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Toshiko Mayeda
Toshiko K. Mayeda (née Kuki) (1923–13 February 2004) was a Japanese American chemist who worked at the Enrico Fermi Institute in the University of Chicago. She worked on climate science and meteorites from 1958 to 2004. Early life and education Toshiko Mayeda was born in Tacoma, Washington. She grew up in Yokkaichi, Mie, and Osaka. When the United States entered World War II after the Japanese attack on Pearl Harbor, she and her father Matsusaburo Kuki were sent to the Tule Lake War Relocation Center. Whilst there she met her future husband, Harry Mayeda. After the war, she graduated with a bachelor's degree in Chemistry from the University of Chicago in 1949. Research Mayeda worked initially as a laboratory assistant to Harold Urey at the University of Chicago, where she was hired initially to wash glassware. They used mass spectrometry to measure oxygen isotopes in the shells of marine molluscs which gave information on the prehistoric temperatures of ocean waters and h ...
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Tacoma, Washington
Tacoma ( ) is the county seat of Pierce County, Washington, United States. A port city, it is situated along Washington's Puget Sound, southwest of Seattle, northeast of the state capital, Olympia, Washington, Olympia, and northwest of Mount Rainier National Park. The city's population was 219,346 at the time of the 2020 United States census, 2020 census. Tacoma is the second-largest city in the Puget Sound area and the List of municipalities in Washington, third-largest in the state. Tacoma also serves as the center of business activity for the South Sound region, which has a population of about 1 million. Tacoma adopted its name after the nearby Mount Rainier, called wikt:Tacoma, təˡqʷuʔbəʔ in the Lushootseed, Puget Sound Salish dialect. It is locally known as the "City of Destiny" because the area was chosen to be the western terminus of the Northern Pacific Railroad in the late 19th century. The decision of the railroad was influenced by Tacoma's neighboring deep-wat ...
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Cosmochemistry
Cosmochemistry (from Greek κόσμος ''kósmos'', "universe" and χημεία ''khemeía'') or chemical cosmology is the study of the chemical composition of matter in the universe and the processes that led to those compositions. This is done primarily through the study of the chemical composition of meteorites and other physical samples. Given that the asteroid parent bodies of meteorites were some of the first solid material to condense from the early solar nebula, cosmochemists are generally, but not exclusively, concerned with the objects contained within the Solar System. History In 1938, Swiss mineralogist Victor Goldschmidt and his colleagues compiled a list of what they called "cosmic abundances" based on their analysis of several terrestrial and meteorite samples. Goldschmidt justified the inclusion of meteorite composition data into his table by claiming that terrestrial rocks were subjected to a significant amount of chemical change due to the inherent processes of ...
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Brachinite
Brachinites are a group of meteorites that are classified either as primitive achondrites or as asteroidal achondrites. Like all primitive achondrites, they have similarities with chondrites and achondrites. Brachinites contain 74 to 98% (volume) olivine. Naming and history Brachinites are named after the Brachina meteorite, the type specimen of this group, which in turn is named after Brachina, South Australia. Description Brachinites consist almost entirely of olivine (74 to 98% by volume). Other minerals include plagioclase (6.7 to 12.9%), iron sulfides (1.8 to 4.0%), clinopyroxene (1.5 to 8.2%) and orthopyroxene (0 to 2.4%). Trace minerals include phosphates and meteoritic iron. The only deviation from chondrites is the very high olivine/orthopyroxene ratio. Specimens As of 2022, there were 56 meteorites classified as brachinites. A notable example is the type specimen, the Brachina meteorite. See also * Glossary of meteoritics This is a glossary of terms used in meteoriti ...
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NASA
The National Aeronautics and Space Administration (NASA ) is an independent agency of the US federal government responsible for the civil space program, aeronautics research, and space research. NASA was established in 1958, succeeding the National Advisory Committee for Aeronautics (NACA), to give the U.S. space development effort a distinctly civilian orientation, emphasizing peaceful applications in space science. NASA has since led most American space exploration, including Project Mercury, Project Gemini, the 1968-1972 Apollo Moon landing missions, the Skylab space station, and the Space Shuttle. NASA supports the International Space Station and oversees the development of the Orion spacecraft and the Space Launch System for the crewed lunar Artemis program, Commercial Crew spacecraft, and the planned Lunar Gateway space station. The agency is also responsible for the Launch Services Program, which provides oversight of launch operations and countdown management f ...
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Allende Meteorite
The Allende meteorite is the largest carbonaceous chondrite ever found on Earth. The fireball was witnessed at 01:05 on February 8, 1969, falling over the Mexican state of Chihuahua. After it broke up in the atmosphere, an extensive search for pieces was conducted and over 2 tonnes (2.2 tons) were recovered. The availability of large quantities of samples of the scientifically-important chondrite class has enabled numerous investigations by many scientists; it is often described as "the best-studied meteorite in history." The Allende meteorite has abundant, large calcium–aluminium-rich inclusions (CAI), which are among the oldest objects formed in the Solar System. Carbonaceous chondrites compose about 4 percent of all meteorites observed to fall from space. Prior to 1969, the carbonaceous chondrite class was known from a small number of uncommon meteorites such as Orgueil, which fell in France in 1864. Meteorites similar to Allende were known, but many were small and poorl ...
