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White Cross (chemical Warfare)
White Cross (Weiẞkreuz) is a World War I chemical warfare agent consisting of one or more lachrymatory agents: bromoacetone (BA), bromobenzyl cyanide (Camite), bromomethyl ethyl ketone (homomartonite, Bn-stoff), chloroacetone (Tonite, A-stoff), ethyl bromoacetate, and/or xylyl bromide. During World War I, White Cross was also a generic code name used by the German Army for artillery shells with an irritant chemical payload affecting the eyes and mucous membranes. See also * Blue Cross (chemical warfare) * Green Cross (chemical warfare) * Yellow Cross (chemical warfare) Yellow Cross (Gelbkreuz) is a World War I chemical warfare agent usually based on sulfur mustard (mustard gas, HS, Yperite, Lost). The original Gelbkreuz was a composition of 80–90% of sulfur mustard and 10–20% of tetrachloromethane or chlor ... References Lachrymatory agents World War I chemical weapons {{weapon-stub ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
World War I
World War I (28 July 1914 11 November 1918), often abbreviated as WWI, was one of the deadliest global conflicts in history. Belligerents included much of Europe, the Russian Empire, the United States, and the Ottoman Empire, with fighting occurring throughout Europe, the Middle East, Africa, the Pacific, and parts of Asia. An estimated 9 million soldiers were killed in combat, plus another 23 million wounded, while 5 million civilians died as a result of military action, hunger, and disease. Millions more died in genocides within the Ottoman Empire and in the 1918 influenza pandemic, which was exacerbated by the movement of combatants during the war. Prior to 1914, the European great powers were divided between the Triple Entente (comprising France, Russia, and Britain) and the Triple Alliance (containing Germany, Austria-Hungary, and Italy). Tensions in the Balkans came to a head on 28 June 1914, following the assassination of Archduke Franz Ferdin ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Chemical Warfare
Chemical warfare (CW) involves using the toxic properties of chemical substances as weapons. This type of warfare is distinct from nuclear warfare, biological warfare and radiological warfare, which together make up CBRN, the military acronym for chemical, biological, radiological, and nuclear (warfare or weapons), all of which are considered "weapons of mass destruction" (WMDs), a term that contrasts with conventional weapons. The use of chemical weapons is prohibited under customary international humanitarian law. Definition Chemical warfare is different from the use of conventional weapons or nuclear weapons because the destructive effects of chemical weapons are not primarily due to any explosive force. The offensive use of living organisms (such as anthrax) is considered biological warfare rather than chemical warfare; however, the use of nonliving toxic products produced by living organisms (e.g. toxins such as botulinum toxin, ricin, and saxitoxin) ''is'' consider ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Lachrymatory Agent
Tear gas, also known as a lachrymator agent or lachrymator (), sometimes colloquially known as "mace" after the early commercial aerosol, is a chemical weapon that stimulates the nerves of the lacrimal gland in the eye to produce tears. In addition, it can cause severe eye and respiratory pain, skin irritation, bleeding, and blindness. Common lachrymators both currently and formerly used as tear gas include pepper spray (OC gas), PAVA spray (nonivamide), CS gas, CR gas, CN gas (phenacyl chloride), bromoacetone, xylyl bromide and Mace (a branded mixture). While lachrymatory agents are commonly deployed for riot control by law enforcement and military personnel, its use in warfare is prohibited by various international treaties.E.g. the Geneva Protocol of 1925 prohibited the use of "asphyxiating gas, or any other kind of gas, liquids, substances or similar materials". During World War I, increasingly toxic and deadly lachrymatory agents were used. The short and long-term effec ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Bromoacetone
