Brine is a high-concentration
solution
Solution may refer to:
* Solution (chemistry), a mixture where one substance is dissolved in another
* Solution (equation), in mathematics
** Numerical solution, in numerical analysis, approximate solutions within specified error bounds
* Soluti ...
of
salt
Salt is a mineral composed primarily of sodium chloride (NaCl), a chemical compound belonging to the larger class of salts; salt in the form of a natural crystalline mineral is known as rock salt or halite. Salt is present in vast quantitie ...
(NaCl) in
water
Water (chemical formula ) is an inorganic, transparent, tasteless, odorless, and nearly colorless chemical substance, which is the main constituent of Earth's hydrosphere and the fluids of all known living organisms (in which it acts as a ...
(H
2O). In diverse contexts, ''brine'' may refer to the salt solutions ranging from about 3.5% (a typical concentration of
seawater
Seawater, or salt water, is water from a sea or ocean. On average, seawater in the world's oceans has a salinity of about 3.5% (35 g/L, 35 ppt, 600 mM). This means that every kilogram (roughly one liter by volume) of seawater has appro ...
, on the lower end of that of solutions used for
brining
In food processing, brining is treating food with brine or coarse salt which preserves and seasons the food while enhancing tenderness and flavor with additions such as herbs, spices, sugar, caramel or vinegar. Meat and fish are typically ...
foods) up to about 26% (a typical
saturated solution, depending on temperature). Brine forms naturally due to
evaporation
Evaporation is a type of vaporization that occurs on the surface of a liquid as it changes into the gas phase. High concentration of the evaporating substance in the surrounding gas significantly slows down evaporation, such as when humidi ...
of ground saline water but it is also generated in the mining of sodium chloride.
[ Brine is used for food processing and cooking (]pickling
Pickling is the process of preserving or extending the shelf life of food by either anaerobic fermentation in brine or immersion in vinegar. The pickling procedure typically affects the food's texture and flavor. The resulting food is cal ...
and brining
In food processing, brining is treating food with brine or coarse salt which preserves and seasons the food while enhancing tenderness and flavor with additions such as herbs, spices, sugar, caramel or vinegar. Meat and fish are typically ...
), for de-icing
Deicing is the process of removing snow, ice or frost from a surface. Anti-icing is the application of chemicals that not only deice but also remain on a surface and continue to delay the reformation of ice for a certain period of time, or prev ...
of roads and other structures, and in a number of technological processes. It is also a by-product of many industrial process
Industrial processes are procedures involving chemical, physical, electrical or mechanical steps to aid in the manufacturing of an item or items, usually carried out on a very large scale. Industrial processes are the key components of heavy in ...
es, such as desalination
Desalination is a process that takes away mineral components from saline water. More generally, desalination refers to the removal of salts and minerals from a target substance, as in Soil salinity control, soil desalination, which is an issue f ...
, so it requires wastewater treatment
Wastewater treatment is a process used to remove contaminants from wastewater and convert it into an effluent that can be returned to the water cycle. Once returned to the water cycle, the effluent creates an acceptable impact on the environme ...
for proper disposal or further utilization (fresh water
Fresh water or freshwater is any naturally occurring liquid or frozen water containing low concentrations of dissolved salts and other total dissolved solids. Although the term specifically excludes seawater and brackish water, it does include ...
recovery).
In nature
Brines are produced in multiple ways in nature. Modification of seawater via evaporation results in the concentration of salts in the residual fluid, a characteristic geologic deposit called an evaporite
An evaporite () is a water- soluble sedimentary mineral deposit that results from concentration and crystallization by evaporation from an aqueous solution. There are two types of evaporite deposits: marine, which can also be described as ocean ...
is formed as different dissolved ions reach the saturation states of minerals, typically gypsum
Gypsum is a soft sulfate mineral composed of calcium sulfate dihydrate, with the chemical formula . It is widely mined and is used as a fertilizer and as the main constituent in many forms of plaster, blackboard or sidewalk chalk, and drywall. ...
and halite
Halite (), commonly known as rock salt, is a type of salt, the mineral (natural) form of sodium chloride ( Na Cl). Halite forms isometric crystals. The mineral is typically colorless or white, but may also be light blue, dark blue, purple, p ...
