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Thiokol (polymer)
''Thiokol'' is a trade mark for various organic polysulfide polymers. Thiokol polymers are used as an elastomer in seals and sealants. The distinction between the polymers first commercialized by the Thiokol Corporation and subsequent polysulfide materials is often unclear. Preparation and structure A variety of thiokols are recognized. Typically they are prepared by the combination of 2-chloroethanol, formaldehyde, and sodium polysulfide (Na2S''x''). The chloroethanol is produced in situ from ethylene oxide and hydrogen chloride. The rank ''x'' of the polysulfide is an important variable. Crosslinking agents are used, such as 1,2,3-trichloropropane. An idealized polymer is represented by this formula HS(CH2CH2OCH2OCH2CH2SS)''n''CH2CH2OCH2OCH2CH2SH. Thiol-terminated resins can be cured oxidatively. History and etymology In 1838, Swiss chemists reported the preparation of hydrophobic rubbery materials by the alkylation of sodium polysulfide with 1,2-dichloroethane. In 1926 chemis ...
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Trademark
A trademark (also written trade mark or trade-mark) is a type of intellectual property consisting of a recognizable sign, design, or expression that identifies products or services from a particular source and distinguishes them from others. The trademark owner can be an individual, business organization, or any legal entity. A trademark may be located on a package, a label, a voucher, or on the product itself. Trademarks used to identify services are sometimes called service marks. The first legislative act concerning trademarks was passed in 1266 under the reign of Henry III of England, requiring all bakers to use a distinctive mark for the bread they sold. The first modern trademark laws emerged in the late 19th century. In France, the first comprehensive trademark system in the world was passed into law in 1857. The Trade Marks Act 1938 of the United Kingdom changed the system, permitting registration based on "intent-to-use", creating an examination based process, an ...
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Polysulfide
Polysulfides are a class of chemical compounds containing chains of sulfur atoms. There are two main classes of polysulfides: inorganic and organic. Among the inorganic polysulfides, there are ones which contain anions, which have the general formula . These anions are the conjugate bases of the hydrogen polysulfides . Organic polysulfides generally have the formulae , where R = alkyl or aryl. Polysulfide salts and complexes The alkali metal polysulfides arise by treatment of a solution of sulfide, e.g. sodium sulfide, with elemental sulfur: : In some cases, these anions have been obtained as organic salts, which are soluble in organic solvents. The energy released in the reaction of sodium and elemental sulfur is the basis of battery technology. The sodium–sulfur battery and the lithium–sulfur battery require high temperatures to maintain liquid polysulfide and -conductive membranes that are unreactive toward sodium, sulfur, and sodium sulfide. Polysulfides are ligands i ...
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Elastomer
An elastomer is a polymer with viscoelasticity (i.e. both viscosity and elasticity) and with weak intermolecular forces, generally low Young's modulus and high failure strain compared with other materials. The term, a portmanteau of ''elastic polymer'', is often used interchangeably with rubber, although the latter is preferred when referring to vulcanisates. Each of the monomers which link to form the polymer is usually a compound of several elements among carbon, hydrogen, oxygen and silicon. Elastomers are amorphous polymers maintained above their glass transition temperature, so that considerable molecular reconformation is feasible without breaking of covalent bonds. At ambient temperatures, such rubbers are thus relatively compliant ( E ≈ 3 M Pa) and deformable. Their primary uses are for seals, adhesives and molded flexible parts. Application areas for different types of rubber are manifold and cover segments as diverse as tires, soles for shoes, and damping and ...