Bromoacetone is an organic compound with the formula . It is a colorless liquid although impure samples appear yellow or even brown. It is a lachrymatory agent and a precursor to other organic compounds. Occurrence in nature Bromoacetone is present (less than 1%) in the essential oil of a seaweed (''Asparagopsis taxiformis'') from the vicinity of the Hawaiian Islands. Synthesis Bromoacetone is available commercially, sometimes stabilized with magnesium oxide. It was first described in the 19th century, attributed to N. Sokolowsky. Bromoacetone is prepared by combining bromine and acetone, with catalytic acid. As with all ketones, acetone enolizes in the presence of acids or bases. The alpha carbon then undergoes electrophilic substitution with bromine. The main difficulty with this method is over-bromination, resulting in di- and tribrominated products. If a base is present, bromoform is obtained instead, by the haloform reaction. Applications It was used in World War I as ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Bromobenzyl Cyanide
Bromobenzyl cyanide (BBC) is an obsolete lachrymatory agent introduced in World War I by the Allied Powers. When implemented in World War I, it revolutionized the use of tear agents due to their extreme potency. BBC is toxic like chlorine gas.AMOS A. FRIES and CLARENCE J. WEST. CHEMICAL WARFARE - First Edition. p 142-143 See also *Chloroacetophenone *CR gas *CS gas *Lachrymatory agent Tear gas, also known as a lachrymator agent or lachrymator (), sometimes colloquially known as "mace" after the early commercial aerosol, is a chemical weapon that stimulates the nerves of the lacrimal gland in the eye to produce tears. In ad ... References External links * * Benzene derivatives Lachrymatory agents Nitriles Organobromides {{aromatic-stub ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Bromomethyl Ethyl Ketone
Bromomethyl ethyl ketone is a brominated ketone with lachrymatory effects. It was used as a chemical warfare agent in World War I. Bromomethyl ethyl ketone was developed as an alternative to bromoacetone, because acetone, the precursor to bromoacetone, was required for explosives production. See also *Bromoacetone *Chloroacetone *Iodoacetone *Bromobenzyl cyanide *Chloroacetophenone * Ethyl bromoacetate *Ethyl iodoacetate Ethyl iodoacetate is a chemical compound that is a derivative of ethyl acetate. Under normal conditions, the compound is a clear, light yellow to orange liquid. Applications Used by the British during World War I, it was codenamed SK gas, for the ... References Lachrymatory agents Ketones Organobromides World War I chemical weapons {{Organohalide-stub ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Chloroacetone
Chloroacetone is a chemical compound with the formula . At STP it is a colourless liquid with a pungent odour. On exposure to light, it turns to a dark yellow-amber colour. It was used as a tear gas in World War I. Synthesis Chloroacetone may be synthesized from the reaction between chlorine and diketene, or by the chlorination of acetone. Applications Chloroacetone is used to make dye couplers for colour photography, and is an intermediate in chemical manufacturing. It is also used in the Feist-Benary synthesis of furans. *Reaction of phenoxide with chloroacetone gives phenoxyacetone, which is used to make a wide variety of different pharmaceuticals. A catalytic amount of potassium iodide is also necessary to facilitate a Finkelstein reaction. Purification Chloroacetone purchased from commercial suppliers contains 5% impurities including mesityl oxide, which is not removed by distillation. Mesityl oxide can be oxidized using acidified KMnO4 to form a diol (followed by s ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Ethyl Bromoacetate
Ethyl bromoacetate is the chemical compound with the formula CH2BrCO2C2H5. It is the ethyl ester of bromoacetic acid and is prepared in two steps from acetic acid. It is a lachrymator and has a fruity, pungent odor. It is also a highly toxic alkylating agent and may be fatal if inhaled. Applications Ethyl bromoacetate is listed by the World Health Organization as a riot control agent, and was first employed for that purpose by French police in 1912. The French army used rifle grenades 'grenades lacrymogènes' filled with this gas against the Germans beginning in August 1914, but the weapons were largely ineffective, even though ethyl bromoacetate is twice as toxic as chlorine. In the early months of the war the British also used the weaponized use of tear gas agents and more toxic gasses including sulfur dioxide. The German army then used these attacks to justify their subsequent employment of it as odorant or warning agent in odorless, toxic gases and chemical weapons in 1915 und ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Xylyl Bromide
