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Copper Monosulfide
Copper monosulfide is a chemical compound of copper and sulfur. It was initially thought to occur in nature as the dark indigo blue mineral covellite. However, it was later shown to be rather a cuprous compound, formula Cu+3S(S2).Liang, W., Whangbo, M.H. (1993) ''Conductivity anisotropy and structural phase transition in Covellite CuS'' Solid State Communications, 85(5), 405-408 CuS is a moderate conductor of electricity.Wells A.F. (1962) ''Structural Inorganic Chemistry'' 3d edition Oxford University Press A black colloidal precipitate of CuS is formed when hydrogen sulfide, H2S, is bubbled through solutions of Cu(II) salts. It is one of a number of binary compounds of copper and sulfur (see copper sulfide for an overview of this subject), and has attracted interest because of its potential uses in catalysis and photovoltaics. Manufacturing Copper monosulfide can be prepared by passing hydrogen sulfide gas into a solution of copper(II) salt. Alternatively, it can be prepared by ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Covellite
Covellite (also known as covelline) is a rare copper sulfide mineral with the formula CuS. This indigo blue mineral is commonly a secondary mineral in limited abundance and although it is not an important ore of copper itself, it is well known to mineral collectors. The mineral is generally found in zones of secondary enrichment ( supergene) of copper sulfide deposits. Commonly found as coatings on chalcocite, chalcopyrite, bornite, enargite, pyrite, and other sulfides, it often occurs as pseudomorphic replacements of other minerals. The first records are from Mount Vesuvius, formally named in 1832 after N. Covelli. Composition Covellite belongs to the binary copper sulfides group, which has the formula CuxSy and can have a wide-ranging copper/sulfur ratio, from 1:2 to 2:1 (Cu/S). However, this series is by no means continuous and the homogeneity range of covellite CuS is narrow. Materials rich in sulfur CuSx where x~ 1.1- 1.2 do exist, but they exhibit " superstructures", a m ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Copper(II) Chloride
Copper(II) chloride is the chemical compound with the chemical formula CuCl2. The anhydrous form is yellowish brown but slowly absorbs moisture to form a blue-green dihydrate. Both the anhydrous and the dihydrate forms occur naturally as the very rare minerals tolbachite and eriochalcite, respectively.Marlene C. Morris, Howard F. McMurdie, Eloise H. Evans, Boris Paretzkin, Harry S. Parker, and Nicolas C. Panagiotopoulos (1981) ''Copper chloride hydrate (eriochalcite)'', in Standard X-ray Diffraction Powder PatternsNational Bureau of Standards, Monograph 25, Section 18; page 33. Structure Anhydrous CuCl2 adopts a distorted cadmium iodide structure. In this motif, the copper centers are octahedral. Most copper(II) compounds exhibit distortions from idealized octahedral geometry due to the Jahn-Teller effect, which in this case describes the localization of one d-electron into a molecular orbital that is strongly antibonding with respect to a pair of chloride ligands. In CuCl2·2H ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Octet Rule
The octet rule is a chemical rule of thumb that reflects the theory that main-group elements tend to bond in such a way that each atom has eight electrons in its valence shell, giving it the same electronic configuration as a noble gas. The rule is especially applicable to carbon, nitrogen, oxygen, and the halogens; although more generally the rule is applicable for the s-block and p-block of the periodic table. Other rules exist for other elements, such as the duplet rule for hydrogen and helium, or the 18-electron rule for transition metals. The valence electrons can be counted using a Lewis electron dot diagram as shown at the right for carbon dioxide. The electrons shared by the two atoms in a covalent bond are counted twice, once for each atom. In carbon dioxide each oxygen shares four electrons with the central carbon, two (shown in red) from the oxygen itself and two (shown in black) from the carbon. All four of these electrons are counted in both the carbon octet and the ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
X-ray Photoelectron Spectroscopy
X-ray photoelectron spectroscopy (XPS) is a surface-sensitive quantitative spectroscopic technique based on the photoelectric effect that can identify the elements that exist within a material (elemental composition) or are covering its surface, as well as their chemical state, and the overall electronic structure and density of the electronic states in the material. XPS is a powerful measurement technique because it not only shows what elements are present, but also what other elements they are bonded to. The technique can be used in line profiling of the elemental composition across the surface, or in depth profiling when paired with Ion beam#Ion beam etching or sputtering, ion-beam etching. It is often applied to study chemical processes in the materials in their as-received state or after cleavage, scraping, exposure to heat, reactive gasses or solutions, ultraviolet light, or during ion implantation. XPS belongs to the family of Photoemission spectroscopy, photoemission spect ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
CuSe , the university's athletic program
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Cuse may refer to: People * Carlton Cuse (born 1959), American screenwriter, producer and director Places * Cuse-et-Adrisans, France * Syracuse, New York ** Syracuse University, in the above city ** Syracuse Orange The Syracuse Orange are the athletic teams that represent Syracuse University. The school is a member of NCAA Division I and the Atlantic Coast Conference. Until 2013, Syracuse was a member of the Big East Conference. The school's mascot is Ott ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Copper(II) Oxide
