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Unitized Regenerative Fuel Cell
A unitized regenerative fuel cell (URFC) is a fuel cell based on the proton exchange membrane which can do the electrolysis of water in regenerative mode and function in the other mode as a fuel cell recombining oxygen and hydrogen gas to produce electricity. Both modes are done with the same fuel cell stack By definition, the process of any fuel cell could be reversed. However, a given device is usually optimized for operating in one mode and may not be built in such a way that it can be operated backwards. Fuel cells operated backwards generally do not make very efficient systems unless they are purpose-built to do so as in high pressure electrolyzers, unitized regenerative fuel cells and regenerative fuel cells. History Livermore physicist Fred Mitlitsky studied the possibilities of reversible technology. In the mid-1990s Mitlitsky received some funding from NASA for development of Helios and from the Department of Energy for leveling peak and intermittent power usage with s ...
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Fuel Cell
A fuel cell is an electrochemical cell that converts the chemical energy of a fuel (often hydrogen) and an oxidizing agent (often oxygen) into electricity through a pair of redox reactions. Fuel cells are different from most batteries in requiring a continuous source of fuel and oxygen (usually from air) to sustain the chemical reaction, whereas in a battery the chemical energy usually comes from substances that are already present in the battery. Fuel cells can produce electricity continuously for as long as fuel and oxygen are supplied. The first fuel cells were invented by Sir William Grove in 1838. The first commercial use of fuel cells came more than a century later following the invention of the hydrogen–oxygen fuel cell by Francis Thomas Bacon in 1932. The alkaline fuel cell, also known as the Bacon fuel cell after its inventor, has been used in NASA space programs since the mid-1960s to generate power for satellites and space capsules. Since then, fuel cells have b ...
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Proton Exchange Membrane
A proton-exchange membrane, or polymer-electrolyte membrane (PEM), is a semipermeable membrane generally made from ionomers and designed to conduct protons while acting as an electronic insulator and reactant barrier, e.g. to oxygen and hydrogen gas. This is their essential function when incorporated into a membrane electrode assembly (MEA) of a proton-exchange membrane fuel cell or of a proton-exchange membrane electrolyser: separation of reactants and transport of protons while blocking a direct electronic pathway through the membrane. PEMs can be made from either pure polymer membranes or from composite membranes, where other materials are embedded in a polymer matrix. One of the most common and commercially available PEM materials is the fluoropolymer (PFSA) Nafion, a DuPont product. While Nafion is an ionomer with a perfluorinated backbone like Teflon, there are many other structural motifs used to make ionomers for proton-exchange membranes. Many use polyaromatic polymers, ...
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Electrolysis Of Water
Electrolysis of water, also known as electrochemical water splitting, is the process of using electricity to decompose water into oxygen and hydrogen gas by electrolysis. Hydrogen gas released in this way can be used as hydrogen fuel, or remixed with the oxygen to create oxyhydrogen gas, which is used in welding and other applications. Electrolysis of water requires a minimum potential difference of 1.23 volts, though at that voltage external heat is required. E lectrolysis is rarely used in industrial applications since hydrogen can be produced less expensively from fossil fuels. History In 1789, Jan Rudolph Deiman and Adriaan Paets van Troostwijk used an electrostatic machine to make electricity that was discharged on gold electrodes in a Leyden jar with water. In 1800 Alessandro Volta invented the voltaic pile, and a few weeks later English scientists William Nicholson and Anthony Carlisle used it to electrolyse water. In 1806 Humphry Davy reported the results of ext ...
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Regenerative Fuel Cell
A regenerative fuel cell or reverse fuel cell (RFC) is a fuel cell run in reverse mode, which consumes electricity and chemical B to produce chemical A. By definition, the process of any fuel cell could be reversed. However, a given device is usually optimized for operating in one mode and may not be built in such a way that it can be operated backwards. Standard fuel cells operated backwards generally do not make very efficient systems unless they are purpose-built to do so as with high-pressure electrolysers, regenerative fuel cells, solid-oxide electrolyser cells and unitized regenerative fuel cells. Process description A hydrogen fueled proton exchange membrane fuel cell, for example, uses hydrogen gas (H2) and oxygen (O2) to produce electricity and water (H2O); a regenerative hydrogen fuel cell uses electricity and water to produce hydrogen and oxygen. When the fuel cell is operated in regenerative mode, the anode for the electricity production mode (fuel cell mode) becomes th ...
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Hydrogen Gas
Hydrogen is the chemical element with the symbol H and atomic number 1. Hydrogen is the lightest element. At standard conditions hydrogen is a gas of diatomic molecules having the formula . It is colorless, odorless, tasteless, non-toxic, and highly combustible. Hydrogen is the most abundant chemical substance in the universe, constituting roughly 75% of all normal matter.However, most of the universe's mass is not in the form of baryons or chemical elements. See dark matter and dark energy. Stars such as the Sun are mainly composed of hydrogen in the plasma state. Most of the hydrogen on Earth exists in molecular forms such as water and organic compounds. For the most common isotope of hydrogen (symbol 1H) each atom has one proton, one electron, and no neutrons. In the early universe, the formation of protons, the nuclei of hydrogen, occurred during the first second after the Big Bang. The emergence of neutral hydrogen atoms throughout the universe occurred about 370,000 ...