Xylyl bromide, also known as methylbenzyl bromide or T-stoff ('substance-T'), is any member or a mixture of organic chemical compounds with the molecular formula C6 H4(CH3)(CH2 Br). The mixture was formerly used as a tear gas and has an odor reminiscent of lilac. All members and the mixture are colourless liquids, although commercial or older samples appear yellowish. Use as a weapon Xylyl bromide is an irritant and lachrymatory agent. It has been incorporated in chemical weapons since the early months of World War I. Some commentators say the first use was in August 1914, when the French attacked German soldiers with tear gas grenades, but the agent used in that incident was more likely to be ethyl bromoacetate, which the French had tested before the war. The first extensive use of xylyl bromide was the firing by German forces of 18,000 "T-shells" at Russian positions in the Battle of Bolimów in January 1915. The shells were modified 15 cm (6 inch) artillery shells ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
German Army (German Empire)
The Imperial German Army (1871–1919), officially referred to as the German Army (german: Deutsches Heer), was the unified ground and air force of the German Empire. It was established in 1871 with the political unification of Germany under the leadership of Prussia, and was dissolved in 1919, after the defeat of the German Empire in World War I (1914–1918). In the Federal Republic of Germany, the term ' identifies the German Army, the land component of the '. Formation and name The states that made up the German Empire contributed their armies; within the German Confederation, formed after the Napoleonic Wars, each state was responsible for maintaining certain units to be put at the disposal of the Confederation in case of conflict. When operating together, the units were known as the Federal Army ('). The Federal Army system functioned during various conflicts of the 19th century, such as the First Schleswig War from 1848–50 but by the time of the Second Schleswig Wa ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Blue Cross (chemical Warfare)
Blue Cross (Blaukreuz) is a World War I chemical warfare agent consisting of diphenylchloroarsine (DA, Clark I), diphenylcyanoarsine (CDA, Clark II), ethyldichloroarsine (Dick), and/or methyldichloroarsine (Methyldick). Clark I and Clark II were the main agents used. Clark I was used with Green Cross munition earlier; however for the first time it was used as a standalone agent in the night from July 10 to July 11 1917 at Nieuwpoort, Belgium, during "Operation Strandfest". The artillery munition used as a delivery vehicle contained a large amount of glass spheres closed with a cork and sealed with trinitrotoluene (TNT). Later N-ethylcarbazole was added. Depending on the caliber, the munition contained between 7 and 120 kilograms of the agent. Blue Cross is also a generic World War I German marking for artillery shells with chemical payload affecting the upper respiratory tract. See also * Green Cross (chemical warfare) * Yellow Cross (chemical warfare) * White Cross (chemic ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Green Cross (chemical Warfare)
Green Cross (Grünkreuz) is a World War I chemical warfare pulmonary agent consisting of chloropicrin (PS, Aquinite, Klop), phosgene (CG, Collongite) and/or trichloromethyl chloroformate (Surpalite, Perstoff). Green Cross is also a generic World War I German marking for artillery shells with pulmonary agents (chemical payload affecting the lungs). The tip of the projectile with the fuse end painted green and a green cross at the bottom of the cartridge. Other Green Cross mixtures were based on phosgene and/or diphosgene. The first use of Green Cross was on May 31 1915 in a German offensive in Ypres. The mixture was chlorine-phosgene, with 95% and 5%. See also * Blue Cross (chemical warfare) * Yellow Cross (chemical warfare) * White Cross (chemical warfare) White Cross (Weiẞkreuz) is a World War I chemical warfare agent consisting of one or more lachrymatory agents: bromoacetone (BA), bromobenzyl cyanide (Camite), bromomethyl ethyl ketone (homomartonite, Bn-stoff), ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
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