Electrospray
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Electrospray
The name electrospray is used for an apparatus that employs electricity to disperse a liquid or for the fine aerosol resulting from this process. High voltage is applied to a liquid supplied through an emitter (usually a glass or metallic capillary). Ideally the liquid reaching the emitter tip forms a Taylor cone, which emits a liquid jet through its apex. Varicose waves on the surface of the jet lead to the formation of small and highly charged liquid droplets, which are radially dispersed due to Coulomb repulsion. History In the late 16th century William GilbertGilbert, W. (1628) De Magnete, Magneticisque Corporibus, et de Magno Magnete Tellure (On the Magnet and Magnetic Bodies, and on That Great Magnet the Earth), London, Peter Short set out to describe the behaviour of magnetic and electrostatic phenomena. He observed that, in the presence of a charged piece of amber, a drop of water deformed into a cone. This effect is clearly related to electrosprays, even though Gilbert ...
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Electrospray Close-up
The name electrospray is used for an apparatus that employs electricity to disperse a liquid or for the fine aerosol resulting from this process. High voltage is applied to a liquid supplied through an emitter (usually a glass or metallic capillary). Ideally the liquid reaching the emitter tip forms a Taylor cone, which emits a liquid jet through its apex. Varicose waves on the surface of the jet lead to the formation of small and highly charged liquid droplets, which are radially dispersed due to Coulomb's law, Coulomb repulsion. History In the late 16th century William Gilbert (astronomer), William GilbertGilbert, W. (1628) De Magnete, Magneticisque Corporibus, et de Magno Magnete Tellure (On the Magnet and Magnetic Bodies, and on That Great Magnet the Earth), London, Peter Short set out to describe the behaviour of magnetic and electrostatic phenomena. He observed that, in the presence of a charged piece of amber, a drop of water deformed into a cone. This effect is clearly re ...
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John Fenn (chemist)
John Bennett Fenn (June 15, 1917December 10, 2010) was an American professor of analytical chemistry who was awarded a share of the Nobel Prize in Chemistry in 2002. Fenn shared half of the award with Koichi Tanaka for their work in mass spectrometry. The other half of the 2002 award went to Kurt Wüthrich. Fenn's contributions specifically related to the development of electrospray ionization, now a commonly used technique for large molecules and routine liquid chromatography-tandem mass spectrometry. Early in his career, Fenn did research in the field of jet propulsion at Project SQUID, and focused on molecular beam studies. Fenn finished his career with more than 100 publications, including one book. Fenn was born in New York City, and moved to Kentucky with his family during the Great Depression. Fenn did his undergraduate work at Berea College, and received his PhD from Yale. He worked in industry at Monsanto and at private research labs before moving to academic posts includ ...
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Taylor Cone
A Taylor cone refers to the cone observed in electrospinning, electrospraying and hydrodynamic spray processes from which a jet of charged particles emanates above a threshold voltage. Aside from electrospray ionization in mass spectrometry, the Taylor cone is important in field-emission electric propulsion (FEEP) and colloid thrusters used in fine control and high efficiency (low power) thrust of spacecraft. History This cone was described by Sir Geoffrey Ingram Taylor in 1964 before electrospray was "discovered". This work followed on the work of Zeleny who photographed a cone-jet of glycerine in a strong electric field and the work of several others: Wilson and Taylor (1925), Nolan (1926) and Macky (1931). Taylor was primarily interested in the behavior of water droplets in strong electric fields, such as in thunderstorms. Formation When a small volume of electrically conductive liquid is exposed to an electric field, the shape of liquid starts to deform from the shape ...
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Liquid Metal Ion Source
A liquid metal ion source (LMIS) is an ion source which uses metal that is heated to the liquid state and used to form an electrospray to form ions. An electrospray Taylor cone is formed by the application of a strong electric field and ions are produced by field evaporation at the sharp tip of the cone, which has a high electric field. Ions from a LMIS are used in ion implantation and in focused ion beam instruments. Typically gallium is preferred for its low melting point, low vapor pressure, its relatively unreactive nature, and because the gallium ion is sufficiently heavy for ion milling. Development The LMIS technique originated in the development of colloid thruster spacecraft propulsion systems. Research beginning in the early 1960s showed that liquid metal can generate large numbers of ions. By the early 1970s, these results spawned the development of LMIS ion microprobes. Initially, in the development of this technique, the liquid metal was supplied by a capillary tube. Thi ...
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John Zeleny
John Zeleny (March 26, 1872 – June 19, 1951) was an American physicist who, in 1911, invented the Zeleny electroscope. He also studied the effect of an electric field on a liquid meniscus. His work is seen by some as a beginning to emergent technologies like liquid metal ion sources and electrospraying and electrospinning. Zeleny was born in Racine, Wisconsin to a Czech immigrant couple from Křídla. He was the older brother of Charles Zeleny. He attended the University of Minnesota (B.S., 1892), followed by Trinity College, Cambridge Trinity College is a constituent college of the University of Cambridge. Founded in 1546 by Henry VIII, King Henry VIII, Trinity is one of the largest Cambridge colleges, with the largest financial endowment of any college at either Cambridge ... (B.A., 1899), and the University of Minnesota (PhD, 1906). Zeleny began his teaching career at the University of Minnesota after earning his B.A. in 1892. In 1915, he joined the faculty at Yale, ...
