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Toshiko K. Mayeda (née Kuki) (1923–13 February 2004) was a Japanese American chemist who worked at the
Enrico Fermi Institute __NOTOC__ The Institute for Nuclear Studies was founded September 1945 as part of the University of Chicago with Samuel King Allison as director. On November 20, 1955, it was renamed The Enrico Fermi Institute for Nuclear Studies. The name was s ...
in the
University of Chicago The University of Chicago (UChicago, Chicago, U of C, or UChi) is a private research university in Chicago, Illinois. Its main campus is located in Chicago's Hyde Park neighborhood. The University of Chicago is consistently ranked among the b ...
. She worked on climate science and meteorites from 1958 to 2004.


Early life and education

Toshiko Mayeda was born in
Tacoma, Washington Tacoma ( ) is the county seat of Pierce County, Washington, United States. A port city, it is situated along Washington's Puget Sound, southwest of Seattle, northeast of the state capital, Olympia, Washington, Olympia, and northwest of Mount ...
. She grew up in
Yokkaichi, Mie is a city located in Mie Prefecture, Japan. , the city had an estimated population of 310,259 in 142162 households and a population density of 1500 persons per km². The total area of the city is . Geography Yokkaichi is located in north-central ...
, and
Osaka is a designated city in the Kansai region of Honshu in Japan. It is the capital of and most populous city in Osaka Prefecture, and the third most populous city in Japan, following Special wards of Tokyo and Yokohama. With a population of 2. ...
. When the United States entered
World War II World War II or the Second World War, often abbreviated as WWII or WW2, was a world war that lasted from 1939 to 1945. It involved the vast majority of the world's countries—including all of the great powers—forming two opposin ...
after the Japanese
attack on Pearl Harbor The attack on Pearl HarborAlso known as the Battle of Pearl Harbor was a surprise military strike by the Imperial Japanese Navy Air Service upon the United States against the naval base at Pearl Harbor in Honolulu, Territory of Hawaii, j ...
, she and her father Matsusaburo Kuki were sent to the
Tule Lake War Relocation Center The Tule Lake National Monument in Modoc County, California, Modoc and Siskiyou County, California, Siskiyou counties in California, consists primarily of the site of the Tule Lake War Relocation Center, one of ten concentration camps constructe ...
. Whilst there she met her future husband, Harry Mayeda. After the war, she graduated with a bachelor's degree in Chemistry from the
University of Chicago The University of Chicago (UChicago, Chicago, U of C, or UChi) is a private research university in Chicago, Illinois. Its main campus is located in Chicago's Hyde Park neighborhood. The University of Chicago is consistently ranked among the b ...
in 1949.


