Strontium Chromate
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Strontium Chromate
Strontium chromate is a chemical compound, with the formula SrCrO4.
US National Institutes of Health TOXNET


Preparation

Strontium chromate is prepared from the reaction of with , or from a reaction between with .


Reac ...
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Ammonia
Ammonia is an inorganic compound of nitrogen and hydrogen with the formula . A stable binary hydride, and the simplest pnictogen hydride, ammonia is a colourless gas with a distinct pungent smell. Biologically, it is a common nitrogenous waste, particularly among aquatic organisms, and it contributes significantly to the nutritional needs of terrestrial organisms by serving as a precursor to 45% of the world's food and fertilizers. Around 70% of ammonia is used to make fertilisers in various forms and composition, such as urea and Diammonium phosphate. Ammonia in pure form is also applied directly into the soil. Ammonia, either directly or indirectly, is also a building block for the synthesis of many pharmaceutical products and is used in many commercial cleaning products. It is mainly collected by downward displacement of both air and water. Although common in nature—both terrestrially and in the outer planets of the Solar System—and in wide use, ammonia is both caust ...
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Magnesium Chromate
Magnesium chromate is a chemical compound, with the formula MgCrO4. It is a yellow, odorless, water-soluble solid with several important industrial uses. This chromate can be manufactured as a powder. History Before 1940, the literature about magnesium chromate and its hydrates was sparse, but studies starting in that year looked at its properties and solubility. Uses It is available commercially in a variety of powders, from nanoscale to micron-sized, either as an anhydrous or hydrated form. As a hydrate, it is useful as a corrosion inhibitor and pigment, or as an ingredient in cosmetics. In 2011, an undecahydrate (containing 11 molecules of water) of this compound was discovered by scientists at the University College London. Hazards Magnesium chromate hydrate should be stored at room temperature, and there is no current therapeutic use. It is a confirmed carcinogen A carcinogen is any substance, radionuclide, or radiation that promotes carcinogenesis (the formation of ...
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Barium Chromate
Barium chromate, named barium tetraoxochromate(VI) by the IUPAC, is a yellow sand like powder with the formula BaCrO4. It is a known oxidizing agent and produces a green flame when heated, a result of the barium ions. History The first naturally occurring barium chromate was found in the country of Jordan. The brown crystals found perched on host rocks were named hashemite in honor of the Hashemite Kingdom of Jordan. The hashemite crystals range in color from light yellowish-brown to a darker greenish-brown and are usually less than 1mm in length. The hashemite crystals are not composed of pure barium chromate but instead contain some small sulfur content as well. The different crystals contain a range of sulfur impurities ranging from the more pure dark crystals, Ba1.00(Cr0.93, S0.07)1.00O4, to the less pure light crystals, Ba1.00(Cr0.64, S0.36)1.00O4. Hashemite was found to be an isostructural chromate analog of baryte, BaSO4. Preparation and Reactions It can be synthesized by ...
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Strontium Chloride
Strontium chloride (SrCl2) is a salt of strontium and chlorine. It is a 'typical' salt, forming neutral aqueous solutions. As with all compounds of strontium, this salt emits a bright red colour in flame, and is commonly used in fireworks to that effect. Its chemical properties are intermediate between those for barium chloride, which is more toxic, and calcium chloride. Preparation Strontium chloride can be prepared by treating aqueous strontium hydroxide or strontium carbonate with hydrochloric acid: : Sr(OH)2 + 2 HCl → SrCl2 + 2 H2O Crystallization from cold aqueous solution gives the hexahydrate, SrCl2·6H2O. Dehydration of this salt occurs in stages, commencing above . Full dehydration occurs at .J. Paul MacMillan, Jai Won Park, Rolf Gerstenberg, Heinz Wagner, Karl Köhler, Peter Wallbrecht "Strontium and Strontium Compounds" in ''Ullmann's Encyclopedia of Industrial Chemistry'', 2005, Wiley-VCH: Weinheim. DOI 10.1002/14356007.a25 321 Structure The crystalline solid adopt ...
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Sodium Chromate
Sodium chromate is the inorganic compound with the formula Na2CrO4. It exists as a yellow hygroscopic solid, which can form tetra-, hexa-, and decahydrates. It is an intermediate in the extraction of chromium from its ores. Production and reactivity It is obtained on a vast scale by roasting chromium ores in air in the presence of sodium carbonate: :2Cr2O3 + 4 Na2CO3 + 3 O2 → 4 Na2CrO4 + 4 CO2 This process converts the chromium into a water-extractable form, leaving behind iron oxides. Typically calcium carbonate is included in the mixture to improve oxygen access and to keep silicon and aluminium impurities in an insoluble form. The process temperature is typically around 1100 °C. For lab and small scale preparations a mixture of chromite ore, sodium hydroxide and sodium nitrate reacting at lower temperatures may be used (even 350 C in the corresponding potassium chromate system). Subsequent to its formation, the chromate salt is converted to sodium dichromate, th ...
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Strontium Carbonate
Strontium carbonate (SrCO3) is the carbonate salt of strontium that has the appearance of a white or grey powder. It occurs in nature as the mineral strontianite. Chemical properties Strontium carbonate is a white, odorless, tasteless powder. Being a carbonate, it is a weak base and therefore is reactive with acids. It is otherwise stable and safe to work with. It is practically insoluble in water (0.0001 g per 100 ml). The solubility is increased significantly if the water is saturated with carbon dioxide, to 0.1 g per 100 ml. Preparation Other than the natural occurrence as a mineral, strontium carbonate is prepared synthetically in one of two processes, both of which start with naturally occurring celestine, a mineral form of strontium sulfate (SrSO4). In the "black ash" process, celesite is roasted with coke at 1100–1300 °C to form strontium sulfide. The sulfate is reduced, leaving the sulfide: :SrSO4 + 2 C → SrS + 2 CO2 A mixture ...
