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Svante Arrhenius
Svante August Arrhenius ( , ; 19 February 1859 – 2 October 1927) was a Swedes, Swedish scientist. Originally a physicist, but often referred to as a chemist, Arrhenius was one of the founders of the science of physical chemistry. He received the Nobel Prize for Chemistry in 1903, becoming the first Sweden, Swedish Nobel laureate. In 1905, he became director of the Nobel Institute, where he remained until his death."Arrhenius, Svante August" in ''Chambers's Encyclopædia''. London: George Newnes Ltd, George Newnes, 1961, Vol. 1, p. 635. Arrhenius was the first to use principles of physical chemistry to estimate the extent to which increases in atmospheric carbon dioxide are responsible for the Earth's increasing surface temperature. His work played an important role in the emergence of modern climate science. In the 1960s, Charles David Keeling demonstrated that the quantity of human-caused carbon dioxide emissions into the air is enough to cause global warming. The Arrhenius ...
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Nobel Prize In Chemistry
) , image = Nobel Prize.png , alt = A golden medallion with an embossed image of a bearded man facing left in profile. To the left of the man is the text "ALFR•" then "NOBEL", and on the right, the text (smaller) "NAT•" then "MDCCCXXXIII" above, followed by (smaller) "OB•" then "MDCCCXCVI" below. , awarded_for = Outstanding contributions in chemistry , presenter = Royal Swedish Academy of Sciences , location = Stockholm, Sweden , reward = 9 million SEK (2017) , year = 1901 , holder = Carolyn R. Bertozzi, Morten P. Meldal and Karl Barry Sharpless (2022) , most_awards = Frederick Sanger and Karl Barry Sharpless (2) , website nobelprize.org, previous = 2021 , year2=2022, main=2022, next=2023 The Nobel Prize in Chemistry is awarded annually by the Royal Swedish Academy of Sciences to scientists in the various fields of chemistry. It is one of the five Nobel Prizes established by the will of Alfred Nobel in 1895, awarded for ...
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