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Oxygen-18
Oxygen-18 (, Ω) is a natural, stable isotope of oxygen and one of the environmental isotopes. is an important precursor for the production of fluorodeoxyglucose (FDG) used in positron emission tomography (PET). Generally, in the radiopharmaceutical industry, enriched water () is bombarded with hydrogen ions in either a cyclotron or linear accelerator, creating fluorine-18. This is then synthesized into FDG and injected into a patient. It can also be used to make an extremely heavy version of water when combined with tritium (hydrogen-3): or . This compound has a density almost 30% greater than that of natural water. The accurate measurements of rely on proper procedures of analysis, sample preparation and storage. Paleoclimatology In ice cores, mainly Arctic and Antarctic, the ratio of to (known as δ) can be used to determine the temperature of precipitation through time. Assuming that atmospheric circulation and elevation has not changed significantly over the poles, ...
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Oxygen-17
Oxygen-17 (17O) is a low-abundance, natural, stable isotope of oxygen (0.0373% in seawater; approximately twice as abundant as deuterium). As the only stable isotope of oxygen possessing a nuclear spin (+5/2) and a favorable characteristic of field-independent relaxation in liquid water, 17O enables NMR studies of oxidative metabolic pathways through compounds containing 17O (i.e. metabolically produced H217O water by oxidative phosphorylation in mitochondria) at high magnetic fields. Water used as nuclear reactor coolant is subjected to intense neutron flux. Natural water starts out with 373 ppm of 17O; heavy water starts out incidentally enriched to about 550 ppm of oxygen-17. The neutron flux slowly converts 16O in the cooling water to 17O by neutron capture, increasing its concentration. The neutron flux slowly converts 17O (with much greater cross section) in the cooling water to carbon-14, an undesirable product that can escape to the environment: : 17O (n,α) → 14 ...
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Oxygen-16
Oxygen-16 (16O) is a stable isotope of oxygen, having 8 neutrons and 8 protons in its nucleus. It has a mass of . Oxygen-16 is the most abundant isotope of oxygen and accounts for 99.762% of oxygen's natural abundance. The relative and absolute abundance of 16O are high because it is a principal product of stellar evolution and because it is a primordial isotope, meaning it can be made by stars that were initially made exclusively of hydrogen. Most 16O is synthesized at the end of the helium fusion process in stars; the triple-alpha process creates 12C, which captures an additional 4He to make 16O. The neon-burning process creates additional 16O. Oxygen-16 is doubly magic. Solid samples (organic and inorganic) for 16O studies are usually stored in silver cups and measured with pyrolysis and mass spectrometry. Researchers need to avoid improper or prolonged storage of the samples for accurate measurements. Oxygen-16 was originally the standard from which the atomic masses of al ...
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Isotopes Of Oxygen
There are three known stable isotopes of oxygen (8O): , , and . Radioactive isotopes ranging from to have also been characterized, all short-lived. The longest-lived radioisotope is with a half-life of , while the shortest-lived isotope is with a half-life of (though the half-lives of the neutron-unbound and are still unknown). List of isotopes , - , , style="text-align:right" , 8 , style="text-align:right" , 3 , , [] , proton emission, 2p , , (3/2−) , , , - , , style="text-align:right" , 8 , style="text-align:right" , 4 , , , 2p , , 0+ , , , - , rowspan=2, , rowspan=2 style="text-align:right" , 8 , rowspan=2 style="text-align:right" , 5 , rowspan=2, , rowspan=2, , β+ () , , rowspan=2, (3/2−) , rowspan=2, , rowspan=2, , - , β+p () , , - , , style="text-align:right" , 8 , style="text-align:right" , 6 , , , β+ , , 0+ , , , - , , style="text-align:right" , 8 , style="text-align:right" , 7 ...
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Bromine Pentafluoride
Bromine pentafluoride, Br F5, is an interhalogen compound and a fluoride of bromine. It is a strong fluorinating agent. BrF5 finds use in oxygen isotope analysis. Laser ablation of solid silicates in the presence of BrF5 releases O2 for subsequent analysis. It has also been tested as an oxidizer in liquid rocket propellants and is used as a fluorinating agent in the processing of uranium. Preparation BrF5 was first prepared in 1931 by the direct reaction of bromine and fluorine. This reaction is suitable for the preparation of large quantities, and is carried out at temperatures over with an excess of fluorine: :Br2 + 5 F2 → 2 BrF5 For the preparation of smaller amounts, potassium bromide is used: :KBr + 3 F2 → KF + BrF5 This route yields BrF5 almost completely free of trifluorides and other impurities. Reactions BrF5 reacts with water to form bromic acid and hydrofluoric acid: :BrF5 + 3 H2O → HBrO3 + 5 HF It is an extremely effective fluorinating agent, being able ...
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Ice Age
An ice age is a long period of reduction in the temperature of Earth's surface and atmosphere, resulting in the presence or expansion of continental and polar ice sheets and alpine glaciers. Earth's climate alternates between ice ages and greenhouse periods, during which there are no glaciers on the planet. Earth is currently in the Quaternary glaciation. Individual pulses of cold climate within an ice age are termed ''glacial periods'' (or, alternatively, ''glacials, glaciations, glacial stages, stadials, stades'', or colloquially, ''ice ages''), and intermittent warm periods within an ice age are called '' interglacials'' or ''interstadials''. In glaciology, ''ice age'' implies the presence of extensive ice sheets in both northern and southern hemispheres. By this definition, Earth is currently in an interglacial period—the Holocene. The amount of anthropogenic greenhouse gases emitted into Earth's oceans and atmosphere is predicted to prevent the next glacial period for th ...
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