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Paleosalinity
Paleosalinity (or palaeosalinity) is the salinity of the global ocean or of an ocean basin at a point in geological history. Importance From Bjerrum plots, it is found that a decrease in the salinity of an aqueous fluid will act to increase the value of the carbon dioxide-carbonate system equilibrium constants, (pK*). This means that the relative proportion of carbonate with respect to carbon dioxide is higher in more saline fluids, e.g. seawater, than in fresher waters. Of crucial importance for paleoclimatology is the observation that an increase in salinity will thus reduce the solubility of carbon dioxide in the oceans. Since there is thought to have been a 120 m depression in sea level at the last glacial maximum due to the extensive formation of ice sheets (which are solely freshwater), this represents a significant fractionation towards saltier seas during glacial periods. Correspondingly, this will cause a net outgassing of carbon dioxide into the atmosphere because ...
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Salinity
Salinity () is the saltiness or amount of salt dissolved in a body of water, called saline water (see also soil salinity). It is usually measured in g/L or g/kg (grams of salt per liter/kilogram of water; the latter is dimensionless and equal to ‰). Salinity is an important factor in determining many aspects of the chemistry of natural waters and of biological processes within it, and is a thermodynamic state variable that, along with temperature and pressure, governs physical characteristics like the density and heat capacity of the water. A contour line of constant salinity is called an ''isohaline'', or sometimes ''isohale''. Definitions Salinity in rivers, lakes, and the ocean is conceptually simple, but technically challenging to define and measure precisely. Conceptually the salinity is the quantity of dissolved salt content of the water. Salts are compounds like sodium chloride, magnesium sulfate, potassium nitrate, and sodium bicarbonate which dissolve into ions ...
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Chlorinity
Salinity () is the saltiness or amount of salt dissolved in a body of water, called saline water (see also soil salinity). It is usually measured in g/L or g/kg (grams of salt per liter/kilogram of water; the latter is dimensionless and equal to ‰). Salinity is an important factor in determining many aspects of the chemistry of natural waters and of biological processes within it, and is a thermodynamic state variable that, along with temperature and pressure, governs physical characteristics like the density and heat capacity of the water. A contour line of constant salinity is called an ''isohaline'', or sometimes ''isohale''. Definitions Salinity in rivers, lakes, and the ocean is conceptually simple, but technically challenging to define and measure precisely. Conceptually the salinity is the quantity of dissolved salt content of the water. Salts are compounds like sodium chloride, magnesium sulfate, potassium nitrate, and sodium bicarbonate which dissolve into io ...
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Practical Salinity Unit
Salinity () is the saltiness or amount of salt dissolved in a body of water, called saline water (see also soil salinity). It is usually measured in g/L or g/kg (grams of salt per liter/kilogram of water; the latter is dimensionless and equal to ‰). Salinity is an important factor in determining many aspects of the chemistry of natural waters and of biological processes within it, and is a thermodynamic state variable that, along with temperature and pressure, governs physical characteristics like the density and heat capacity of the water. A contour line of constant salinity is called an ''isohaline'', or sometimes ''isohale''. Definitions Salinity in rivers, lakes, and the ocean is conceptually simple, but technically challenging to define and measure precisely. Conceptually the salinity is the quantity of dissolved salt content of the water. Salts are compounds like sodium chloride, magnesium sulfate, potassium nitrate, and sodium bicarbonate which dissolve into ions ...
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Pore Fluid
Pore may refer to: Biology Animal biology and microbiology * Sweat pore, an anatomical structure of the skin of humans (and other mammals) used for secretion of sweat * Hair follicle, an anatomical structure of the skin of humans (and other mammals) used for secretion of sebum * Canal pore, an anatomical structure that is part of the lateral line sense system of some aquatic organisms * Gonopore, a genital pore present in some invertebrates, particularly insects * Ozopore, the external discharge site of defensive glands in millipedes and some arachnids * An opening across both inner and outer bacterial membranes, a part of many Gram-negative bacterial secretion systems * One of the openings communicating with the skin surface at the terminus of lactiferous ducts in milk-producing mammals Plant and fungal biology * Germ pore, a small pore in the outer wall of a fungal spore through which the germ tube exits upon germination * Stoma, a small opening on a plant leaf used for g ...
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Fresh Water
Fresh water or freshwater is any naturally occurring liquid or frozen water containing low concentrations of dissolved salts and other total dissolved solids. Although the term specifically excludes seawater and brackish water, it does include non- salty mineral-rich waters such as chalybeate springs. Fresh water may encompass frozen and meltwater in ice sheets, ice caps, glaciers, snowfields and icebergs, natural precipitations such as rainfall, snowfall, hail/ sleet and graupel, and surface runoffs that form inland bodies of water such as wetlands, ponds, lakes, rivers, streams, as well as groundwater contained in aquifers, subterranean rivers and lakes. Fresh water is the water resource that is of the most and immediate use to humans. Water is critical to the survival of all living organisms. Many organisms can thrive on salt water, but the great majority of higher plants and most insects, amphibians, reptiles, mammals and birds need fresh water to survive. Fresh ...
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Haline Contraction Coefficient
The Haline contraction coefficient, abbreviated as β, is a coefficient that describes the change in ocean density due to a salinity change, while the potential temperature and the pressure are kept constant. It is a parameter in the Equation Of State (EOS) of the ocean. β is also described as the saline contraction coefficient and is measured in g in the EOS that describes the ocean. An example is TEOS-10. This is the thermodynamic equation of state. β is the salinity variant of the thermal expansion coefficient α, where the density changes due to a change in temperature instead of salinity. With these two coefficients, the density ratio can be calculated. This determines the contribution of the temperature and salinity to the density of a water parcel. β is called a contraction coefficient, because when salinity increases, water becomes denser, and if the temperature increases, water becomes less dense. Definition Τhe haline contraction coefficient is defined ...