. Dissolution of such salt deposits into water can produce brines as well. As seawater freezes, dissolved ions tend to remain in solution resulting in a fluid termed a cryogenic brine. At the time of formation, these cryogenic brines are by definition cooler than the freezing temperature of seawater and can produce a feature called a brinicle
A brinicle ( brine icicle, also known as ice stalactite) is a downward-growing hollow tube of ice enclosing a plume of descending brine that is formed beneath developing sea ice.
As seawater freezes in the polar ocean, salt brine concentrates ar ...
where cool brines descend, freezing the surrounding seawater.
The brine cropping out at the surface as saltwater springs are known as "licks" or "salines". The contents of dissolved solids in groundwater
Groundwater is the water present beneath Earth's surface in rock and soil pore spaces and in the fractures of rock formations. About 30 percent of all readily available freshwater in the world is groundwater. A unit of rock or an unconsolidate ...
vary highly from one location to another on Earth, both in terms of specific constituents (e.g. halite, anhydrite
Anhydrite, or anhydrous calcium sulfate, is a mineral with the chemical formula CaSO4. It is in the orthorhombic crystal system, with three directions of perfect cleavage parallel to the three planes of symmetry. It is not isomorphous with the ...
, carbonate
A carbonate is a salt of carbonic acid (H2CO3), characterized by the presence of the carbonate ion, a polyatomic ion with the formula . The word ''carbonate'' may also refer to a carbonate ester, an organic compound containing the carbonate g ...
s, gypsum, fluoride-salts, organic halide
Halocarbon compounds are chemicals in which one or more carbon atoms are linked by covalent bonds with one or more halogen atoms ( fluorine, chlorine, bromine or iodine – ) resulting in the formation of organofluorine compounds, organoch ...
s, and sulfate
The sulfate or sulphate ion is a polyatomic anion with the empirical formula . Salts, acid derivatives, and peroxides of sulfate are widely used in industry. Sulfates occur widely in everyday life. Sulfates are salts of sulfuric acid and many ...
-salts) and regarding the concentration level. Using one of several classification of groundwater based on total dissolved solids
Total dissolved solids (TDS) is a measure of the dissolved combined content of all inorganic and organic substances present in a liquid in molecular, ionized, or micro-granular ( colloidal sol) suspended form. TDS concentrations are often report ...
(TDS), brine is water containing more than 100,000 mg/L TDS. Brine is commonly produced during well completion operations, particularly after the hydraulic fracturing of a well.
Uses
Culinary
Brine is a common agent in food processing
Food processing is the transformation of agricultural products into food, or of one form of food into other forms. Food processing includes many forms of processing foods, from grinding grain to make raw flour to home cooking to complex industr ...
and cooking. Brining is used to preserve
The word preserve may refer to:
Common uses
* Fruit preserves, a type of sweet spread or condiment
* Nature reserve, an area of importance for wildlife, flora, fauna or other special interest, usually protected
Arts, entertainment, and media
...
or season
A season is a division of the year based on changes in weather, ecology, and the number of daylight hours in a given region. On Earth, seasons are the result of the axial parallelism of Earth's tilted orbit around the Sun. In temperate and pol ...
the food. Brining can be applied to vegetable
Vegetables are parts of plants that are consumed by humans or other animals as food. The original meaning is still commonly used and is applied to plants collectively to refer to all edible plant matter, including the flowers, fruits, stems, ...
s, cheese
Cheese is a dairy product produced in wide ranges of flavors, textures, and forms by coagulation of the milk protein casein. It comprises proteins and fat from milk, usually the milk of cows, buffalo, goats, or sheep. During production, ...
s and fruit
In botany, a fruit is the seed-bearing structure in flowering plants that is formed from the ovary after flowering.