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Sodium Dichromate
Sodium dichromate is the inorganic compound with the formula Na2 Cr2 O7. However, the salt is usually handled as its dihydrate Na2Cr2O7·2 H2O. Virtually all chromium ore is processed via conversion to sodium dichromate and virtually all compounds and materials based on chromium are prepared from this salt.Gerd Anger, Jost Halstenberg, Klaus Hochgeschwender, Christoph Scherhag, Ulrich Korallus, Herbert Knopf, Peter Schmidt, Manfred Ohlinger, "Chromium Compounds" in Ullmann's Encyclopedia of Industrial Chemistry, Wiley-VCH, Weinheim, 2005. In terms of reactivity and appearance, sodium dichromate and potassium dichromate are very similar. The sodium salt is, however, around twenty times more soluble in water than the potassium salt (49 g/L at 0 °C) and its equivalent weight is also lower, which is often desirable.Freeman, F. "Sodium Dichromate" in Encyclopedia of Reagents for Organic Synthesis (Ed: L. Paquette) 2004, J. Wiley & Sons, New York. . Preparation Sodium dichromate is g ...
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Pigment
A pigment is a colored material that is completely or nearly insoluble in water. In contrast, dyes are typically soluble, at least at some stage in their use. Generally dyes are often organic compounds whereas pigments are often inorganic compounds. Pigments of prehistoric and historic value include ochre, charcoal, and lapis lazuli. Economic impact In 2006, around 7.4 million tons of inorganic, organic, and special pigments were marketed worldwide. Estimated at around US$14.86 billion in 2018 and will rise at over 4.9% CAGR from 2019 to 2026. The global demand for pigments was roughly US$20.5 billion in 2009. According to an April 2018 report by ''Bloomberg Businessweek'', the estimated value of the pigment industry globally is $30 billion. The value of titanium dioxide – used to enhance the white brightness of many products – was placed at $13.2 billion per year, while the color Ferrari red is valued at $300 million each year. Physical principles ...
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Zinc
Zinc is a chemical element with the symbol Zn and atomic number 30. Zinc is a slightly brittle metal at room temperature and has a shiny-greyish appearance when oxidation is removed. It is the first element in group 12 (IIB) of the periodic table. In some respects, zinc is chemically similar to magnesium: both elements exhibit only one normal oxidation state (+2), and the Zn2+ and Mg2+ ions are of similar size.The elements are from different metal groups. See periodic table. Zinc is the 24th most abundant element in Earth's crust and has five stable isotopes. The most common zinc ore is sphalerite (zinc blende), a zinc sulfide mineral. The largest workable lodes are in Australia, Asia, and the United States. Zinc is refined by froth flotation of the ore, roasting, and final extraction using electricity ( electrowinning). Zinc is an essential trace element for humans, animals, plants and for microorganisms and is necessary for prenatal and postnatal development. It ...
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Magnesium
Magnesium is a chemical element with the symbol Mg and atomic number 12. It is a shiny gray metal having a low density, low melting point and high chemical reactivity. Like the other alkaline earth metals (group 2 of the periodic table) it occurs naturally only in combination with other elements and it almost always has an oxidation state of +2. It reacts readily with air to form a thin passivation coating of magnesium oxide that inhibits further corrosion of the metal. The free metal burns with a brilliant-white light. The metal is obtained mainly by electrolysis of magnesium salts obtained from brine. It is less dense than aluminium and is used primarily as a component in strong and lightweight alloys that contain aluminium. In the cosmos, magnesium is produced in large, aging stars by the sequential addition of three helium nuclei to a carbon nucleus. When such stars explode as supernovas, much of the magnesium is expelled into the interstellar medium where it ma ...
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Aluminum
Aluminium (aluminum in American and Canadian English) is a chemical element with the symbol Al and atomic number 13. Aluminium has a density lower than those of other common metals, at approximately one third that of steel. It has a great affinity towards oxygen, and forms a protective layer of oxide on the surface when exposed to air. Aluminium visually resembles silver, both in its color and in its great ability to reflect light. It is soft, non-magnetic and ductile. It has one stable isotope, 27Al; this isotope is very common, making aluminium the twelfth most common element in the Universe. The radioactivity of 26Al is used in radiodating. Chemically, aluminium is a post-transition metal in the boron group; as is common for the group, aluminium forms compounds primarily in the +3 oxidation state. The aluminium cation Al3+ is small and highly charged; as such, it is polarizing, and bonds aluminium forms tend towards covalency. The strong affinity towards ox ...
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Chromates
Chromate salts contain the chromate anion, . Dichromate salts contain the dichromate anion, . They are oxyanions of chromium in the +6 oxidation state and are moderately strong oxidizing agents. In an aqueous solution, chromate and dichromate ions can be interconvertible. Chemical properties Potassium-chromate-sample.jpg, potassium chromate Potassium-dichromate-sample.jpg, potassium dichromate Chromates react with hydrogen peroxide, giving products in which peroxide, , replaces one or more oxygen atoms. In acid solution the unstable blue peroxo complex Chromium(VI) oxide peroxide, CrO(O2)2, is formed; it is an uncharged covalent molecule, which may be extracted into ether. Addition of pyridine results in the formation of the more stable complex CrO(O2)2py. Acid–base properties In aqueous solution, chromate and dichromate anions exist in a chemical equilibrium. :2  + 2 H+ + H2O The predominance diagram shows that the position of the equilibrium depends on b ...
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