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Sealant
Sealant is a substance used to block the passage of fluids through openings in materials, a type of mechanical seal. In building construction ''sealant'' is sometimes synonymous with ''caulking'' and also serve the purposes of blocking dust, sound and heat transmission. Sealants may be weak or strong, flexible or rigid, permanent or temporary. Sealants are not adhesives but some have adhesive qualities and are called ''adhesive-sealants'' or ''structural sealants''. History Sealants were first used in prehistory in the broadest sense as mud, grass and reeds to seal dwellings from the weather such as the daub in wattle and daub and thatching. Natural sealants and adhesive-sealants included plant resins such as pine pitch and birch pitch, bitumen, wax, tar, natural gum, clay (mud) mortar, lime mortar, lead, blood and egg. In the 17th century glazing putty was first used to seal window glass made with linseed oil and chalk, later other drying oils were also used to make oil-bas ...
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2-chloroethanol
2-Chloroethanol (also called ethylene chlorohydrin or glycol chlorohydrin) is an organic chemical compound with the chemical formula HOCH2CH2Cl and the ''simplest'' beta-halohydrin (chlorohydrin). This colorless liquid has a pleasant ether-like odor. It is miscible with water. The molecule is bifunctional, consisting of both an alkyl chloride and an alcohol functional group. Synthesis and applications 2-Chloroethanol is produced by treating ethylene with hypochlorous acid: : 2-Chloroethanol was once produced on a large scale as a precursor to ethylene oxide: : :HOCH2CH2Cl + NaOH → C2H4O + NaCl + H2O This application has been supplanted by the more economic direct oxidation of ethylene. Otherwise chloroethanol is still used in the production of pharmaceuticals, biocides, and plasticizers. Many of these applications entail its use in installing 2-hydroxyethyl groups. Several dyes are prepared by the alkylation of aniline derivatives with chloroethanol. It is also used for ...
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Formaldehyde
Formaldehyde ( , ) (systematic name methanal) is a naturally occurring organic compound with the formula and structure . The pure compound is a pungent, colourless gas that polymerises spontaneously into paraformaldehyde (refer to section Forms below), hence it is stored as an aqueous solution (formalin), which is also used to store animal specimens. It is the simplest of the aldehydes (). The common name of this substance comes from its similarity and relation to formic acid. Formaldehyde is an important precursor to many other materials and chemical compounds. In 1996, the installed capacity for the production of formaldehyde was estimated at 8.7 million tons per year. It is mainly used in the production of industrial resins, e.g., for particle board and coatings. Forms Formaldehyde is more complicated than many simple carbon compounds in that it adopts several diverse forms. These compounds can often be used interchangeably and can be interconverted. *Molecular formald ...
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Hydrogen Chloride
The compound hydrogen chloride has the chemical formula and as such is a hydrogen halide. At room temperature, it is a colourless gas, which forms white fumes of hydrochloric acid upon contact with atmospheric water vapor. Hydrogen chloride gas and hydrochloric acid are important in technology and industry. Hydrochloric acid, the aqueous solution of hydrogen chloride, is also commonly given the formula HCl. Reactions Hydrogen chloride is a diatomic molecule, consisting of a hydrogen atom H and a chlorine atom Cl connected by a polar covalent bond. The chlorine atom is much more electronegative than the hydrogen atom, which makes this bond polar. Consequently, the molecule has a large dipole moment with a negative partial charge (δ−) at the chlorine atom and a positive partial charge (δ+) at the hydrogen atom. In part because of its high polarity, HCl is very soluble in water (and in other polar solvents). Upon contact, and HCl combine to form hydronium cations and ...
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1,2,3-trichloropropane
1,2,3-Trichloropropane (TCP) is an organic compound with the formula CHCl(CH2Cl)2. It is a colorless liquid that is used as a solvent and in other specialty applications. Production 1,2,3-Trichloropropane is produced the addition of chlorine to allyl chloride. TCP also may be produced as a by-product also is produced in significant quantities as an unwanted by-product of the production of other chlorinated compounds such as epichlorohydrin and dichloropropene. Uses Historically, TCP has been used as a paint or varnish remover, a cleaning and degreasing agent, and a solvent. It is also used as an intermediate in the production of hexafluoropropylene. It is a crosslinking agent for polysulfide polymers and sealants. Effects of exposure Humans can be exposed to TCP by inhaling its fumes or through skin contact and ingestion. TCP is recognized in California as a human carcinogen, and extensive animal studies have shown that it causes cancer. Short term exposure to TCP can c ...