Fruits are the means by which flowering plants (also known as angiosperms) disseminate their seeds. Edible fruits in particu ...
in a process known as pickling
Pickling is the process of preserving or extending the shelf life of food by either anaerobic fermentation in brine or immersion in vinegar. The pickling procedure typically affects the food's texture and flavor. The resulting food is cal ...
. Meat
Meat is animal flesh that is eaten as food. Humans have hunted, farmed, and scavenged animals for meat since prehistoric times. The establishment of settlements in the Neolithic Revolution allowed the domestication of animals such as chic ...
and fish
Fish are aquatic, craniate, gill-bearing animals that lack limbs with digits. Included in this definition are the living hagfish, lampreys, and cartilaginous and bony fish as well as various extinct related groups. Approximately 95% of li ...
are typically steeped in brine for shorter periods of time, as a form of marination
Marinating is the process of soaking foods in a seasoned, often acidic, liquid before cooking. The origin of the word alludes to the use of brine (''aqua marina'' or sea water) in the pickling process, which led to the technique of adding flav ...
, enhancing its tenderness and flavor
Flavor or flavour is either the sensory perception of taste or smell, or a flavoring in food that produces such perception.
Flavor or flavour may also refer to:
Science
*Flavors (programming language), an early object-oriented extension to Lis ...
, or to enhance shelf period.
Chlorine production
Elemental chlorine can be produced by electrolysis of brine (NaCl
Sodium chloride , commonly known as salt (although sea salt also contains other chemical salts), is an ionic compound with the chemical formula NaCl, representing a 1:1 ratio of sodium and chloride ions. With molar masses of 22.99 and 35.45 g/ ...
solution). This process also produces sodium hydroxide (NaOH) and Hydrogen
Hydrogen is the chemical element with the symbol H and atomic number 1. Hydrogen is the lightest element. At standard conditions hydrogen is a gas of diatomic molecules having the formula . It is colorless, odorless, tasteless, non-toxic, an ...
gas (H2). The reaction equations are as follows:
* Cathode: 2 H+ + 2 e- -> H2 (^)
* Anode: 2 Cl- -> Cl2 (^) + 2 e-
* Overall process: 2 NaCl + 2 H2O -> Cl2 + H2 + 2 NaOH
Refrigerating fluid
Brine is used as a secondary fluid
In physics, a fluid is a liquid, gas, or other material that continuously deforms (''flows'') under an applied shear stress, or external force. They have zero shear modulus, or, in simpler terms, are substances which cannot resist any shear ...
in large refrigeration installations for the transport of thermal energy
The term "thermal energy" is used loosely in various contexts in physics and engineering. It can refer to several different well-defined physical concepts. These include the internal energy or enthalpy of a body of matter and radiation; heat, d ...
. Most commonly used brines are based on inexpensive calcium chloride
Calcium chloride is an inorganic compound, a salt with the chemical formula . It is a white crystalline solid at room temperature, and it is highly soluble in water. It can be created by neutralising hydrochloric acid with calcium hydroxide.
Ca ...
and sodium chloride
Sodium chloride , commonly known as salt (although sea salt also contains other chemical salts), is an ionic compound with the chemical formula NaCl, representing a 1:1 ratio of sodium and chloride ions. With molar masses of 22.99 and 35.45 g ...
. It is used because the addition of salt to water lowers the freezing temperature of the solution and the heat transport efficiency can be greatly enhanced for the comparatively low cost of the material. The lowest freezing point obtainable for NaCl brine is at the concentration of 23.3% NaCl by weight.[ This is called the eutectic point.
Because of their corrosive properties salt-based brines have been replaced by organic liquids such as ]ethylene glycol
Ethylene glycol (IUPAC name: ethane-1,2-diol) is an organic compound (a vicinal diol) with the formula . It is mainly used for two purposes, as a raw material in the manufacture of polyester fibers and for antifreeze formulations. It is an odo ...
.
Sodium chloride brine spray is used on some fishing vessels to freeze fish. The brine temperature is generally . Air blast freezing temperatures are or lower. Given the higher temperature of brine, the system efficiency over air blast freezing can be higher. High-value fish usually are frozen at much lower temperatures, below the practical temperature limit for brine.