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Jean-Antoine Nollet
Jean-Antoine Nollet (; 19 November 170025 April 1770) was a French clergyman and physicist who did a number of experiments with electricity and discovered osmosis. As a deacon in the Catholic Church, he was also known as Abbé Nollet. Biography Nollet studied humanities at the Collège de Clermont in Beauvais, starting in 1715. He completed a master's degree in the Faculty of Theology at the University of Paris in 1724. He was ordained a deacon in the Catholic Church in 1728, but suspended his clerical career. However he used the title of Abbé throughout his life. Nollet was particularly interested in the new science of electricity. He joined the Société des Arts in 1728, an association which was reestablished from a previous version which ended in 1723. Formed under the patronage of Comte de Clermont, the Société focused on applying natural philosophy to practical arts. This association gave Nollet the opportunity to come into contact with important natural philosophers. ...
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Aerosol
An aerosol is a suspension (chemistry), suspension of fine solid particles or liquid Drop (liquid), droplets in air or another gas. Aerosols can be natural or Human impact on the environment, anthropogenic. Examples of natural aerosols are fog or mist, dust, forest exudates, and geyser steam. Examples of anthropogenic aerosols include particulate air pollutants, mist from the discharge at Hydroelectric dam, hydroelectric dams, Irrigation, irrigation mist, Perfume, perfume from atomizers, smoke, steam from a kettle, Pesticide, sprayed pesticides, and medical treatments for respiratory illnesses. When a person inhales the contents of a vape pen or e-cigarette, they are inhaling an Human impact on the environment, anthropogenic aerosol. The liquid or solid particles in an aerosol have diameters typically less than micrometre, 1 μm (larger particles with a significant settling speed make the mixture a Suspension (chemistry), suspension, but the distinction is not clear-cut) ...
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Colloids
A colloid is a mixture in which one substance consisting of microscopically dispersed insoluble particles is suspended throughout another substance. Some definitions specify that the particles must be dispersed in a liquid, while others extend the definition to include substances like aerosols and gels. The term colloidal suspension refers unambiguously to the overall mixture (although a narrower sense of the word ''suspension'' is distinguished from colloids by larger particle size). A colloid has a dispersed phase (the suspended particles) and a continuous phase (the medium of suspension). The dispersed phase particles have a diameter of approximately 1 nanometre to 1 micrometre. Some colloids are translucent because of the Tyndall effect, which is the scattering of light by particles in the colloid. Other colloids may be opaque or have a slight color. Colloidal suspensions are the subject of interface and colloid science. This field of study was introduced in 1845 by Italian ...
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Nanotechnology
Nanotechnology, also shortened to nanotech, is the use of matter on an atomic, molecular, and supramolecular scale for industrial purposes. The earliest, widespread description of nanotechnology referred to the particular technological goal of precisely manipulating atoms and molecules for fabrication of macroscale products, also now referred to as molecular nanotechnology. A more generalized description of nanotechnology was subsequently established by the National Nanotechnology Initiative, which defined nanotechnology as the manipulation of matter with at least one dimension sized from 1 to 100 nanometers (nm). This definition reflects the fact that quantum mechanical effects are important at this quantum-realm scale, and so the definition shifted from a particular technological goal to a research category inclusive of all types of research and technologies that deal with the special properties of matter which occur below the given size threshold. It is therefore common to ...
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Satellite
A satellite or artificial satellite is an object intentionally placed into orbit in outer space. Except for passive satellites, most satellites have an electricity generation system for equipment on board, such as solar panels or radioisotope thermoelectric generators (RTGs). Most satellites also have a method of communication to ground stations, called Transponder (satellite communications), transponders. Many satellites use a Satellite bus, standardized bus to save cost and work, the most popular of which is small CubeSats. Similar satellites can work together as a group, forming Satellite constellation, constellations. Because of the high launch cost to space, satellites are designed to be as lightweight and robust as possible. Most communication satellites are radio Broadcast relay station, relay stations in orbit and carry dozens of transponders, each with a bandwidth of tens of megahertz. Satellites are placed from the surface to orbit by launch vehicles, high enough to ...
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Rocket Engine
A rocket engine uses stored rocket propellants as the reaction mass for forming a high-speed propulsive jet of fluid, usually high-temperature gas. Rocket engines are reaction engines, producing thrust by ejecting mass rearward, in accordance with Newton's third law. Most rocket engines use the combustion of reactive chemicals to supply the necessary energy, but non-combusting forms such as cold gas thrusters and nuclear thermal rockets also exist. Vehicles propelled by rocket engines are commonly called rockets. Rocket vehicles carry their own oxidiser, unlike most combustion engines, so rocket engines can be used in a vacuum to propel spacecraft and ballistic missiles. Compared to other types of jet engine, rocket engines are the lightest and have the highest thrust, but are the least propellant-efficient (they have the lowest specific impulse). The ideal exhaust is hydrogen, the lightest of all elements, but chemical rockets produce a mix of heavier species, reducing the e ...
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Electrically Powered Spacecraft Propulsion
Spacecraft electric propulsion (or just electric propulsion) is a type of spacecraft propulsion technique that uses electrostatic or electromagnetic fields to accelerate mass to high speed and thus generate thrust to modify the velocity of a spacecraft in orbit. The propulsion system is controlled by power electronics. Electric thrusters typically use much less propellant than chemical rockets because they have a higher exhaust speed (operate at a higher specific impulse) than chemical rockets.Choueiri, Edgar Y. (2009New dawn of electric rocket''Scientific American'' 300, 58–65 Due to limited electric power the thrust is much weaker compared to chemical rockets, but electric propulsion can provide thrust for a longer time. Electric propulsion was first successfully demonstrated by NASA and is now a mature and widely used technology on spacecraft. American and Russian satellites have used electric propulsion for decades. , over 500 spacecraft operated throughout the Sola ...
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