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Joseph C
Joseph is a common male given name, derived from the Hebrew Yosef (יוֹסֵף). "Joseph" is used, along with "Josef", mostly in English, French and partially German languages. This spelling is also found as a variant in the languages of the modern-day Nordic countries. In Portuguese and Spanish, the name is "José". In Arabic, including in the Quran, the name is spelled '' Yūsuf''. In Persian, the name is "Yousef". The name has enjoyed significant popularity in its many forms in numerous countries, and ''Joseph'' was one of the two names, along with ''Robert'', to have remained in the top 10 boys' names list in the US from 1925 to 1972. It is especially common in contemporary Israel, as either "Yossi" or "Yossef", and in Italy, where the name "Giuseppe" was the most common male name in the 20th century. In the first century CE, Joseph was the second most popular male name for Palestine Jews. In the Book of Genesis Joseph is Jacob's eleventh son and Rachel's first son, and k ...
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Nathan Mnookin
Thiokol (variously Thiokol Chemical Corporation(/Company), Morton Thiokol Inc., Cordant Technologies Inc., Thiokol Propulsion, AIC Group, ATK Thiokol, ATK Launch Systems Group; finally Orbital ATK before becoming part of Northrop Grumman) was an American corporation concerned initially with rubber and related chemicals, and later with rocket and missile propulsion systems. Its name is a portmanteau of the Greek words for sulfur (θεῖον ''"theion"'') and glue (κόλλα ''"kolla"''), an allusion to the company's initial product, Thiokol polymer. The Thiokol Chemical Company was founded in 1929. Its initial business was a range of synthetic rubber and polymer sealants. Thiokol was a major supplier of liquid polymer sealants during World War II. When scientists at the Jet Propulsion Laboratory discovered that Thiokol's polymers made ideal binders for solid rocket fuels, Thiokol moved into the new field, opening laboratories at Elkton, Maryland, and later production facilities ...
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Elkton, Maryland
Elkton is a town in and the county seat of Cecil County, Maryland, Cecil County, Maryland, United States. The population was 15,443 at the 2010 United States Census, 2010 census. It was formerly called Head of Elk because it sits at the head of navigation on the Elk River (Maryland), Elk River, which flows into the nearby Chesapeake Bay. Elkton was once known as the Gretna Green of the East of the US because of its popularity as a place for Elopement, eloping couples to marry. History The town was founded by New Sweden, Swedish mariners and fisherman from Fort Casimir who settled the area in 1694. They called their settlement Head of Elk, as it was the head of navigation of the Elk River (Maryland), Elk River. The town saw several actions during the American Revolutionary War. On August 25, 1777, Sir William Howe, 5th Viscount Howe, William Howe's Anglo-German army (13,000 British soldiers and 5,000 Germans) landed on the Elk River and marched 11 miles north to Head of Elk. Howe ...
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Maryland
Maryland ( ) is a state in the Mid-Atlantic region of the United States. It shares borders with Virginia, West Virginia, and the District of Columbia to its south and west; Pennsylvania to its north; and Delaware and the Atlantic Ocean to its east. Baltimore is the largest city in the state, and the capital is Annapolis. Among its occasional nicknames are '' Old Line State'', the ''Free State'', and the '' Chesapeake Bay State''. It is named after Henrietta Maria, the French-born queen of England, Scotland, and Ireland, who was known then in England as Mary. Before its coastline was explored by Europeans in the 16th century, Maryland was inhabited by several groups of Native Americans – mostly by Algonquian peoples and, to a lesser degree, Iroquoian and Siouan. As one of the original Thirteen Colonies of England, Maryland was founded by George Calvert, 1st Baron Baltimore, a Catholic convert"George Calvert and Cecilius Calvert, Barons Baltimore" William Hand Browne, ...
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