Research

Mayeda worked initially as a laboratory assistant to
Harold Urey Harold Clayton Urey ( ; April 29, 1893 – January 5, 1981) was an American physical chemist whose pioneering work on isotopes earned him the Nobel Prize in Chemistry in 1934 for the discovery of deuterium. He played a significant role in the d ...
at the University of Chicago, where she was hired initially to wash glassware. They used
mass spectrometry Mass spectrometry (MS) is an analytical technique that is used to measure the mass-to-charge ratio of ions. The results are presented as a ''mass spectrum'', a plot of intensity as a function of the mass-to-charge ratio. Mass spectrometry is use ...
to measure oxygen isotopes in the shells of marine
molluscs Mollusca is the second-largest phylum of invertebrate animals after the Arthropoda, the members of which are known as molluscs or mollusks (). Around 85,000 extant taxon, extant species of molluscs are recognized. The number of fossil sp ...
which gave information on the prehistoric temperatures of ocean waters and hence paleoclimates. Urey developed the field of
cosmochemistry Cosmochemistry (from Greek κόσμος ''kósmos'', "universe" and χημεία ''khemeía'') or chemical cosmology is the study of the chemical composition of matter in the universe and the processes that led to those compositions. This is done ...
and with Mayeda studied primitive
meteorite A meteorite is a solid piece of debris from an object, such as a comet, asteroid, or meteoroid, that originates in outer space and survives its passage through the atmosphere to reach the surface of a planet or Natural satellite, moon. When the ...
s, also by using
oxygen isotope There are three known stable isotopes of oxygen (8O): , , and . Radioactive isotopes ranging from to have also been characterized, all short-lived. The longest-lived radioisotope is with a half-life of , while the shortest-lived isotope is ...
analysis. Later, she worked with Cesare Emiliani on isotopic evaluation of the
ice age An ice age is a long period of reduction in the temperature of Earth's surface and atmosphere, resulting in the presence or expansion of continental and polar ice sheets and alpine glaciers. Earth's climate alternates between ice ages and gree ...
. When Urey retired from the university in 1958, Mayeda was persuaded to remain there by
Robert N. Clayton Robert Norman Clayton (March 20, 1930 – December 30, 2017) was a Canadian-American chemist and academic. He was the Enrico Fermi Distinguished Service Professor Emeritus of Chemistry at the University of Chicago. Clayton studied cosmochemistry ...
, and collaborate with him on applications of mass spectroscopy. She was described as an ''indomitable'' research assistant''.'' Mayeda and Clayton's first research paper considered the use of
Bromine pentafluoride Bromine pentafluoride, Br F5, is an interhalogen compound and a fluoride of bromine. It is a strong fluorinating agent. BrF5 finds use in oxygen isotope analysis. Laser ablation of solid silicates in the presence of BrF5 releases O2 for subseq ...
to extract
Isotopes of oxygen There are three known stable isotopes of oxygen (8O): , , and . Radioactive isotopes ranging from to have also been characterized, all short-lived. The longest-lived radioisotope is with a half-life of , while the shortest-lived isotope is ...
from rocks and minerals. It remains their most cited work. From the 1970s until the late 1990s Mayeda and Clayton became famous for their use of oxygen isotopes to classify meteorites. They developed several tests that were used across the field of meteorite and lunar sample analysis. They studied variations in the abundances of the stable isotopes of oxygen,
oxygen-16 Oxygen-16 (16O) is a stable isotope of oxygen, having 8 neutrons and 8 protons in its nucleus. It has a mass of . Oxygen-16 is the most abundant isotope of oxygen and accounts for 99.762% of oxygen's natural abundance. The relative and absolute ...
,
oxygen-17 Oxygen-17 (17O) is a low-abundance, natural, stable isotope of oxygen (0.0373% in seawater; approximately twice as abundant as deuterium). As the only stable isotope of oxygen possessing a nuclear spin (+5/2) and a favorable characteristic of fi ...
and
oxygen-18 Oxygen-18 (, Ω) is a natural, stable isotope of oxygen and one of the environmental isotopes. is an important precursor for the production of fluorodeoxyglucose (FDG) used in positron emission tomography (PET). Generally, in the radiopharmaceu ...
, and deduced differences in the formation temperatures of the meteorites. They also worked on the mass spectroscopy and chemistry of the
Allende meteorite The Allende meteorite is the largest carbonaceous chondrite ever found on Earth. The fireball was witnessed at 01:05 on February 8, 1969, falling over the Mexican state of Chihuahua. After it broke up in the atmosphere, an extensive search for ...
. They published many scientific papers on the "oxygen thermometer" and analysed approximately 300 lunar samples that had been collected during
NASA The National Aeronautics and Space Administration (NASA ) is an independent agency of the US federal government responsible for the civil space program, aeronautics research, and space research. NASA was established in 1958, succeeding t ...
s Apollo Program. In 1992, a new type of meteorite, the Brachinite, was identified. Clayton and Mayeda studied the
Achondrite An achondrite is a stony meteorite that does not contain chondrules. It consists of material similar to terrestrial basalts or plutonic rocks and has been differentiated and reprocessed to a lesser or greater degree due to melting and recrystalliz ...
meteorites and showed that variations in the oxygen-17 isotope ratios within a planet are due to inhomogeneities in the
Solar Nebula The formation of the Solar System began about 4.6 billion years ago with the gravitational collapse of a small part of a giant molecular cloud. Most of the collapsing mass collected in the center, forming the Sun, while the rest flattened into a ...
. They analysed
Shergotty meteorite The Shergotty meteorite (Named after Sherghati) is the first example of the shergottite Martian meteorite family. It was a meteorite which fell to Earth at Sherghati, in the Gaya district, Bihar, India on 25 August 1865, and was retrieved by wit ...
s, proposing that there could have been a water-rich atmosphere on
Mars Mars is the fourth planet from the Sun and the second-smallest planet in the Solar System, only being larger than Mercury (planet), Mercury. In the English language, Mars is named for the Mars (mythology), Roman god of war. Mars is a terr ...
and studied the Bocaiuva meteorite, finding that the
Eagle Station meteorite The Eagle Station meteorite is a pallasite and type specimen of the Eagle Station group. It was found in 1880 close to Eagle Station, Carroll County, Kentucky (United States). The first description was made by George F. Kunz in 1887. Referen ...
was formed due to impact heating. In 2002 Mayeda was awarded the Society Merit Prize from the
Geochemical Society of Japan Geochemistry is the science that uses the tools and principles of chemistry to explain the mechanisms behind major geological systems such as the Earth's crust and its oceans. The realm of geochemistry extends beyond the Earth, encompassing the e ...
. In the same year, an asteroid was named after her. Mayeda's husband, Harry, died in 2003. Mayeda suffered from cancer and died on February 13, 2004. In 2008, the book ''Oxygen in the Solar System'' was dedicated to Clayton and Mayeda.


References


Further reading

* {{DEFAULTSORT:Mayeda, Toshiko American people of Japanese descent American women chemists University of Chicago alumni University of Chicago faculty Geochemists 1923 births 2004 deaths People from Tacoma, Washington People from Yokkaichi People from Osaka Japanese-American internees 20th-century American women American women academics 21st-century American women