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Thermal Expansion Coefficient
Thermal expansion is the tendency of matter to change its shape, area, volume, and density in response to a change in temperature, usually not including phase transitions. Temperature is a monotonic function of the average molecular kinetic energy of a substance. When a substance is heated, molecules begin to vibrate and move more, usually creating more distance between themselves. Substances which contract with increasing temperature are unusual, and only occur within limited temperature ranges (see examples below). The relative expansion (also called strain) divided by the change in temperature is called the material's coefficient of linear thermal expansion and generally varies with temperature. As energy in particles increases, they start moving faster and faster weakening the intermolecular forces between them, therefore expanding the substance. Overview Predicting expansion If an equation of state is available, it can be used to predict the values of the thermal expan ...
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Brine
Brine is a high-concentration solution of salt (NaCl) in water (H2O). In diverse contexts, ''brine'' may refer to the salt solutions ranging from about 3.5% (a typical concentration of seawater, on the lower end of that of solutions used for brining foods) up to about 26% (a typical saturated solution, depending on temperature). Brine forms naturally due to evaporation of ground saline water but it is also generated in the mining of sodium chloride. Brine is used for food processing and cooking (pickling and brining), for de-icing of roads and other structures, and in a number of technological processes. It is also a by-product of many industrial processes, such as desalination, so it requires wastewater treatment for proper disposal or further utilization (fresh water recovery). In nature Brines are produced in multiple ways in nature. Modification of seawater via evaporation results in the concentration of salts in the residual fluid, a characteristic geologic deposit call ...
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Isotopic Fractionation
Isotope fractionation describes fractionation processes that affect the relative abundance of isotopes, phenomena which are taken advantage of in isotope geochemistry and other fields. Normally, the focus is on stable isotopes of the same element. Isotopic fractionation can be measured by isotope analysis, using isotope-ratio mass spectrometry or cavity ring-down spectroscopy to measure ratios of isotopes, an important tool to understand geochemical and biological systems. For example, biochemical processes cause changes in ratios of stable carbon isotopes incorporated into biomass. Definition Stable isotopes partitioning between two substances ''A'' and ''B'' can be expressed by the use of the isotopic fractionation factor (alpha): where ''R'' is the ratio of the heavy to light isotope (e.g., 2H/1H or 18O/16O). Values for alpha tend to be very close to 1. McGlynn, Shawn E.; "Biological Isotope Fractionation and Earth History: From Enzymes to Cells to Ecosystems" pp 59-79 in " ...
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Sea Ice
Sea ice arises as seawater freezes. Because ice is less dense than water, it floats on the ocean's surface (as does fresh water ice, which has an even lower density). Sea ice covers about 7% of the Earth's surface and about 12% of the world's oceans. Much of the world's sea ice is enclosed within the polar ice packs in the Earth's polar regions: the Arctic ice pack of the Arctic Ocean and the Antarctic ice pack of the Southern Ocean. Polar packs undergo a significant yearly cycling in surface extent, a natural process upon which depends the Arctic ecology, including the ocean's ecosystems. Due to the action of winds, currents and temperature fluctuations, sea ice is very dynamic, leading to a wide variety of ice types and features. Sea ice may be contrasted with icebergs, which are chunks of ice shelves or glaciers that calve into the ocean. Depending on location, sea ice expanses may also incorporate icebergs. General features and dynamics Sea ice does not simply grow and ...
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Southern Ocean
The Southern Ocean, also known as the Antarctic Ocean, comprises the southernmost waters of the World Ocean, generally taken to be south of 60° S latitude and encircling Antarctica. With a size of , it is regarded as the second-smallest of the five principal oceanic divisions: smaller than the Pacific, Atlantic, and Indian oceans but larger than the Arctic Ocean. Over the past 30 years, the Southern Ocean has been subject to rapid climate change, which has led to changes in the marine ecosystem. By way of his voyages in the 1770s, James Cook proved that waters encompassed the southern latitudes of the globe. Since then, geographers have disagreed on the Southern Ocean's northern boundary or even existence, considering the waters as various parts of the Pacific, Atlantic, and Indian oceans, instead. However, according to Commodore John Leech of the International Hydrographic Organization (IHO), recent oceanographic research has discovered the importance of Southern ...
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Florida Strait
The Straits of Florida, Florida Straits, or Florida Strait ( es, Estrecho de Florida) is a strait located south-southeast of the North American mainland, generally accepted to be between the Gulf of Mexico and the Atlantic Ocean, and between the Florida Keys (U.S.) and Cuba. It is 93 mi (150 km) wide at the narrowest point between Key West and the Cuban shore, and has been sounded to a depth of 6,000 feet (1,800 m). The strait carries the Florida Current, the beginning of the Gulf Stream, from the Gulf of Mexico. Oil and gas Five wells were drilled in state waters south of the Florida Keys from 1947 to 1962. Gulf Oil drilled three wells in federal waters south of the Florida Keys in 1960 and 1961. All the wells were dry holes. The boundary between the Exclusive Economic Zones of the US and Cuba is halfway between Cuba and Florida, as determined by the 1977 Cuba–United States Maritime Boundary Agreement. Offshore Cuba Cuba has three producing offshore oil f ...
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