Copper(II) oxide or cupric oxide is an inorganic compound with the formula CuO. A black solid, it is one of the two stable oxides of copper, the other being Cu2O or copper(I) oxide (cuprous oxide). As a mineral, it is known as tenorite. It is a product of copper mining and the precursor to many other copper-containing products and chemical compounds. Production It is produced on a large scale by pyrometallurgy, as one stage in extracting copper from its ores. The ores are treated with an aqueous mixture of ammonium carbonate, ammonia, and oxygen to give copper(I) and copper(II) ammine complexes, which are extracted from the solids. These complexes are decomposed with steam to give CuO. It can be formed by heating copper in air at around 300–800°C: : 2 Cu + O2 → 2 CuO For laboratory uses, pure copper(II) oxide is better prepared by heating copper(II) nitrate, copper(II) hydroxide, or basic copper(II) carbonate: : 2 Cu(NO3)2(s) → 2 CuO(s) + 4 NO2(g) + O2(g) (180° ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Space Group
In mathematics, physics and chemistry, a space group is the symmetry group of an object in space, usually in three dimensions. The elements of a space group (its symmetry operations) are the rigid transformations of an object that leave it unchanged. In three dimensions, space groups are classified into 219 distinct types, or 230 types if chiral copies are considered distinct. Space groups are discrete cocompact groups of isometries of an oriented Euclidean space in any number of dimensions. In dimensions other than 3, they are sometimes called Bieberbach groups. In crystallography, space groups are also called the crystallographic or Fedorov groups, and represent a description of the symmetry of the crystal. A definitive source regarding 3-dimensional space groups is the ''International Tables for Crystallography'' . History Space groups in 2 dimensions are the 17 wallpaper groups which have been known for several centuries, though the proof that the list was complete was only ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Thiourea
Thiourea () is an organosulfur compound with the formula and the structure . It is structurally similar to urea (), except that the oxygen atom is replaced by a sulfur atom (as implied by the ''thio-'' prefix); however, the properties of urea and thiourea differ significantly. Thiourea is a reagent in organic synthesis. "Thioureas" refer to a broad class of compounds with the general structure . Thioureas are related to thioamides, e.g. , where R is methyl, ethyl, etc. Structure and bonding Thiourea is a planar molecule. The C=S bond distance is 1.71 Å. The C-N distances average 1.33 Å. The weakening of the C-S bond by C-N pi-bonding is indicated by the short C=S bond in thiobenzophenone, which is 1.63 Å. Thiourea occurs in two tautomeric forms, of which the thione form predominates in aqueous solutions. The equilibrium constant has been calculated as ''K''eq is . The thiol form, which is also known as an isothiourea, can be encountered in substituted compounds such as i ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Ethylenediamine
Ethylenediamine (abbreviated as en when a ligand) is the organic compound with the formula C2H4(NH2)2. This colorless liquid with an ammonia-like odor is a basic amine. It is a widely used building block in chemical synthesis, with approximately 500,000 tonnes produced in 1998.Karsten Eller, Erhard Henkes, Roland Rossbacher, Hartmut Höke "Amines, Aliphatic" in Ullmann's Encyclopedia of Industrial Chemistry, 2005 Wiley-VCH Verlag, Weinheim. Ethylenediamine is the first member of the so-called polyethylene amines. Synthesis Ethylenediamine is produced industrially by treating 1,2-dichloroethane with ammonia under pressure at 180 °C in an aqueous medium:Hans-Jürgen Arpe, Industrielle Organische Chemie, 6. Auflage (2007), Seite 245, Wiley VCH : In this reaction hydrogen chloride is generated, which forms a salt with the amine. The amine is liberated by addition of sodium hydroxide and can then be recovered by . Diethylenetriamine (DETA) and triethylenetetramine (TETA) a ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Raman Spectroscopy
Raman spectroscopy () (named after Indian physicist C. V. Raman) is a spectroscopic technique typically used to determine vibrational modes of molecules, although rotational and other low-frequency modes of systems may also be observed. Raman spectroscopy is commonly used in chemistry to provide a structural fingerprint by which molecules can be identified. Raman spectroscopy relies upon inelastic scattering of photons, known as Raman scattering. A source of monochromatic light, usually from a laser in the visible, near infrared, or near ultraviolet range is used, although X-rays can also be used. The laser light interacts with molecular vibrations, phonons or other excitations in the system, resulting in the energy of the laser photons being shifted up or down. The shift in energy gives information about the vibrational modes in the system. Infrared spectroscopy typically yields similar yet complementary information. Typically, a sample is illuminated with a laser beam. Electr ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Copper Sulfate
Copper sulfate may refer to: * Copper(II) sulfate, CuSO4, a common compound used as a fungicide and herbicide * Copper(I) sulfate Copper(I) sulfate, also known as cuprous sulfate, is an inorganic compound with the chemical formula Cu2 SO4. It is a white solid that has attracted little attention, in contrast to copper(II) sulfate. It is an unusual example of a copper(I) ..., Cu2SO4, which is uncommonly used * Copper(II) sulfate, CuSO4 is greenish blue Copper compounds {{Chem-stub ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
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