Water softening and purification
Brine is an auxiliary agent in water softening
Water softening is the removal of calcium, magnesium, and certain other metal cations in hard water. The resulting soft water requires less soap for the same cleaning effort, as soap is not wasted bonding with calcium ions. Soft water also exten ...
and water purification
Water purification is the process of removing undesirable chemicals, biological contaminants, suspended solids, and gases from water. The goal is to produce water that is fit for specific purposes. Most water is purified and disinfected for hu ...
systems involving ion exchange
Ion exchange is a reversible interchange of one kind of ion present in an insoluble solid with another of like charge present in a solution surrounding the solid with the reaction being used especially for softening or making water demineralised, ...
technology. The most common example are household dishwasher
A dishwasher is a machine that is used to clean dishware, cookware, and cutlery automatically. Unlike manual dishwashing, which relies heavily on physical scrubbing to remove soiling, the mechanical dishwasher cleans by spraying hot water, ty ...
s, utilizing sodium chloride in form of dishwasher salt
Dishwasher salt is a particular grade of granulated, crystalline sodium chloride intended for regenerating the water softener circuit of household or industrial dishwashers. Analogous to water softener salt, dishwasher salt regenerates ion exc ...
. Brine is not involved in the purification process itself, but used for regeneration of ion-exchange resin
An ion-exchange resin or ion-exchange polymer is a resin or polymer that acts as a medium for ion exchange. It is an insoluble matrix (or support structure) normally in the form of small (0.25–1.43 mm radius) microbeads, usually white or ye ...
on cyclical basis. The water being treated flows through the resin container until the resin is considered exhausted and water is purified to a desired level. Resin is then regenerated by sequentially backwashing the resin bed to remove accumulated solids, flushing removed ions from the resin with a concentrated solution of replacement ions, and rinsing the flushing solution from the resin. After treatment, ion-exchange resin beads saturated with calcium
Calcium is a chemical element with the symbol Ca and atomic number 20. As an alkaline earth metal, calcium is a reactive metal that forms a dark oxide-nitride layer when exposed to air. Its physical and chemical properties are most similar to ...
and magnesium
Magnesium is a chemical element with the symbol Mg and atomic number 12. It is a shiny gray metal having a low density, low melting point and high chemical reactivity. Like the other alkaline earth metals (group 2 of the periodic ta ...
ions from the treated water, are regenerated by soaking in brine containing 6–12% NaCl. The sodium
Sodium is a chemical element with the symbol Na (from Latin ''natrium'') and atomic number 11. It is a soft, silvery-white, highly reactive metal. Sodium is an alkali metal, being in group 1 of the periodic table. Its only stable iso ...
ions from brine replace the calcium and magnesium ions on the beads.
De-icing
In lower temperatures, a brine solution can be used to de-ice
Deicing is the process of removing snow, ice or frost from a surface. Anti-icing is the application of chemicals that not only deice but also remain on a surface and continue to delay the reformation of ice for a certain period of time, or prev ...
or reduce freezing temperatures on roads.
Wastewater
Brine is a byproduct of many industrial processes, such as desalination
Desalination is a process that takes away mineral components from saline water. More generally, desalination refers to the removal of salts and minerals from a target substance, as in Soil salinity control, soil desalination, which is an issue f ...
, power plant cooling tower
A cooling tower is a device that rejects waste heat to the atmosphere through the cooling of a coolant stream, usually a water stream to a lower temperature. Cooling towers may either use the evaporation of water to remove process heat an ...
s, produced water
Produced water is a term used in the oil industry or geothermal industry to describe water that is produced as a byproduct during the extraction of oil and natural gas, or used as a medium for heat extraction. Produced water is the kind of brackis ...
from oil and natural gas
Natural gas (also called fossil gas or simply gas) is a naturally occurring mixture of gaseous hydrocarbons consisting primarily of methane in addition to various smaller amounts of other higher alkanes. Low levels of trace gases like carbo ...
