Takuzo Aida
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Takuzo Aida
is a polymer chemist known for his work in the fields of supramolecular chemistry, materials chemistry and polymer chemistry. Aida, who is the Deputy Director for the RIKEN Center for Emergent Matter Science (CEMS) and a Distinguished University Professor at the University of Tokyo, has made pioneering contributions to the initiation, fundamental progress, and conceptual expansion of supramolecular polymerization. Aida has also been a leader and advocate for addressing critical environmental issues caused by plastic waste and microplastics in the oceans, soil, and food supply, through the development of dynamic, responsive, healable, reorganizable, and adaptive supramolecular polymers and related soft materials. Education Aida received his Bachelor of Engineering in Colloidal Science at the Yokohama National University in 1979, before moving to the University of Tokyo for his Master of Engineering (1981) and Doctor of Engineering (1984) degrees in Polymer Chemistry. He was a ...
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Ōita Prefecture
is a prefecture of Japan located on the island of Kyūshū. Ōita Prefecture has a population of 1,136,245 (1 June 2019) and has a geographic area of 6,340 km2 (2,448 sq mi). Ōita Prefecture borders Fukuoka Prefecture to the northwest, Kumamoto Prefecture to the southwest, and Miyazaki Prefecture to the south. Ōita is capital and largest city of Ōita Prefecture, with other major cities including Beppu, Nakatsu, and Saiki. Ōita Prefecture is located in the northeast of Kyūshū on the Bungo Channel, connecting the Pacific Ocean and Seto Inland Sea, across from Ehime Prefecture on the island of Shikoku. Ōita Prefecture is famous for its hot springs and is a popular tourist destination in Japan for its '' onsens'' and '' ryokans'', particularly in and around the city of Beppu. History Around the 6th century Kyushu consisted of four regions: Tsukushi Province, Hi Province, Kumaso Province and Toyo Province. Toyo Province was later divided into two regions, upper and ...
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Microplastics
Microplastics are fragments of any type of plastic less than in length, according to the U.S. National Oceanic and Atmospheric Administration (NOAA) and the European Chemicals Agency. They cause pollution by entering natural ecosystems from a variety of sources, including cosmetics, clothing, food packaging, and industrial processes. The term ''macroplastics'' is used to differentiate microplastics from larger plastic waste, such as plastic bottles. Two classifications of microplastics are currently recognized. Primary microplastics include any plastic fragments or particles that are already 5.0 mm in size or less before entering the environment. These include microfibers from clothing, microbeads, and plastic pellets (also known as nurdles). Secondary microplastics arise from the degradation (breakdown) of larger plastic products through natural weathering processes after entering the environment. Such sources of secondary microplastics include water and soda bottles, fis ...
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Review Article
A review article is an article that summarizes the current state of understanding on a topic within a certain discipline. A review article is generally considered a secondary source since it may analyze and discuss the method and conclusions in previously published studies. It resembles a survey article or, in news publishing, overview article, which also surveys and summarizes previously published primary and secondary sources, instead of reporting new facts and results. Survey articles are however considered tertiary sources, since they do not provide additional analysis and synthesis of new conclusions. A review of such sources is often referred to as a tertiary review. Academic publications that specialize in review articles are known as review journals. Review journals have their own requirements for the review articles they accept, so review articles may vary slightly depending on the journal they are being submitted to. Review articles teach about: * the main people wo ...
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Stereoselectivity
In chemistry, stereoselectivity is the property of a chemical reaction in which a single reactant forms an unequal mixture of stereoisomers during a non- stereospecific creation of a new stereocenter or during a non-stereospecific transformation of a pre-existing one. The selectivity arises from differences in steric and electronic effects in the mechanistic pathways leading to the different products. Stereoselectivity can vary in degree but it can never be total since the activation energy difference between the two pathways is finite. Both products are at least possible and merely differ in amount. However, in favorable cases, the minor stereoisomer may not be detectable by the analytic methods used. An enantioselective reaction is one in which one enantiomer is formed in preference to the other, in a reaction that creates an optically active product from an achiral starting material, using either a chiral catalyst, an enzyme or a chiral reagent. The degree of selectivity is meas ...
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Ring-opening Polymerization
In polymer chemistry, ring-opening polymerization (ROP) is a form of chain-growth polymerization, in which the terminus of a polymer chain attacks cyclic monomers to form a longer polymer (see figure). The reactive center can be radical, anionic or cationic. Some cyclic monomers such as norbornene or cyclooctadiene can be polymerized to high molecular weight polymers by using metal catalysts. ROP is a versatile method for the synthesis of biopolymers. Ring-opening of cyclic monomers is often driven by the relief of bond-angle strain. Thus, as is the case for other types of polymerization, the enthalpy change in ring-opening is negative. Monomers Cyclic monomers that are amenable to ROP include epoxides, cyclic trisiloxanes, some lactones, lactides, cyclic carbonates, and amino acid N-carboxyanhydrides. Many strained cycloalkenes, e.g norbornene, are suitable monomers via ring-opening metathesis polymerization. History Ring-opening polymerization has been used since the ...
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Living Polymerization
In polymer chemistry, living polymerization is a form of chain growth polymerization where the ability of a growing polymer chain to terminate has been removed. This can be accomplished in a variety of ways. Chain termination and chain transfer reactions are absent and the rate of chain initiation is also much larger than the rate of chain propagation. The result is that the polymer chains grow at a more constant rate than seen in traditional chain polymerization and their lengths remain very similar (i.e. they have a very low polydispersity index). Living polymerization is a popular method for synthesizing block copolymers since the polymer can be synthesized in stages, each stage containing a different monomer. Additional advantages are predetermined molar mass and control over end-groups. Living polymerization is desirable because it offers precision and control in macromolecular synthesis. This is important since many of the novel/useful properties of polymers result from t ...