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High Pressure Electrolysis
High-pressure electrolysis (HPE) is the electrolysis of water by decomposition of water (H2O) into oxygen (O2) and hydrogen gas (H2) due to the passing of an electric current through the water. The difference with a standard proton exchange membrane electrolyzer is the compressed hydrogen output around at 70 °C. By pressurising the hydrogen in the electrolyser the need for an external hydrogen compressor is eliminated, the average energy consumption for internal differential pressure compression is around 3%. Approaches As the required compression power for water is less than that for hydrogen-gas the water is pumped up to a high-pressure, in the other approach differential pressure is used. There is also an importance for the electrolyser stacks to be able to accept a fluctuating electrical input, such as that found with renewable energy. This then enables the ability to help with grid balancing and energy storage. Ultrahigh-pressure electrolysis Ultrahigh-pressure elec ...
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Regenerative Fuel Cell
A regenerative fuel cell or reverse fuel cell (RFC) is a fuel cell run in reverse mode, which consumes electricity and chemical B to produce chemical A. By definition, the process of any fuel cell could be reversed. However, a given device is usually optimized for operating in one mode and may not be built in such a way that it can be operated backwards. Standard fuel cells operated backwards generally do not make very efficient systems unless they are purpose-built to do so as with high-pressure electrolysers, regenerative fuel cells, solid-oxide electrolyser cells and unitized regenerative fuel cells. Process description A hydrogen fueled proton exchange membrane fuel cell, for example, uses hydrogen gas (H2) and oxygen (O2) to produce electricity and water (H2O); a regenerative hydrogen fuel cell uses electricity and water to produce hydrogen and oxygen. When the fuel cell is operated in regenerative mode, the anode for the electricity production mode (fuel cell mode) becomes th ...
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Lawrence Livermore National Laboratory
Lawrence Livermore National Laboratory (LLNL) is a federal research facility in Livermore, California, United States. The lab was originally established as the University of California Radiation Laboratory, Livermore Branch in 1952 in response to the detonation of the first atomic bomb by the Soviet Union during the Cold War. It later became autonomous in 1971 and was designated a national laboratory in 1981. A federally funded research and development center, Lawrence Livermore Lab is primarily funded by the U.S. Department of Energy and it is managed privately and operated by Lawrence Livermore National Security, LLC (a partnership of the University of California), Bechtel, BWX Technologies, AECOM, and Battelle Memorial Institute in affiliation with the Texas A&M University System. In 2012, the laboratory had the synthetic chemical element livermorium (element 116) named after it. Overview LLNL is self-described as a "premier research and development institution for sci ...
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NASA
The National Aeronautics and Space Administration (NASA ) is an independent agency of the US federal government responsible for the civil space program, aeronautics research, and space research. NASA was established in 1958, succeeding the National Advisory Committee for Aeronautics (NACA), to give the U.S. space development effort a distinctly civilian orientation, emphasizing peaceful applications in space science. NASA has since led most American space exploration, including Project Mercury, Project Gemini, the 1968-1972 Apollo Moon landing missions, the Skylab space station, and the Space Shuttle. NASA supports the International Space Station and oversees the development of the Orion spacecraft and the Space Launch System for the crewed lunar Artemis program, Commercial Crew spacecraft, and the planned Lunar Gateway space station. The agency is also responsible for the Launch Services Program, which provides oversight of launch operations and countdown management f ...
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NASA Helios
The Helios Prototype was the fourth and final aircraft developed as part of an evolutionary series of Solar energy, solar- and fuel cell, fuel-cell-system-powered unmanned aerial vehicles. AeroVironment, AeroVironment, Inc. developed the vehicles under NASA's NASA ERAST Program, Environmental Research Aircraft and Sensor Technology (ERAST) program. They were built to develop the technologies that would allow long-term, high-altitude aircraft to serve as atmospheric satellites, to perform atmospheric research tasks as well as serve as communications platforms. It was developed from the NASA Pathfinder and NASA Centurion aircraft. Helios Prototype The NASA Centurion was modified into the Helios Prototype configuration by adding a sixth wing section and a fifth landing gear and systems pod, becoming the fourth configuration in the series of solar-powered flying wing demonstrator aircraft developed by AeroVironment under the ERAST project. The larger wing on the Helios Prototype acc ...
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United States Department Of Energy
The United States Department of Energy (DOE) is an executive department of the U.S. federal government that oversees U.S. national energy policy and manages the research and development of nuclear power and nuclear weapons in the United States. The DOE oversees the U.S. nuclear weapons program, nuclear reactor production for the United States Navy, energy-related research, and domestic energy production and energy conservation. The DOE was created in 1977 in the aftermath of the 1973 oil crisis. It sponsors more physical science research than any other U.S. federal agency, the majority of which is conducted through its system of National Laboratories. The DOE also directs research in genomics, with the Human Genome Project originating from a DOE initiative. The department is headed by the Secretary of Energy, who reports directly to the president of the United States and is a member of the Cabinet. The current Secretary of Energy is Jennifer Granholm, who has served ...
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Glossary Of Fuel Cell Terms
The Glossary of fuel cell terms lists the definitions of many terms used within the fuel cell industry. The terms in this fuel cell glossary may be used by fuel cell industry associations, in education material and fuel cell codes and standards to name but a few. A Activation loss : See overpotential Adsorption : Adsorption is a process that occurs when a gas or liquid solute accumulates on the surface of a solid or a liquid (adsorbent), forming a film of molecules or atoms (the adsorbate). Alkali : In chemistry, an alkali is a basic, ionic salt of an alkali metal or alkaline earth metal element. Alkali anion exchange membrane An alkali anion exchange membrane (AAEM) is a semipermeable membrane generally made from ionomers and designed to conduct anions while being impermeable to gases such as oxygen or hydrogen. Alkaline fuel cell : Alkaline fuel cell (AFC) also known as the Bacon fuel cell. Alloy : An alloy is a solid solution or homogeneous mixture of two or m ...
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