extraction, acid mine or acid rock drainage, reverse osmosis
Reverse osmosis (RO) is a water purification process that uses a partially permeable membrane to separate ions, unwanted molecules and larger particles from drinking water. In reverse osmosis, an applied pressure is used to overcome osmotic pre ...
reject, chlor-alkali
The chloralkali process (also chlor-alkali and chlor alkali) is an industrial process for the electrolysis of sodium chloride (NaCl) solutions. It is the technology used to produce chlorine and sodium hydroxide (caustic soda), which are commodit ...
wastewater treatment, pulp and paper mill effluent, and waste streams from food and beverage processing. Along with diluted salts, it can contain residues of pretreatment and cleaning chemicals, their reaction byproducts and heavy metals due to corrosion.
Wastewater brine can pose a significant environmental hazard, both due to corrosive and sediment-forming effects of salts and toxicity of other chemicals diluted in it.
Unpolluted brine from desalination plants and cooling towers can be returned to the ocean. To limit the environmental impact, it can be diluted with another stream of water, such as the outfall of a wastewater treatment
Wastewater treatment is a process used to remove contaminants from wastewater and convert it into an effluent that can be returned to the water cycle. Once returned to the water cycle, the effluent creates an acceptable impact on the environme ...
or power plant. Since brine is heavier than seawater and would accumulate on the ocean bottom, it requires methods to ensure proper diffusion, such as installing underwater diffusers in the sewerage
Sewerage (or sewage system) is the infrastructure that conveys sewage or surface runoff (stormwater, meltwater, rainwater) using sewers. It encompasses components such as receiving drainage, drains, manholes, pumping stations, storm overflows, a ...
. Other methods include drying in evaporation pond
Evaporation ponds are artificial ponds with very large surface areas that are designed to efficiently evaporate water by sunlight and expose water to the ambient temperatures. Evaporation ponds are inexpensive to design making it ideal for multip ...
s, injecting to deep wells, and storing and reusing the brine for irrigation, de-icing or dust control purposes.[
Technologies for treatment of polluted brine include: membrane filtration processes, such as ]reverse osmosis
Reverse osmosis (RO) is a water purification process that uses a partially permeable membrane to separate ions, unwanted molecules and larger particles from drinking water. In reverse osmosis, an applied pressure is used to overcome osmotic pre ...
and forward osmosis
Forward osmosis (FO) is an osmotic process that, like reverse osmosis (RO), uses a semi-permeable membrane to effect separation of water from dissolved solutes. The driving force for this separation is an osmotic pressure gradient, such that a "d ...
; ion exchange processes such as electrodialysis
Electrodialysis (ED) is used to transport salt ions from one solution through ion-exchange membranes to another solution under the influence of an applied electric potential difference. This is done in a configuration called an electrodialysis ...
or weak acid cation exchange; or evaporation processes, such as thermal brine concentrators and crystallizers employing mechanical vapour recompression and steam. New methods for membrane brine concentration, employing osmotically assisted reverse osmosis and related processes, are beginning to gain ground as part of zero liquid discharge systems (ZLD).
Composition and purification
Brine consists of concentrated solution of Na+ and Cl− ions. Sodium chloride per se does not exist in water: it is fully ionized. Other cations found in various brines include K+, Mg2+, Ca2+, and Sr2+. The latter three are problematic because they form scale and they react with soaps. Aside from chloride, brines sometimes contain Br− and I− and, most problematically, . Purification steps often include the addition of calcium oxide to precipitate solid magnesium hydroxide together with gypsum (CaSO4), which can be removed by filtration. Further purification is achieved by fractional crystallization. The resulting purified salt is called evaporated salt or vacuum salt.
See also
*
*
* Brine pool
A brine pool, sometimes called an underwater lake, deepwater or brine lake, is a volume of brine collected in a seafloor depression. The pools are dense bodies of water that have a salinity that is three to eight times greater than the surrou ...
s – Anoxic pockets of high salinity on the ocean bottom
References
{{Authority control
Salts
Coolants
Refrigerants
Hydrology
Industrial minerals