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Nanotube
A nanotube is a nanometer-scale hollow tube-like structure. Kinds of nanotubes * BCN nanotube, composed of comparable amounts of boron, carbon, and nitrogen atoms * Boron nitride nanotube, a polymorph of boron nitride * Carbon nanotube, includes general nanotube terminology and diagrams * DNA nanotechnology#DNA nanotubes, DNA nanotube, a two-dimensional lattice which curves back upon itself, somewhat similar in size and shape to a carbon nanotube * Gallium nitride nanotube, a nanotube of gallium nitride * Silicon nanotube, made of silicon atoms * Non-carbon nanotube, especially Tungsten(IV) sulfide#Nanotubes, tungsten(IV) sulfide nanotubes * Tunneling nanotube, a tubular membrane connection between cells * Titanium dioxide#Nanotubes, Titanium nanotubes, created by the conversion of the mineral anatase by hydrothermal synthesis References

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Porphyrin
Porphyrins ( ) are a group of heterocyclic macrocycle organic compounds, composed of four modified pyrrole subunits interconnected at their α carbon atoms via methine bridges (=CH−). The parent of porphyrin is porphine, a rare chemical compound of exclusively theoretical interest. Substituted porphines are called porphyrins. With a total of 26 π-electrons, of which 18 π-electrons form a planar, continuous cycle, the porphyrin ring structure is often described as aromatic. One result of the large conjugated system is that porphyrins typically absorb strongly in the visible region of the electromagnetic spectrum, i.e. they are deeply colored. The name "porphyrin" derives from the Greek word πορφύρα (''porphyra''), meaning ''purple''. Complexes of porphyrins Concomitant with the displacement of two N-''H'' protons, porphyrins bind metal ions in the N4 "pocket". The metal ion usually has a charge of 2+ or 3+. A schematic equation for these syntheses is shown: :H2porp ...
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Amphiphile
An amphiphile (from the Greek αμφις amphis, both, and φιλíα philia, love, friendship), or amphipath, is a chemical compound possessing both hydrophilic (''water-loving'', polar) and lipophilic (''fat-loving'') properties. Such a compound is called amphiphilic or amphipathic. Common amphiphilic substances are soaps, detergents, and lipoproteins. The phospholipid amphiphiles are the major structural component of cell membranes. Amphiphiles are the basis for a number of areas of research in chemistry and biochemistry, notably that of lipid polymorphism. Organic compounds containing hydrophilic groups at both ends of the molecule are called bolaamphiphilic. The micelles they form in the aggregate are prolate. Structure The lipophilic group is typically a large hydrocarbon moiety, such as a long chain of the form CH3(CH2)n, with n > 4. The hydrophilic group falls into one of the following categories: # charged groups #* anionic. Examples, with the lipophilic part of the m ...
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Non-covalent Interaction
In chemistry, a non-covalent interaction differs from a covalent bond in that it does not involve the sharing of electrons, but rather involves more dispersed variations of electromagnetic interactions between molecules or within a molecule. The chemical energy released in the formation of non-covalent interactions is typically on the order of 1–5 kcal/ mol (1000–5000 calories per 6.02 molecules). Non-covalent interactions can be classified into different categories, such as electrostatic, π-effects, van der Waals forces, and hydrophobic effects. Non-covalent interactions are critical in maintaining the three-dimensional structure of large molecules, such as proteins and nucleic acids. In addition, they are also involved in many biological processes in which large molecules bind specifically but transiently to one another (see the properties section of the DNA page). These interactions also heavily influence drug design, crystallinity and design of materials, particularly fo ...
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Japan Science And Technology Agency
The Japan Science and Technology Agency (JST; Japanese: 科学技術振興機構) is a Japanese government agency which aims to build infrastructure that supports knowledge creation and dissemination in Japan. It is one of the , overseen by the Ministry of Education, Culture, Sports, Science and Technology (MEXT) and the Council for Science, Technology and Innovation (CSTI). It operates from headquarters in Kawaguchi, Saitama in the Greater Tokyo Area, and in Chiyoda in central Tokyo. The agency formed in 2003, as successor to the Japan Science and Technology Corporation. The corporation had formed in 1996 through the merging of the Japan Information Center of Science and Technology (JICST, est. 1957) and the Research Development Corporation of Japan (JRDC, est. 1961). Among other activities, the agency runs J-STAGE, an "electronic journal platform for science and technology information in Japan," and publishes the ''Journal of Information Processing and Management'' (). As a f ...
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IBM Research
IBM Research is the research and development division for IBM, an American multinational information technology company headquartered in Armonk, New York, with operations in over 170 countries. IBM Research is the largest industrial research organization in the world and has twelve labs on six continents. IBM employees have garnered six Nobel Prizes, six Turing Awards, 20 inductees into the U.S. National Inventors Hall of Fame, 19 National Medals of Technology, five National Medals of Science and three Kavli Prizes. , the company has generated more patents than any other business in each of 25 consecutive years, which is a record. History The roots of today's IBM Research began with the 1945 opening of the Watson Scientific Computing Laboratory at Columbia University. This was the first IBM laboratory devoted to pure science and later expanded into additional IBM Research locations in Westchester County, New York, starting in the 1950s,Beatty, Jack, (editor''Colussus: how ...
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